205:
112:
558:. The chemical formula is SnS. Its natural occurrence concerns herzenbergite (α-SnS), a rare mineral. At elevated temperatures above 905 K, SnS undergoes a second order phase transition to β-SnS (space group: Cmcm, No. 63). In recent years, it has become evident that a new polymorph of SnS exists based upon the cubic crystal system, known as π-SnS (space group: P2
511:
696:
of a solar cell utilizing a tin(II) sulfide absorber layer could be as high as 32%, which is comparable to crystalline silicon. Finally, Tin(II) sulfide is stable in both alkaline and acidic conditions. All aforementioned characteristics suggest tin(II) sulfide as an interesting material to be used
700:
At present, tin(II) sulfide thin films for use in photovoltaic cells are still in the research phase of development with power conversion efficiencies currently less than 5%. Barriers for use include a low open circuit voltage and an inability to realize many of the above properties due to
934:
Price, Louise S.; Parkin, Ivan P.; Field, Mark N.; Hardy, Amanda M. E.; Clark, Robin J. H.; Hibbert, Thomas G.; Molloy, Kieran C. (27 Jan 2000) . "Atmospheric pressure chemical vapour deposition of tin(II) sulfide films on glass substrates from
688:) are used as p-type absorber layers, but they are formulated from toxic, scarce constituents. Tin(II) sulfide, by contrast, is formed from cheap, earth abundant elements, and is nontoxic. This material also has a high optical absorption coefficient, p-type conductivity, and a mid range
667:
S. It has a layer structure similar to that of black phosphorus. As per black phosphorus, tin(II) sulfide can be ultrasonically exfoliated in liquids to produce atomically thin semiconducting SnS sheets that have a wider optical band gap (>1.5 eV) compared to the bulk crystal.
727:
1005:.) "The chlorides of tin and phosphorus were all soluble, and slow decomposition resulted in the formation of the respective sulfides." See also Table 1, wherein "Stannous chloride" and "Stannic chloride" are both listed as "Soluble and reactive".
810:
Rabkin, Alexander; Samuha, Shmuel; Abutbul, Ran E.; Ezersky, Vladimir; Meshi, Louisa; Golan, Yuval (2015-03-11). "New
Nanocrystalline Materials: A Previously Unknown Simple Cubic Phase in the SnS Binary System".
524:
862:
Abutbul, R. E.; Segev, E.; Zeiri, L.; Ezersky, V.; Makov, G.; Golan, Y. (2016-01-12). "Synthesis and properties of nanocrystalline π-SnS – a new cubic phase of tin sulphide".
775:
Wiedemeier, Heribert; von
Schnering, Hans Georg (1978-01-01). "Refinement of the structures of GeS, GeSe, SnS and SnSe : Zeitschrift für Kristallographie".
1121:
Andrade-Arvizu, Jacob A.; Courel-Piedrahita, Maykel; Vigil-Galán, Osvaldo (2015-04-14). "SnS-based thin film solar cells: perspectives over the last 25 years".
241:
692:
of 1.3-1.4 eV, required electronic properties for this type of absorber layer. Based on the a detailed balance calculation using the material bandgap, the
1299:
740:
del
Bucchia, S.; Jumas, J.C.; Maurin, M. (1981). "Contribution a l'etude de composes sulfures d'etain (II): Affinement de la structure de Sn S".
1218:
Sato, N.; Ichimura, E. (2003). "Characterization of electrical properties of SnS thin films prepared by the electrochemical deposition method".
1167:
Nair, P. K.; Garcia-Angelmo, A. R.; Nair, M. T. S. (2016-01-01). "Cubic and orthorhombic SnS thin-film absorbers for tin sulfide solar cells".
1031:
1238:
1610:
219:
1049:"Tin(II) Sulfide (SnS) Nanosheets by Liquid-Phase Exfoliation of Herzenbergite: IV–VI Main Group Two-Dimensional Atomic Crystals"
586:
solution, the same reaction still gives a mixture of 60% stannous and 35% stannic sulfide. Likewise metallic tin contaminates
701:
challenges in fabrication, but tin(II) sulfide still remains a promising material if these technical challenges are overcome.
