Knowledge (XXG)

Heat of combustion

Source πŸ“

834:. The combustion of a stoichiometric mixture of fuel and oxidizer (e.g. two moles of hydrogen and one mole of oxygen) in a steel container at 25 Β°C (77 Β°F) is initiated by an ignition device and the reactions allowed to complete. When hydrogen and oxygen react during combustion, water vapor is produced. The vessel and its contents are then cooled to the original 25 Β°C and the higher heating value is determined as the heat released between identical initial and final temperatures. 686:) indicates the upper limit of the available thermal energy produced by a complete combustion of fuel. It is measured as a unit of energy per unit mass or volume of substance. The HHV is determined by bringing all the products of combustion back to the original pre-combustion temperature, including condensing any vapor produced. Such measurements often use a standard temperature of 25 Β°C (77 Β°F; 298 K). This is the same as the thermodynamic heat of combustion since the 3390: 3404: 732:) is another measure of available thermal energy produced by a combustion of fuel, measured as a unit of energy per unit mass or volume of substance. In contrast to the HHV, the LHV considers energy losses such as the energy used to vaporize water - although its exact definition is not uniformly agreed upon. One definition is simply to subtract the 873:). For hydrogen, the difference is much more significant as it includes the sensible heat of water vapor between 150 Β°C and 100 Β°C, the latent heat of condensation at 100 Β°C, and the sensible heat of the condensed water between 100 Β°C and 25 Β°C. In all, the higher heating value of hydrogen is 18.2% above its lower heating value (142 1096:
Engine manufacturers typically rate their engines fuel consumption by the lower heating values since the exhaust is never condensed in the engine, and doing this allows them to publish more attractive numbers than are used in conventional power plant terms. The conventional power industry had used
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The difference between HHV and LHV definitions causes endless confusion when quoters do not bother to state the convention being used. since there is typically a 10% difference between the two methods for a power plant burning natural gas. For simply benchmarking part of a reaction the LHV may be
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By convention, the (higher) heat of combustion is defined to be the heat released for the complete combustion of a compound in its standard state to form stable products in their standard states: hydrogen is converted to water (in its liquid state), carbon is converted to carbon dioxide gas, and
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The difference between the two heating values depends on the chemical composition of the fuel. In the case of pure carbon or carbon monoxide, the two heating values are almost identical, the difference being the sensible heat content of carbon dioxide between 150 Β°C and 25 Β°C
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HHV (high heat value) exclusively for decades, even though virtually all of these plants did not condense exhaust either. American consumers should be aware that the corresponding fuel-consumption figure based on the higher heating value will be somewhat higher.
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used for space heat). In other words, HHV assumes all the water component is in liquid state at the end of combustion (in product of combustion) and that heat delivered at temperatures below 150 Β°C (302 Β°F) can be put to use.
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The definition in which the combustion products are all returned to the reference temperature is more easily calculated from the higher heating value than when using other definitions and will in fact give a slightly different answer.
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change for the reaction assumes a common temperature of the compounds before and after combustion, in which case the water produced by combustion is condensed to a liquid. The higher heating value takes into account the
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and other reaction products is not recovered. It is useful in comparing fuels where condensation of the combustion products is impractical, or heat at a temperature below 150 Β°C (302 Β°F) cannot be put to use.
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Both HHV and LHV can be expressed in terms of AR (all moisture counted), MF and MAF (only water from combustion of hydrogen). AR, MF, and MAF are commonly used for indicating the heating values of coal:
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It gives 545 kJ/mole, whereas the value calculated from heats of formation is around 1561 kJ/mole. For glycerine trinitrate (nitroglycerine) it gives 0, though nitroglycerine does not actually combust.
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Most applications that burn fuel produce water vapor, which is unused and thus wastes its heat content. In such applications, the lower heating value must be used to give a 'benchmark' for the process.
3724:"The difference between LCV and HCV (or Lower and Higher Heating Value, or Net and Gross) is clearly understood by all energy engineers. There is no 'right' or 'wrong' definition. - Claverton Group" 3176:
There is no difference between the lower and higher heating values for the combustion of carbon, carbon monoxide and sulfur since no water is formed during the combustion of those substances.
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accounts for water in the exhaust leaving as vapor, as does LHV, but gross heating value also includes liquid water in the fuel prior to combustion. This value is important for fuels like
848:
Note: Higher heating value (HHV) is calculated with the product of water being in liquid form while lower heating value (LHV) is calculated with the product of water being in vapor form.
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of all combustion products minus the enthalpy of the fuel at the reference temperature (API research project 44 used 25 Β°C. GPSA currently uses 60 Β°F), minus the enthalpy of the
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Hosokai, Sou; Matsuoka, Koichi; Kuramoto, Koji; Suzuki, Yoshizo (1 November 2016). "Modification of Dulong's formula to estimate heating value of gas, liquid and solid fuels".
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There are two kinds of enthalpy of combustion, called high(er) and low(er) heat(ing) value, depending on how much the products are allowed to cool and whether compounds like
758:
Another definition of the LHV is the amount of heat released when the products are cooled to 150 Β°C (302 Β°F). This means that the latent heat of vaporization of
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of the products and reactants (though this approach is somewhat artificial since most heats of formation are typically calculated from measured heats of combustion)..
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Zwolinski and Wilhoit defined, in 1972, "gross" and "net" values for heats of combustion. In the gross definition the products are the most stable compounds, e.g.
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Dlugogorski, B. Z.; Mawhinney, J. R.; Duc, V. H. (1994). "The Measurement of Heat Release Rates by Oxygen Consumption Calorimetry in Fires Under Suppression".
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indicates that the fuel heating value has been measured after the fuel has been dried of all inherent moisture but still retaining its ash-forming minerals.
