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Deacon process

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The Leblanc-Deacon process is a modification of the Leblanc process. The Leblanc process was notoriously environmentally unfriendly, and resulted in some of the first Air and Water pollution acts. In 1874,
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Peter Schmittinger et al. "Chlorine," Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH Verlag GmbH & Co, 2006,
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The reaction takes place at about 400 to 450 °C in the presence of a variety of catalysts, including
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The MT-Chlor process developed by the Mitsui Toatsu Company, which utilizes chromium-based catalysts.
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was curtailed. To some extent this technically sophisticated process superseded the earlier
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The Deacon process is now outdated technology. Most chlorine today is produced by using
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was no longer the primary product of these plants, and henceforth sold at a loss.
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Deacon chemistry revisited: new catalysts for chlorine recycling. ETH (2013).
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http://www.electrochem.org/dl/interface/fal/fal98/IF8-98-Pages32-36.pdf
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had derived a process to reduce HCl emissions as mandated by the
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gas, which was then used to manufacture a commercially valuable
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The process was based on the oxidation of hydrogen chloride:
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http://www.che.lsu.edu/COURSES/4205/2000/Lim/paper.htm
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Index

Henry Deacon
manufacture
alkalis
sodium carbonate
Leblanc process
Hydrogen chloride
chlorine
bleaching powder
hydrochloric acid
manganese dioxide
2H2O
copper chloride
chlorine
M. W. Kellogg Company
nitrosylsulfuric acid
Shell Oil Company
electrolytic processes
ruthenium(IV) oxide
Sumitomo
Henry Deacon
Alkali Act
hydrogen chloride
copper chloride
catalyst
chlorine
sodium carbonate
Chlorine production


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