Knowledge (XXG)

Light-emitting electrochemical cell

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In 2012 the first inherently stretchable LEC using an elastomeric emissive material (at room temperature) was reported. Dispersing an ionic transition metal complex into an elastomeric matrix enables the fabrication of intrinsically stretchable light-emitting devices that possess large emission areas
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There are two distinct types of LECs, those based on inorganic transition metal complexes (iTMC) or light emitting polymers. iTMC devices are often more efficient than their LEP based counterparts due to the emission mechanism being phosphorescent rather than fluorescent.
88:(~175 mm2) and tolerate linear strains up to 27% and repetitive cycles of 15% strain. This work demonstrates the suitability of this approach to new applications in conformable lighting that require uniform, diffuse light emission over large areas. 83:
While electroluminescence had been seen previously in similar devices, the invention of the polymer LEC is attributed to Pei et al. Since then, numerous research groups and a few companies have worked on improving and commercializing the devices.
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Filiatrault, H. L.; Porteous, G. C.; Carmichael, R. S.; Davidson, G. J. E.; Carmichael, T. B. (2012). "Stretchable Light-Emitting Electrochemical Cells Using an Elastomeric Emissive Material".
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Shin, J.-H.; Dzwilewski, A.; Iwasiewicz, A.; Xiao, S.; Fransson, Å.; Ankah, G. N.; Edman, L. (2006). "Light Emission at 5 V from a Polymer Device with a Millimeter-Sized Interelectrode Gap".
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Matyba, P.; Yamaguchi, H.; Eda, G.; Chhowalla, M.; Edman, L.; Robinson, N. D. (2010). "Graphene and Mobile Ions: The Key to All-Plastic, Solution-Processed Light-Emitting Devices".
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In 2017, a new design approach developed by a team of Swedish researchers promised to deliver substantially higher efficiency: 99.2 cd A at a bright luminance of 1910 cd m.
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Yu, Z.; Hu, L.; Liu, Z.; Sun, M.; Wang, M.; Grüner, G.; Pei, Q. (2009). "Fully Bendable Polymer Light Emitting Devices with Carbon Nanotubes as Cathode and Anode".
305:; Kock, A.; Bruckl, H.; Kast, M.; Stepper, C.; List, E. J. W. (2008). "Inkjet Printed Surface Cell Light-Emitting Devices from a Water-Based Polymer Dispersion". 658: 51:
of the electrodes. Consequently, the electrodes can be made of the same material (e.g. gold). Similarly, the device can still be operated at low voltages.
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Gao, J.; Dane, J. (2003). "Planar Polymer Light-Emitting Electrochemical Cells with extremely Large Interelectrode Spacing".
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LECs can be printed with relatively inexpensive printing processes (where control over film thicknesses can be difficult).
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Tang, S.; Sandström, A.; Lundberg P.; Lanz, T.; Larsen, C.; van Reenen, S.; Kemerink, M.; Edman, L. (30 October 2017).
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The thickness of the active electroluminescent layer is not critical for the device to operate. This means that:
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Pei, Q. B.; Yu, G.; Zhang, C.; Yang, Y.; Heeger, A. J. (1995). "Polymer Light-Emitting Electrochemical-Cells".
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Tang, Shi; Edman, Ludvig (2016-06-13). "Light-Emitting Electrochemical Cells: A Review on Recent Progress".
334:"Visualization of Electrochemical Doping and Light-Emitting Junction Formation in Conjugated Polymer Films" 1125: 875: 790: 230: 1012: 1006: 33: 528:"Ambient Fabrication of Flexible and Large-Area Organic Light-Emitting Devices Using Slot-Die Coating" 1017: 891: 596: 539: 484: 433: 345: 302: 275: 195: 160: 121: 111: 235: 1163: 1067: 974: 857: 818: 745: 36:
containing mobile ions. Aside from the mobile ions, their structure is very similar to that of an
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In a planar device configuration, internal device operation can be observed directly.
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and polymers have been used as electrodes, eliminating the need for using