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The heating value of a fuel can be calculated with the results of ultimate analysis of fuel. From analysis, percentages of the combustibles in the fuel (
3767: 787:
Another definition, used by Gas Processors Suppliers Association (GPSA) and originally used by API (data collected for API research project 44), is the
3835: 3657: 1141:(dry and ash-free) indicates that the fuel heating value has been measured in the absence of inherent moisture- and ash-forming minerals. 3881: 3857: 743:
LHV calculations assume that the water component of a combustion process is in vapor state at the end of combustion, as opposed to the
1021:{\displaystyle \mathrm {HHV} =\mathrm {LHV} +H_{\mathrm {v} }\left({\frac {n_{\mathrm {H_{2}O,out} }}{n_{\mathrm {fuel,in} }}}\right)} 1071:
However, for true energy calculations in some specific cases, the higher heating value is correct. This is particularly relevant for
841:(LHV) is determined, cooling is stopped at 150 Β°C and the reaction heat is only partially recovered. The limit of 150 Β°C is based on 3896: 82: 3359:
The lower heating value of natural gas is normally about 90% of its higher heating value. This table is in Standard cubic metres (1
614:) are known. Since the heat of combustion of these elements is known, the heating value can be calculated using Dulong's Formula: 133: 889:
the higher heating value exceeds the lower heating value by about 10% and 7%, respectively, and for natural gas about 11%.
132:. Low heat values are calculated from high heat value test data. They may also be calculated as the difference between the 3423: 1121:(as received) indicates that the fuel heating value has been measured with all moisture- and ash-forming minerals present. 3438: 767: 3418: 3189: 1102: 655:
are the contents of carbon, hydrogen, oxygen, nitrogen, and sulfur on any (wet, dry or ash free) basis, respectively.
3363: 503:(l). In the net definition the products are the gases produced when the compound is burned in an open flame, e.g. 404:
Chlorine and sulfur are not quite standardized; they are usually assumed to convert to hydrogen chloride gas and
3663: 799:) at the reference temperature, minus the heat of vaporization of the vapor content of the combustion products. 3906: 3901: 755:) which assumes that all of the water in a combustion process is in a liquid state after a combustion process. 733: 692: 3802: 740:
O formed as a vapor that is released as a waste. The energy required to vaporize the water is therefore lost.
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calculations if only to avoid confusion, and in any case, the value or convention should be clearly stated.
2638: 2061: 432:, respectively, when the combustion is conducted in a bomb calorimeter containing some quantity of water. 191:
usually to a good approximation (Β±3%), though it gives poor results for some compounds such as (gaseous)
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that condense the water vapor produced by combustion, recovering heat which would otherwise be wasted.
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Air Quality Engineering, CE 218A, W. Nazaroff and R. Harley, University of California Berkeley, 2007
3628:"Theoretical Analysis of Waste Heat Recovery from an Internal Combustion Engine in a Hybrid Vehicle" 3886: 3453: 2042: 3488: 2104: 2023: 870: 43: 3514: 3831: 3653: 2142: 1076: 3784: 3749: 3696: 3607: 3549: 3395: 866: 129: 3473: 3458: 3433: 3107: 3007: 2864: 2657: 2453: 2004: 881:
MJ/kg). For hydrocarbons, the difference depends on the hydrogen content of the fuel. For
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in the combustion products, and is useful in calculating heating values for fuels where
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reports the following typical higher heating values per Standard cubic metre of gas:
3026: 2348: 1411: 1080: 858: 792: 429: 3748:. NIST Standard Reference Database Number 69. NIST Office of Data and Informatics. 3317: 3307: 2988: 2969: 2945: 2907: 2820: 2619: 2410: 2391: 2223: 2085: 1345: 1309: 700: 192: 3700: 128:
are allowed to condense. The high heat values are conventionally measured with a
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nitrogen is converted to nitrogen gas. That is, the heat of combustion, Ξ”
