48:
260:
157:
39:
1177:
579:
574:
903:. Reacts with organic compounds to cause fire. Evolves highly toxic and corrosive gases when exposed to fire. When heated to decomposition, it emits highly toxic fumes like bromides, oxybromides and oxides of phosphorus. It is corrosive to metals and tissues.
587:
554:
665:
657:
1221:
309:
661:
1214:
1111:
1078:
1002:
865:, with intermolecular BrâO bridges creating infinite chains within the structure. The intermolecular bonding causes distortions from the
1250:
274:
1207:
1057:
Booth, Harold S.; Seegmiller, C. G.; Baker, Philip S.; Wexler, Sol; Johnson, Roy D. (2007-01-05), Fernelius, W. Conard (ed.),
1240:
535:
517:
649:
754:
623:
207:
858:
238:
689:
578:
164:
857:
Phosphoryl bromide forms colorless crystals or thin plates with a faint orange tint. Its crystals belong to the
801:
673:
653:
573:
152:
47:
951:
726:
114:
994:
838:
721:
601:
566:
1245:
805:
669:
1184:
1019:
842:
736:
731:
255:
80:
928:
968:
774:
637:
511:
1135:
Okuda, Tsutomu.; Hosokawa, Kazuto.; Yamada, Koji.; Furukawa, Yoshihiro.; Negita, Hisao. (1975).
633:
645:
1187:
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1074:
1039:
998:
1191:
1148:
1066:
1031:
986:
960:
900:
469:
440:
411:
332:
685:
677:
216:
134:
896:
629:
90:
259:
156:
1176:
681:
748:
611:
1234:
444:
428:
400:
390:
145:
17:
972:
945:
Templeton, Lieselotte K.; Templeton, David H. (1971). "The crystal structure of POBr
701:
1136:
641:
494:
1058:
196:
38:
1137:"Structural study of phosphoryl bromide by means of nuclear quadrupole resonance"
615:
457:
1070:
964:
779:
521:
436:
422:
349:
125:
1160:
1121:
1043:
1035:
693:
227:
607:
1152:
876:
834:
785:
432:
380:
183:
165:
895:
Phosphoryl bromide reacts violently with water evolving heat, forming
846:
782:
747:
Except where otherwise noted, data are given for materials in their
1065:, Hoboken, NJ, USA: John Wiley & Sons, Inc., pp. 151â152,
113:
103:
887:
Phosphoryl bromide finds use as a specialist brominating agent.
697:
370:
1106:(2nd ed.). Boca Raton: Taylor & Francis. p. 310.
1020:"Das Atomgewicht des Phosphors. Analyse des Phosphoroxybromids"
929:
https://pubchem.ncbi.nlm.nih.gov/compound/Phosphorus-oxybromide
243:
46:
37:
365:
Colorless crystals or thin plates with a faint orange tint
841:
at 0 °C, followed by the slow addition of water and
833:
It can also be prepared via the slow addition of liquid
1195:
800:
Phosphoryl bromide is prepared by the reaction between
1059:"Phosphorus(V) Oxybromide: (Phosphoryl Tribromide)"
1024:Zeitschrift fĂŒr anorganische und allgemeine Chemie
1018:Hönigschmid, O.; HirschboldâWittner, F. (1940).
949:: space group and refinement by least squares".
195:
89:
1215:
8:
940:
938:
936:
1222:
1208:
258:
155:
133:
26:
924:
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918:
916:
215:
826:
822:
818:
814:
788:
340:
1097:
1095:
912:
314:
279:
254:
405:192 °C (378 °F; 465 K)
146:
872:symmetry found in the free molecule.
395:56 °C (133 °F; 329 K)
286:Key: UXCDUFKZSUBXGM-UHFFFAOYSA-N
7:
1173:
1171:
296:Key: UXCDUFKZSUBXGM-UHFFFAOYAH
186:
1194:. You can help Knowledge (XXG) by
25:
1175:
577:
572:
1104:Handbook of Inorganic Compounds
751:(at 25 °C , 100 kPa).
536:Occupational safety and health
1:
875:It is stored in sealed glass
417:Reacts violently with water
33:
1267:
1170:
1071:10.1002/9780470132333.ch44
991:Chemistry of the Elements
989:; Earnshaw, Alan (1997).
965:10.1107/S0567740871004564
745:
707:
553:
533:
528:
450:
325:
305:
283:InChI=1S/Br3OP/c1-5(2,3)4
270:
73:
65:
60:
32:
1251:Inorganic compound stubs
1036:10.1002/zaac.19402430406
853:Structure and properties
624:Precautionary statements
293:InChI=1/Br3OP/c1-5(2,3)4
1102:Perry, Dale L. (2011).
802:phosphorus pentabromide
1190:ârelated article is a
727:Thiophosphoryl bromide
483: = 9.938 Ă
,
479: = 9.467 Ă
,
51:
42:
1241:Phosphorus oxohalides
995:Butterworth-Heinemann
987:Greenwood, Norman N.
839:phosphorus tribromide
771:phosphorus oxybromide
722:Phosphorus tribromide
68:Phosphorus oxybromide
50:
41:
18:Phosphorus oxybromide
997:. pp. 501â503.
