420:
606:
633:
549:
576:
1011:
31:
664:
2816:
Müller, A.; Sessoli, R.; Krickemeyer, E.; Bögge, H; Meyer, J.; Gatteschi, D.; Pardi, L.; Westphal, J.; Hovemeier, K.; Rohlfing, R.; Döring, J; Hellweg, F.; Beugholt, C.; Schmidtmann, M. (1997). "Polyoxovanadates: High-Nuclearity Spin
Clusters with Interesting Host–Guest Systems and Different Electron
1702:
German, Konstantin E.; Fedoseev, Alexander M.; Grigoriev, Mikhail S.; Kirakosyan, Gayane A.; Dumas, Thomas; Den Auwer, Christophe; Moisy, Philippe; Lawler, Keith V.; Forster, Paul M.; Poineau, Frederic (24 September 2021). "A 70-Year-Old
Mystery in Technetium Chemistry Explained by the New Technetium
817:
solution. Corresponding ammonium polyoxotechnetate salt was recently isolated from trifluoromethanesulfonic acid and it has very similar structure. The only polyoxorhenate formed in acidic conditions in presence of pyrazolium cation. The first empirically isolated polyoxorhenate was the white
255:. The replacement of terminal M=O bonds, which in fact have triple bond character, is compensated by the increase in coordination number. The nonobservation of polyoxochromate cages is rationalized by the small radius of Cr(VI), which may not accommodate octahedral coordination geometry.
731:
1883:
Anderson, T. M.; Thoma, S. G.; Bonhomme, F.; Rodriguez, M. A.; Park, H.; Parise, J. B.; Alan, T. M.; Larentzos, J. P.; Nyman, M. (2007). "Lithium
Polyniobates. A Lindqvist-Supported Lithium−Water Adamantane Cluster and Conversion of Hexaniobate to a Discrete Keggin Complex".
2921:
Busche, C.; Vila-Nadal, L.; Yan, J.; Miras, H. N.; Long, D.-L.; Georgiev, V. P.; Asenov, A.; Pedersen, R. H.; Gadegaard, N.; Mirza, M. M.; Paul, D. J.; Poblet, J. M.; Cronin, L. (2014). "Design and fabrication of memory devices based on nanoscale polyoxometalate clusters".
483:
units, with 6-coordinate metal centres. Usually, these units share edges and/or vertices. The coordination number of the oxide ligands varies according to their location in the cage. Surface oxides tend to be terminal or doubly bridging
888:
in alkaline media. These polyoxometalates display an anomalous aqueous solubility trend of their alkali metal salts inasmuch as their Cs and Rb salts are more soluble than their Na and Li salts. The opposite trend is observed in
1054:
consists of more than 700 atoms and is the size of a small protein. The anion is in the form of a tire (the cavity has a diameter of more than 20 Å) and an extremely large inner and outer surface. The incorporation of
2114:"Chiral Polyoxotungstates. 1. Stereoselective Interaction of Amino Acids with Enantiomers of [Ce III (α 1 -P 2 W 17 O 61 )(H 2 O) x ] 7- . The Structure of dl -[Ce 2 (H 2 O) 8 (P 2 W 17 O 61 ) 2 ] 14-"
1812:
Volkov, Mikhail A.; Novikov, Anton P.; Borisova, Nataliya E.; Grigoriev, Mikhail S.; German, Konstantin E. (10 August 2023). "Intramolecular Re···O Nonvalent
Interactions as a Stabilizer of the Polyoxorhenate(VII)".
1253:, activity appears related to its redox properties. The Wells-Dawson structure can efficiently inhibit amyloid β (Aβ) aggregation in a therapeutic strategy for Alzheimer's disease. antibacterial and antiviral uses.
2694:
Hiskia, A.; Troupis, A.; Antonaraki, S.; Gkika, E.; Kormali, P.; Papaconstantinou, E. (2006). "Polyoxometallate photocatalysis for decontaminating the aquatic environment from organic and inorganic pollutants".
1754:
Zegke, Markus; Grödler, Dennis; Roca
Jungfer, Maximilian; Haseloer, Alexander; Kreuter, Meike; Neudörfl, Jörg M.; Sittel, Thomas; James, Christopher M.; Rothe, Jörg; Altmaier, Marcus; Klein, Axel (2022-01-17).
706:
The polymolybdates and polytungstates are derived, formally at least, from the dianionic precursors. The most common units for polymolybdates and polyoxotungstates are the octahedral {MO
2341:
Errington, R. John; Wingad, Richard L.; Clegg, William; Elsegood, Mark R. J. (2000). "Direct
Bromination of Keggin Fragments To Give : A Polyoxotungstate with a Hexabrominated Face".
2519:
Blazevic, Amir; Rompel, Annette (January 2016). "The
Anderson–Evans polyoxometalate: From inorganic building blocks via hybrid organic–inorganic structures to tomorrows "Bio-POM"".
867:), or in the case of Nb even from mixtures of niobic acid and alkali metal hydroxides in aqueous solution. The hexatantalate can also be prepared by condensation of peroxotantalate
503:
form distinct structures because the main group center is usually tetrahedral. The
Lindqvist and Keggin structures are common motifs for iso- and heteropolyanions, respectively.
2411:
Schreiber, Roy E.; Avram, Liat; Neumann, Ronny (2018). "Self-Assembly through
Noncovalent Preorganization of Reactants: Explaining the Formation of a Polyfluoroxometalate".
1431:
Gouzerh, P.; Che, M. (2006). "From
Scheele and Berzelius to Müller: polyoxometalates (POMs) revisited and the "missing link" between the bottom up and top down approaches".
2667:
Gaspar, A. R.; Gamelas, J. A. F.; Evtuguin, D. V.; Neto, C. P. (2007). "Alternatives for lignocellulosic pulp delignification using polyoxometalates and oxygen: a review".
2765:
Rausch, B.; Symes, M. D.; Chisholm, G.; Cronin, L. (2014). "Decoupled catalytic hydrogen evolution from a molecular metal oxide redox mediator in water splitting".
2446:
Song, Y.-F.; Long, D.-L.; Cronin, L. (2007). "Non covalently connected frameworks with nanoscale channels assembled from a tethered polyoxometalate–pyrene hybrid".
2738:
Wölfel, R.; Taccardi, N.; Bösmann, A.; Wasserscheid, P. (2011). "Selective catalytic conversion of biobased carbohydrates to formic acid using molecular oxygen".