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BTU/lb values are calculated from MJ/kg (1 MJ/kg = 430 BTU/lb).
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Amount of heat released by combustion of a quantity of substance
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of the water from the higher heating value. This treats any H
552:(g). In both definitions the products for C, F, Cl and N are 703:
of the reaction products is practical (e.g., in a gas-fired
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released during the combustion of a specified amount of it.
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Higher heating values of natural gases from various sources
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at constant temperature. Examples: heat of vaporization or
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The higher heating value is experimentally determined in a
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and release heat. It may be expressed with the quantities:
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gas, respectively, or to dilute aqueous hydrochloric and
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or other organic molecule reacting with oxygen to form
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One definition of lower heating value, adopted by the
244:, is the heat of reaction of the following process: 901: 73:
released as heat when a substance undergoes complete
3768:"CDP Technical Note: Conversion of fuel data to MWh" 3370:Β°C), to convert to values per Normal cubic metre (1 770:(API), uses a reference temperature of 60 Β°F ( 1020: 3830:. Publication de l'Institut FranΓ§ais du PΓ©trole. 3648:. In Dwight E., Gray; Billings, Bruce H. (eds.). 3641:Zwolinski, Bruno J; Wilhoit, Randolf C. (1972). 1101:appropriate, but HHV should be used for overall 1686:Lower heating value for some organic compounds 861:exchange causes a change of temperature, while 1057:is the number of moles of water vaporized and 8: 3643:"Heats of formation and Heats of Combustion" 1433: 1151:Higher (HHV) and lower (LHV) heating values 892:A common method of relating HHV to LHV is: 3596:"Heats of combustion of organic compounds" 1064:is the number of moles of fuel combusted. 3611: 3553: 987: 986: 958: 953: 952: 946: 935: 934: 916: 902: 900: 744: 838: 228: 224: 220: 216: 3739: 3737: 3600:Bureau of Standards Journal of Research 3528:Schmidt-Rohr, Klaus (8 December 2015). 3506: 85:. The chemical reaction is typically a 3650:American Institute of Physics Handbook 1038:is the heat of vaporization of water, 3378:Β°C), multiply above table by 1.0549. 175:, the (higher) heat of combustion is 7: 3803:"Key World Energy Statistics (2016)" 213:, such as for glycerine dinitrate, 3867:. U.S. Department of Energy. 2011. 1006: 1003: 997: 994: 991: 988: 976: 973: 970: 964: 955: 936: 923: 920: 917: 909: 906: 903: 199:, and can be significantly off if 25: 3652:. McGraw-Hill. pp. 316–342. 3594:Kharasch, M.S. (February 1929). 3402: 3388: 852:Relation between heating values 663:The higher heating value (HHV; 3517:. Taylor & Francis Online. 1153:of some common fuels at 25 Β°C 716:The lower heating value (LHV; 1: 3534:Journal of Chemical Education 3424:Cost of electricity by source 3701:10.1016/j.fuproc.2016.06.040 3439:Energy conversion efficiency 1137:(moisture- and ash-free) or 768:American Petroleum Institute 3555:10.1021/acs.jchemed.5b00333 3419:Adiabatic flame temperature 3190:International Energy Agency 865:is added or subtracted for 693:latent heat of vaporization 151:For a fuel of composition C 3923: 3882:Engineering thermodynamics 3689:Fuel Processing Technology 1667: 1651: 1635: 1619: 1603: 1587: 1571: 1555: 1539: 1509:of some less common fuels 1486: 1468: 1450: 1428: 1402: 1380: 1362: 1344: 1326: 1308: 1289: 1270: 1251: 1232: 1213: 1194: 3063: 2963: 2882: 2697: 2509: 2428: 2385: 2342: 2160: 2079: 1960: 1727: 1160: 1157: 1146:Heat of combustion tables 111:energy/volume of the fuel 3897:Thermodynamic properties 3865:Biomass Energy Data Book 3744:Linstrom, Peter (2021). 3728:www.claverton-energy.com 826:Measuring heating values 1109:Accounting for moisture 3852:NIST Chemistry WebBook 3826:Guibet, J.-C. (1997). 