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475:
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601:"The Redox Potential of Dithionite and SO from Equilibrium Reactions with Flavodoxins, Methyl Viologen and Hydrogen plus Hydrogenase"
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José Jiménez Barberá; Adolf
Metzger; Manfred Wolf (2000). "Sulfites, Thiosulfates, and Dithionites".
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The unusual structure of the dithionite anion. It has a remarkably long sulfur-sulfur bond.
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140:
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Wietelmann, Ulrich; Felderhoff, Michael; Rittmeyer, Peter (2016-09-29) . "Hydrides".
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iron(II) compounds and to remove amorphous iron(III)-bearing mineral phases in
391:
208:
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77:. The dianion has a steric number of 4 and trigonal pyramidal geometry.
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The decomposition of dithionite produces reduced species of
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It also undergoes alkaline hydrolytic disproportionation to
562:. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA.
144:
85:
In its main applications, dithionite is generally prepared
65:
with the formula . It is commonly encountered as the salt
347:), but this acid does not exist in any practical sense.
694:
69:. For historical reasons, it is sometimes called
476:International Union of Pure and Applied Chemistry
101:, described by the following idealized equation:
559:Ullmann's Encyclopedia of Industrial Chemistry
521:Ullmann's Encyclopedia of Industrial Chemistry
484:(IUPAC Recommendations 2005). Cambridge (UK):
714:
27:Oxyanion of sulfur at the oxidation number +3
8:
73:, but it contains no hydrogen and is not a
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378:Dithionite is used in conjunction with
358:finds widespread use in industry as a
7:
675:
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410:that can be very aggressive for the
481:Nomenclature of Inorganic Chemistry
693:. You can help Knowledge (XXG) by
618:10.1111/j.1432-1033.1978.tb12269.x
25:
398:analyses (selective extraction).
677:
605:European Journal of Biochemistry
1:
568:10.1002/14356007.a13_199.pub2
362:. It is for example used in
331:It is formally derived from
455:(S, HS) is responsible for
786:
672:
207:Dithionite undergoes acid
29:
649:Chemistry of the Elements
647:; Earnshaw, Alan (1997).
457:stress corrosion cracking
390:(III) oxy-hydroxide into
159:occurs with formation of
530:10.1002/14356007.a25_477
81:Production and reactions
30:Not to be confused with
524:. Weinheim: Wiley-VCH.
765:Chemical process stubs
760:Electrochemistry stubs
689:-related article is a
599:Mayhew, S. G. (2008).
364:bleaching of wood pulp
114:+ 8 NaOH → 4 Na
54:
53:of the dithionite ion.
42:
653:Butterworth-Heinemann
645:Greenwood, Norman N.
447:) is known to induce
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40:
51:ball-and-stick model
502:Electronic version.
151:is −0.66 V vs
149:reduction potential
402:Harmful properties
351:Use and occurrence
212:disproportionation
99:sodium borohydride
55:
43:
702:
701:
662:978-0-08-037941-8
577:978-3-527-30673-2
449:pitting corrosion
380:complexing agents
374:Chemical analyses
356:Sodium dithionite
67:sodium dithionite
16:(Redirected from
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755:Sulfur oxyanions
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651:(2nd ed.).
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311:+ 6 NaOH → 5 Na
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71:hydrosulfite
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18:Hydrosulfite
770:Metal stubs
750:Dithionites
424:Thiosulfate
384:citric acid
216:thiosulfate
734:Categories
463:References
451:, whereas
209:hydrolytic
191:O → 2
59:dithionite
32:dithionate
745:Corrosion
687:corrosion
586:751968805
412:corrosion
366:and some
220:bisulfite
157:oxidation
91:reduction
478:(2005).
63:oxyanion
459:(SCC).
453:sulfide
392:soluble
323:S + 3 H
293:sulfide
289:sulfite
161:sulfite
126:+ NaBO
110:+ 8 SO
87:in situ
75:sulfite
61:is the
659:
627:648533
625:
584:
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408:sulfur
187:+ 2 H
155:. Its
143:. At
130:+ 6 H
685:This
490:IUPAC
416:steel
691:stub
657:ISBN
623:PMID
582:OCLC
572:ISBN
534:ISBN
494:ISBN
418:and
396:soil
388:iron
368:dyes
319:+ Na
299:3 Na
291:and
272:+ 2
251:O →
218:and
106:NaBH
57:The
613:doi
564:doi
526:doi
486:RSC
414:of
274:HSO
247:+ H
214:to
193:HSO
153:SHE
97:by
93:of
89:by
736::
655:.
621:.
609:85
607:.
603:.
580:.
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548:^
532:.
508:^
492:.
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335:(H
315:SO
295::
226:2
222::
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145:pH
49:A
722:e
715:t
708:v
697:.
665:.
629:.
615::
588:.
566::
542:.
528::
488:–
442:3
437:O
433:2
428:S
426:(
345:4
343:O
341:2
339:S
337:2
327:O
325:2
321:2
317:3
313:2
309:4
307:O
305:2
303:S
301:2
279:3
267:3
262:O
258:2
253:S
249:2
242:4
237:O
233:2
228:S
198:3
189:2
182:4
177:O
173:2
168:S
134:O
132:2
128:2
124:4
122:O
120:2
118:S
116:2
112:2
108:4
34:.
20:)
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