Knowledge (XXG)

Tin(II) sulfide

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205: 112: 558:. The chemical formula is SnS. Its natural occurrence concerns herzenbergite (α-SnS), a rare mineral. At elevated temperatures above 905 K, SnS undergoes a second order phase transition to β-SnS (space group: Cmcm, No. 63). In recent years, it has become evident that a new polymorph of SnS exists based upon the cubic crystal system, known as π-SnS (space group: P2 511: 696:
of a solar cell utilizing a tin(II) sulfide absorber layer could be as high as 32%, which is comparable to crystalline silicon. Finally, Tin(II) sulfide is stable in both alkaline and acidic conditions. All aforementioned characteristics suggest tin(II) sulfide as an interesting material to be used
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At present, tin(II) sulfide thin films for use in photovoltaic cells are still in the research phase of development with power conversion efficiencies currently less than 5%. Barriers for use include a low open circuit voltage and an inability to realize many of the above properties due to
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Price, Louise S.; Parkin, Ivan P.; Field, Mark N.; Hardy, Amanda M. E.; Clark, Robin J. H.; Hibbert, Thomas G.; Molloy, Kieran C. (27 Jan 2000) . "Atmospheric pressure chemical vapour deposition of tin(II) sulfide films on glass substrates from
688:) are used as p-type absorber layers, but they are formulated from toxic, scarce constituents. Tin(II) sulfide, by contrast, is formed from cheap, earth abundant elements, and is nontoxic. This material also has a high optical absorption coefficient, p-type conductivity, and a mid range 667:
S. It has a layer structure similar to that of black phosphorus. As per black phosphorus, tin(II) sulfide can be ultrasonically exfoliated in liquids to produce atomically thin semiconducting SnS sheets that have a wider optical band gap (>1.5 eV) compared to the bulk crystal.
727: 1005:.) "The chlorides of tin and phosphorus were all soluble, and slow decomposition resulted in the formation of the respective sulfides." See also Table 1, wherein "Stannous chloride" and "Stannic chloride" are both listed as "Soluble and reactive". 810:
Rabkin, Alexander; Samuha, Shmuel; Abutbul, Ran E.; Ezersky, Vladimir; Meshi, Louisa; Golan, Yuval (2015-03-11). "New Nanocrystalline Materials: A Previously Unknown Simple Cubic Phase in the SnS Binary System".
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Abutbul, R. E.; Segev, E.; Zeiri, L.; Ezersky, V.; Makov, G.; Golan, Y. (2016-01-12). "Synthesis and properties of nanocrystalline π-SnS – a new cubic phase of tin sulphide".
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Wiedemeier, Heribert; von Schnering, Hans Georg (1978-01-01). "Refinement of the structures of GeS, GeSe, SnS and SnSe : Zeitschrift für Kristallographie".
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Andrade-Arvizu, Jacob A.; Courel-Piedrahita, Maykel; Vigil-Galán, Osvaldo (2015-04-14). "SnS-based thin film solar cells: perspectives over the last 25 years".
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of 1.3-1.4 eV, required electronic properties for this type of absorber layer. Based on the a detailed balance calculation using the material bandgap, the
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del Bucchia, S.; Jumas, J.C.; Maurin, M. (1981). "Contribution a l'etude de composes sulfures d'etain (II): Affinement de la structure de Sn S".
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Sato, N.; Ichimura, E. (2003). "Characterization of electrical properties of SnS thin films prepared by the electrochemical deposition method".
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Nair, P. K.; Garcia-Angelmo, A. R.; Nair, M. T. S. (2016-01-01). "Cubic and orthorhombic SnS thin-film absorbers for tin sulfide solar cells".
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solution, the same reaction still gives a mixture of 60% stannous and 35% stannic sulfide. Likewise metallic tin contaminates
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challenges in fabrication, but tin(II) sulfide still remains a promising material if these technical challenges are overcome.
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Tin(II) sulfide is a dark brown or black solid, insoluble in water, but soluble in concentrated
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However, the high-temperature reaction vaporizes sulfur. Consequently effecting the proper
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Jaramillo, R.; Steinmann, V.; Yang, C.; Chakraborty, R.; Poindexter, J. R. (2015).
