119:(NVAL) to construct an intermediate phase with low formation enthalpy and COO coordination. This new intermediate phase altered the crystallization pathway, effectively inhibiting phase segregation. Consequently, high-quality large-area quasi-2D perovskite films were achieved. They further fine-tuned the film's composite dynamics, leading to high-efficiency quasi-2D perovskite green LEDs with an effective area of 9.0 cm. An external quantum efficiency (EQE) of 16.4% was attained at <n> = 3, making it the most efficient large-area perovskite LED. Moreover, a
162:(LiF/Al/Ag/LiF). The red perovskite nano-crystalline layer allows the waveguide mode and surface plasmon polarization mode captured in the blue perovskite diode to be extracted and converted into red light emission, increasing the light extraction efficiency by 50%. At the same time, the complementary emission spectra of blue photons and down-converted red photons contribute to the formation of white LEDs. Finally, the off-device quantum efficiency exceeds 12%, and the brightness exceeds 2000 cd/m, which are both the highest in white PeLEDs.
136:, which consisted of Lewis base benzoic acid anions and alkali metal cations. This passivator had a dual role: it effectively passivated the deficient lead atom while inhibited the migration of halide ions. The outcome of this innovative approach was the realization of an efficient perovskite LED that emitted light at a stable wavelength of 483 nm. The LED exhibited a commendable external quantum efficiency (EQE) of 16.58%, with a peak EQE reaching 18.65%. Through optical coupling enhancement, the EQE was further boosted to 28.82%.
153:(PEAI)/3-fluorophenylethylammonium iodide (m-F-PEA) and 1-naphthylmethylammonium iodide (NMAI), they achieved precise control over the phase distribution of quasi-2D perovskite materials. This approach effectively reduced the prevalence of smaller n-index phases and concurrently addressed lead and halide defects in the perovskite films. The outcome of this research was the development of perovskite LEDs capable of achieving an EQE of 25.8% at 680 nm, accompanied by a peak brightness of 1300 cd/m.
22:
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Preparing high-quality all-inorganic perovskite films through solution-based methods remains a formidable challenge, primarily attributed to the rapid and uncontrollable crystallization of such materials. The key innovation involved controlling the crystal orientation of the all-inorganic perovskite
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On
September 20, 2021, the team led by Sargent et al. from the University of Toronto published their research findings in the Journal of the American Chemical Society (JACS) on bright and stable light-emitting diodes (LEDs) based on perovskite quantum dots within a perovskite matrix. The research
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High-performance white perovskite LED with high light extraction efficiency can be constructed through near-field optical coupling. The near-field optical coupling between blue perovskite diode and red perovskite nanocrystal was achieved by a reasonably designed multi-layer translucent electrode
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To address this challenge, Jiang et al. published their findings in
Advanced Materials on July 20, 2022. Their research focused on strategically incorporating large cations to enhance the efficiency of red light perovskite LEDs. By introducing phenethylammonium iodide
104:(EQE) exceeding 30% was reported by Bai and his colleagues on May 29, 2023. This achievement was made by adjustments in charge carrier transport and the distribution of near-field light. These optimizations resulted in a light output coupling efficiency of 41.82%.
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have demonstrated potential for high emission efficiency due to robust carrier confinement. However, the external quantum efficiencies (EQE) of most red quasi-2D PeLEDs are not optimal due to different n-value phases within complex quasi-2D perovskite films.
580:
Liu, Yuan; Dong, Yitong; Zhu, Tong; Ma, Dongxin; Proppe, Andrew; Chen, Bin; Zheng, Chao; Hou, Yi; Lee, Seungjin; Sun, Bin; Jung, Eui Hyuk; Yuan, Fanglong; Wang, Ya-kun; Sagar, Laxmi
Kishore; Hoogland, Sjoerd (2021-09-29).
