178:: Some studies have shown that certain pyridines can inhibit corrosion caused by the presence of acid gases, such as carbon dioxide and hydrogen sulfide, which are common in the oil industry. Pyridine and its derivatives have been shown to be effective inhibitors for a wide range of metals, such as carbon steel, stainless steel, and copper alloys. They act by adsorbing to the metal surface and forming a protective film, which can be physical or chemical in nature. Pyridine and its derivatives are also effective in inhibiting localized corrosion, such as pitting and crevice corrosion (Figure 4).
166:
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36:
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251:, and phosphonate salts. Inorganic inhibitors such as lanthanides, molybdates, silicates, boric and phosphoric acids, and combinations of nitrates and nitrites are also widely employed. Environmentally friendly inhibitors such as some biomass wastes, amino acids, and ionic liquids have been investigated.
254:
It is critical to choose the right corrosion inhibitor based on environmental conditions (temperature, pressure, and type of metal to be protected) and to ensure that the right amount is applied for maximum protection. The corrosion progress should also be monitored periodically to adjust the dosage
102:
in several steps, including drilling, production, transportation, and storage of oil and gas. They can mitigate different types of corrosion in the petroleum industry, such as generalized corrosion, pitting corrosion, erosion corrosion, stress corrosion, galvanic corrosion, cavitation corrosion, and
236:: These polymers are used as corrosion inhibitors in the industry due to their good adsorption capacity on metal surfaces and their high solubility in oil and drilling fluids. They offer protection against the corrosive effects of hydrogen sulfide (H2S) present in the drilling fluid. (Figure 6).
94:
Anodic inhibitors and cathodic inhibitors are the two main categories of corrosion inhibitors. While cathodic inhibitors act as catalysts to slow down corrosion, anodic inhibitors protect metal surfaces by acting as physical barriers. They can also be divided into organic and inorganic corrosion
161:
d and citric acid are used as corrosion inhibitors. These acids react with metal ions to form insoluble compounds that protect the metal surface. These inhibitors are often used in combination with other corrosion inhibitors and techniques, such as cathodic protection and coatings, to provide
218:: Polymers are large molecules used in the petroleum industry as corrosion inhibitors. These polymers can adsorb onto the metal surface and form a protective coating. They can also be used as dispersants to prevent the formation of corrosive deposits. Some examples are:
137:: These corrosion inhibitors are organic compounds that contain an amino group and an alkyl group. They act as cathodic inhibitors and form a protective layer on the metal surface.They work efficiently against corrosion brought about by carbon dioxide (CO2) and
162:
comprehensive corrosion protection. CO2 and H2S are regularly seen in oilfields and are notorious for causing corrosion of metal sections. Fortunately, they can be kept under control with measures that have been found to be effective (Figure 3).
230:: These polymers are used as corrosion inhibitors in the industry due to their good compatibility with oil and drilling fluids. They are effective against corrosion caused by the presence of hydrochloric acid (HCl) in drilling fluids.
120:: These are imidazole-based compounds, usually with a long unsaturated chain length, derived mainly from oleic acid. They are very effective in preventing acid corrosion of carbon steel (Figure 1).
642:
Likhanova, Natalya V.; López-Prados, Nallely; Guzmán-Lucero, Diego; Olivares-Xometl, Octavio; Lijanova, Irina V.; Arellanes-Lozada, Paulina; Arriola-Morales, Janette (2022-04-18).
224:: These polymers are used for corrosion protection of metal surfaces in the oil industry. They are highly effective in preventing salt water and hydrogen sulfide (H2S) corrosion.
202:
are organic compounds used as corrosion inhibitors in the petroleum industry. They act as anodic inhibitors and form a protective layer on the metal surface (Figure 5).
570:
Likhanova, Natalya V.; Martínez-Palou, Rafael; Veloz, M. Aurora; Matías, Diana J.; Reyes-Cruz, Victor E.; Höpfl, Herbert; Olivares, Octavio (January 2007).
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is a common problem in the oil industry due to the presence of water, gases, and other corrosive contaminants in the production environment.
239:
463:"Experimental and theoretical study of 1-(2-ethylamino)-2-methylimidazoline as an inhibitor of carbon steel corrosion in acid media"
500:
Martínez-Palou, R.; Rivera, J.; Zepeda, L. G.; Rodríguez, A. N.; Hernández, M. A.; Marín-Cruz, J.; Estrada, A. (May 2004).