3746:NIST Chemistry WebBook 3434:Energy content of fuel 2964:Aldehydes and ketones 2639:1,2,4-Trimethylbenzene 2062:2,2,4-Trimethylpentane 1022: 680:higher calorific value 18:Enthalpy of combustion 3828:Carburants et moteurs 3484:Mechanical efficiency 3429:Electrical efficiency 1507:Higher heating value 1085:flue-gas condensation 1023: 749:gross calorific value 726:lower calorific value 673:gross calorific value 436:Ways of determination 3613:10.6028/jres.002.007 3449:Energy value of coal 899: 745:higher heating value 734:heat of vaporization 659:Higher heating value 58:), is the amount of 3570:Fire Safety Science 3546:2015JChEd..92.2094S 3454:Exothermic reaction 2043:2,3-Dimethylpentane 1689: 1510: 1154: 1127:(moisture-free) or 839:lower heating value 812:Gross heating value 807:Gross heating value 718:net calorific value 712:Lower heating value 669:upper heating value 592:(g), respectively. 108:energy/mass of fuel 83:standard conditions 3489:Thermal efficiency 2306:2-Methyl-1-pentene 2105:Methylcyclopentane 2024:2,3-Dimethylbutane 1685: 1506: 1150: 1077:condensing boilers 1018: 3837:978-2-7108-0704-9 3659:978-0-07-001485-5 3540:(12): 2094–2099. 3168: 3167: 3151: 3070:Carbon (graphite) 2143:Methylcyclohexane 1688:(at 25 Β°C ) 1683: 1682: 1504: 1503: 1103:energy efficiency 1012: 867:phase transitions 134:heat of formation 16:(Redirected from 3914: 3868: 3862: 3841: 3814: 3813: 3807: 3799: 3793: 3792: 3789:webbook.nist.gov 3781: 3775: 3774: 3772: 3764: 3758: 3757: 3741: 3732: 3731: 3720: 3714: 3711: 3705: 3704: 3684: 3678: 3677: 3675: 3674: 3668: 3662:. 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3733: 3715: 3706: 3679: 3658: 3633: 3619: 3586: 3577: 3561: 3520: 3505: 3503: 3500: 3498: 3497: 3496:: heat density 3491: 3486: 3481: 3476: 3471: 3466: 3461: 3456: 3451: 3446: 3444:Energy density 3441: 3436: 3431: 3426: 3421: 3415: 3414: 3413: 3399: 3383: 3380: 3356: 3355: 3345: 3335: 3328:United Kingdom 3325: 3315: 3305: 3295: 3285: 3275: 3265: 3255: 3245: 3235: 3225: 3215: 3205: 3194: 3185: 3182: 3181: 3180: 3177: 3173: 3172: 3166: 3165: 3162: 3159: 3156: 3153: 3142: 3141: 3138: 3135: 3132: 3129: 3123: 3122: 3119: 3116: 3113: 3110: 3104: 3103: 3100: 3097: 3094: 3091: 3085: 3084: 3081: 3078: 3075: 3072: 3066: 3065: 3064:Other species 3061: 3060: 3057: 3054: 3051: 3048: 3042: 3041: 3038: 3035: 3032: 3029: 3023: 3022: 3019: 3016: 3013: 3010: 3004: 3003: 3000: 2997: 2994: 2991: 2985: 2984: 2981: 2978: 2975: 2972: 2966: 2965: 2961: 2960: 2957: 2954: 2951: 2948: 2942: 2941: 2938: 2935: 2932: 2929: 2927:Propoxypropane 2923: 2922: 2919: 2916: 2913: 2910: 2904: 2903: 2900: 2897: 2894: 2891: 2889:Methoxymethane 2885: 2884: 2880: 2879: 2876: 2873: 2870: 2867: 2861: 2860: 2857: 2854: 2851: 2848: 2839: 2838: 2835: 2832: 2829: 2826: 2817: 2816: 2813: 2810: 2807: 2804: 2798: 2797: 2794: 2791: 2788: 2785: 2776: 2775: 2772: 2769: 2766: 2763: 2757: 2756: 2753: 2750: 2747: 2744: 2738: 2737: 2734: 2731: 2728: 2725: 2719: 2718: 2715: 2712: 2709: 2706: 2700: 2699: 2695: 2694: 2691: 2688: 2685: 2682: 2676: 2675: 2672: 2669: 2666: 2663: 2661:-Propylbenzene 2654: 2653: 2650: 2647: 2644: 2641: 2635: 2634: 2631: 2628: 2625: 2622: 2616: 2615: 2612: 2609: 2606: 2603: 2594: 2593: 2590: 2587: 2584: 2581: 2572: 2571: 2568: 2565: 2562: 2559: 2550: 2549: 2546: 2543: 2540: 2537: 2531: 2530: 2527: 2524: 2521: 2518: 2512: 2511: 2507: 2506: 2503: 2500: 2497: 2494: 2488: 2487: 2484: 2481: 2478: 2475: 2469: 2468: 2465: 2462: 2459: 2456: 2450: 2449: 2446: 2443: 2440: 2437: 2431: 2430: 2426: 2425: 2422: 2419: 2416: 2413: 2407: 2406: 2403: 2400: 2397: 2394: 2388: 2387: 2383: 2382: 2379: 2376: 2373: 2370: 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1840: 1837: 1834: 1831: 1825: 1824: 1821: 1818: 1815: 1812: 1806: 1805: 1802: 1799: 1796: 1793: 1787: 1786: 1783: 1780: 1777: 1774: 1768: 1767: 1764: 1761: 1758: 1755: 1749: 1748: 1745: 1742: 1739: 1736: 1730: 1729: 1725: 1724: 1715: 1709: 1700: 1694: 1681: 1680: 1677: 1674: 1671: 1665: 1664: 1661: 1658: 1655: 1649: 1648: 1645: 1642: 1639: 1633: 1632: 1629: 1626: 1623: 1617: 1616: 1613: 1610: 1607: 1601: 1600: 1597: 1594: 1591: 1585: 1584: 1581: 1578: 1575: 1569: 1568: 1565: 1562: 1559: 1553: 1552: 1549: 1546: 1543: 1537: 1536: 1527: 1521: 1515: 1502: 1501: 1499: 1497: 1494: 1491: 1484: 1483: 1481: 1479: 1476: 1473: 1466: 1465: 1462: 1460: 1457: 1454: 1448: 1447: 1445: 1443: 1440: 1437: 1426: 1425: 1423: 1421: 1418: 1415: 1400: 1399: 1397: 1395: 1392: 1389: 1378: 1377: 1374: 1372: 1369: 1366: 