3248:
Long, D. L.; Burkholder, E.; Cronin, L. (2007). "Polyoxometalate Clusters, Nanostructures and Materials: From Self-Assembly to Designer Materials and Devices".
751:
1094:
Oxoalkoxometalates are clusters that contain both oxide and alkoxide ligands. Typically they lack terminal oxo ligands. Examples include the dodecatitanate Ti
2214:
Bino, Avi; Ardon, Michael; Lee, Dongwhan; Spingler, Bernhard; Lippard, Stephen J. (2002). "Synthesis and Structure of : The First Open-Shell Keggin Ion".
838:
The polyniobates, polytantalates, and vanadates are derived, formally at least, from highly charged precursors. For Nb and Ta, most common members are
859:(M = Nb, Ta), which adopt the Lindqvist structure. These octaanions form in strongly basic conditions from alkali melts of the extended metal oxides (M
711:
2376:
Gouzerh, P.; Jeannin, Y.; Proust, A.; Robert, F.; Roh, S.-G. (1993). "Functionalization of polyoxomolybdates: the example of nitrosyl derivatives".
231:, the nature of the dissolved species at high pH is less clear, but these oxides also form polyoxometalates. As the pH is lowered, orthometalates
632:
1539:
Kampf, Anthony R.; Rossman, George R.; Ma, Chi; Belmonte, Donato; Biagioni, Cristian; Castellaro, Fabrizio; Chiappino, Luigi (April 4, 2018).
419:
3066:
2171:
1602:
1309:
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drugs. The Anderson-type polyoxomolybdates and heptamolybdates exhibit activity for suppressing the growth of some tumors. In the case of (NH
2067:"Lanthanide Complexes of the Monovacant Dawson Polyoxotungstate [α1-P2W17O61]10− as Selective and Recoverable Lewis Acid Catalysts"
605:
1201:-based wood pulp bleaching processes, a method of decontaminating water, and a method to catalytically produce formic acid from biomass (
457:
of POMs. This innovation enabled systematic study without the complications of hydrolysis and acid/base reactions. The introduction of O
1848:
Fullmer, L. B.; Molina, P. I.; Antonio, M. R.; Nyman, M. (2014). "Contrasting ion-association behaviour of Ta and Nb polyoxometalates".
542:. However, metal-metal bonds are not completely absent in polyoxometalates and they are often present among the highly reduced species.
1217:
Some POMs exhibit unusual magnetic properties, which has prompted visions of many applications. One example is storage devices called
1541:"Ramazzoite, [Mg8Cu12(PO4)(CO3)4(OH)24(H2O)20][(H0.33SO4)3(H2O)36], the first mineral with a polyoxometalate cation"
1363:
2354:
2904:
2187:
Day, V. W.; Eberspacher, T. A.; Klemperer, W. G.; Park, C. W. (1993). "Dodecatitanates: a new family of stable polyoxotitanates".
2481:
Guo, Hong-Xu; Liu, Shi-Xiong (2004). "A novel 3D organic–inorganic hybrid based on sandwich-type cadmium heteropolymolybdate: Cd
2844:
Lehmann, J.; Gaita-Ariño, A.; Coronado, E.; Loss, D. (2007). "Spin qubits with electrically gated polyoxometalate molecules".
2632:
Kozhevnikov, Ivan V. (1998). "Catalysis by Heteropoly Acids and Multicomponent Polyoxometalates in Liquid-Phase Reactions".
2040:"Scandium(III) or lanthanide(III) triflates as recyclable catalysts for the direct acetylation of alcohols with acetic acid"
1946:
Matsumoto, M.; Ozawa, Y.; Yagasaki, A.; Zhe, Y. (2013). "Decatantalate—The Last Member of the Group 5 Decametalate Family".
404:
2065:
Boglio, Cécile; Lemière, Gilles; Hasenknopf, Bernold; Thorimbert, Serge; Lacôte, Emmanuel; Malacria, Max (2006-05-12).
3277:
Pope, M. T.; Müller, A. (1991). "Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines".
488:. Interior oxides are typically triply bridging or even octahedral. POMs are sometimes viewed as soluble fragments of
2249:
Sadeghi, Omid; Zakharov, Lev N.; Nyman, May (2015). "Aqueous formation and manipulation of the iron-oxo Keggin ion".
1122:
The terminal oxide centers of polyoxometalate framework can in certain cases be replaced with other ligands, such as
3084:"Transition-metal-substituted polyoxometalate derivatives as functional anti-amyloid agents for Alzheimer's disease"
1488:
Day, V. W.; Klemperer, W. G. (1985). "Metal Oxide Chemistry in Solution: The Early Transition Metal Polyoxoanions".
548:
3381:
2546:
Dexter, D. D.; Silverton, J. V. (1968). "A New Structural Type for Heteropoly Anions. The Crystal Structure of (NH
427:
507:
454:
663:
2302:"Breaking the Gordian Knot in the Structural Chemistry of Polyoxometalates: Copper(II)–Oxo/Hydroxo Clusters"
1757:"Ammonium Pertechnetate in Mixtures of Trifluoromethanesulfonic Acid and Trifluoromethanesulfonic Anhydride"
750:
467:, the first example of a mineral with a polyoxometalate cation, was described in 2016 in Mt. Ramazzo Mine,
3376:
2597:
Misono, Makoto (1993). "Catalytic chemistry of solid polyoxometalates and their industrial applications".
1983:"Lanthanides Singing the Blues: Their Fascinating Role in the Assembly of Gigantic Molybdenum Blue Wheels"
1540:
1197:
Efforts continue to extend this theme. POM-based aerobic oxidations have been promoted as alternatives to
1015:
719:
539:
141:
1618:
Chisholm, M. H.; of Newnham, Lord Lewis of (2008). "Frank Albert Cotton. 9 April 1930—20 February 2007".
766:
or trifluoromethanesulfonic acid solutions. The first empirically isolated polyoxotechnetate was the red
575:
3190:"The antibacterial activity of polyoxometalates: structures, antibiotic effects and future perspectives"
1083:
1071:
443:
531:
510:
metal-oxo bonds of different multiplicity and strength. In a typical POM such as the Keggin structure
3095:
2931:
2863:
2774:
2704:
2258:
1552:
1497:
1459:
389:
3082:
Gao, Nan; Sun, Hanjun; Dong, Kai; Ren, Jinsong; Duan, Taicheng; Xu, Can; Qu, Xiaogang (2014-03-04).
