781:
280:
205:
780:
24:
569:
559:
564:
776:
878:
1218:, (organo-magnesium compounds), which are easier to handle and less flammable, replaced organo-zinc compounds in most laboratory syntheses. Due to differences in reactivity (as well as in reaction byproducts) between organo-zinc compounds and Grignard reagents, organo-zinc compounds may be preferred in some syntheses.
1063:, eventually causing blindness. If dimethylzinc contacts the skin, it causes thermal and acid burns by reacting with moisture on skin. Unless washed quickly, skin may be scarred. Ingestion, while unlikely, also causes immediate burns. Nausea, vomiting, cramps, and diarrhea may follow, and tissues may
1461:
A. Haaland; J. C. Green; G. S. McGrady; A. J. Downs; E. Gullo; M. J. Lyall; J. Timberlake; A. V. Tutukin; H. V. Volden; K.-A. Østby (2003). "The length, strength and polarity of metal–carbon bonds: dialkylzinc compounds studied by density functional theory calculations, gas electron diffraction and
782:
779:
804:
797:
577:
539:
1059:
and death. Eyes are immediately and severely irritated and burned by liquid, vapor, or dilute solutions. If not removed by thorough flushing with water, this chemical may permanently damage the
891:
691:
329:
695:
1595:
1214:. It was used for a long time to introduce methyl groups into organic molecules or to synthesize organometallic compounds containing methyl groups.
1416:
1194:
in an airtight vessel, a flame burst out when the seal was broken. In the laboratory, this synthesis method remains unchanged today, except that
627:
1532:
1118:
Dimethylzinc fire must be extinguished with dry sand. The fire reacts violently or explosively with water, generating very flammable
1276:
1233:
294:
23:
2129:
1107:
in air. It burns in air with a blue flame, giving off a garlic-like odor. The products of decomposition (fire smoke) include
1044:
605:
520:
2139:
2124:
679:
898:
811:
1588:
621:
237:
568:
2119:
1410:
John Bacsa; Felix Hanke; Sarah
Hindley; Rajesh Odedra; George R. Darling; Anthony C. Jones; Alexander Steiner (2011).
258:
639:
790:
1288:
1055:
Inhalation of dimethylzinc mist or vapor causes immediate irritation of the upper respiratory tract, and may cause
723:
2134:
1253:
1040:
1338:
1550:
826:
655:
558:
1581:
683:
563:
200:
1083:
1009:
1135:
663:
2054:
1625:
1187:
1166:
is ordered. The molecules are linear with Zn-C bond lengths measuring 192.7(6) pm. The structure of the
715:
591:
551:
51:
1067:
if not promptly treated. Upon heating, dimethylzinc vapor decomposes to irritating and toxic products.
743:
727:
1664:
1548:
Mohammad Afzaal; Mohammad A. Malik; Paul O’Brien (2007). "Preparation of zinc containing materials".
1326:
914:
470:
613:
1464:
275:
108:
1162:
high-temperature phase shows a two-dimensional disorder, while the low-temperature phase which is
651:
1848:
1207:
534:
Spontaneously ignites in air and violently reacts with water, evolving irritant and toxic fumes.
1146:. Improperly handled containers of dimethylzinc can explode, causing serious injuries or death.
667:
2002:
1528:
1443:
1334:
1215:
1211:
941:
182:
142:
1912:
1793:
1559:
1505:
1492:"Notiz über eine neue Reihe organischer Körper, welche Metalle, Phosphor u. s. w. enthalten"
1487:
1469:
1433:
1425:
1179:
1112:
918:
735:
601:
352:
711:
246:
1986:
1864:
1496:
857:
852:
1379:
118:
731:
279:
204:
162:
1920:
1900:
1843:
1817:
1760:
1692:
1604:
1438:
1411:
1222:
1020:
869:
609:
460:
2113:
1876:
1838:
1785:
1736:
1728:
1716:
1708:
1191:
1183:
1100:
957:
703:
496:
441:
421:
411:
193:
755:
719:
2070:
2034:
2018:
1974:
1888:
1830:
1825:
1768:
1744:
1700:
1684:
1396:
1032:
671:
445:
597:
226:
747:
675:
1958:
1752:
1315:
997:
945:
635:
1780:
1672:
1163:
1159:
1123:
1122:
gas which can explode in air upon catching fire, and lung-irritating smoke of
1108:
1104:
643:
631:
431:
373:
173:
1509:
1330:
1167:
1075:
1056:
1036:
659:
480:
1447:
1429:
707:
1319:
1230:
1127:
1071:
929:
810:
803:
796:
789:
762:
30:
1111:, which itself is not toxic, but its fumes can irritate lungs and cause
1221:
Its high vapor pressure has led to extensive uses in the production of
1131:
1119:
1024:
449:
401:
213:
1563:
1473:
1272:
1195:
1139:
1060:
1028:
1012:
965:
926:
437:
34:
1491:
868:
Except where otherwise noted, data are given for materials in their
1226:
1155:
1143:
1064:
968:
453:
153:
141:
131:
1573:
739:
1307:
1249:
1245:
1035:
of dimethylzinc is 230.13 K (−43.02 °C) ± 0.02 K. The
1016:
996:
Sodium assists the reaction of the zinc with the methyl iodide.