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Quam, G. N. (8 Jan 1925) . "A study of reactions in liquid hydrogen sulfide".
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Tin(II) sulfide is an interesting potential candidate for next generation
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In principle, tin(II) sulfide can be prepared directly from the elements:
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Proceedings of 3rd World Conference on Photovoltaic Energy Conversion
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Except where otherwise noted, data are given for materials in their
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Baudler, M. (1963) . "Tin and lead". In Brauer, Georg (ed.).
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to SnS at 450 °C. An aqueous rinse then removes the
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Journal of Materials Science: Materials in Electronics
1479: 1315: 399:asymmetric 3-fold (strongly distorted octahedral) 150: 64: 1604: 1293: 8: 1090:"Solar energy conversion towards 1 terawatt" 728:Institute for Occupational Safety and Health 910:Handbook of Preparative Inorganic Chemistry 903: 901: 582:is difficult. At near-room temperature in 1611: 1597: 1589: 1300: 1286: 1278: 308:882 °C (1,620 °F; 1,155 K) 203: 110: 15: 1258: 1105: 1064: 170: 2139: 2135: 2126: 1575: 1571: 1561: 1557: 1468: 1377: 1373: 985:Journal of the American Chemical Society 709: 639: + 2 KSCN → SnS + K 246: 224: 199: 1646: 101: 2509: 1162: 1160: 929: 927: 659:. Tin(II) sulfide is insoluble in (NH 7: 1632: 141: 14: 1088:Ginley, D.; Green, M.A. (2008). 1001:(Excerpted from a PhD thesis at 777:Zeitschrift für Kristallographie 697:as a solar cell absorber layer. 509: 505:(at 25 °C , 100 kPa). 954:Journal of Materials Chemistry 686:copper indium gallium selenide 411:Occupational safety and health 1: 789:10.1524/zkri.1978.148.3-4.295 833:10.1021/acs.nanolett.5b00209 1047:Brent; et al. (2015). 694:power conversion efficiency 280:150.775 g/mol 2865: 2511: 1648: 1629: 1135:10.1007/s10854-015-3050-z 1020:Chemistry of the Elements 1018:; Earnshaw, Alan (1997). 762:10.1107/s0567740881007528 724:GESTIS Substance Database 672:Photovoltaic applications 499: 428: 408: 403: 347:GeS type (orthorhombic), 334: 257: 237: 215: 48: 36: 26: 21: 952:with hydrogen sulfide". 730:, accessed on 4/9/2007. 1169:Physica Status Solidi A 1189:10.1002/pssa.201532426 378: = 11.18 Å, 1024:Butterworth-Heinemann 1016:Greenwood, Norman N. 678:thin-film solar cells 621:potassium thiocyanate 474:Germanium monosulfide 394:Coordination geometry 382: = 3.98 Å, 2849:IV-VI semiconductors 1066:10.1021/jacs.5b08236 605:dissolves in liquid 494:Tributyl tin sulfide 1181:2016PSSAR.213..170N 1059:(39): 12689–12696. 