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LECs have most of the advantages of OLEDs, as well as additional ones:
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Sandström, A.; Dam, H. F.; Krebs, F. C.; Edman, L. (2012).
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compatible process under ambient conditions was reported.
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light-emitting electrochemical cells (LECs) using a
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Thick-film dielectric electroluminescent technology
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(2004). 1224: 832:Liquid crystal on silicon 387:10.1007/s41061-016-0040-4 1023:Fourteen-segment display 826:Digital Light Processing 117:Electrochemiluminescence 1029:Sixteen-segment display 715:Rear-projection display 338:Applied Physics Letters 268:Applied Physics Letters 188:Applied Physics Letters 153:Applied Physics Letters 91:In 2012 fabrication of 876:Field-emission display 791:Liquid-crystal display 497:10.1002/adma.201200448 1307:Molecular electronics 1013:Eight-segment display 1007:Seven-segment display 595:(1190 (2017)): 1190. 589:Nature Communications 532:Nature Communications 34:organic semiconductor 1135:Display capabilities 1018:Nine-segment display 720:Plasma display panel 122:Light-emitting diode 112:Electrochemical cell 1312:Conductive polymers 1164:See-through display 1068:Holographic display 746:Quantum dot display 601:2017NatCo...8.1190T 544:2012NatCo...3.1002S 489:2012AdM....24.2673F 438:1995Sci...269.1086P 350:2004ApPhL..84.2778G 307:Organic Electronics 280:2009ApPhL..95t3304Y 200:2006ApPhL..89a3509S 165:2003ApPhL..83.3027G 30:electroluminescence 1302:Display technology 1206:Color Light Output 1200:High Dynamic Range 1002:Dot-matrix display 997:Lightguide display 668:Display technology 552:10.1038/ncomms2002 477:Advanced Materials 1317:Electronics stubs 1264: 1263: 1233: 1232: 1159:Always-on display 950:Electromechanical 938: 937: 359:10.1063/1.1702126 288:10.1063/1.3266869 245:10.1021/nn9018569 208:10.1063/1.2219122 173:10.1063/1.1618948 132:Photoelectrolysis 1324: 1285: 1278: 1271: 1247: 1240: 1211:Flexible display 1173:Related articles 1053:Autostereoscopic 752:Electronic paper 698:Cathode-ray tube 681: 661: 654: 647: 638: 631: 630: 620: 580: 574: 573: 563: 523: 517: 516: 472: 466: 465: 432:(5227): 1086–8. 421: 415: 414: 370: 364: 363: 361: 329: 323: 322: 298: 292: 291: 263: 257: 256: 238: 218: 212: 211: 183: 177: 176: 148: 64:indium tin oxide 60:carbon nanotubes 1332: 1331: 1327: 1326: 1325: 1323: 1322: 1321: 1292: 1291: 1290: 1289: 1236: 1234: 1229: 1220: 1168: 1130: 1116:Slide projector 1106:Movie projector 1089: 1034: 934: 844: 837: 738: 732: 685: 670: 665: 635: 634: 582: 581: 577: 525: 524: 520: 474: 473: 469: 423: 422: 418: 372: 371: 367: 331: 330: 326: 300: 299: 295: 265: 264: 260: 236:10.1.1.474.2436 220: 219: 215: 185: 184: 180: 150: 149: 145: 140: 108: 12: 11: 5: 1330: 1328: 1320: 1319: 1314: 1309: 1304: 1294: 1293: 1288: 1287: 1280: 1273: 1265: 1262: 1261: 1248: 1231: 1230: 1225: 1222: 1221: 1219: 1218: 1213: 1208: 1203: 1197: 1192: 1187: 1182: 1176: 1174: 1170: 1169: 1167: 1166: 1161: 1156: 1151: 1150: 1149: 1138: 1136: 1132: 1131: 1129: 1128: 1123: 1118: 1113: 1108: 1103: 1097: 1095: 1091: 1090: 1088: 1087: 1082: 1077: 1076: 1075: 1070: 1060: 1055: 1050: 1044: 1042: 1036: 1035: 1033: 1032: 1026: 1020: 1015: 1010: 1004: 999: 994: 988: 982: 977: 972: 967: 966: 965: 962: 957: 946: 944: 940: 939: 936: 935: 933: 932: 926: 920: 914: 913: 912: 907: 896: 895: 894: 892:Liquid crystal 889: 879: 873: 867: 861: 855: 849: 847: 839: 838: 836: 835: 829: 823: 822: 821: 816: 811: 810: 809: 804: 788: 787: 786: 785: 784: 766: 765: 764: 759: 749: 742: 740: 734: 733: 731: 730: 729: 728: 717: 712: 706: 701: 695: 689: 687: 678: 676:Video displays 672: 671: 666: 664: 663: 656: 649: 641: 633: 632: 575: 518: 483:(20): 2673–8. 467: 416: 365: 324: 303:Landfester, K. 301:Mauthner, G.; 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Index

electroluminescence
organic semiconductor
organic light-emitting diode
work function
graphene
carbon nanotubes
indium tin oxide
organic
roll-to-roll
Electrochemical cell
Electrochemiluminescence
Light-emitting diode
Organic light-emitting diode
Photoelectrolysis
Bibcode
2003ApPhL..83.3027G
doi
10.1063/1.1618948
Bibcode
2006ApPhL..89a3509S
doi
10.1063/1.2219122
CiteSeerX
10.1.1.474.2436
doi
10.1021/nn9018569
PMID
20131906
Bibcode
2009ApPhL..95t3304Y

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