181:
24:
513:
Edward M. Dexheimer and
Leornard Spialter, Lee D. Smithson "Tri-t-butylsilane: synthesis, physical properties, derivatives, and reactivity towards ozonolysis, chlorination, fluorination, and hydrolysis" Journal of Organometallic Chemistry 102, 1975,
399:
display high reactivity so long as they do not undergo intramolecular reactions. Silox offers this possibility. Examples of high reactivity exhibited by metal-silox compounds include the C-O bond in carbon monoxide and the C-N bond in pyridine.
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and is a poorer donor. It is also larger than silylamides. For these reasons, silox anion forms highly unsaturated complexes.
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472:: Synthesis and X-ray Crystal Structure Analysis" Organometallics 2002, 21, 3827-3830.
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Peter T. Wolczanski "Chemistry of electrophilic metal centres coordinated by silox (Bu
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Lerner, Hans-Wolfram; Scholz, Stefan; Bolte, Michael "The Sodium
Siloxides (tBu
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SiOH, which is prepared by a multistep route via the intermediacy of (t-Bu)
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CO) and related bifunctional ligands" Polyhedron, 1995, 14, 3335-3362.
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InChI=1S/C12H27OSi.Na/c1-10(2,3)14(13,11(4,5)6)12(7,8)9;/h1-9H3;/q-1;+1
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often adopt with low coordination numbers. Examples include Ti(silox)
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Na(silox) is usually prepared by deprotonation of the silanol (t-Bu)
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Except where otherwise noted, data are given for materials in their
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The sodium derivative, which has salt-like properties, is a
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322:that serves as a source of the siloxide anion
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420:. It is also obtained by treatment of Bu
346:Properties of silox and related complexes
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357:Related bulky anionic ligands include
326:SiO. Complexes of this bulky anionic
207:Key: QAGFKHQOLBYGIF-UHFFFAOYSA-N
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300:(at 25 °C , 100 kPa).
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520:10.1016/S0022-328X(00)90256-0
228:.CC(C)(C)()(C(C)(C)C)C(C)(C)C
502:10.1016/0277-5387(95)85014-7
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397:coordinative unsaturation
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438:Sodium trimethylsiloxide
539:Organosilicon compounds
380:. Silox has a larger
320:organosilicon compound
47:Systematic IUPAC name
395:Complexes with high
352:cubane-type cluster
318:is the name for an
282: g·mol
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304:Infobox references
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478:10.1021/om020318v
432:Related compounds
312:Chemical compound
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290:colourless solid
160:CompTox Dashboard
103:Interactive image
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544:Sodium compounds
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492:SiO), tritox (Bu
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244:Chemical formula
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55:-butylsilanolate
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17:Sodium silox
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316:Sodium silox
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62:Identifiers
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40:Sodium silox
404:Preparation
334:, Nb(silox)
287:Appearance
237:Properties
79:461703-02-6
51:Sodium tri-
533:Categories
444:References
424:SiNa with
382:cone angle
275:Molar mass
114:ChemSpider
90:3D model (
69:CAS Number
37:IUPAC name
342:), and .
468:PhSiONa)
464:and (tBu
148:23701721
123:35766904
376:N, and
280:238.422
135:PubChem
514:21-27.
460:SiONa)
384:than C
378:NacNac
328:ligand
221:SMILES
31:Names
368:, (Me
196:InChI
92:JSmol
338:(PMe
53:tert
516:doi
498:doi
474:doi
416:SiF
372:Si)
165:EPA
138:CID
535::
428:.
388:Me
363:Me
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268:Si
262:Na
259:27
253:12
522:.
518::
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500::
494:3
490:3
476::
470:4
466:2
462:4
458:3
422:3
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414:2
410:3
390:5
386:5
374:2
370:3
365:5
361:5
359:C
340:3
336:3
332:3
324:3
265:O
256:H
250:C
167:)
163:(
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