997:10.1021/ja01678a014 876:2016RSCAd...6.5848A 825:2015NanoL..15.2174R 754:1981AcCrB..37.1903D 742:Acta Crystallogr. B 470:Silicon monosulfide 386: = 4.32 Å 325:Solubility in water 18: 1107:10.1557/mrs2008.71 1003:Iowa State College 884:10.1039/c5ra23092f 680:. Currently, both 532:Infobox references 466:Carbon monosulfide 429:Related compounds 16: 2834:Tin(II) compounds 2821: 2820: 2815: 2814: 1586: 1585: 1033:978-0-08-037941-8 682:cadmium telluride 657:hydrochloric acid 629:potassium sulfide 623:reliably reduces 603:stannous chloride 548:chemical compound 540:Chemical compound 538: 537: 485:Related compounds 342:Crystal structure 288:dark brown solid 184:CompTox Dashboard 90:Interactive image 2856: 2345: 2344: 2343: 2142: 2129: 1960: 1954: 1944: 1938: 1792: 1791: 1774: 1768: 1633: 1624: 1613: 1606: 1599: 1590: 1579: 1565: 1471: 1426: 1425: 1424: 1416: 1415: 1407: 1406: 1381: 1302: 1295: 1288: 1279: 1273: 1272: 1262: 1234: 1228: 1227: 1215: 1209: 1208: 1164: 1155: 1154: 1129:(7): 4541–4556. 1118: 1112: 1111: 1109: 1085: 1079: 1078: 1068: 1053:J. Am. Chem. Soc 1044: 1038: 1037: 1026:. p. 1233. 1022:(2nd ed.). 1012: 1006: 1000: 980: 974: 973: 966:10.1039/a907939d 943: 942: 931: 922: 921: 905: 896: 895: 870:(7): 5848–5855. 859: 853: 852: 819:(3): 2174–2179. 807: 801: 800: 783:(3–4): 295–303. 772: 766: 765: 737: 731: 714: 643:S + 2CO + N 607:hydrogen sulfide 522: 516: 513: 512: 478:Lead(II) sulfide 369:Lattice constant 265:Chemical formula 208: 207: 192: 190: 174: 154: 143: 122: 114: 103: 92: 68: 19: 17:Tin(II) sulfide 2864: 2863: 2859: 2858: 2857: 2855: 2854: 2853: 2844:Reducing agents 2824: 2823: 2822: 2817: 2816: 2780: 2775: 2765: 2757: 2753: 2740: 2736: 2731: 2724: 2720: 2715: 2708: 2704: 2699: 2692: 2688: 2683: 2676: 2672: 2667: 2660: 2656: 2651: 2644: 2640: 2635: 2628: 2624: 2619: 2612: 2608: 2603: 2596: 2592: 2587: 2580: 2576: 2571: 2564: 2560: 2555: 2548: 2544: 2539: 2532: 2528: 2523: 2434: 2430: 2422: 2417: 2409: 2396: 2392: 2387: 2384: 2376: 2371: 2364: 2359: 2357: 2353: 2342: 2339: 2338: 2337: 2335: 2330: 2326: 2321: 2319: 2311: 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601:temperatures, 584:liquid ammonia 576: 575: 567: 564: 559: 539: 536: 535: 530: 508: 507: 503:standard state 500: 497: 496: 487: 484: 481: 480: 463: 457: 454: 453: 440: 434: 431: 430: 426: 425: 422: 419: 416: 415: 406: 405: 401: 400: 397: 392: 389: 388: 374: 372: 367: 364: 363: 360: 355: 352: 351: 345: 340: 337: 336: 332: 331: 328: 323: 320: 319: 318:about 1230 ˚C 316: 310: 309: 306: 300: 299: 296: 290: 289: 286: 282: 281: 278: 272: 271: 268: 263: 260: 259: 255: 254: 252: 251: 248: 240: 239: 238: 235: 234: 232: 231: 227: 226: 218: 217: 216: 213: 212: 210: 209: 196: 194: 182: 179: 178: 176: 175: 167: 165: 159: 158: 156: 155: 147: 145: 137: 134: 133: 131: 130: 126: 124: 116: 115: 105: 97: 96: 94: 