1360: 1359: 1356: 1354: 1351: 1348: 1342: 1341: 1338: 1336: 1333: 1330: 1324: 1323: 1320: 1318: 1315: 1312: 1306: 1305: 1302: 1299: 1296: 1293: 1287: 1286: 1283: 1280: 1277: 1274: 1268: 1267: 1264: 1261: 1258: 1255: 1249: 1248: 1245: 1242: 1239: 1236: 1230: 1229: 1226: 1223: 1220: 1217: 1211: 1210: 1207: 1204: 1201: 1198: 1192: 1191: 1188: 1179: 1173: 1166: 1165: 1162: 1159: 1147: 1144: 1143: 1142: 1132: 1122: 1110: 1107: 1093: 1092:Usage of terms 1090: 1089: 1088: 1069: 1061: 1048: 1042: 1035: 1029: 1028: 1016: 1008: 1005: 1002: 999: 996: 993: 990: 985: 978: 975: 972: 969: 966: 961: 957: 951: 945: 938: 933: 929: 925: 922: 919: 915: 911: 908: 905: 871:heat of fusion 853: 850: 827: 824: 808: 805: 796: 793:stoichiometric 747:(HHV) (a.k.a. 737: 713: 710: 660: 657: 652: 648: 644: 640: 636: 630: 626: 622: 618: 596: 586: 574: 558: 546: 534: 522: 509: 497: 488: 476: 464: 451: 442: 439: 437: 434: 430:sulfuric acids 422: 410: 402: 401: 394: 366: 343: 328: 286: 275: 264: 253: 241: 177:419 kJ/mol Γ— ( 170: 164: 158: 152: 143: 121: 113: 112: 109: 106: 91:carbon dioxide 26: 24: 14: 13: 10: 9: 6: 4: 3: 2: 3919: 3908: 3905: 3903: 3900: 3898: 3895: 3893: 3890: 3888: 3885: 3883: 3880: 3879: 3877: 3866: 3859: 3855: 3853: 3850: 3849: 3845: 3839: 3833: 3829: 3824: 3823: 3819: 3811: 3804: 3798: 3795: 3790: 3786: 3780: 3777: 3769: 3763: 3760: 3755: 3751: 3747: 3740: 3738: 3734: 3729: 3725: 3719: 3716: 3710: 3707: 3702: 3698: 3694: 3690: 3683: 3680: 3669:on 2021-08-06 3665: 3661: 3655: 3651: 3644: 3637: 3634: 3629: 3623: 3620: 3614: 3609: 3605: 3601: 3597: 3590: 3587: 3581: 3578: 3574: 3571: 3565: 3562: 3556: 3551: 3547: 3543: 3539: 3535: 3531: 3524: 3521: 3516: 3510: 3507: 3501: 3495: 3492: 3490: 3487: 3485: 3482: 3480: 3477: 3475: 3472: 3470: 3467: 3465: 3462: 3460: 3457: 3455: 3452: 3450: 3447: 3445: 3442: 3440: 3437: 3435: 3432: 3430: 3427: 3425: 3422: 3420: 3417: 3416: 3411: 3410:Energy portal 3405: 3400: 3397: 3386: 3381: 3379: 3365: 3349: 3346: 3339: 3338:United States 3336: 3329: 3326: 3319: 3316: 3309: 3306: 3299: 3296: 3289: 3286: 3279: 3276: 3269: 3266: 3259: 3256: 3249: 3246: 3239: 3236: 3229: 3226: 3219: 3216: 3209: 3206: 3199: 3196: 3195: 3193: 3191: 3183: 3178: 3175: 3174: 3170: 3169: 3163: 3160: 3157: 3154: 3147: 3144: 3143: 3139: 3136: 3133: 3130: 3128: 3125: 3124: 3120: 3117: 3114: 3111: 3109: 3106: 3105: 3101: 3098: 3095: 3092: 3090: 3087: 3086: 3082: 3079: 3076: 3073: 3071: 3068: 3067: 3062: 3058: 3055: 3052: 3049: 3047: 3044: 3043: 3039: 3036: 3033: 3030: 3028: 3027:Butyraldehyde 3025: 3024: 3020: 3017: 3014: 3011: 3009: 3006: 3005: 3001: 2998: 2995: 2992: 2990: 2987: 2986: 2982: 2979: 2976: 2973: 2971: 2968: 2967: 2962: 2958: 2955: 2952: 2949: 2947: 2944: 2943: 2939: 2936: 2933: 2930: 2928: 2925: 2924: 2920: 2917: 2914: 2911: 2909: 2906: 2905: 2901: 2898: 2895: 2892: 2890: 2887: 2886: 2881: 2877: 2874: 2871: 2868: 2866: 2863: 2862: 2858: 2855: 2852: 2849: 2847: 2845: 2841: 2840: 2836: 2833: 2830: 2827: 2825: 2823: 2819: 2818: 2814: 2811: 2808: 2805: 2803: 2800: 2799: 2795: 2792: 2789: 2786: 2784: 2782: 2778: 2777: 2773: 2770: 2767: 2764: 2762: 2759: 2758: 2754: 2751: 2748: 2745: 2743: 2740: 2739: 2735: 2732: 2729: 2726: 2724: 2721: 2720: 2716: 2713: 2710: 2707: 2705: 2702: 2701: 2696: 2692: 2689: 2686: 2683: 2681: 2678: 2677: 2673: 2670: 2667: 2664: 2662: 2660: 2656: 2655: 2651: 2648: 2645: 2642: 2640: 2637: 2636: 2632: 2629: 2626: 2623: 2621: 2618: 2617: 2613: 2610: 2607: 2604: 2602: 2600: 2596: 2595: 2591: 2588: 2585: 2582: 2580: 2578: 2574: 2573: 2569: 2566: 2563: 2560: 2558: 2556: 2552: 2551: 2547: 2544: 2541: 2538: 2536: 2533: 2532: 2528: 2525: 2522: 2519: 2517: 2514: 2513: 2508: 2504: 2501: 2498: 2495: 2493: 2490: 2489: 2485: 2482: 2479: 2476: 2474: 2471: 2470: 2466: 2463: 2460: 2457: 2455: 2452: 2451: 2447: 2444: 2441: 2438: 2436: 2433: 2432: 2427: 2423: 2420: 2417: 2414: 2412: 2409: 2408: 2404: 2401: 2398: 2395: 2393: 2390: 2389: 2384: 2380: 2377: 2374: 2371: 2369: 2366: 2365: 2361: 2358: 2355: 2352: 2350: 2349:1,3-Butadiene 2347: 2346: 2341: 2337: 2334: 2331: 2328: 2326: 2323: 2322: 2318: 2315: 2312: 2309: 2307: 2304: 2303: 2299: 2296: 2293: 2290: 2288: 2285: 2284: 2280: 2277: 2274: 2271: 2269: 2266: 2265: 2261: 2258: 2255: 2252: 2250: 2248: 2244: 2243: 2239: 2236: 2233: 2230: 2228: 2226: 2222: 2221: 2217: 2214: 2211: 2208: 2206: 2203: 2202: 2198: 2195: 2192: 2189: 