961:
922:
751:
391:
38:
1577:
1311:
1284:
1280:
1241:
1237:
1079:
1412:"The Solid State Structures of Dimethylzinc and Diethylzinc"
263:
699:
687:
647:
1126:. Dimethylzinc fire reacts violently or explosively with
774:
886:
1015:, which has a characteristic disagreeable garlic-like
913:, also known as zinc methyl, DMZ, or DMZn, is a toxic
509:
129.20 J/(mol∙K) (liquid at 25 °C (77 °F))
1940:
1657:
1618:
1611:
1198:or copper compounds are used to activate the zinc.
1170:shows a very similar Zn-C distance of 193.0(2) pm.
1206:Dimethylzinc has been of great importance in the
225:
1225:, e.g. metalorganic chemical vapor deposition (
778:
117:
1158:the compound exists in two modifications. The
1589:
313:InChI=1/2CH3.Zn/h2*1H3;/rC2H6Zn/c1-3-2/h1-2H3
8:
940:. It belongs to the large series of similar
475:0.1627 W/(m∙K) at 70 °C (158 °F)
1937:
1615:
1596:
1582:
1574:
1374:
278:
203:
181:
15:
1437:
1372:
1370:
1368:
1366:
1364:
1362:
1360:
1358:
1356:
1354:
245:
1525:Organozinc reagents in organic synthesis
1497:Liebigs Annalen der Chemie und Pharmacie
1391:
1389:
1297:
1291:
1262:
1256:
1092:
1088:
989:
985:
981:
977:
936:
932:
364:
360:
1417:Angewandte Chemie International Edition
1350:
485:0.807 mPa·s at 70 °F (21 °C)
334:
299:
274:
1190:. After heating a mixture of zinc and
416:−42 °C (−44 °F; 231 K)
194:
426:46 °C (115 °F; 319 K)
306:Key: AXAZMDOAUQTMOW-UHFFFAOYSA-N
161:
7:
1178:Dimethylzinc was first prepared by
1019:. It is a very reactive and strong
1008:Dimethylzinc is a colorless mobile
316:Key: AXAZMDOAUQTMOW-WPFVDKAYAX
216:
14:
1325:It is used as an accelerator in
1027:and often sold as a solution in
876:
567:
562:
557:
22:
872:(at 25 °C , 100 kPa).
1229:) for the preparation of wide
956:It is formed by the action of
521:Occupational safety and health
1:
1462:photoelectron spectroscopy".
1397:"Dimethylzinc (CAS 544-97-8)"
1070:Contact of dimethylzinc with
1039:molecule of dimethylzinc is
1236:semiconducting films (e.g.
1115:, severe injury, or death.
1078:. Dimethylzinc oxidises in
971:at elevated temperatures.
2156:
1339:methyltitanium trichloride
1000:is formed as a byproduct.
378:95.478 g/mol
1527:. Boca Raton: CRC Press.
866:
838:
538:
518:
513:
489:
345:
325:
290:
101:
93:Zinc trihydrogenmethanide
60:
50:
45:
21:
1941:Organozinc(II) compounds
1551:New Journal of Chemistry
1510:10.1002/jlac.18490710206
834:0 °F (−18 °C)
622:Precautionary statements
303:InChI=1S/2CH3.Zn/h2*1H3;
2130:Foul-smelling chemicals
1619:Organozinc(I) compounds
1082:very slowly, producing
448:; decomposes in water,
1430:10.1002/anie.201105099
1103:and can spontaneously
785:
406:1.386 g/cm at 10.5 °C
1523:Erdik, Ender (1996).
1279:semiconductors (e.g.
