31:
599:
375:
Dalton's law is not strictly followed by real gases, with the deviation increasing with pressure. Under such conditions the volume occupied by the molecules becomes significant compared to the free space between them. In particular, the short average distances between molecules increases
197:
359:
276:
83:
530:
761:
598:
480:
380:
between gas molecules enough to substantially change the pressure exerted by them, an effect not included in the ideal gas model.
314:
231:
588:
756:
659:
523:
573:
715:
690:
705:
700:
680:
618:
685:
746:
710:
516:
30:
623:
377:
17:
725:
472:
408:
720:
613:
751:
654:
578:
496:
476:
77:
695:
583:
464:
426:
402:
50:
568:
553:
465:
432:
390:
438:
414:
396:
740:
628:
308:
288:
192:{\displaystyle p_{\text{total}}=\sum _{i=1}^{n}p_{i}=p_{1}+p_{2}+p_{3}+\cdots +p_{n}}
539:
411: – Relationship between pressure and temperature of a gas at constant volume
420:
58:
649:
62:
54:
65:
46:
644:
563:
34:
An illustration of Dalton's law using the gases of air at sea level.
664:
405: – Combination of Charles', Boyle's and Gay-Lussac's gas laws
29:
441: – Pressure exerted by a vapor in thermodynamic equilibrium
512:
508:
500:
Memoirs of the
Literary and Philosophical Society of Manchester
435: – Law of thermodynamics for vapour pressure of a mixture
61:
in 1801 and published in 1802. Dalton's law is related to the
45:) states that in a mixture of non-reacting gases, the total
417: – Gas law regarding proportionality of dissolved gas
497:"Essay IV. On the expansion of elastic fluids by heat,"
307:
The relationship below provides a way to determine the
317:
234:
86:
467:
Chemistry: the molecular nature of matter and change
673:
637:
606:
546:
226:represent the partial pressures of each component.
393: – Gas law describing volume of a gas mixture
353:
270:
191:
76:Mathematically, the pressure of a mixture of non-
429: – Pressure of a component gas in a mixture
399: – Relation between gas pressure and volume
524:
502:, vol. 5, pt. 2, pages 595–602; see page 600.
471:(5th ed.). Boston: McGraw-Hill. p.
8:
458:
456:
354:{\displaystyle p_{i}=p_{\text{total}}c_{i}}
271:{\displaystyle p_{i}=p_{\text{total}}x_{i}}
531:
517:
509:
345:
335:
322:
316:
262:
252:
239:
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183:
164:
151:
138:
125:
115:
104:
91:
85:
452:
80:gases can be defined as the summation:
423: – SI unit of amount of substance
295:th component in the total mixture of
18:Dalton's law of partial pressure
7:
311:of any individual gaseous component
49:exerted is equal to the sum of the
368:is the concentration of component
27:Empirical law of partial pressures
25:
43:Dalton's law of partial pressures
597:
463:Silberberg, Martin S. (2009).
53:of the individual gases. This
1:
778:
762:Engineering thermodynamics
660:Spinning band distillation
309:volume-based concentration
303:Volume-based concentration
595:
589:Vapor–liquid equilibrium
619:Continuous distillation
355:
272:
193:
120:
35:
378:intermolecular forces
356:
273:
194:
100:
33:
624:Fractionating column
607:Industrial processes
574:McCabe–Thiele method
315:
232:
84:
57:law was observed by
757:Physical chemistry
638:Laboratory methods
614:Batch distillation
495:J. Dalton (1802),
351:
268:
189:
36:
734:
733:
655:Rotary evaporator
579:Theoretical plate
338:
255:
94:
51:partial pressures
16:(Redirected from
769:
601:
584:Partial pressure
533:
526:
519:
510:
503:
493:
487:
486:
470:
460:
427:Partial pressure
409:Gay-Lussac's law
403:Combined gas law
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21:
777:
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771:
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736:
735:
730:
669:
633:
602:
593:
569:Fenske equation
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331:
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147:
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28:
23:
22:
15:
12:
11:
5:
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749:
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732:
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729:
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723:
718:
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703:
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528:
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513:
505:
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488:
481:
451:
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448:
445:
443:
442:
439:Vapor pressure
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430:
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406:
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364:
348:
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73:
70:
26:
24:
14:
13:
10:
9:
6:
4:
3:
2:
774:
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742:
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724:
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719:
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666:
663:
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643:
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629:Spinning cone
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587:
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582:
580:
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567:
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562:
560:
557:
555:
552:
551:
549:
545:
541:
534:
529:
527:
522:
520:
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501:
498:
492:
489:
484:
482:9780073048598
478:
474:
469:
468:
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440:
437:
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431:
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422:
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398:
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389:
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383:
381:
379:
373:
371:
367:
346:
342:
332:
328:
323:
319:
310:
302:
300:
299:components .
298:
294:
290:
289:mole fraction
285:
263:
259:
249:
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227:
224:
212:
203:
184:
180:
176:
173:
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165:
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144:
139:
135:
131:
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71:
69:
67:
64:
60:
56:
52:
48:
44:
41:(also called
40:
32:
19:
747:Distillation
726:Vacuum-based
559:Dalton's law
558:
554:Raoult's law
540:Distillation
499:
491:
466:
433:Raoult's law
391:Amagat's law
374:
369:
362:
306:
296:
292:
280:
228:
219:
210:
201:
75:
42:
39:Dalton's law
38:
37:
721:Steam-based
716:Salt-effect
691:Destructive
421:Mole (unit)
415:Henry's law
397:Boyle's law
59:John Dalton
741:Categories
706:Fractional
701:Extractive
681:Azeotropic
674:Techniques
547:Principles
447:References
686:Catalytic
650:Kugelrohr
174:⋯
102:∑
55:empirical
752:Gas laws
711:Reactive
384:See also
78:reactive
66:gas laws
47:pressure
645:Alembic
291:of the
287:is the
217:, ...,
72:Formula
564:Reflux
479:
361:where
278:where
199:where
665:Still
337:total
254:total
93:total
63:ideal
477:ISBN
696:Dry
473:206
743::
475:.
455:^
372:.
208:,
68:.
532:e
525:t
518:v
485:.
370:i
365:i
363:c
347:i
343:c
333:p
329:=
324:i
320:p
297:n
293:i
283:i
281:x
264:i
260:x
250:p
246:=
241:i
237:p
222:n
220:p
214:2
211:p
205:1
202:p
185:n
181:p
177:+
171:+
166:3
162:p
158:+
153:2
149:p
145:+
140:1
136:p
132:=
127:i
123:p
117:n
112:1
109:=
106:i
98:=
89:p
20:)
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