2187: 2184: 2183: 2179: 2176: 2173: 2170: 2168: 2165: 2164: 2159: 2155: 2152: 2149: 2146: 2144: 2141: 2140: 2136: 2133: 2130: 2127: 2125: 2122: 2121: 2117: 2114: 2111: 2108: 2106: 2103: 2102: 2098: 2095: 2092: 2089: 2087: 2084: 2083: 2078: 2074: 2071: 2068: 2065: 2063: 2060: 2059: 2055: 2052: 2049: 2046: 2044: 2041: 2040: 2036: 2033: 2030: 2027: 2025: 2022: 2021: 2017: 2014: 2011: 2008: 2006: 2003: 2002: 1998: 1995: 1992: 1989: 1987: 1984: 1983: 1979: 1976: 1973: 1970: 1968: 1965: 1964: 1961:Isoparaffins 1959: 1955: 1952: 1949: 1946: 1944: 1941: 1940: 1936: 1933: 1930: 1927: 1925: 1922: 1921: 1917: 1914: 1911: 1908: 1906: 1903: 1902: 1898: 1895: 1892: 1889: 1887: 1884: 1883: 1879: 1876: 1873: 1870: 1868: 1865: 1864: 1860: 1857: 1854: 1851: 1849: 1846: 1845: 1841: 1838: 1835: 1832: 1830: 1827: 1826: 1822: 1819: 1816: 1813: 1811: 1808: 1807: 1803: 1800: 1797: 1794: 1792: 1789: 1788: 1784: 1781: 1778: 1775: 1773: 1770: 1769: 1765: 1762: 1759: 1756: 1754: 1751: 1750: 1746: 1743: 1740: 1737: 1735: 1732: 1731: 1726: 1723: 1719: 1716: 1713: 1710: 1708: 1704: 1701: 1698: 1695: 1692: 1691: 1678: 1675: 1672: 1670: 1666: 1662: 1659: 1656: 1654: 1650: 1646: 1643: 1640: 1638: 1634: 1630: 1627: 1624: 1622: 1618: 1614: 1611: 1608: 1606: 1602: 1598: 1595: 1592: 1590: 1586: 1582: 1579: 1576: 1574: 1570: 1566: 1563: 1560: 1558: 1554: 1550: 1547: 1544: 1542: 1538: 1535: 1531: 1528: 1525: 1522: 1519: 1516: 1513: 1512: 1500: 1498: 1495: 1492: 1489: 1485: 1482: 1480: 1477: 1474: 1471: 1467: 1463: 1461: 1458: 1455: 1453: 1449: 1446: 1444: 1441: 1438: 1435: 1431: 1427: 1424: 1422: 1419: 1416: 1413: 1409: 1405: 1401: 1398: 1396: 1393: 1390: 1387: 1383: 1379: 1375: 1373: 1370: 1367: 1365: 1361: 1357: 1355: 1352: 1349: 1347: 1343: 1339: 1337: 1334: 1331: 1329: 1325: 1321: 1319: 1316: 1313: 1311: 1307: 1303: 1300: 1297: 1294: 1292: 1288: 1284: 1281: 1278: 1275: 1273: 1269: 1265: 1262: 1259: 1256: 1254: 1250: 1246: 1243: 1240: 1237: 1235: 1231: 1227: 1224: 1221: 1218: 1216: 1212: 1208: 1205: 1202: 1199: 1197: 1193: 1189: 1187: 1183: 1180: 1177: 1174: 1171: 1168: 1167: 1163: 1156: 1145: 1140: 1136: 1133: 1130: 1126: 1123: 1120: 1117: 1116: 1115: 1108: 1106: 1104: 1098: 1091: 1086: 1082: 1078: 1074: 1070: 1067: 1066: 1065: 1060: 1041: 1034: 1014: 1000: 983: 967: 959: 949: 943: 931: 927: 913: 895: 894: 893: 890: 888: 884: 877:MJ/kg vs. 120 872: 868: 864: 860: 859:sensible heat 851: 849: 846: 844: 840: 835: 833: 825: 823: 821: 817: 813: 806: 804: 800: 794: 790: 785: 769: 764: 761: 756: 754: 750: 746: 741: 735: 731: 727: 723: 719: 711: 709: 706: 702: 698: 694: 689: 685: 681: 677: 674: 670: 666: 658: 656: 633: 615: 613: 609: 605: 600: 599: 593: 441:Gross and net 440: 435: 433: 431: 382: 376: 354: 337: 315: 303: 297: 289: 278: 267: 256: 247: 246: 245: 239: 233: 211: 207: 203: 198: 194: 188: 184: 180: 173: 167: 161: 155: 149: 139: 135: 131: 110: 107: 104: 100: 99: 98: 96: 92: 88: 84: 80: 76: 72: 69:is the total 68: 63: 61: 57: 53: 49: 45: 41: 37: 33: 32:heating value 19: 3864: 3827: 3809: 3797: 3788: 3779: 3762: 3745: 3727: 3718: 3709: 3692: 3688: 3682: 3671:. Retrieved 3664:the original 3649: 3636: 3622: 3603: 3599: 3589: 3580: 3572: 3569: 3564: 3537: 3533: 3523: 3509: 3358: 3318:Turkmenistan 3308:Saudi Arabia 3187: 2989:Acetaldehyde 2970:Formaldehyde 2946:Butoxybutane 2908:Ethoxyethane 2843: 2821: 2780: 2658: 2620:Ethylbenzene 2598: 2576: 2554: 2411:Nitropropane 2392:Nitromethane 2246: 2224: 2161:Monoolefins 2086:Cyclopentane 1346:Jet kerosene 1310:Paraffin wax 1138: 1134: 1128: 1124: 1118: 1112: 1099: 1095: 1081:power plants 1058: 1039: 1032: 1030: 891: 855: 847: 836: 829: 811: 810: 801: 786: 765: 757: 752: 748: 742: 729: 725: 721: 717: 715: 701:condensation 683: 679: 675: 672: 668: 665:gross energy 664: 662: 634: 617:HHV = 33.87m 616: 601: 595: 594: 444: 403: 380: 374: 352: 335: 313: 301: 295: 287: 276: 265: 254: 237: 234: 209: 205: 201: 193:formaldehyde 186: 182: 178: 171: 165: 159: 153: 150: 137: 114: 66: 64: 46:, usually a 39: 36:energy value 35: 31: 29: 3695:: 399–405. 3494:Wobbe index 3469:Food energy 3258:Netherlands 2761:Isopropanol 2429:Acetylenes 2124:Cyclohexane 2080:Naphthenes 1073:natural gas 863:latent heat 845:dew-point. 784: Β°C). 629:Γ· 8) + 9.4m 87:hydrocarbon 56:food energy 3887:Combustion 3876:Categories 3785:"Methanal" 3673:2021-08-06 3606:(2): 359. 