3010:"Polyoxometalates: introduction to a class of inorganic compounds and their biomedical applications"
3333:
Cronin, L.; Müller, A. (2012). Cronin, L.; Müller, A. (eds.). "Special Issue on Polyoxometalates".
1343:
1222:
271:
3386:
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2720:
2614:
2393:
2282:
1736:
1684:
1635:
1568:
1521:
957:
951:
917:(M = Nb, Ta) are isostructural with decavanadate. They are formed exclusively by edge-sharing {MO
500:
121:
464:
3350:
3321:
3265:
3227:
3209:
3170:
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116:. Two broad families are recognized, isopolymetalates, composed of only one kind of metal and
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3342:
3311:
3286:
3257:
3217:
3201:
3160:
3144:
3103:
3054:
3021:
2982:
2973:
Rhule, Jeffrey T.; Hill, Craig L.; Judd, Deborah A. (1998). "Polyoxometalates in Medicine".
2939:
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1351:
1079:
535:
458:
447:
63:
35:
1911:
Graeber, E. J.; Morosin, B. (1977). "The molecular configuration of the decaniobate ion (Nb
730:
442:
anion, was reported in 1826. The isostructural phosphotungstate anion was characterized by
1206:
1063:
1023:
890:
715:
106:
94:
78:
74:
3133:"Polyoxometalates as Potential Next-Generation Metallodrugs in the Combat Against Cancer"
2817:
Populations. Synthesis, Spin Organization, Magnetochemistry, and Spectroscopic Studies".
3099:
2935:
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2778:
2708:
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1556:
1501:
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2015:
1982:
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55:
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2397:
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1998:
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1572:
3053:. Topics in Molecular Organization and Engineering. Vol. 10. pp. 337–342.
2802:
2724:
1639:
1525:
2959:
2891:
1564:
1226:
1202:
1181:, which has face-shared octahedra with Mo atoms at the vertices of an icosahedron.
581:
1826:
2505:
1509:
489:
232:
110:
17:
1355:
1082:
and are also able to form inorganic–organic adducts, which can be exploited in
124:, composed of one or more metals, oxide, and eventually a main group oxyanion (
3058:
2716:
2532:
1932:
1450:
Keggin, J. F. (1934). "The Structure and Formula of 12-Phosphotungstic Acid".
1267:
1194:
POMs are employed as commercial catalysts for oxidation of organic compounds.
1138:. Other ligands replacing the oxide ions have also been demonstrated, such as
1075:
1067:
1056:
485:
480:
98:
3213:
3156:
3051:
Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity - Springer
2137:
2113:
2090:
2006:
1780:
1406:
522:, each addenda center connects to single terminal oxo ligand, four bridging μ
2786:
2270:
1595:
Bonding and Charge Distribution in Polyoxometalates: A Bond Valence Approach
1262:
1242:
1238:
1014:
Two views of a cluster, omitting water and counter ions. Also shown is the
1010:
961:
779:
408:
381:
125:
66:
43:
3354:
3325:
3290:
3269:
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2318:
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2145:
2098:
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2024:
1967:
1869:
1834:
1798:
1772:
1732:
1724:
1680:
1631:
1517:
1471:
1414:
778:. It contains both Tc(V) and Tc(VII) in ratio 4: 16 and is obtained as the
73:
atoms to form closed 3-dimensional frameworks. The metal atoms are usually
2355:
10.1002/1521-3773(20001103)39:21<3884::AID-ANIE3884>3.0.CO;2-M
30:
2858:
1198:
1139:
989:
975:
385:
129:
90:
82:
2943:
2583:
2200:
2112:
Sadakane, Masahiro; Dickman, Michael H.; Pope, Michael T. (2001-06-01).
499:-polyoxometalates (isopolyanions) feature octahedral metal centers. The
3346:
3205:
3108:
3083:
2751:
2610:
2389:
1861:
1671:
1654:
1397:
1380:
1149:
Polyfluoroxometalate are yet another class of O-replaced oxometalates.
1127:
1123:
960:. Many different elements can serve as heteroatoms but most common are
830:. It contains Re(VII) in both octahedral and tetrahedral coordination.
757:
Polyoxotechnetates form only in strongly acidic conditions, such as in
468:
252:
102:
86:
3316:
3299:
3131:
Bijelic, Aleksandar; Aureliano, Manuel; Rompel, Annette (2019-03-04).
2986:
2830:
2645:
2227:
2129:
1959:
1897:
956:
Heteroatoms aside from the transition metal are a defining feature of
3261:
2680:
2051:
2039:
1143:
1110:
group), the iron oxoalkoxometalates and iron and copper Keggin ions.
1107:
710:} centers, sometimes slightly distorted. Some polymolybdates contain
70:
1157:
Numerous hybrid organic–inorganic materials that contain POM cores,
534:
in polyoxometalates are normally absent and owing to this property,
305:
An abbreviated condensation sequence illustrated with vanadates is:
2164:
Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity
1655:"Metal-MetalBonds, Metal–metal bonds in polyoxometalate chemistry"
1218:
1131:
1009:
749:
729:
418:
117:
113:
59:
29:
3026:
3009:
3188:
Bijelic, Aleksandar; Aureliano, Manuel; Rompel, Annette (2018).
942:
comprises edge-sharing and corner-sharing tungstate octahedra).
1059:
461:
allowed the structural characterization of POMs in solution.
423:
Dr. James F. Keggin, the discoverer of the Keggin Structure.
132:, etc.). Many exceptions to these general statements exist.
170:
1381:"Polyoxometalates in solution: speciation under spotlight"
380:
When such acidifications are conducted in the presence of
2038:
Barrett, Anthony G. M.; Christopher Braddock, D. (1997).
1160:
Illustrative of the diverse structures of POM is the ion
495:
Recurring structural motifs allow POMs to be classified.
638:
Paratungstate B, also called dihydrogen paratungstate,
109:. Polyoxometalates are often colorless, orange or red
266:species entails loss of water and the formation of
2157:
2155:
1346:(1990). "Tetrabutylammonium Isopolyoxometalates".
