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For example, a polymer with Nā200 is able to reach the gel point with only 0.5% of monomers reacting. This shows the ease at which polymers are able to form infinite networks. The critical extent of reaction for
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will not. The gel is often a small percentage of the mixture, even though it greatly influences the properties of the bulk.
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Paul, Hiemenz C., and Lodge P. Timothy. Polymer
Chemistry. Second ed. Boca Raton: CRC P, 2007. 381-389
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appears at the gel point. Assuming that it is possible to measure the extent of reaction,
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of a solution containing polymerizable components. At the gel point, a solution undergoes
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that can form 2- or 3-dimensional networks. For example, the condensation of a
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can be determined as a function of the properties of the monomer mixture,
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Abrupt change in the viscosity of a solution of polymerizable materials
98:, the gel point can be determined. The critical extent of reaction
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Pinner, S.H. (1956). "Functionality of non-equivalent mixtures".
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will give rise to a gel whereas the same dicarboxylic acid and a
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The
Elements of Polymer Science and Engineering, 3rd Edition
182:{\displaystyle p_{c}={\frac {1}{N-1}}\approx {\frac {1}{N}}}
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319:{\displaystyle p_{c}={\frac {1}{\sqrt {r+rp(f-2)}}}}
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438:Rudin, Alfred; Choi, Phillip (2012).
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442:. Elsevier Science. p. 410.
365:R.J. Young; P. A. Lovell (1991).
369:. London: Chapman & Hall.
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401:Journal of Polymer Science
341:Cold filter plugging point
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19:Not to be confused with
62:Mathematical definition
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118:{\displaystyle p_{c}}
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250:{\displaystyle f}
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66:An infinite
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44:crosslinkers
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461:Categories
352:References
336:Pour point
346:Petroleum
305:−
167:≈
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36:viscosity
32:gel point
330:See also
195:gelation
92:monomers
40:gelation
409:Bibcode
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50:and a
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26:In
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302:f
299:(
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283:1
278:=
273:c
269:p
245:f
225:p
205:r
175:N
172:1
161:1
155:N
151:1
146:=
141:c
137:p
111:c
107:p
78:p
23:.
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