3502:References 3348:Uzbekistan 3208:Bangladesh 2802:Isobutanol 2742:1-Propanol 2510:Aromatics 2343:Diolefins 1986:Isopentane 1573:1-Propanol 1386:anthracite 294:(std.) + ( 75:combustion 3479:ISO 15971 3238:Indonesia 2878:2,769.3? 2846:-Pentanol 2698:Alcohols 2492:1-Pentyne 2435:Acetylene 2287:1-Pentene 2268:Isobutene 2249:-2-Butene 2227:-2-Butene 2186:Propylene 2118:3,756.6? 1967:Isobutane 1637:Hydrazine 1589:Acetylene 1452:Wood fuel 837:When the 795:oxygen (O 621:+ 122.3(m 44:substance 3630:. Jstor. 3382:See also 3278:Pakistan 3093:120.971 3089:Hydrogen 2983:570.78 2959:4,922.4 2940:3,568.0 2921:2,510.2 2902:1,322.3 2875:13,509? 2869:31.416? 2859:3,061.2 2837:2,415.3 2824:-Butanol 2815:2,442.9 2796:2,501.6 2783:-Butanol 2774:1,829.9 2755:1,843.9 2736:1,230.1 2704:Methanol 2473:1-Butyne 2368:Isoprene 2325:1-Hexene 2205:1-Butene 2167:Ethylene 2156:4,259.5 2137:3,656.8 2115:19,193? 2109:44.636? 2099:3,129.0 2075:5,061.5 2056:4,458.5 2037:3,848.7 2018:3,850.7 1999:3,264.1 1980:2,651.0 1956:7,519.6 1943:Dodecane 1937:6,908.0 1924:Undecane 1918:6,294.5 1899:5,683.3 1880:5,074.9 1861:4,465.8 1842:3,856.7 1823:3,272.6 1804:2,659.3 1785:2,044.2 1766:1,437.2 1728:Alkanes 1663:4,200.0 1653:Hexamine 1541:Methanol 1328:Kerosene 1196:Hydrogen 883:gasoline 843:acid gas 789:enthalpy 753:gross CV 688:enthalpy 608:hydrogen 580:(g) and 540:(g) and 482:(s) and 3810:iea.org 3542:Bibcode 3350:: 37.89 3340:: 38.42 3330:: 39.71 3320:: 37.89 3310:: 38.00 3300:: 38.23 3290:: 41.40 3280:: 34.90 3270:: 39.24 3260:: 33.32 3250:: 39.36 3240:: 40.60 3230:: 38.93 3220:: 39.00 3210:: 36.00 3200:: 39.57 3198:Algeria 3164:293.82 3140:317.56 3131:18.646 3127:Ammonia 3121:283.24 3112:10.112 3099:52,017 3074:32.808 3050:28.548 3046:Acetone 3031:31.610 3012:28.889 2993:24.156 2974:17.259 2956:16,253 2950:37.798 2937:15,633 2931:36.355 2918:14,563 2912:33.867 2899:12,342 2893:28.703 2883:Ethers 2872:35.64? 2856:14,933 2850:34.727 2834:14,012 2828:32.587 2812:14,172 2806:32.959 2793:14,222 2787:33.075 2771:13,092 2765:30.447 2752:13,192 2746:30.680 2733:12,412 2723:Ethanol 2708:19.930 2684:41.217 2665:41.193 2643:40.984 2624:40.938 2605:40.798 2601:-Xylene 2583:40.961 2579:-Xylene 2561:40.961 2557:-Xylene 2539:40.589 2535:Toluene 2520:40.170 2516:Benzene 2496:45.217 2477:45.590 2458:46.194 2439:48.241 2415:20.693 2396:10.513 2372:44.078 2353:44.613 2329:44.426 2310:44.799 2291:45.031 2272:45.055 2253:45.124 2231:45.194 2209:45.334 2190:45.799 2171:47.195 2153:18,653 2147:43.380 2134:18,684 2128:43.450 2112:33.43? 2096:19,193 2090:44.636 2072:19,053 2066:44.310 2053:19,133 2047:44.496 2034:19,203 2028:44.659 2015:19,213 2009:44.682 1996:19,454 1990:45.241 1977:19,614 1971:45.613 1953:18,983 1947:44.147 1934:19,003 1928:44.194 1915:19,023 1909:44.240 1896:19,054 1890:44.311 1877:19,104 1871:44.427 1858:19,163 1852:44.566 1848:Heptane 1839:19,504 1833:44.752 1820:21,706 1814:45.357 1810:Pentane 1801:19,673 1795:45.752 1782:19,934 1776:46.357 1772:Propane 1763:20,551 1757:47.794 1747:802.34 1744:21,504 1738:50.009 1734:Methane 1621:Ammonia 1605:Benzene 1557:Ethanol 1408:lignite 1291:Pentane 1253:Propane 1215:Methane 1209:119.96 1062:fuel,in 779:⁄ 651:, and m 635:where m 384:⁄ 356:⁄ 317:⁄ 305:⁄ 105:of fuel 101:energy/ 42:) of a 3834:  3656:  3575:: 877. 3376:  3374:atm, 0 3372:  3368:  3361:  3352:  3342:  3332:  3322:  3312:  3302:  3298:Russia 3292:  3282:  3272:  3268:Norway 3262:  3252:  3242:  3232:  3222:  3218:Canada 3212:  3202:  3161:3,940 3155:9.163 3146:Sulfur 3137:8,018 3118:4,348 3053:22.62 2953:28.88 2934:26.76 2915:24.16 2853:28.28 2831:25.45 2809:26.43 2790:26.79 2768:23.93 2749:24.65 2730:22.77 2727:26.70 2717:638.6 2714:8,570 2711:15.78 2680:Cumene 2150:33.40 2131:33.85 2093:33.52 2069:30.49 2050:30.92 2031:29.56 2012:29.18 1993:27.87 1950:33.11 1931:32.70 1912:33.29 1905:Decane 1893:31.82 1886:Nonane 1867:Octane 1855:30.48 1836:29.30 1829:Hexane 1817:28.39 1791:Butane 1753:Ethane 1679:393.5 1676:14,100 1669:Carbon 1660:12,900 1647:622.0 1631:382.6 1615:3,268 1612:18,000 1599:1,300 1596:21,500 1583:2,020 1580:14,500 1567:1,367 1564:12,800 1490:(damp) 1394:14,000 1371:19,300 1364:Diesel 1340:43.00 1335:19,862 1322:41.50 1317:19,900 1304:45.35 1298:21,876 1285:45.75 1279:20,900 1272:Butane 1266:46.35 1260:21,700 1247:47.62 1241:22,400 1234:Ethane 1228:50.00 1222:23,900 1203:61,000 1200:141.80 1190:MJ/kg 1031:where 887:diesel 879:  875:  705:boiler 