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process (35-40 °C). This precise control led to the orderly stacking of crystals, which significantly increased surface coverage and reduced defects within the material. After thorough optimization, the well-oriented
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perovskite LED achieved an external quantum efficiency (EQE) of up to 16.45%, a remarkable brightness of 79,932 cd/m, and a lifespan of 136 hours when initially operated at a brightness level of 100 cd/m.
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The modified structure of green PeLED achieved record external quantum efficiency of 30.84% at a brightness level of 6514 cd/m. This work introduced an approach to building ultra-efficient PeLEDs by balancing
131:
On March 16, 2023, Zhou et al. published a study demonstrating their successful control of ion behavior to create highly efficient sky-blue perovskite light-emitting diodes. They achieved this by utilizing a
73:(PeLEDs) are candidates for display and lighting technologies. Researchers have shown interest in perovskite light-emitting diodes (PeLEDs) owing to their capacity for emitting light with narrow
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of 18% and maintain high performance at a brightness exceeding 4700 cd/m. The new material extends the LED's operating half-life to 2400 hours at an initial brightness of 100 cd/m.
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Sun, Changjiu; Jiang, Yuanzhi; Cui, Minghuan; Qiao, Lu; Wei, Junli; Huang, Yanmin; Zhang, Li; He, Tingwei; Li, Saisai; Hsu, Hsien-Yi; Qin, Chaochao; Long, Run; Yuan, Mingjian (2021-04-13).
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The new material exhibits suppressed biexciton Auger recombination and bright luminescence even at high excitation (600 W/cm). The red LEDs based on the new material demonstrate an
528:
Feng, Wenjing; Lin, Kebin; Li, Wenqiang; Xiao, Xiangtian; Lu, Jianxun; Yan, Chuanzhong; Liu, Xinyi; Xie, Liqiang; Tian, Chengbo; Wu, Dan; Wang, Kai; Wei, Zhanhua (2021-05-04).
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of the perovskite matrix using strain quantum dots as nucleation centers. The type I band alignment ensures that quantum dots act as charge acceptors and radiative emitters.
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Chen, Ziming; Li, Zhenchao; Chen, Zhen; Xia, Ruoxi; Zou, Guangruixing; Chu, Linghao; Su, Shi-Jian; Peng, Junbiao; Yip, Hin-Lap; Cao, Yong (February 2021).
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Zhou, Wei; Shen, Yang; Cao, Long-Xue; Lu, Yu; Tang, Ying-Yi; Zhang, Kai; Ren, Hao; Xie, Feng-Ming; Li, Yan-Qing; Tang, Jian-Xin (July 2023).
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Jiang, Ji; Chu, Zema; Yin, Zhigang; Li, Jingzhen; Yang, Yingguo; Chen, Jingren; Wu, Jinliang; You, Jingbi; Zhang, Xingwang (September 2022).
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reported that perovskite quantum dots remain stable in a precursor solution thin film of perovskite and drive the uniform
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423:"Manipulating Ionic Behavior with Bifunctional Additives for Efficient Sky-Blue Perovskite Light-Emitting Diodes"
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Bai, Wenhao; Xuan, Tongtong; Zhao, Haiyan; Dong, Haorui; Cheng, Xinru; Wang, Le; Xie, Rong-Jun (September 2023).
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One of the most crucial aspects of lighting and display technology is the efficient generation of red emission.
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530:"Efficient all-inorganic perovskite light-emitting diodes enabled by manipulating the crystal orientation"
473:"Utilization of Trapped Optical Modes for White Perovskite Light-Emitting Diodes with Efficiency over 12%"
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Expanding the effective area of perovskite LEDs can decrease their performance. Sun et al. introduced
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219:"Red Perovskite Light-Emitting Diodes with Efficiency Exceeding 25% Realized by Co-Spacer Cations"
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583:"Bright and Stable Light-Emitting Diodes Based on Perovskite Quantum Dots in Perovskite Matrix"
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of 9.1×104 cd/m was achieved in the <n> = 10 films.
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may be in need of reorganization to comply with
Knowledge's
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100:The development of efficient green PeLEDs with a
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359:Nature Communications
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