1205:). Polyoxometalates have been shown to catalyse
538:opposed to consider polyoxometalates as form of
251:. These species condense via the process called
1304:(2nd ed.). Oxford: Butterworth-Heinemann.
1981:Al-Sayed, Emir; Rompel, Annette (2022-03-02).
714:units. These building blocks are found in the
388:, heteropolymetalate result. For example, the
1379:Gumerova, Nadiia I.; Rompel, Annette (2020).
1026:anions and spherical keplerates. The cluster
8:
921:} octahedra (the structure of decatungstate
1022:Polyoxomolybdates include the wheel-shaped
2162:Pope, Michael Thor; Müller, Achim (1994).
834:Polyoxotantalates, niobates, and vanadates
530:-O deriving from the central heterogroup.
479:The typical framework building blocks are
235:to give oxide–hydroxide compounds such as
3315:
3221:
3164:
3107:
3025:
2857:
2317:
2014:
1788:
1670:
1426:
1424:
1396:
1295:
1293:
1291:
1289:
1287:
407:tungsten oxyanions surrounding a central
1049:
1045:
1041:
1037:
1033:
1029:
825:
821:
813:
801:
797:
793:
789:
785:
773:
769:
761:
741:
737:
684:
680:
676:
645:
641:
614:
587:
557:
517:
513:
453:The 1970s witnessed the introduction of
437:
433:
398:
394:
372:
359:
355:
342:
333:
320:
297:
293:
289:
261:
246:
238:
227:
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216:
212:
165:
158:
151:
147:
3137:Angewandte Chemie International Edition
2071:Angewandte Chemie International Edition
1761:Angewandte Chemie International Edition
1300:Greenwood, N. N.; Earnshaw, A. (1997).
1283:
611:Line drawing of disodium decavanadate,
544:
38:anion, an example of a polyoxometalate
3049:Pope, Michael; Müller, Achim (1994).
1483:
1481:
1338:
1336:
1134:. Sulfur-substituted POMs are called
7:
3300:"Special Volume on Polyoxometalates"
2300:Kondinski, A.; Monakhov, K. (2017).
1327:Heteropoly and Isopoly Oxometalates
896:The decametalates with the formula
506:Polyoxometalates typically exhibit
446:1934. This structure is called the
2905:"Flash memory breaches nanoscales"
2494:Inorganic Chemistry Communications
1078:-containing polyoxometalates show
1074:and perform catalytic properties.
403:consists of a framework of twelve
105:) transition metals in their high
25:
1185:Use and aspirational applications
62:, that consists of three or more
1999:10.1021/acsnanoscienceau.1c00036
1350:. Vol. 27. pp. 74–85.
1223:non-volatile (permanent) storage
662:
631:
604:
574:
547:
270:linkages. The stoichiometry for
734:The structure of the polyanion
726:Polyoxotechnetates and rhenates
27:Ion with many transition metals
2521:Coordination Chemistry Reviews
2413:Chemistry - A European Journal
1713:Chemistry – A European Journal
1653:Kondinski, Aleksandar (2021).
1545:European Journal of Mineralogy
1:
2306:Chemistry: A European Journal
1827:10.1021/acs.inorgchem.3c01863
702:Polymolybdates and tungstates
526:-O ligands and one bridging μ
3008:Hasenknopf, Bernold (2005).
2506:10.1016/j.inoche.2004.09.010
1510:10.1126/science.228.4699.533
1329:. New York: Springer Verlag.
1066:is particularly intriguing.
1886:Crystal Growth & Design
3403:
3279:Angew. Chem. Int. Ed. Engl
1620:Biogr. Mem. Fellows R. Soc
1565:10.1127/ejm/2018/0030-2748
1356:10.1002/9780470132586.ch15
1225:components, also known as
1114:Sulfido, imido, and other
1106:(where OPri stands for an
949:
69:linked together by shared
3059:10.1007/978-94-011-0920-8
2717:10.1080/03067310500247520
2533:10.1016/j.ccr.2015.07.001
1933:10.1107/S0567740877007900
1302:Chemistry of the Elements
554:Lindqvist hexamolybdate,
455:quaternary ammonium salts
428:Ammonium phosphomolybdate
77:(Mo, W) or less commonly
1921:Acta Crystallographica B
1385:Chemical Society Reviews
173:to give orthometalates,
3194:Chemical Communications
3014:Frontiers in Bioscience
2787:10.1126/science.1257443
2697:Int. J. Env. Anal. Chem
2271:10.1126/science.aaa4620
2044:Chemical Communications
1593:Mingos, D.M.P. (1999).
720:mixed valence compounds
3291:10.1002/anie.199100341
3149:10.1002/anie.201803868
2876:10.1038/nnano.2007.110
2460:10.1002/anie.200604734
2425:10.1002/chem.201704287
2319:10.1002/chem.201605876
2083:10.1002/anie.200600364
1773:10.1002/anie.202113777
1725:10.1002/chem.202102035
1632:10.1098/rsbm.2008.0003
1472:10.1098/rspa.1934.0035
1118:-replaced oxometalates
1019:
754:
747:
712:pentagonal bipyramidal
450:after its discoverer.
424:
390:phosphotungstate anion
39:
3088:Nature Communications
1213:Molecular electronics
1013:
753:
733:
475:Structure and bonding
444:X-ray crystallography
422:
33:
3298:Hill, C. L. (1998).
2448:Angew. Chem. Int. Ed
1433:L'Actualité Chimique
1325:Pope, M. T. (1983).
1136:polyoxothiometalates
1016:X-ray powder pattern
810:by concentrating an
288:+ 10 HCl → [Mo
258:Condensation of the
3100:2014NatCo...5.3422G
2944:10.1038/nature13951
2936:2014Natur.515..545B
2868:2007NatNa...2..312L
2779:2014Sci...345.1326R
2773:(6202): 1326–1330.
2709:2006IJEAC..86..233H
2584:10.1021/ja01015a067
2263:2015Sci...347.1359S
2257:(6228): 1359–1362.
2201:10.1021/ja00071a075
2118:Inorganic Chemistry
1856:(41): 15295–15299.
1821:(33): 13485–13494.
1815:Inorganic Chemistry
1719:(54): 13624–13631.
1665:(32): 13574–13592.
