Knowledge (XXG)

Guanidine nitrate

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The compound is a hazardous substance, being an explosive and containing an oxidant (nitrate). It is also harmful to the eyes, skin, and respiratory tract.
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Thomas Güthner, Bernd Mertschenk and Bernd Schulz "Guanidine and Derivatives" in Ullmann's Encyclopedia of Industrial Chemistry, 2006, Wiley-VCH, Weinheim.
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1000 lbf/in (700 kPa) chamber pressure, 14.7 lbf/in (101 kPa) exit pressure, shifting equilibrium theoretical performance, calculated in ProPEP.
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E.-C. Koch, Insensitive High Explosives: III. Nitroguanidine - Synthesis - Structure - Spectroscopy- Sensitiveness,
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The chemical reaction used to deploy airbags has evolved, but one iteration resulted in massive recalls
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Guanidine nitrate's explosive decomposition is given by the following equation:
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Except where otherwise noted, data are given for materials in their
486: 961:{\displaystyle {\ce {NO3 (s) -> 3 H2O (g) + 2 N2 (g) + C (s)}}} 502: 195: 101: 91: 768:, guanidine nitrate is produced industrially by the reaction of 608: 980:. It is less toxic than the mixture used in older airbags of 976:
Guanidine nitrate is used as the gas generator in automobile
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https://onlinelibrary.wiley.com/doi/10.1002/prep.201800253
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InChI=1S/CH5N3.HNO3/c2*2-1(3)4/h(H5,2,3,4);(H,2,3,4)
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InChI=1/CH5N3.HNO3/c2*2-1(3)4/h(H5,2,3,4);(H,2,3,4)
960: 183: 635: 77: 8: 732:is the chemical compound with the formula NO 262: 143: 121: 22: 1077: 1075: 946: 929: 925: 920: 915: 898: 891: 886: 881: 864: 860: 855: 843: 838: 830: 825: 817: 809: 808: 806: 219: 1048: 1033: 318: 283: 258: 1134:Halford, Bethany (November 15, 2022). 392:216 °C (421 °F; 489 K) 134: 290:Key: CNUNWZZSUJPAHX-UHFFFAOYSA-N 7: 300:Key: CNUNWZZSUJPAHX-UHFFFAOYAZ 174: 14: 1162: 695: 452: 447: 442: 402:Decomposes commencing at 240 °C 38: 29: 1141:Chemical & Engineering News 691:(at 25 °C , 100 kPa). 953: 947: 936: 930: 905: 899: 875: 871: 865: 847: 834: 818: 810: 795:of 177 seconds (1.7 kN·s/kg). 1: 1087:10.1002/14356007.a12_545.pub2 1057:Propellants Explos. Pyrotech. 740:, fuel in pyrotechnics and 1242: 15: 752:Production and properties 685: 423: 418: 329: 309: 274: 61: 51: 46: 37: 28: 515:Precautionary statements 16:Not to be confused with 760:formed by neutralizing 744:. Its correct name is 962: 779:It has been used as a 772:(or calcium salt) and 642: 1211:Guanidinium compounds 963: 641: 805: 624:(fire diamond) 1226:Explosive chemicals 928: 894: 863: 846: 833: 756:Although it is the 746:guanidinium nitrate 409:Solubility in water 364:122.1 56:Guanidinium nitrate 25: 1193:2004-05-05 at the 1107:The New York Times 958: 916: 882: 851: 821: 816: 718:Infobox references 643: 24:Guanidine nitrate 23: 1188:Guanidine Nitrate 986:potassium nitrate 952: 945: 935: 919: 904: 897: 885: 870: 854: 824: 815: 730:Guanidine nitrate 726:Chemical compound 724: 723: 674:Safety data sheet 477:Hazard statements 414:160 g/L at 20 °C 321:C(=N)(N)N.