790:
785:
613:"Effect of the molecular structure on the inhibitor properties of azoles on mild steel corrosion in 1M hydrochloric acid"
205:
111:
There are different chemical families of corrosion inhibitors used in the oil industry, among them are the following:
65:
775:
644:"Some polymeric imidazolates from alkylimidazolium as corrosion inhibitors of API 5L X52 steel in production water"
502:"Evaluation of Corrosion Inhibitors Synthesized from Fatty Acids and Fatty Alcohols Isolated from Sugar Cane Wax"
247:
Other organic products used as corrosion inhibitors in the oil industry are nitriles, amides, oximes, ureas and,
424:"Electrochemistry and XPS study of an imidazoline as corrosion inhibitor of mild steel in an acidic environment"
318:"Development of environmentally benign corrosion inhibitors for organic acid environments for oil-gas industry"
17:
720:
Martinez, Rafael; Olivares-Xomelt, Octavio; V. Likhanov, Natalya (2014-02-20), Aliofkhazraei, M. (ed.),
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691:"Lanthanide compounds as environmentally-friendly corrosion inhibitors of aluminium alloys: a review"
643:
572:"Microwave-assisted synthesis of 2-(2-pyridyl)azoles. Study of their corrosion inhibiting properties"
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Olivares-Xometl, O.; Likhanova, N. V.; Martínez-Palou, R.; Domínguez-Aguilar, M. A. (January 2009).
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Bethencourt, M.; Botana, F.J.; Calvino, J.J.; Marcos, M.; RodrÍguez-Chacón, M.A. (November 1998).
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are substances used in the oil industry to protect equipment and pipes against corrosion.
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541:"Some pyridine derivatives as corrosion inhibitors for carbon steel in acidic medium"
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141:(H2S). Also, ethoxylated amines are widely applied for the same purpose (Figure 2).
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Applications of Ionic
Liquids in the Oil Industry: Towards A Sustainable Industry
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382:"Application of ionic liquids as Corrosion Inhibitors in the Oil Industry"
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Cruz, J; Martı́nez-Palou, R; Genesca, J; Garcı́a-Ochoa, E (2004-05-01).
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Quraishi, M.A.; Chauhan, Dheeraj Singh; Ansari, Farhat A. (May 2021).
194:: Azoles, such as triazole and benzotriazole, oxazole and benzoxazoles
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356:"Corrosion inhibitors in the oil and gas industry | WorldCat.org"
274:"Corrosion Inhibitors – Principles, Mechanisms and Applications"
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Figure 3. Example of organic acids used as corrosion inhibitors
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Martínez Palou, Rafael; Likhanova, Natalya V. (January 2023),
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Figure 6. Example of polymers used as corrosion inhibitors.
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Figure 2. Example of fatty amines and ethoxylated amines
60:
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Popova, A.; Christov, M.; Zwetanova, A. (May 2007).
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Abd El-Maksoud, S.A.; Fouda, A.S. (September 2005).
27:
Application of
Corrosion Inhibitors to oil industry
95:inhibitors based on their chemical composition.
722:"Environmentally Friendly Corrosion Inhibitors"
388:, BENTHAM SCIENCE PUBLISHERS, pp. 94–121,
157:: Organic acids such as acetic acid, formic aci
209:Figure 5. Example of benzoazoles and triazoles
8:
18:Corrosion inhibitors for petroleum industry
648:Journal of Adhesion Science and Technology
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272:G., Camila; F., Alexandre (2014-02-20),
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127:Figure 1. Example of fatty imidazolines
467:Journal of Electroanalytical Chemistry
98:Corrosion inhibitors are used in the
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726:Developments in Corrosion Protection
278:Developments in Corrosion Protection
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576:Journal of Heterocyclic Chemistry
557:10.1016/j.matchemphys.2005.02.020
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545:Materials Chemistry and Physics
255:of the inhibitor if necessary.
198:thioazoles, and benzothioazoles
479:10.1016/j.jelechem.2003.11.018
394:10.2174/9789815079579123010008
185:Figure 4. Example of pyridines
1:
707:10.1016/S0010-938X(98)00077-8
660:10.1080/01694243.2021.1939600
629:10.1016/j.corsci.2006.10.021
334:10.1016/j.molliq.2021.115514
322:Journal of Molecular Liquids
107:Corrosion Inhibitor Families
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259:References
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781:Petroleum
771:Chemistry
676:237921290
668:0169-4243
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487:1572-6657
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