612:sulfur 604:carbon 349:(g) + 334:(g) β†’ 185:βˆ’ 0.5 181:+ 0.3 81:under 79:oxygen 71:energy 3892:Fuels 3861:(PDF) 3806:(PDF) 3771:(PDF) 3667:(PDF) 3646:(PDF) 3354:MJ/Sm 3344:MJ/Sm 3334:MJ/Sm 3324:MJ/Sm 3314:MJ/Sm 3304:MJ/Sm 3294:MJ/Sm 3288:Qatar 3284:MJ/Sm 3274:MJ/Sm 3264:MJ/Sm 3254:MJ/Sm 3244:MJ/Sm 3234:MJ/Sm 3228:China 3224:MJ/Sm 3214:MJ/Sm 3204:MJ/Sm 3150:solid 2247:trans 1779:25.3 1693:Fuel 1644:8,370 1628:9,690 1548:9,800 1496:2,500 1478:6,500 1475:15.00 1472:(dry) 1464:17.0 1459:6,400 1442:8,700 1439:21.70 1420:6,500 1417:15.00 1391:32.50 1376:43.4 1368:44.80 1358:44.1 1350:46.42 1332:46.20 1314:46.00 1301:3,509 1295:48.60 1282:2,877 1276:49.50 1263:2,220 1257:50.35 1244:1,560 1238:51.90 1219:55.50 1158:Fuel 1083:with 760:water 724:, or 697:water 678:, or 568:(g), 564:(g), 528:(g), 516:(g), 470:(l), 458:(l), 208:> 95:water 77:with 54:(see 3832:ISBN 3654:ISBN 3573:1007 3464:Fire 3366:, 15 3248:Iran 3188:The 3171:Note 3102:244 3096:1.8 2822:tert 1741:6.9 1714:/lb 1699:/kg 1673:32.8 1657:30.0 1641:19.4 1625:22.5 1609:41.8 1593:49.9 1577:33.6 1561:29.7 1551:726 1545:22.7 1514:Fuel 1493:6.00 1488:Peat 1470:Peat 1456:16.0 1430:Wood 1404:Coal 1382:Coal 1178:/lb 1172:/kg 1164:LHV 1161:HHV 1079:and 1055:,out 885:and 820:coal 816:wood 377:) + 242:comb 195:and 103:mole 93:and 65:The 60:heat 52:food 48:fuel 34:(or 30:The 3750:doi 3697:doi 3693:152 3608:doi 3550:doi 3364:atm 2225:cis 1722:mol 1712:BTU 1534:mol 1526:/lb 1524:BTU 1520:/kg 1434:MAF 1412:USA 1225:890 1206:286 1186:mol 1176:BTU 1139:DAF 1135:MAF 1129:dry 818:or 751:or 730:LCV 722:NCV 695:of 684:HCV 676:GCV 647:, m 643:, m 639:, m 625:- m 416:or 400:(g) 50:or 38:or 3878:: 3863:. 3808:. 3787:. 3736:^ 3726:. 3691:. 3602:. 3598:. 3548:. 3538:92 3536:. 3532:. 3158:β€” 3152:) 3134:β€” 3115:β€” 3083:β€” 3080:β€” 3077:β€” 3059:β€” 3056:β€” 3040:β€” 3037:β€” 3034:β€” 3021:β€” 3018:β€” 3015:β€” 3002:β€” 2999:β€” 2996:β€” 2980:β€” 2977:β€” 2896:β€” 2693:β€” 2690:β€” 2687:β€” 2674:β€” 2671:β€” 2668:β€” 2652:β€” 2649:β€” 2646:β€” 2633:β€” 2630:β€” 2627:β€” 2614:β€” 2611:β€” 2608:β€” 2592:β€” 2589:β€” 2586:β€” 2570:β€” 2567:β€” 2564:β€” 2548:β€” 2545:β€” 2542:β€” 2529:β€” 2526:β€” 2523:β€” 2505:β€” 2502:β€” 2499:β€” 2486:β€” 2483:β€” 2480:β€” 2467:β€” 2464:β€” 2461:β€” 2448:β€” 2445:β€” 2442:β€” 2424:β€” 2421:β€” 2418:β€” 2405:β€” 2402:β€” 2399:β€” 2381:β€” 2378:β€” 2375:- 2362:β€” 2359:β€” 2356:β€” 2338:β€” 2335:β€” 2332:β€” 2319:β€” 2316:β€” 2313:β€” 2300:β€” 2297:β€” 2294:β€” 2281:β€” 2278:β€” 2275:β€” 2262:β€” 2259:β€” 2256:β€” 2240:β€” 2237:β€” 2234:β€” 2218:β€” 2215:β€” 2212:β€” 2199:β€” 2196:β€” 2193:β€” 2180:β€” 2177:β€” 2174:β€” 1974:β€” 1874:β€” 1798:β€” 1760:β€” 1718:kJ 1703:MJ 1697:MJ 1530:kJ 1518:MJ 1410:- 1182:kJ 1170:MJ 1125:MF 1119:AR 772:15 728:; 720:; 682:; 671:, 667:, 610:, 606:, 570:Cl 566:HF 554:CO 542:SO 518:Br 493:SO 460:Br 418:SO 406:SO 339:CO 322:) 310:- 298:+ 232:. 204:+ 3840:. 3812:. 3791:. 3773:. 3756:. 3752:: 3730:. 3703:. 3699:: 3676:. 3616:. 3610:: 3604:2 3558:. 3552:: 3544:: 3148:( 2844:n 2781:n 2659:n 2599:p 2577:m 2555:o 1720:/ 1707:L 1705:/ 1532:/ 1436:) 1432:( 1414:) 1406:( 1388:) 1384:( 1353:- 1184:/ 1059:n 1053:O 1049:2 1044:H 1040:n 1036:v 1033:H 1015:) 1007:n 1004:i 1001:, 998:l 995:e 992:u 989:f 984:n 977:t 974:u 971:o 968:, 965:O 960:2 956:H 950:n 944:( 937:v 932:H 928:+ 924:V 921:H 918:L 914:= 910:V 907:H 904:H 857:( 797:2 781:9 777:5 774:+ 738:2 653:S 649:N 645:O 641:H 637:C 631:S 627:O 623:H 619:C 587:2 582:N 575:2 559:2 547:2 535:2 530:I 523:2 514:O 510:2 505:H 498:4 489:2 484:H 477:2 472:I 465:2 456:O 452:2 447:H 423:3 411:2 395:2 390:N 386:2 381:n 375:l 373:( 371:O 367:2 362:H 358:2 353:h 344:2 336:c 329:2 324:O 319:2 314:o 307:4 302:h 296:c 288:o 282:O 277:n 271:N 266:h 260:H 255:c 249:C 240:Β° 238:H 229:2 227:N 225:7 223:O 221:6 219:H 217:3 215:C 210:c 206:n 202:o 189:) 187:o 183:h 179:c 172:n 169:N 166:o 163:O 160:h 157:H 154:c 144:f 138:H 136:Ξ” 126:O 122:2 117:H 20:)

Index

Enthalpy of combustion
substance
fuel
food
food energy
heat
energy
combustion
oxygen
standard conditions
hydrocarbon
carbon dioxide
water
mole
bomb calorimeter
heat of formation
formaldehyde
carbon monoxide
sulfuric acids
carbon
hydrogen
sulfur
enthalpy
latent heat of vaporization
water
condensation
boiler
heat of vaporization
higher heating value
water

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