(=O)(O) 243:CompTox Dashboard 103:Interactive image 1233: 1168: 1167: 1166: 1160: 1155: 1153: 1131: 1125: 1124: 1122: 1121: 1095: 1089: 1079: 1070: 1053: 1041: 1038: 1006:ammonium nitrate 967: 965: 964: 959: 957: 956: 950: 943: 939: 933: 927: 924: 917: 908: 902: 895: 893: 890: 883: 874: 868: 862: 859: 852: 850: 845: 842: 837: 832: 829: 822: 813: 793:specific impulse 774:ammonium nitrate 708: 702: 699: 698: 663: 656: 649: 634: 614: 610: 606: 602: 598: 594: 590: 586: 582: 578: 574: 570: 566: 562: 558: 554: 550: 546: 542: 538: 534: 530: 526: 522: 508: 504: 500: 496: 492: 488: 484: 456: 451: 446: 337:Chemical formula 267: 266: 251: 249: 223: 187: 176: 155: 147: 136: 125: 105: 81: 42: 33: 26: 1241: 1240: 1236: 1235: 1234: 1232: 1231: 1230: 1201: 1200: 1195:Wayback Machine 1177: 1172: 1171: 1161: 1151: 1149: 1133: 1132: 1128: 1119: 1117: 1099:Tabuchi, Hiroko 1097: 1096: 1092: 1080: 1073: 1054: 1050: 1045: 1044: 1039: 1035: 1030: 1022: 1015: 1011: 1003: 999: 995: 974: 803: 802: 789:model airplanes 754: 735: 727: 720: 715: 714: 713:  ?) 704: 700: 696: 692: 668: 667: 666: 665: 658: 651: 644: 640: 632: 517: 479: 465: 439: 411: 353: 349: 345: 339: 325: 322: 317: 316: 305: 302: 301: 298: 292: 291: 288: 282: 281: 270: 252: 245: 226: 206: 190: 177: 165: 128: 108: 95: 84: 71: 57: 21: 12: 11: 5: 1239: 1237: 1229: 1228: 1223: 1218: 1213: 1203: 1202: 1199: 1198: 1184: 1176: 1175:External links 1173: 1170: 1169: 1126: 1101:(2016-08-26). 1090: 1071: 1047: 1046: 1043: 1042: 1032: 1031: 1029: 1026: 1021: 1018: 1013: 1009: 1001: 997: 993: 973: 970: 969: 968: 955: 949: 942: 938: 932: 923: 914: 911: 907: 901: 889: 880: 877: 873: 867: 858: 849: 841: 836: 828: 820: 812: 781:monopropellant 753: 750: 742:gas generators 738:nitroguanidine 733: 725: 722: 721: 716: 694: 693: 689:standard state 686: 683: 682: 677: 670: 669: 659: 652: 645: 630: 629: 628: 627: 625: 616: 615: 569:P305+P351+P338 518: 513: 510: 509: 480: 475: 472: 471: 466: 461: 458: 457: 440: 435: 432: 431: 421: 420: 416: 415: 412: 407: 404: 403: 400: 394: 393: 390: 384: 383: 380: 374: 373: 370: 366: 365: 362: 356: 355: 351: 347: 343: 340: 335: 332: 331: 327: 326: 324: 323: 320: 312: 311: 310: 307: 306: 304: 303: 299: 296: 295: 293: 289: 286: 285: 277: 276: 275: 272: 271: 269: 268: 255: 253: 241: 238: 237: 234: 228: 227: 225: 224: 216: 214: 208: 207: 205: 204: 200: 198: 192: 191: 189: 188: 180: 178: 170: 167: 166: 164: 163: 159: 157: 149: 148: 138: 130: 129: 127: 126: 118: 116: 110: 109: 107: 106: 98: 96: 89: 86: 85: 83: 82: 74: 72: 67: 64: 63: 59: 58: 55: 49: 48: 44: 43: 35: 34: 18:Nitroguanidine 13: 10: 9: 6: 4: 3: 2: 1238: 1227: 1224: 1222: 1219: 1217: 1214: 1212: 1209: 1208: 1206: 1196: 1192: 1189: 1185: 1183: 1179: 1178: 1174: 1165: 1159: 1147: 1143: 1142: 1137: 1130: 1127: 1116: 1112: 1108: 1104: 1100: 1094: 1091: 1088: 1084: 1078: 1076: 1072: 1069: 1065: 1061: 1058: 1052: 1049: 1037: 1034: 1027: 1025: 1019: 1017: 1007: 991: 987: 983: 979: 971: 940: 921: 912: 909: 887: 878: 856: 839: 826: 801: 800: 799: 796: 794: 790: 786: 782: 777: 775: 771: 770:dicyandiamide 767: 763: 759: 751: 749: 747: 743: 739: 731: 719: 712: 707: 690: 684: 