1188:University of Marburg
1182:during his work with
1099:Dimethylzinc is very
784:
2140:Pyrophoric materials
2125:Organozinc compounds
1327:rubber vulcanization
1084:methylzinc methoxide
1051:Toxicity and hazards
767:(fire diamond)
471:Thermal conductivity
1465:Dalton Transactions
1424:(49): 11685–11687.
1314:), which have many
1136:2,2-dichloropropane
1074:may form explosive
1023:. It is soluble in
915:organozinc compound
18:
2120:Methylating agents
899:Infobox references
839:Related compounds
786:
16:
2107:
2106:
2066:
2065:
1653:
1652:
1558:(12): 2029–2040.
1534:978-0-8493-9151-4
1468:(22): 4356–4366.
1335:methylating agent
1216:Grignard reagents
1212:organic compounds
1138:. It explodes in
1043:at Zn center and
907:Chemical compound
905:
904:
845:Related compounds
592:Hazard statements
386:Colorless liquid
259:CompTox Dashboard
143:Interactive image
2147:
2135:Methyl complexes
2099:
2098:
2097:
2089:
2088:
2080:
2079:
1938:
1813:
1812:
1811:
1803:
1802:
1616:
1598:
1591:
1584:
1575:
1568:
1567:
1564:10.1039/b712235g
1545:
1539:
1538:
1520:
1514:
1513:
1484:
1478:
1477:
1474:10.1039/B306840B
1458:
1452:
1451:
1441:
1407:
1401:
1400:
1393:
1384:
1383:
1376:
1304:
1269:
1180:Edward Frankland
1113:metal fume fever
1095:
992:
939:
919:chemical formula
889:
883:
880:
879:
815:
814:
806:
799:
792:
777:
757:
753:
749:
745:
741:
737:
733:
729:
725:
721:
717:
713:
709:
705:
701:
697:
693:
689:
685:
681:
677:
673:
669:
665:
661:
657:
653:
649:
645:
641:
637:
633:
629:
615:
611:
607:
603:
599:
571:
566:
561:
505:
490:Thermochemistry
367:
353:Chemical formula
283:
282:
267:
265:
249:
229:
218:
207:
196:
185:
165:
145:
121:
26:
19:
2155:
2154:
2150:
2149:
2148:
2146:
2145:
2144:
2110:
2109:
2108:
2103:
2096:
2093:
2092:
2091:
2087:
2084:
2083:
2082:
2078:
2075:
2074:
2073:
2071:
2062:
2058:
2050:
2046:
2042:
2038:
2030:
2026:
2022:
2014:
2010:
2006:
1998:
1994:
1990:
1982:
1978:
1970:
1966:
1962:
1954:
1950:
1936:
1932:
1928:
1924:
1916:
1908:
1904:
1896:
1892:
1884:
1880:
1872:
1868:
1860:
1856:
1852:
1834:
1821:
1810:
1807:
1806:
1805:
1801:
1798:
1797:
1796:
1794:
1789:
1776:
1772:
1764:
1756:
1748:
1740:
1732:
1724:
1720:
1712:
1704:
1696:
1688:
1680:
1676:
1668:
1649:
1645:
1641:
1637:
1633:
1629:
1607:
1602:
1572:
1571:
1547:
1546:
1542:
1535:
1522:
1521:
1517:
1486:
1485:
1481:
1460:
1459:
1455:
1409:
1408:
1404:
1395:
1394:
1387:
1378:
1377:
1352:
1347:
1302:
1295:
1289:
1275:precursors for
1267:
1260:
1254:
1204:
1186:in 1849 at the
1176:
1152:
1094:
1090:
1086:
1053:
1006:
991:
987:
983:
979:
975:
954:
938:
934:
921:
908:
901:
896:
895:
894: ?)