1557:2018EJMin..30..827K
1502:1985Sci...228..533D
1464:1934RSPSA.144...75K
1348:Inorganic Syntheses
1190:Oxidation catalysts
958:heteropolymetalates
501:heteropolymetalates
122:heteropolymetalates
3347:10.1039/C2CS90087D
3206:10.1039/C7CC07549A
3109:10.1038/ncomms4422
2752:10.1039/C1GC15434F
2611:10.1007/BF00999633
2390:10.1007/BF00999625
1987:ACS Nanoscience Au
1862:10.1039/C4DT02394C
1672:10.1039/D1NR02357H
1398:10.1039/D0CS00392A
1090:Oxoalkoxometalates
1020:
952:heteropolymetalate
755:
748:
425:
40:
3382:Cluster chemistry
3341:(22): 7325–7648.
3317:10.1021/cr960395y
3200:(10): 1153–1169.
3143:(10): 2980–2999.
3068:978-94-010-4397-7
2987:10.1021/cr960396q
2930:(7528): 545–549.
2831:10.1021/ic9703641
2825:(23): 5239–5240.
2646:10.1021/cr960400y
2578:(13): 3589–3590.
2454:(21): 3900–3904.
2349:(21): 3884–3886.
2312:(33): 7841–7852.
2228:10.1021/ja025590a
2222:(17): 4578–4579.
2195:(18): 8469–8470.
2173:978-0-7923-2421-8
2130:10.1021/ic0014383
2124:(12): 2715–2719.
2077:(20): 3324–3327.
1960:10.1021/ic400864e
1954:(14): 7825–7827.
1898:10.1021/cg0606904
1767:(3): e202113777.
1604:978-3-662-15621-6
1496:(4699): 533–541.
1391:(21): 7568–7601.
1311:978-0-7506-3365-9
1273:Metal aromaticity
540:cluster materials
532:Metal–metal bonds
169:dissolve at high
16:(Redirected from
3394:
3358:
3329:
3319:
3294:
3273:
3262:10.1039/b502666k
3236:
3235:
3225:
3185:
3179:
3178:
3168:
3128:
3122:
3121:
3111:
3079:
3073:
3072:
3046:
3040:
3039:
3029:
3005:
2999:
2998:
2970:
2964:
2963:
2918:
2912:
2902:
2896:
2895:
2861:
2859:cond-mat/0703501
2841:
2835:
2834:
2813:
2807:
2806:
2762:
2756:
2755:
2735:
2729:
2728:
2691:
2685:
2684:
2681:10.1039/b607824a
2664:
2658:
2657:
2629:
2623:
2622:
2605:(1–3): 193–203.
2594:
2588:
2587:
2572:J. Am. Chem. Soc
2543:
2537:
2536:
2516:
2510:
2509:
2478:
2472:
2471:
2443:
2437:
2436:
2408:
2402:
2401:
2373:
2367:
2366:
2338:
2332:
2331:
2321:
2297:
2291:
2290:
2246:
2240:
2239:
2216:J. Am. Chem. Soc
2211:
2205:
2204:
2189:J. Am. Chem. Soc
2184:
2178:
2177:
2159:
2150:
2149:
2109:
2103:
2102:
2062:
2056:
2055:
2052:10.1039/a606484a
2035:
2029:
2028:
2018:
1978:
1972:
1971:
1943:
1937:
1936:
1927:(7): 2137–2143.
1908:
1902:
1901:
1880:
1874:
1873:
1845:
1839:
1838:
1809:
1803:
1802:
1792:
1751:
1745:
1744:
1703:Polyoxometalate
1699:
1693:
1692:
1674:
1650:
1644:
1643:
1615:
1609:
1608:
1590:
1584:
1583:
1581:
1579:
1536:
1530:
1529:
1485:
1476:
1475:
1447:
1441:
1440:
1428:
1419:
1418:
1400:
1376:
1370:
1369:
1344:Klemperer, W. G.
1340:
1331:
1330:
1322:
1316:
1315:
1297:
1180:
1179:
1178:
1170:
1169:
1080:chemoselectivity
1070:can behave like
1064:molybdenum blues
1053:
1006:Giant structures
1000:
999:
998:
986:
985:
984:
972:
971:
970:
941:
940:
939:
931:
930:
916:
915:
914:
906:
905:
887:
886:
885:
877:
876:
858:
857:
856:
848:
847:
829:
816:
809:
777:
764:
745:
716:molybdenum blues
696:
695:
694:
691:
673:-polymolybdate,
666:
657:
656:
655:
652:
635:
626:
625:
624:
621:
608:
599:
598:
597:
594:
578:
569:
568:
567:
564:
551:
536:F. Albert Cotton
521:
459:NMR spectroscopy
448:Keggin structure
441:
402:
376:
370:
369:
366:
353:
352:
349:
337:
331:
330:
327:
318:
317:
314:
301:
287:
286:
283:
269:
265:
250:
242:
230:
219:
208:
207:
206:
203:
196:
195:
194:
191:
184:
183:
182:
179:
168:
161:
154:
107:oxidation states
64:transition metal
36:phosphotungstate
21:
18:Polyoxometallate
3402:
3401:
3397:
3396:
3395:
3393:
3392:
3391:
3362:
3361:
3332:
3297:
3276:
3247:
3244:
3242:Further reading
3239:
3187:
3186:
3182:
3130:
3129:
3125:
3081:
3080:
3076:
3069:
3048:
3047:
3043:
3020:(1–3): 275–87.
3007:
3006:
3002:
2972:
2971:
2967:
2920:
2919:
2915:
2903:
2899:
2843:
2842:
2838:
2815:
2814:
2810:
2764:
2763:
2759:
2737:
2736:
2732:
2693:
2692:
2688:
2666:
2665:
2661:
2631:
2630:
2626:
2596:
2595:
2591:
2569:
2565:
2561:
2557:
2553:
2549:
2545:
2544:
2540:
2518:
2517:
2513:
2491:
2487:
2484:
2480:
2479:
2475:
2445:
2444:
2440:
2410:
2409:
2405:
2375:
2374:
2370:
2340:
2339:
2335:
2299:
2298:
2294:
2248:
2247:
2243:
2213:
2212:
2208:
2186:
2185:
2181:
2174:
2161:
2160:
2153:
2111:
2110:
2106:
2064:
2063:
2059:
2037:
2036:
2032:
1980:
1979:
1975:
1945:
1944:
1940:
1918:
1914:
1910:
1909:
1905:
1882:
1881:
1877:
1847:
1846:
1842:
1811:
1810:
1806:
1753:
1752:
1748:
1710:
1706:
1701:
1700:
1696:
1652:
1651:
1647:
1617:
1616:
1612:
1605:
1592:
1591:
1587:
1577:
1575:
1538:
1537:
1533:
1487:
1486:
1479:
1458:(851): 75–100.