806:phosphorus pentoxide
549:Corrosive to tissue
487: = 6.192 Ă
1153:10.1021/ic50147a048
1141:Inorganic Chemistry
1063:Inorganic Syntheses
952:Acta Crystallogr. B
843:vacuum distillation
737:Phosphoryl chloride
732:Phosphoryl fluoride
443:, and concentrated
412:Solubility in water
357: g·mol
29:
28:Phosphoryl bromide
775:inorganic compound
767:Phosphoryl bromide
755:Infobox references
708:Related compounds
52:
43:
27:
1203:
1202:
1113:978-1-4398-1461-1
1080:978-0-470-13233-3
1004:978-0-08-037941-8
845:of the resulting
777:with the formula
763:Chemical compound
761:
760:
714:Related compounds
602:Hazard statements
239:CompTox Dashboard
115:Interactive image
56:
55:
16:(Redirected from
1258:
1224:
1217:
1210:
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1172:
1165:
1164:
1147:(5): 1207â1209.
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1054:
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1015:
1009:
1008:
993:(2nd ed.).
983:
977:
976:
959:(8): 1678â1679.
942:
931:
926:
901:hydrobromic acid
829:
791:
769:, also known as
703:
699:
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470:Lattice constant
441:carbon disulfide
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333:Chemical formula
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1005:
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897:phosphoric acid
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764:
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512:Molecular shape
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1030:(4): 355â360.
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978:
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905:
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881:
869:
854:
851:
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830:
797:
794:
762:
759:
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753:
749:standard state
746:
743:
742:
740:
739:
734:
729:
724:
718:
716:
713:
710:
709:
705:
704:
666:P305+P351+P338
658:P303+P361+P353
654:P301+P330+P331
627:
622:
619:
618:
605:
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1026:(in German).
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1021:
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988:
982:
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873:
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836:
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542:
538:
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519:
516:
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508:
504:
500:
496:
495:Formula units
492:
491:
486:
482:
478:
474:
471:
467:
466:
463:Pnma, No. 62
462:
459:
455:
454:
449:
446:
445:sulfuric acid
442:
438:
434:
430:
429:diethyl ether
426:
424:
421:
420:
416:
413:
409:
408:
404:
402:
401:Boiling point
399:
398:
394:
392:
391:Melting point
389:
388:
384:
382:
379:
378:
374:
372:
369:
368:
364:
361:
360:
353:
351:
348:
347:
337:
334:
330:
329:
324:
317:O=P(Br)(Br)Br
315:
311:
304:
290:
280:
276:
269:
261:
257:
256:DTXSID2064868
253:
252:
250:
240:
236:
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218:
214:
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211:
209:
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205:
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191:
185:
181:
180:
173:
172:
170:
168:
163:
162:
158:
154:
151:
149:
147:ECHA InfoCard
144:
143:
136:
132:
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49:
45:
40:
36:
35:
31:
19:
1196:expanding it
1182:
1144:
1140:
1130:
1103:
1084:, retrieved
1062:
1052:
1027:
1023:
1013:
990:
981:
956:
950:
894:
886:
874:
866:
862:
861:space group
859:orthorhombic
856:
832:
799:
770:
766:
765:
593:
555:
545:Main hazards
534:
498:
484:
480:
476:
74:Identifiers
66:Other names
1246:Oxobromides
796:Preparation
588:Signal word
539:(OHS/OSH):
518:Tetrahedral
458:Space group
427:Soluble in
385:2.822 g/cm
362:Appearance
326:Properties
153:100.029.252
1235:Categories
1086:2020-09-30
907:References
567:Pictograms
451:Structure
437:chloroform
423:Solubility
350:Molar mass
232:1939 2576
217:H98H8Y87QQ
126:ChemSpider
102:3D model (
81:CAS Number
1185:inorganic
1161:0020-1669
1122:587104373
1044:1521-3749
690:P403+P233
662:P304+P340
558:labelling
228:UN number
174:232-177-7
166:EC Number
91:7789-59-5
1188:compound
973:97905269
877:ampoules
825:â 5 POBr
773:, is an
529:Hazards
375:Pungent
835:bromine
520:at the
433:benzene
381:Density
355:286.685
344:
184:PubChem
1159:
1120:
1110:
1077:
1042:
1001:
971:
891:Safety
847:slurry
594:Danger
310:SMILES
61:Names
1183:This
969:S2CID
813:3 PBr
524:atom
275:InChI
197:24613
135:23015
104:JSmol
1192:stub
1157:ISSN
1118:OCLC
1108:ISBN
1075:ISBN
1040:ISSN
999:ISBN
899:and
883:Uses
863:Pnma
804:and
702:P501
698:P405
694:P404
686:P390
682:P363
678:P321
674:P312
670:P310
650:P280
646:P271
642:P264
638:P261
634:P260
630:P234
616:H335
612:H314
608:H290
371:Odor
339:POBr
208:UNII
1149:doi
1067:doi
1032:doi
1028:243
961:doi
837:to
817:+ P
556:GHS
244:EPA
187:CID
1237::
1155:.
1145:14
1143:.
1139:.
1116:.
1094:^
1073:,
1061:,
1038:.
1022:.
967:.
957:27
955:.
935:^
915:^
879:.
870:3v
849:.
808::
792:.
786:Br
700:,
696:,
692:,
688:,
684:,
680:,
676:,
672:,
668:,
664:,
660:,
656:,
652:,
648:,
644:,
640:,
636:,
632:,
614:,
610:,
560::
505:4
439:,
435:,
431:,
1223:e
1216:t
1209:v
1198:.
1163:.
1151::
1124:.
1069::
1046:.
1034::
1007:.
975:.
963::
947:3
867:C
827:3
823:5
821:O
819:2
815:5
789:3
783:O
780:P
522:P
501:)
499:Z
497:(
485:c
481:b
477:a
341:3
246:)
242:(
106:)
20:)
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