885:
881:
877:
873:
862:
858:Dimethylmercury
853:Dimethylcadmium
846:
831:
828:
820:
819:
818:
817:
812:
808:
801:
794:
787:
783:
775:
624:
594:
580:
554:
531:
506:
499:
366:
362:
358:
355:
341:
338:
333:
332:
321:
318:
317:
314:
308:
307:
304:
298:
297:
286:
268:
261:
252:
232:
219:
188:
168:
148:
135:
124:
111:
97:
96:
72:Dimethylzincane
56:
41:
27:
12:
11:
5:
2153:
2151:
2143:
2142:
2137:
2132:
2127:
2122:
2112:
2111:
2105:
2104:
2102:
2101:
2094:
2085:
2076:
2067:
2064:
2063:
2061:
2056:
2052:
2048:
2044:
2040:
2036:
2032:
2028:
2024:
2020:
2016:
2012:
2008:
2004:
2000:
1996:
1992:
1988:
1984:
1980:
1976:
1972:
1968:
1964:
1960:
1956:
1952:
1948:
1944:
1942:
1935:
1934:
1930:
1926:
1922:
1918:
1914:
1910:
1906:
1902:
1898:
1894:
1890:
1886:
1882:
1878:
1874:
1870:
1866:
1862:
1858:
1854:
1850:
1846:
1841:
1836:
1832:
1828:
1823:
1819:
1815:
1808:
1799:
1791:
1787:
1783:
1778:
1774:
1770:
1766:
1762:
1758:
1754:
1750:
1746:
1742:
1738:
1734:
1730:
1726:
1722:
1718:
1714:
1710:
1706:
1702:
1698:
1694:
1690:
1686:
1682:
1678:
1674:
1670:
1666:
1661:
1659:
1655:
1654:
1651:
1650:
1648:
1647:
1643:
1639:
1635:
1631:
1627:
1622:
1620:
1613:
1609:
1608:
1605:Zinc compounds
1603:
1601:
1600:
1593:
1586:
1578:
1570:
1569:
1540:
1533:
1515:
1504:(2): 213–216.
1479:
1453:
1402:
1385:
1380:"Dimethylzinc"
1349:
1348:
1346:
1343:
1322:applications.
1223:semiconductors
1203:
1200:
1175:
1172:
1151:
1148:
1052:
1049:
1047:at C centers.
1021:reducing agent
1005:
1002:
994:
993:
953:
950:
906:
903:
902:
897:
875:
874:
870:standard state
867:
864:
863:
861:
860:
855:
849:
847:
844:
841:
840:
836:
835:
832:
825:
822:
821:
809:
802:
795:
788:
773:
772:
771:
770:
768:
759:
758:
692:P303+P361+P353
684:P301+P330+P331
625:
620:
617:
616:
595:
590:
587:
586:
581:
576:
573:
572:
555:
550:
547:
546:
536:
535:
532:
529:
526:
525:
516:
515:
511:
510:
507:
495:
492:
491:
487:
486:
483:
477:
476:
473:
467:
466:
463:
461:Vapor pressure
457:
456:
434:
428:
427:
424:
418:
417:
414:
408:
407:
404:
398:
397:
394:
388:
387:
384:
380:
379:
376:
370:
369:
356:
351:
348:
347:
343:
342:
340:
339:
336:
328:
327:
326:
323:
322:
320:
319:
315:
312:
311:
309:
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302:
301:
293:
292:
291:
288:
287:
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284:
271:
269:
257:
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242:
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178:
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169:
167:
166:
158:
156:
150:
149:
147:
146:
138:
136:
129:
126:
125:
123:
122:
114:
112:
107:
104:
103:
99:
98:
95:
94:
91:
88:
87:Zinc methanide
85:
84:Zinc carbanide
82:
79:
76:
73:
70:
67:
66:2-Zincapropane
63:
62:
58:
57:
54:
48:
47:
43:
42:
28:
13:
10:
9:
6:
4:
3:
2:
2152:
2141:
2138:
2136:
2133:
2131:
2128:
2126:
2123:
2121:
2118:
2117:
2115:
2100:
2069:
2068:
2060:
2053:
2051:
2033:
2031:
2017:
2015:
2001:
1999:
1985:
1983:
1973:
1971:
1957:
1955:
1945:
1943:
1939:
1933:
1919:
1917:
1911:
1909:
1899:
1897:
1887:
1885:
1875:
1873:
1863:
1861:
1847:
1845:
1842:
1840:
1837:
1835:
1829:
1827:
1824:
1822:
1816:
1814:
1792:
1790:
1784:
1782:
1779:
1777:
1767:
1765:
1759:
1757:
1751:
1749:
1743:
1741:
1735:
1733:
1727:
1725:
1715:
1713:
1707:
1705:
1699:
1697:
1691:
1689:
1683:
1681:
1671:
1669:
1663:
1662:
1660:
1656:
1646:
1624:
1623:
1621:
1617:
1614:
1610:
1606:
1599:
1594:
1592:
1587:
1585:
1580:
1579:
1576:
1565:
1561:
1557:
1553:
1552:
1544:
1541:
1536:
1530:
1526:
1519:
1516:
1511:
1507:
1503:
1499:
1498:
1493:
1489:
1483:
1480:
1475:
1471:
1467:
1466:
1457:
1454:
1449:
1445:
1440:
1435:
1431:
1427:
1423:
1419:
1418:
1413:
1406:
1403:
1398:
1392:
1390:
1386:
1381:
1375:
1373:
1371:
1369:
1367:
1365:
1363:
1361:
1359:
1357:
1355:
1351:
1344:
1342:
1340:
1336:
1332:
1328:
1323:
1321:
1317:
1313:
1309:
1305:
1301:
1294:
1286:
1282:
1278:
1274:
1270:
1266:
1259:
1251:
1247:
1243:
1239:
1235:
1232:
1228:
1224:
1219:
1217:
1213:
1209:
1201:
1199:
1197:
1193:
1192:methyl iodide
1189:
1185:
1184:Robert Bunsen
1181:
1173:
1171:
1169:
1165:
1161:
1157:
1149:
1147:
1145:
1141:
1137:
1133:
1129:
1125:
1121:
1116:
1114:
1110:
1106:
1102:
1097:
1085:
1081:
1077:
1073:
1068:
1066:
1062:
1058:
1050:
1048:
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1038:
1034:
1030:
1026:
1022:
1018:
1014:
1011:
1003:
1001:
999:
974:
973:
972:
970:
967:
963:
959:
958:methyl iodide
951:
949:
947:
943:
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928:
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920:
916:
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893:
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865:
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848:
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508:
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497:Heat capacity
494:
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479:
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474:
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469:
468:
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443:
442:diethyl ether
439:
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422:Boiling point
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412:Melting point
410:
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276:DTXSID5060271
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195:ECHA InfoCard
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71:
69:Dimethyl zinc
68:
65:
64:
59:
53:
49:
44:
40:
36:
32:
25:
20:
17:Dimethylzinc
1946:
1555:
1549:
1543:
1524:
1518:
1501:
1495:
1488:E. Frankland
1482:
1463:
1456:
1421:
1415:
1405:
1324:
1299:
1292:
1264:
1257:
1220:
1205:
1177:
1153:
1117:
1098:
1069:
1054:
1033:triple point
1007:
995:
955:
911:Dimethylzinc
910:
909:
827:Autoignition
763:
583:
540:
530:Main hazards
519:
501:
446:hydrocarbons
102:Identifiers
61:Other names
55:Dimethylzinc
1333:, and as a
1271:) and as p-
1156:solid state
998:Zinc iodide
976:2 Zn + 2 CH
952:Preparation
946:diethylzinc
829:temperature
578:Signal word
524:(OHS/OSH):
436:Soluble in
383:Appearance
346:Properties
201:100.008.077
163:CHEBI:51497
90:Zinc methyl
2114:Categories
1345:References
1316:electronic
1164:monoclinic
1160:tetragonal
1124:zinc oxide
1109:zinc oxide
1101:pyrophoric
1045:tetragonal
1004:Properties
552:Pictograms
465:50.13 kPa
432:Solubility
374:Molar mass
247:8H6R0N8W2F
174:ChemSpider
130:3D model (
109:CAS Number
81:Methylzinc
52:IUPAC name
1331:fungicide
1208:synthesis
1168:gas-phase
1150:Structure
1076:peroxides
1057:pneumonia
1037:monomeric
980:I → Zn(CH
942:compounds
917:with the
744:P402+P404
736:P370+P378
696:P304+P340
640:P231+P232
543:labelling
481:Viscosity
33:, Black:
1987:Zn(CH(CH
1665:Zn(acac)
1658:Zinc(II)
1490:(1849).