1452:Proc. R. Soc. A
1449:
1448:
1444:
1430:
1429:
1422:
1378:
1377:
1373:
1366:
1342:
1341:
1334:
1324:
1323:
1319:
1312:
1299:
1298:
1285:
1281:
1259:
1252:
1248:
1235:
1215:
1207:water splitting
1192:
1187:
1177:
1174:
1173:
1172:
1168:
1165:
1164:
1163:
1161:
1155:
1120:
1105:
1101:
1097:
1092:
1051:
1047:
1043:
1039:
1035:
1031:
1027:
1024:molybdenum blue
1008:
997:
994:
993:
992:
990:
983:
980:
979:
978:
976:
969:
966:
965:
964:
962:
954:
948:
938:
935:
934:
933:
929:
926:
925:
924:
922:
920:
913:
910:
909:
908:
904:
901:
900:
899:
897:
884:
881:
880:
879:
875:
872:
871:
870:
868:
866:
862:
855:
852:
851:
850:
846:
843:
842:
841:
839:
836:
827:
823:
819:
815:
811:
807:
803:
799:
795:
791:
787:
783:
775:
771:
767:
763:
759:
743:
739:
735:
728:
709:
704:
697:
692:
689:
688:
686:
682:
678:
674:
672:
667:
658:
653:
650:
649:
647:
643:
639:
636:
627:
622:
619:
618:
616:
612:
609:
600:
595:
592:
591:
589:
585:
579:
570:
565:
562:
561:
559:
555:
552:
529:
525:
519:
515:
511:
477:
439:
435:
431:
417:
400:
396:
392:
374:
367:
364:
363:
361:
357:
350:
347:
346:
344:
340:
335:
328:
325:
324:
322:
315:
312:
311:
309:
299:
296:] + 10 Cl + 5 H
295:
291:
284:
281:
280:
278:
267:
263:
259:
248:
244:
240:
236:
229:
225:
221:
218:
214:
210:
204:
201:
200:
198:
192:
189:
188:
186:
180:
177:
176:
174:
167:
163:
160:
156:
153:
149:
145:
144:metals such as
138:
48:polyoxometalate
28:
23:
22:
15:
12:
11:
5:
3400:
3398:
3390:
3389:
3384:
3379:
3374:
3364:
3363:
3360:
3359:
3335:Chem. Soc. Rev
3330:
3295:
3274:
3256:(1): 105–121.
3250:Chem. Soc. Rev
3243:
3240:
3238:
3237:
3180:
3123:
3074:
3067:
3041:
3000:
2981:(1): 327–358.
2965:
2913:
2897:
2852:(5): 312–317.
2846:Nanotechnology
2836:
2808:
2757:
2730:
2686:
2675:(7): 717–730.
2659:
2640:(1): 171–198.
2624:
2589:
2567:
2563:
2559:
2555:
2551:
2547:
2538:
2511:
2489:
2485:
2482:
2473:
2438:
2419:(2): 369–379.
2403:
2384:(1–3): 79–91.
2368:
2333:
2292:
2241:
2206:
2179:
2172:
2151:
2104:
2057:
2046:(4): 351–352.
2030:
1993:(3): 179–197.
1973:
1938:
1916:
1912:
1903:
1892:(4): 719–723.
1875:
1840:
1804:
1746:
1708:
1704:
1694:
1645:
1610:
1603:
1585:
1551:(4): 182–186.
1531:
1477:
1442:
1420:
1371:
1364:
1332:
1317:
1310:
1282:
1280:
1277:
1276:
1275:
1270:
1265:
1258:
1255:
1250:
1246:
1234:
1231:
1214:
1211:
1191:
1188:
1186:
1183:
1175:
1166:
1154:
1151:
1119:
1112:
1103:
1099:
1095:
1091:
1088:
1007:
1004:
995:
981:
967:
950:Main article:
947:
944:
936:
927:
918:
911:
902:
882:
873:
864:
860:
853:
844:
835:
832:
805:
727:
724:
707:
703:
700:
699:
698:
670:
668:
661:
659:
637:
630:
628:
610:
603:
601:
580:
573:
571:
553:
546:
527:
523:
476:
473:
469:Liguria, Italy
416:
413:
378:
377:
354:+ 12 H → 2 V
338:
303:
302:
140:The oxides of
137:
134:
56:polyatomic ion
26:
24:
14:
13:
10:
9:
6:
4:
3:
2:
3399:
3388:
3385:
3383:
3380:
3378:
3377:Oxometallates
3375:
3373:
3370:
3369:
3367:
3356:
3352:
3348:
3344:
3340:
3336:
3331:
3327:
3323:
3318:
3313:
3309:
3305:
3301:
3296:
3292:
3288:
3284:
3280:
3275:
3271:
3267:
3263:
3259:
3255:
3251:
3246:
3245:
3241:
3233:
3229:
3224:
3219:
3215:
3211:
3207:
3203:
3199:
3195:
3191:
3184:
3181:
3176:
3172:
3167:
3162:
3158:
3154:
3150:
3146:
3142:
3138:
3134:
3127:
3124:
3119:
3115:
3110:
3105:
3101:
3097:
3093:
3089:
3085:
3078:
3075:
3070:
3064:
3060:
3056:
3052:
3045:
3042:
3037:
3033:
3028:
3023:
3019:
3015:
3011:
3004:
3001:
2996:
2992:
2988:
2984:
2980:
2976:
2969:
2966:
2961:
2957:
2953:
2949:
2945:
2941:
2937:
2933:
2929:
2925:
2917:
2914:
2910:
2906:
2901:
2898:
2893:
2889:
2885:
2881:
2877:
2873:
2869:
2865:
2860:
2855:
2851:
2847:
2840:
2837:
2832:
2828:
2824:
2820:
2812:
2809:
2804:
2800:
2796:
2792:
2788:
2784:
2780:
2776:
2772:
2768:
2761:
2758:
2753:
2749:
2745:
2741:
2734:
2731:
2726:
2722:
2718:
