232:. The strength and frequency of the emitted radio waves allows the concentration of such nuclei to be measured. Another potential application is the use of doublets as the emitting layer in light emitting diodes (LEDs). These materials have the advantage of having 100% theoretical quantum efficiency based on spin statistics whereas singlet systems and triplet systems have significantly lower efficiencies or rely on noble metals such as Pt and Ir to emit light.
130:
33:
200:
observations, allowing astronomers to deduce the existence of, and measure the strength of magnetic fields around the Sun, stars and galaxies. Conversely, it was the observation of doublets in spectroscopy that allowed physicists to deduce that the
228:, whose doublet splitting is in the radio-frequency range. By applying both a magnetic field and carefully tuning a radio-frequency transmitter, the nuclear spins will flip and re-emit radiation, in an effect known as the
271:
Imran, Muhammad; Wehrmann, Caleb; Chen, Mark (2020). "Open-Shell
Effects on Optoelectronic Properties: Antiambipolar Charge Transport and Anti-Kasha Doublet Emission from a N-Substituted Bisphenalenyl".
314:
157:
of 1/2, such that there are two allowed values of the spin component, −1/2 and +1/2. Quantum systems with two possible states are sometimes called
116:
54:
50:
97:
69:
353:
205:
had a spin, and that furthermore, the magnitude of the spin had to be 1/2. See the history section of the article on
76:
221:
217:
166:
43:
83:
358:
193:
65:
348:
162:
297:
289:
251:
146:
328:
281:
158:
184:
The term "doublet" dates back to the early 19th century, when it was observed that certain
129:
90:
324:
196:. Such spectral lines were observed not only in the laboratory, but also in astronomical
225:
206:
189:
185:
154:
342:
301:
246:
241:
138:
134:
197:
332:
17:
319:
188:
of an ionized, excited gas would split into two under the influence of a strong
32:
229:
213:
323:, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "
170:
293:
285:
212:
Doublets continue to play an important role in physics. For example, the
202:
224:. In this technology, a spectroscopic doublet occurs in a spin-1/2
173:
128:
161:. Essentially all occurrences of doublets in nature arise from
26:
153:
is a composite quantum state of a system with an effective
57:. Unsourced material may be challenged and removed.
8:
117:Learn how and when to remove this message
274:Journal of the American Chemical Society
263:
7:
55:adding citations to reliable sources
320:Compendium of Chemical Terminology
165:; spin 1/2 is associated with the
25:
31:
42:needs additional citations for
1:
333:10.1351/goldbook.D01853.html
192:, in an effect known as the
375:
222:nuclear magnetic resonance
218:magnetic resonance imaging
167:fundamental representation
180:History and applications
194:anomalous Zeeman effect
142:
133:Examples of atoms in
132:
286:10.1021/jacs.9b10677
209:for greater detail.
51:improve this article
354:Rotational symmetry
163:rotational symmetry
143:
252:Spin multiplicity
159:two-level systems
147:quantum mechanics
127:
126:
119:
101:
18:Doublet (physics)
16:(Redirected from
366:
306:
305:
268:
122:
115:
111:
108:
102:
100:
59:
35:
27:
21:
374:
373:
369:
368:
367:
365:
364:
363:
339:
338:
337:
310:
309:
270:
269:
265:
260:
238:
182:
137:, doublet, and
123:
112:
106:
103:
66:"Doublet state"
60:
58:
48:
36:
23:
22:
15:
12:
11:
5:
372:
370:
362:
361:
359:Quantum states
356:
351:
341:
340:
336:
335:
311:
308:
307:
262:
261:
259:
256:
255:
254:
249:
244:
237:
234:
226:atomic nucleus
216:technology of
207:Spin (physics)
190:magnetic field
186:spectral lines
181:
178:
125:
124:
39:
37:
30:
24:
14:
13:
10:
9:
6:
4:
3:
2:
371:
360:
357:
355:
352:
350:
347:
346:
344:
334:
330:
326:
325:doublet state
322:
321:
316:
313:
312:
303:
299:
295:
291:
287:
283:
279:
275:
267:
264:
257:
253:
250:
248:
247:Triplet state
245:
243:
242:Singlet state
240:
239:
235:
233:
231:
227:
223:
219:
215:
210:
208:
204:
199:
195:
191:
187:
179:
177:
175:
172:
168:
164:
160:
156:
152:
148:
140:
136:
131:
121:
118:
110:
99:
96:
92:
89:
85:
82:
78:
75:
71:
68: –
67:
63:
62:Find sources:
56:
52:
46:
45:
40:This article
38:
34:
29:
28:
19:
349:Spectroscopy
318:
280:(1): 38–43.
277:
273:
266:
220:is based on
211:
198:spectroscopy
183:
150:
144:
113:
104:
94:
87:
80:
73:
61:
49:Please help
44:verification
41:
343:Categories
258:References
230:Rabi cycle
214:healthcare
77:newspapers
302:209418125
171:Lie group
294:31854979
236:See also
203:electron
107:May 2013
169:of the
151:doublet
141:states.
139:triplet
135:singlet
91:scholar
300:
292:
93:
86:
79:
72:
64:
315:IUPAC
298:S2CID
174:SU(2)
98:JSTOR
84:books
290:PMID
155:spin
149:, a
70:news
329:doi
327:".
282:doi
278:142
145:In
53:by
345::
317:,
296:.
288:.
276:.
176:.
331::
304:.
284::
120:)
114:(
109:)
105:(
95:·
88:·
81:·
74:·
47:.
20:)
Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.