1448:21919175
1320:photonic
1231:band gap
1128:methanol
1072:oxidants
1065:ulcerate
1010:volatile
964:or zinc-
944:such as
764:NFPA 704
514:Hazards
183:10254473
119:544-97-8
37:, Grey:
2003:Zn(C(CH
1612:Zinc(I)
1439:3326375
1329:, as a
1174:History
1154:In the
1132:ethanol
1120:methane
1029:hexanes
1025:alkanes
892:what is
890: (
450:ethanol
402:Density
396:Garlic
368:
214:PubChem
29:White:
1818:Zn(OH)
1795:Zn(ClO
1717:Zn(ClO
1701:Zn(CN)
1531:
1446:
1436:
1273:dopant
1196:copper
1140:oxygen
1105:ignite
1061:cornea
1041:linear
1031:. The
1013:liquid
966:sodium
887:verify
884:
584:Danger
438:xylene
330:SMILES
46:Names
2055:ZnICH
1975:Zn(CH
1947:Zn(CH
1769:Zn(NO
1761:ZnMoO
1729:ZnCrO
1277:III–V
1234:II–VI
1227:MOCVD
1144:ozone
1091:ZnOCH
988:+ ZnI
969:alloy
454:acids
359:Zn(CH
295:InChI
227:11010
154:ChEBI
132:JSmol
2035:Zn(C
2019:Zn(C
1979:COO)
1959:Zn(C
1844:ZnTe
1839:ZnSe
1831:ZnSO
1709:ZnCl
1693:ZnCO
1685:ZnBr
1673:Zn(N
1529:ISBN
1444:PMID
1318:and
1308:GaAs
1250:ZnTe
1246:ZnSe
1202:Uses
1142:and
1134:and
1017:odor
962:zinc
756:P501
752:P405
748:P403
740:P391
732:P363
728:P361
724:P338
720:P335
716:P334
712:P321
708:P317
704:P316
700:P305
688:P302
680:P280
676:P273
672:P264
668:P260
664:P243
660:P242
656:P241
652:P240
648:P235
644:P233
636:P223
632:P222
628:P210
614:H410
610:H314
606:H260
602:H250
598:H225
452:and
392:Odor
238:UNII
78:DMZn
2090:ZnO
1925:(PO
1913:ZnP
1826:ZnS
1786:ZnO
1781:ZnO
1753:ZnI
1745:ZnH
1737:ZnF
1634:(CH
1560:doi
1506:doi
1470:doi
1434:PMC
1426:doi
1337:in
1312:InP
1285:AlP
1281:AlN
1242:ZnS
1238:ZnO
1210:of
1080:air
960:on
541:GHS
264:EPA
217:CID
75:DMZ
2116::
2086:46
2077:24
1921:Zn
1901:Zn
1889:Zn
1881:As
1877:Zn
1869:Sb
1865:Zn
1849:Zn
1630:(C
1626:Zn
1556:31
1554:.
1502:71
1500:.
1494:.
1442:.
1432:.
1422:50
1420:.
1414:.
1388:^
1353:^
1341:.
1310:,
1306:,
1303:As
1298:1−
1296:Ga
1290:Al
1287:,
1283:,
1268:Te
1263:1−
1261:Hg
1255:Cd
1252:,
1248:,
1244:,
1240:,
1130:,
1096:.
1087:CH
948:.
923:Zn
754:,
750:,
746:,
742:,
738:,
734:,
730:,
726:,
722:,
718:,
714:,
710:,
706:,
702:,
698:,
694:,
690:,
686:,
682:,
678:,
674:,
670:,
666:,
662:,
658:,
654:,
650:,
646:,
642:,
638:,
634:,
630:,
612:,
608:,
604:,
600:,
545::
444:,
440:,
337:CC
39:Zn
2095:4
2081:H
2072:C
2059:I
2057:2
2049:2
2047:)
2045:3
2043:O
2041:5
2039:H
2037:3
2029:2
2027:)
2025:5
2023:H
2021:6
2013:2
2011:)
2009:3
2007:)
2005:3
1997:2
1995:)
1993:2
1991:)
1989:3
1981:2
1977:3
1969:2
1967:)
1965:5
1963:H
1961:2
1953:2
1951:)
1949:3
1931:2
1929:)
1927:4
1923:3
1915:2
1907:2
1905:P
1903:3
1895:2
1893:N
1891:3
1883:2
1879:3
1871:2
1867:3
1859:7
1857:O
1855:2
1853:P
1851:2
1833:4
1820:2
1809:2
1804:)
1800:4
1788:2
1775:2
1773:)
1771:3
1763:4
1755:2
1747:2
1739:2
1731:4
1723:2
1721:)
1719:3
1711:2
1703:2
1695:3
1687:2
1679:2
1677:)
1675:3
1667:2
1644:2
1642:)
1640:5
1638:)
1636:3
1632:5
1628:2
1597:e
1590:t
1583:v
1566:.
1562::
1537:.
1512:.
1508::
1476:.
1472::
1450:.
1428::
1399:.
1382:.
1300:x
1293:x
1265:x
1258:x
1093:3
1089:3
990:2
986:2
984:)
982:3
978:3
937:2
935:)
933:3
930:H
927:C
925:(
882:N
813:W
805:3
798:4
791:3
504:)
502:C
500:(
365:2
363:)
361:3
266:)
262:(
134:)
35:C
31:H
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