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104:. Their approach was similar in that it involved adding graphite to a solution of concentrated acid. However, they simplified it to just graphite, concentrated sulfuric acid, sodium nitrate, and potassium permanganate. They also did not have to use temperatures above 98 °C and avoided most of the explosive risk of the Staudenmeier–Hoffman–Hamdi method.
257:. After discovering that graphite oxide is reactive to many of the wavelengths of light found within sunlight, teams have been looking into methods of using it to bolster the speed of reaction in decomposition of water and organic matter. The most common method for producing the graphite oxide in these experiments has been Hummers' method.
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Graphite oxide captured the attention of the scientific community after the discovery of graphene in 2004. Many teams are looking into ways of using graphite oxide as a shortcut to mass production of graphene. So far, the materials produced by these methods have shown to have more defects than those
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of graphite, introducing molecules of oxygen to the pure carbon graphene. The reaction occurs between the graphene and the concentrated sulfuric acid with the potassium permanganate and sodium nitrate acting as catalysts. The process is capable of yielding approximately 188 g of graphite oxide
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The method has been taken up by many researchers and chemists who are interested in the use of graphite oxide for other purposes, because it is the fastest conventional method of producing graphite oxide while maintaining a relatively high C/O ratio. When researchers and chemists are introducing a
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The procedure starts with 100 g graphite and 50 g of sodium nitrate in 2.3 liters of sulfuric acid at 66 °C which is then cooled to 0 °C. 300 g of potassium permanganate is then added to the solution and stirred. Water is then added in increments until the solution is
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Hummers' method was developed in 1958 as a safer, faster and more efficient method of producing graphite oxide. Before the method was developed, the production of graphite oxide was slow and hazardous to make because of the use of concentrated sulfuric and nitric acid. The
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Kovtyukhova, N.I.; Ollivier, P.J.; Martin, B.J.; Mallouk, T.E.; Chizhik, S.A.; Buzaneva, E.V.; Gorchinskiy, A.D. (January 1999). "Layer-by-Layer
Assembly of Ultrathin Composite Films from Micron-Size Graphite Oxide Sheets and Polycations".
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to 100 g of graphite used. The ratio of carbon to oxygen produced is within the range of 1 to 2.1–2.9 that is characteristic of graphite oxide. The contaminants are determined to be mostly ash and water. Toxic gases such as
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are evolved in the process. The final product is typically 47.06% carbon, 27.97% oxygen, 22.99% water, and 1.98% ash with a carbon-to-oxygen ratio of 2.25. All of these results are comparable to the methods that preceded them.
39:. It is commonly used by engineering and lab technicians as a reliable method of producing quantities of graphite oxide. It is also able to be revised in the creation of a one-atom-thick version of the substance known as
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Tu, Wenguang; Zhou, Yong; Zou, Zhigang (October 2013). "Versatile
Graphene-Promoting Photocatalytic Performance of Semiconductors: Basic Principles, Synthesis, Solar Energy Conversion, and Environmental Applications".
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where there is a ratio between 2.1 and 2.9 of carbon to oxygen. Graphite oxide is typically a yellowish solid. It is also known as graphene oxide when used to form unimolecular sheets.
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Other groups have been focused on making improvements to the
Hummers' method to make it more efficient and environmentally friendly. One such process is eliminating the use of NaNO
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introduced the addition of potassium chlorate. However, this method had more hazards and produced one gram of graphite oxide to ten grams of potassium chlorate.
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produced directly from graphite. Hummers' method remains a key point of interest because it is an easy method of producing large quantities of graphite oxide.
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Chen, Ji; Yao, Bowen; Li, Chun; Shi, Gaoquan (November 2013). "An improved
Hummers method for eco-friendly synthesis of graphene oxide".
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created their method as an alternative to the above methods after noting the hazards they posed to workers at the
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large quantity of graphite oxide within time limitations, Hummers' method is usually referenced in some form.
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The final solution contains about 0.5% of solids to then be cleaned of impurities and dehydrated with
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Hummers, William S.; Offeman, Richard E. (March 20, 1958). "Preparation of
Graphitic Oxide".
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Ojha, Kasinath; Anjaneyulu, Oruganti; Ganguli, Ashok (10 August 2014).
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The basic chemical reaction involved in the
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244:Structural Model of a Molecule of Graphene Oxide
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261:See also
152:% Oxygen
149:% Carbon
75:hydrogen
29:graphite
356:YouTube
166:Hummers
155:% Water
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146:Method
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