93: 85: 83: 76: 73: 72: 70: 69: 61: 59: 54: 51: 50: 46: 45: 38: 34: 33: 30: 24: 23: 13: 10: 9: 6: 4: 3: 2: 2861: 2850: 2847: 2845: 2842: 2840: 2837: 2835: 2832: 2831: 2829: 2810: 2807: 2804: 2801: 2798: 2795: 2792: 2789: 2786: 2783: 2781: 2774: 2771: 2768: 2766: 2760: 2758: 2748: 2745: 2744: 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oxide 441: 438: 433: 432: 427: 423: 418: 417: 413: 412: 407: 402: 398: 395: 391: 390: 385: 381: 377: 373: 370: 366: 365: 362:Pnma, No. 62 361: 358: 354: 353: 350: 346: 343: 339: 338: 333: 329: 326: 322: 321: 317: 315: 314:Boiling point 312: 311: 307: 305: 304:Melting point 302: 301: 297: 295: 292: 291: 287: 284: 283: 279: 277: 274: 273: 269: 266: 262: 261: 256: 247: 243: 236: 228:InChI=1S/S.Sn 225: 221: 214: 206: 202: 198: 197: 195: 185: 181: 180: 173: 169: 168: 166: 164: 161: 160: 153: 149: 148: 146: 140: 136: 135: 128: 127: 125: 123: 118: 117: 113: 109: 106: 104: 102:ECHA InfoCard 99: 98: 91: 87: 86: 84: 80: 75: 74: 67: 63: 62: 60: 57: 53: 52: 47: 43: 42:Herzenbergite 35: 29: 25: 20: 2839:Monosulfides 2192: 1460: 1243:J. Vis. Exp. 1242: 1232: 1223: 1219: 1213: 1172: 1168: 1126: 1122: 1116: 1097: 1094:MRS Bulletin 1093: 1083: 1056: 1052: 1042: 1019: 1010: 988: 984: 978: 968:– via 957: 953: 909: 867: 864:RSC Advances 863: 857: 816: 813:Nano Letters 812: 805: 780: 776: 770: 748:(10): 1903. 745: 741: 735: 718: 712: 699: 675: 654: 611: 596: 577: 574:Sn + S → SnS 569: 543: 542: 447:Tin selenide 420:Main hazards 409: 383: 379: 375: 49:Identifiers 37:Other names 991:: 105–106. 631:coproduct: 592:pyrolysates 414:(OHS/OSH): 357:Space group 285:Appearance 258:Properties 108:100.013.863 2828:Categories 960:(2): 527. 717:Record of 705:References 684:and CIGS ( 651:Properties 588:triaryltin 335:Structure 330:Insoluble 298:5.22 g/cm 276:Molar mass 270:SnS 172:J4580W867H 77:3D model ( 56:CAS Number 28:IUPAC name 1205:124780995 1197:1862-6319 1151:137524157 1143:0957-4522 970:CiteSeerX 892:2046-2069 841:1530-6984 618:anhydrous 612:Instead, 599:cryogenic 566:Synthesis 424:Irritant 129:215-248-7 121:EC Number 66:1314-95-0 1620:Sulfides 1269:26067454 1075:26352047 918:63-14307 849:25710674 797:53314748 616:, pure, 590:sulfide 404:Hazards 2512:  1260:4542955 1177:Bibcode 872:Bibcode 821:Bibcode 750:Bibcode 726:of the 722:in the 525:what is 523: ( 460:cations 294:Density 139:PubChem 1480:Sn(IV) 1390:Sn(OH) 1316:Sn(II) 1267:  1257:  1203:  1195:  1149:  1141:  1073:  1030:  916:  890:  847:  839:  795:  614:molten 556:sulfur 520:verify 517:  458:Other 437:anions 435:Other 242:SMILES 152:426379 22:Names 1570:Sn(IO 1556:Sn(NO 1543:Sn(CH 1439:Sn(CH 1201:S2CID 1147:S2CID 793:S2CID 546:is a 220:InChI 79:JSmol 1547:COO) 1495:SnCl 1487:SnBr 1456:SnTe 1451:SnSe 1443:COO) 1431:SnSO 1339:Sn(C 1331:SnCl 1323:SnBr 1265:PMID 1193:ISSN 1139:ISSN 1071:PMID 1028:ISBN 914:LCCN 888:ISSN 845:PMID 837:ISSN 594:. 