2714:
2710:
2706:
2702:
2698:
2690:
2687:
2682:
2678:
2674:
2670:
2663:
2660:
2655:
2651:
2647:
2643:
2639:
2635:
2628:
2625:
2620:
2616:
2612:
2608:
2604:
2600:
2593:
2590:
2585:
2581:
2577:
2573:
2542:
2539:
2534:
2530:
2526:
2522:
2515:
2512:
2507:
2503:
2499:
2495:
2477:
2474:
2469:
2465:
2461:
2457:
2453:
2449:
2442:
2439:
2434:
2430:
2426:
2422:
2418:
2414:
2407:
2404:
2399:
2395:
2391:
2387:
2383:
2379:
2372:
2369:
2364:
2360:
2356:
2352:
2348:
2344:
2337:
2334:
2329:
2325:
2320:
2315:
2311:
2307:
2303:
2296:
2293:
2288:
2284:
2280:
2276:
2272:
2268:
2264:
2260:
2256:
2252:
2245:
2242:
2237:
2233:
2229:
2225:
2221:
2217:
2210:
2207:
2202:
2198:
2194:
2190:
2183:
2180:
2175:
2169:
2165:
2158:
2156:
2152:
2147:
2143:
2139:
2135:
2131:
2127:
2123:
2119:
2115:
2108:
2105:
2100:
2096:
2092:
2088:
2084:
2080:
2076:
2072:
2068:
2061:
2058:
2053:
2049:
2045:
2041:
2034:
2031:
2026:
2022:
2017:
2012:
2008:
2004:
2000:
1996:
1992:
1988:
1984:
1977:
1974:
1969:
1965:
1961:
1957:
1953:
1949:
1942:
1939:
1934:
1930:
1926:
1922:
1907:
1904:
1899:
1895:
1891:
1887:
1879:
1876:
1871:
1867:
1863:
1859:
1855:
1851:
1844:
1841:
1836:
1832:
1828:
1824:
1820:
1816:
1808:
1805:
1800:
1796:
1791:
1786:
1782:
1778:
1774:
1770:
1766:
1762:
1758:
1750:
1747:
1742:
1738:
1734:
1730:
1726:
1722:
1718:
1714:
1698:
1695:
1690:
1686:
1682:
1678:
1673:
1668:
1664:
1660:
1656:
1649:
1646:
1641:
1637:
1633:
1629:
1625:
1621:
1614:
1611:
1606:
1600:
1596:
1589:
1586:
1574:
1570:
1566:
1562:
1558:
1554:
1550:
1546:
1542:
1535:
1532:
1527:
1523:
1519:
1515:
1511:
1507:
1503:
1499:
1495:
1491:
1484:
1482:
1478:
1473:
1469:
1465:
1461:
1457:
1453:
1446:
1443:
1438:
1434:
1427:
1425:
1421:
1416:
1412:
1408:
1404:
1399:
1394:
1390:
1386:
1382:
1375:
1372:
1367:
1365:9780470132586
1361:
1357:
1353:
1349:
1345:
1339:
1337:
1333:
1328:
1321:
1318:
1313:
1307:
1303:
1296:
1294:
1292:
1290:
1288:
1284:
1278:
1274:
1271:
1269:
1266:
1264:
1261:
1260:
1256:
1254:
1244:
1240:
1232:
1230:
1228:
1224:
1220:
1212:
1210:
1208:
1204:
1200:
1195:
1189:
1184:
1182:
1158:
1152:
1150:
1147:
1145:
1141:
1137:
1133:
1129:
1125:
1117:
1113:
1111:
1109:
1089:
1087:
1086:recognition.
1085:
1081:
1077:
1073:
1069:
1065:
1061:
1058:
1025:
1018:for the salt.
1017:
1012:
1005:
1003:
1001:
987:
973:
959:
953:
945:
943:
894:
892:
833:
831:
781:
765:
752:
732:
725:
723:
721:
717:
713:
701:
665:
660:
634:
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607:
602:
583:
577:
572:
550:
545:
543:
541:
537:
533:
509:
504:
502:
498:
493:
491:
487:
482:
474:
472:
470:
466:
462:
460:
456:
451:
449:
445:
429:
421:
414:
412:
410:
406:
391:
387:
383:
339:
308:
307:
306:
277:
276:
275:
273:
272:hexamolybdate
256:
254:
234:
172:
143:
135:
133:
131:
127:
123:
119:
115:
112:
108:
104:
100:
96:
92:
88:
84:
80:
76:
72:
68:
65:
61:
58:, usually an
57:
53:
50:(abbreviated
49:
45:
37:
32:
19:
3338:
3334:
3307:
3303:
3282:
3278:
3253:
3249:
3197:
3193:
3183:
3140:
3136:
3126:
3091:
3087:
3077:
3050:
3044:
3027:10.2741/1527
3017:
3013:
3003:
2978:
2974:
2968:
2927:
2923:
2916:
2908:
2900:
2849:
2845:
2839:
2822:
2818:
2811:
2770:
2766:
2760:
2746:(10): 2759.
2743:
2739:
2733:
2703:(3–4): 233.
2700:
2696:
2689:
2672:
2668:
2662:
2637:
2633:
2627:
2602:
2598:
2592:
2575:
2571:
2541:
2524:
2520:
2514:
2500:(11): 1217.
2497:
2493:
2476:
2451:
2447:
2441:
2416:
2412:
2406:
2381:
2377:
2371:
2346:
2342:
2336:
2309:
2305:
2295:
2254:
2250:
2244:
2219:
2215:
2209:
2192:
2188:
2182:
2166:. Springer.
2163:
2121:
2117:
2107:
2074:
2070:
2060:
2043:
2033:
1990:
1986:
1976:
1951:
1947:
1941:
1924:
1920:
1906:
1889:
1885:
1878:
1853:
1850:Dalton Trans
1849:
1843:
1818:
1814:
1807:
1764:
1760:
1749:
1716:
1712:
1697:
1662:
1658:
1648:
1623:
1619:
1613:
1597:. Springer.