681: 678: 675: 672: 671: 664: 657: 650: 626: 623: 622: 618: 617: 519: 516: 512: 511: 481: 478: 474: 473: 470: 467: 464: 460: 459: 455: 450: 445: 441: 438: 434: 433: 429: 427: 422: 417: 413: 410: 406: 405: 401: 399: 398:Boiling point 396: 395: 391: 389: 388:Melting point 386: 385: 381: 379: 376: 375: 371: 368: 367: 363: 361: 358: 357: 341: 338: 334: 333: 328: 319: 315: 308: 294: 284: 280: 273: 265: 261: 260:DTXSID3027164 257: 256: 254: 244: 240: 239: 235: 233: 230: 229: 222: 218: 217: 215: 213: 210: 209: 202: 201: 199: 197: 194: 193: 186: 182: 181: 179: 173: 169: 168: 161: 160: 158: 156: 151: 150: 146: 142: 139: 137: 135:ECHA InfoCard 132: 131: 124: 120: 119: 117: 115: 112: 111: 104: 100: 99: 97: 93: 88: 87: 80: 76: 75: 73: 70: 66: 65: 60: 54: 50: 45: 41: 36: 32: 27: 19: 1221:Rocket fuels 1157: 1150:. Retrieved 1145: 1139: 1129: 1118:. Retrieved 1106: 1093: 1063: 1059: 1056: 1051: 1036: 1023: 982:sodium azide 975: 797: 785:Jetex engine 778: 755: 745: 729: 728: 620: 468: 425: 372:White solid 196:RTECS number 62:Identifiers 1182:Propellants 766:nitric acid 463:Signal word 382:1.436 g/cm 369:Appearance 330:Properties 141:100.007.328 1205:Categories 1186:PhysChem: 1120:2021-03-10 1066:, 267-292. 437:Pictograms 360:Molar mass 221:B542239A4E 114:ChemSpider 90:3D model ( 69:CAS Number 53:IUPAC name 1115:0362-4331 1000:, and SiO 876:⟶ 762:guanidine 605:P403+P233 601:P370+P378 593:P337+P313 589:P332+P313 565:P304+P340 561:P304+P312 557:P302+P352 553:P301+P312 428:labelling 232:UN number 203:MF4350000 162:208-060-1 154:EC Number 1216:Nitrates 1191:Archived 621:NFPA 704 419:Hazards 79:506-93-4 1180:Jetex: 978:airbags 783:in the 711:what is 709: ( 378:Density 354: 172:PubChem 1152:4 June 1113:  1020:Safety 990:silica 706:verify 703:  676:(SDS) 469:Danger 314:SMILES 47:Names 1028:Notes 996:, KNO 764:with 279:InChI 236:1467 185:10481 123:10049 92:JSmol 1197:MSDS 1154:2023 1148:(41) 1111:ISSN 1060:2019 992:(NaN 988:and 972:Uses 787:for 758:salt 680:MSDS 613:P501 609:P405 597:P362 585:P330 581:P321 577:P312 573:P310 549:P280 545:P271 541:P270 537:P264 533:P261 529:P221 525:P220 521:P210 507:H335 503:H332 499:H319 495:H318 491:H315 487:H302 483:H272 212:UNII 1146:100 1083:doi 1016:). 1008:(NH 776:. 426:GHS 248:EPA 175:CID 1207:: 1156:. 1144:. 1138:. 1109:. 1105:. 1074:^ 1064:44 1062:, 1012:NO 984:, 853:NO 823:NH 611:, 607:, 603:, 599:, 595:, 591:, 587:, 583:, 579:, 575:, 571:, 567:, 563:, 559:, 555:, 551:, 547:, 543:, 539:, 535:, 531:, 527:, 523:, 505:, 501:, 497:, 493:, 489:, 485:, 430:: 342:CH 1123:. 1085:: 1014:3 1010:4 1002:2 998:3 994:3 954:) 951:s 948:( 944:C 941:+ 937:) 934:g 931:( 922:2 918:N 913:2 910:+ 906:) 903:g 900:( 896:O 888:2 884:H 879:3 872:) 869:s 866:( 857:3 848:] 840:3 835:) 827:2 819:( 814:C 811:[ 734:3 701:Y 662:4 655:1 648:2 352:3 350:O 348:4 346:N 344:6 250:) 246:( 94:) 20:.

Index

Nitroguanidine

Ball-and-stick models of the constituent ions
IUPAC name
CAS Number
506-93-4
JSmol
Interactive image
ChemSpider
10049
ECHA InfoCard
100.007.328
Edit this at Wikidata
EC Number
PubChem
10481
RTECS number
UNII
B542239A4E
UN number
CompTox Dashboard
DTXSID3027164
Edit this at Wikidata
InChI
SMILES
Chemical formula
Molar mass
Density
Melting point
Boiling point

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