554:and 163:UNII 2811:No 2808:Md 2805:Fm 2802:Es 2799:Cf 2796:Bk 2793:Cm 2790:Am 2787:Pu 2784:Np 2769:Pa 2762:ThS 2746:** 2729:YbS 2713:TmS 2697:ErS 2681:HoS 2665:DyS 2649:TbS 2633:GdS 2617:EuS 2601:SmS 2585:PmS 2569:NdS 2553:PrS 2537:CeS 2521:LaS 2505:Og 2502:Ts 2499:Lv 2496:Mc 2493:Fl 2490:Nh 2487:Cn 2484:Rg 2481:Ds 2478:Mt 2475:Hs 2472:Bh 2469:Sg 2466:Db 2463:Rf 2460:Lr 2457:** 2454:Ra 2451:Fr 2446:Rn 2443:At 2439:PoS 2419:PbS 2415:PbS 2401:HgS 2373:PtS 2369:PtS 2361:IrS 2336:OsS 2316:ReS 2293:TaS 2285:HfS 2269:LuS 2261:BaS 2246:Xe 2236:TeS 2231:-Sb 2204:-Sn 2197:SnS 2193:SnS 2176:CdS 2162:PdS 2146:Ru 2125:TcS 2116:MoS 2109:MoS 2101:NbS 2093:ZrS 2074:SrS 2057:Kr 2054:Br 2050:+Se 2043:SeS 2038:-As 2011:-Ge 2004:GeS 2000:GeS 1984:GaS 1979:ZnS 1974:CuS 1918:FeS 1910:MnS 1906:MnS 1890:CrS 1859:TiS 1841:TiS 1837:TiS 1821:ScS 1814:CaS 1799:Ar 1796:Cl 1759:-Si 1752:SiS 1748:SiS 1731:MgS 1716:Ne 1706:)SH 1702:(NH 1697:COS 1682:+BO 1666:BeS 1651:He 1623:(S) 1535:SnS 1527:SnO 1519:SnI 1511:SnH 1503:SnF 1467:SnP 1461:SnS 1417:SnO 1385:SnO 1372:SnC 1363:SnI 1355:SnF 1255:PMC 1247:doi 1185:doi 1173:213 1131:doi 1102:doi 1061:doi 1057:137 993:doi 962:doi 948:CCF 944:SnO 880:doi 829:doi 785:doi 781:148 758:doi 635:SnO 597:At 552:tin 550:of 349:oP8 189:EPA 142:CID 2830:: 2777:US 2773:US 2750:Ac 2733:Yb 2717:Tm 2701:Er 2685:Ho 2669:Dy 2653:Tb 2637:Gd 2621:Eu 2605:Sm 2589:Pm 2573:Nd 2557:Pr 2541:Ce 2525:La 2517:* 2427:Bi 2406:Tl 2389:Au 2381:Au 2350:Ir 2323:Re 2308:WS 2301:WS 2273:Lu 2265:* 2252:Cs 2243:I 2220:Sb 2209:Sb 2181:In 2167:Ag 2150:Rh 2134:Tc 2063:Rb 2027:As 2016:As 1988:Ga 1966:Cu 1950:Ni 1934:Co 1922:Fe 1894:Cr 1871:VS 1867:VS 1848:Ti 1825:Sc 1784:-S 1779:-P 1736:Al 1722:Na 1713:F 1710:O 1690:CS 1657:Li 1413:36 1404:18 1263:. 1253:. 1241:. 1222:. 1199:. 1191:. 1183:. 1171:. 1159:^ 1145:. 1137:. 1127:26 1125:. 1098:33 1096:. 1092:. 1069:. 1055:. 1051:. 989:47 987:. 958:10 956:. 935:Bu 926:^ 900:^ 886:. 878:. 866:. 843:. 835:. 827:. 817:15 815:. 791:. 779:. 756:. 746:37 744:. 249:S= 2779:2 2764:2 2756:3 2754:S 2752:2 2739:3 2737:S 2735:2 2723:3 2721:S 2719:2 2707:3 2705:S 2703:2 2691:3 2689:S 2687:2 2675:3 2673:S 2671:2 2659:3 2657:S 2655:2 2643:3 2641:S 2639:2 2627:3 2625:S 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Index

IUPAC name
Herzenbergite
CAS Number
1314-95-0
JSmol
Interactive image
ECHA InfoCard
100.013.863
Edit this at Wikidata
EC Number
PubChem
426379
UNII
J4580W867H
CompTox Dashboard
DTXSID401014321
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InChI
SMILES
Chemical formula
Molar mass
Density
Melting point
Boiling point
Solubility in water
Crystal structure
oP8
Space group
Lattice constant
Coordination geometry

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