1594:
1588:
1576:. Retrieved
1548:
1544:
1534:
1493:
1489:
1455:
1451:
1445:
1436:
1432:
1388:
1384:
1374:
1347:
1326:
1320:
1301:
1236:
1227:flash memory
1216:
1203:OxFA process
1196:
1193:
1159:
1156:
1148:
1135:
1121:
1115:
1093:
1021:
955:
895:
837:
756:
718:, which are
705:
582:Decavanadate
505:
496:
494:
490:metal oxides
478:
463:
452:
426:
379:
304:
257:
139:
51:
47:
41:
2819:Inorg. Chem
2343:Angew. Chem
1948:Inorg. Chem
1072:Lewis acids
1068:Lanthanides
946:Heteroatoms
486:oxo ligands
319:+ 8 H → V
111:diamagnetic
3366:Categories
3310:(1): 1–2.
2740:Green Chem
2669:Green Chem
1626:: 95–115.
1279:References
1268:Perovskite
1237:Potential
1076:Lanthanide
1057:lanthanide
508:coordinate
481:polyhedral
465:Ramazzoite
405:octahedral
274:is shown:
3387:Catalysts
3372:Oxyanions
3304:Chem. Rev
3285:: 34–48.
3214:1359-7345
3157:1433-7851
2975:Chem. Rev
2909:The Hindu
2634:Chem. Rev
2619:195235697
2527:: 42–64.
2398:195235379
2287:206634621
2138:0020-1669
2091:1433-7851
2007:2694-2496
1781:1433-7851
1741:235787236
1689:237398818
1659:Nanoscale
1573:134883484
1407:0306-0012
1263:Superatom
1243:antiviral
1239:antitumor
1229:devices.
804:]·4H
780:hydronium
409:phosphate
382:phosphate
233:protonate
136:Formation
126:phosphate
67:oxyanions
44:chemistry
3355:23052289
3326:11851497
3270:17173149
3232:29355262
3175:29893459
3118:24595206
3094:: 3422.
3036:15574368
2995:11851509
2952:25409147
2884:18654290
2803:20572410
2795:25214625
2725:93535976
2654:11851502
2599:Mol. Eng
2468:17429852
2433:29064591
2378:Mol. Eng
2363:29711675
2328:28083988
2279:25721507
2236:11971702
2146:11375685
2099:16619320
2025:35726275
1968:23795610
1870:25189708
1835:37599582
1799:34752692
1733:34245056
1681:34477632
1640:71372188
1526:32953306
1518:17736064
1415:32990698
1257:See also
1199:chlorine
1146:groups.
1140:nitrosyl
432:[PMo
386:silicate
130:silicate
3223:5804480
3166:6391951
3096:Bibcode
2960:4455788
2932:Bibcode
2892:1011997
2864:Bibcode
2775:Bibcode
2767:Science
2705:Bibcode
2259:Bibcode
2251:Science
2016:9204829
1790:9299680
1553:Bibcode
1498:Bibcode
1490:Science
1460:Bibcode
1028:[Mo
891:group 6
820:[Re
796:[Tc
768:[Tc
736:[Tc
512:[PW
415:History
411:group.
393:[PW
253:olation
95:group 7
79:group 5
75:group 6
54:) is a
3353:
3324:
3268:
3230:
3220:
3212:
3173:
3163:
3155:
3116:
3065:
3034:
2993:
2958:
2950:
2924:Nature
2890:
2882:
2801:
2793:
2723:
2652:
2617:
2466:
2431:
2396:
2361:
2326:
2285:
2277:
2234:
2170:
2144:
2136:
2097:
2089:
2023:
2013:
2005:
1966:
1868:
1833:
1797:
1787:
1779:
1739:
1731:
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1679:
1638:
1601:
1578:21 May
1571:
1524:
1516:
1413:
1405:
1362:
1308:
1219:qubits
1144:alkoxy
1130:, and
1108:alkoxy
1102:(OPri)
1084:chiral
988:, and
893:POMs.
784:[H
209:. For
120:, and
114:anions
93:) and
71:oxygen
2956:S2CID
2888:S2CID
2854:arXiv
2799:S2CID
2721:S2CID
2615:S2CID
2566:)·12H
2558:(CeMo
2394:S2CID
2283:S2CID
1737:S2CID
1685:S2CID
1636:S2CID
1569:S2CID
1522:S2CID
1233:Drugs
1153:Other
782:salt
371:+ 4 H
332:+ 4 H
279:6 MoO
268:M−O−M
118:oxide
60:anion
3351:PMID
3339:2012
3322:PMID
3266:PMID
3228:PMID
3210:ISSN
3171:PMID
3153:ISSN
3114:PMID
3063:ISBN
3032:PMID
2991:PMID
2948:PMID
2880:PMID
2791:PMID
2650:PMID
2576:1968
2570:O".
2492:O".
2464:PMID
2429:PMID
2359:PMID
2324:PMID
2275:PMID
2232:PMID
2168:ISBN
2142:PMID
2134:ISSN
2095:PMID
2087:ISSN
2021:PMID
2003:ISSN
1964:PMID
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1866:PMID
1854:2014
1831:PMID
1795:PMID
1777:ISSN
1729:PMID
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1677:PMID
1599:ISBN
1580:2018
1514:PMID
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1411:PMID
1403:ISSN
1360:ISBN
1306:ISBN
1241:and
1162:CeMo
1142:and
1060:ions
1040:(OH)
1036:(NO)
869:Ta(O
812:HTcO
760:HTcO
362:(OH)
310:4 VO
264:(OH)
249:(OH)
243:and
241:(OH)
220:and
46:, a
34:The
3343:doi
3312:doi
3287:doi
3258:doi
3218:PMC
3202:doi
3161:PMC
3145:doi
3104:doi
3055:doi
3022:doi
2983:doi
2940:doi
2928:515
2872:doi
2827:doi
2783:doi
2771:345
2748:doi
2713:doi
2677:doi
2642:doi
2607:doi
2580:doi
2529:doi
2525:307
2502:doi
2488:·3H
2456:doi
2421:doi
2386:doi
2351:doi
2314:doi
2267:doi
2255:347
2224:doi
2220:124
2197:doi
2193:115
2126:doi
2079:doi
2048:doi
2011:PMC
1995:doi
1956:doi
1929:doi
1894:doi
1858:doi
1823:doi
1785:PMC
1769:doi
1721:doi
1707:⋅4H
1667:doi
1628:doi
1561:doi
1506:doi
1494:228
1468:doi
1456:144
1437:298
1393:doi
1352:doi
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1062:in
1034:420
1030:154
991:AsO
977:SiO
681:112
651:10−
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341:5 V
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