685:
410:
2848:
689:
531:
693:
162:
1292:
183:
2833:
2556:
723:
119:
2843:
2552:
2636:
2668:
2588:
2132:
2026:
2620:
2272:
1877:
107:
2732:
2716:
2664:
2652:
2632:
2584:
2572:
2524:
2268:
1866:
1603:
1285:
493:
2712:
2700:
2235:
2838:
2749:
2728:
2696:
2604:
2568:
2520:
2219:
2161:
2123:
2115:
2003:
1999:
1905:
1893:
1870:
1847:
1824:
1701:
1023:
620:
473:
393:
27:
912:. Vol. 1. Translated by Riley, Reed F. (2nd ed.). New York: Academic. pp. 739–740.
2684:
2616:
2600:
2368:
2349:
2322:
2292:
2149:
2108:
1987:
1921:
1889:
1836:
1820:
1176:
871:
820:
749:
677:
200:
2772:
2761:
2680:
2648:
2540:
2334:
2307:
2208:
2092:
1983:
1909:
1858:
1747:
587:
469:
55:
41:
2536:
2372:
2300:
2042:
2015:
1973:
1840:
1763:
1200:
1146:
1002:
792:
465:
655:
Tin(II) sulfide is a dark brown or black solid, insoluble in water, but soluble in concentrated
89:
2776:
2388:
2360:
2315:
2284:
2100:
2073:
1965:
1804:
1751:
1735:
1730:
1665:
1596:
1389:
1264:
1192:
1138:
1070:
1027:
913:
887:
844:
836:
681:
656:
628:
602:
547:
341:
1239:"Making Record-efficiency SnS Solar Cells by Thermal Evaporation and Atomic Layer Deposition"
2438:
2418:
2414:
2405:
2062:
1917:
1696:
1689:
1636:
1502:
1494:
1465:
1397:
1354:
1330:
1254:
1246:
1184:
1130:
1101:
1060:
1015:
992:
961:
879:
828:
784:
757:
606:
578:
However, the high-temperature reaction vaporizes sulfur. Consequently effecting the proper
477:
368:
324:
264:
171:
2426:
2400:
2380:
2196:
2175:
2080:
2037:
1813:
1656:
1555:
1542:
1534:
1486:
1438:
1430:
1371:
1322:
489:
65:
1180:
875:
824:
753:
204:
111:
2260:
2251:
2230:
2180:
2166:
1949:
1933:
1721:
1681:
1569:
1518:
1362:
1259:
583:
502:
348:
716:
2827:
2049:
2010:
1778:
1670:
1526:
1455:
1384:
1308:
1204:
1150:
624:
579:
450:
442:
313:
303:
100:
796:
2203:
1978:
1758:
1450:
1237:
Jaramillo, R.; Steinmann, V.; Yang, C.; Chakraborty, R.; Poindexter, J. R. (2015).
983:
Quam, G. N. (8 Jan 1925) . "A study of reactions in liquid hydrogen sulfide".
446:
151:
788:
832:
613:
356:
1783:
1338:
1134:
761:
275:
1196:
1142:
891:
840:
969:
617:
598:
591:
1268:
1188:
1074:
848:
676:
Tin(II) sulfide is an interesting potential candidate for next generation
570:
In principle, tin(II) sulfide can be prepared directly from the elements:
1510:
1065:
1048:
996:
1619:
1106:
1089:
883:
293:
138:
120:
1220:
Proceedings of 3rd World
Conference on Photovoltaic Energy Conversion
965:
555:
501:
Except where otherwise noted, data are given for materials in their
1250:
88:
78:
1588:
1277:
917:
1592:
1281:
551:
459:
436:
908:
Baudler, M. (1963) . "Tin and lead". In Brauer, Georg (ed.).
188:
627:
to SnS at 450 °C. An aqueous rinse then removes the
609:. It then decomposes to the sulfide, but only slowly.
519:
1123:
Journal of
Materials Science: Materials in Electronics
1479:
1315:
399:asymmetric 3-fold (strongly distorted octahedral)
150:
64:
1604:
1293:
8:
1090:"Solar energy conversion towards 1 terawatt"
728:Institute for Occupational Safety and Health
910:Handbook of Preparative Inorganic Chemistry
903:
901:
582:is difficult. At near-room temperature in
1611:
1597:
1589:
1300:
1286:
1278:
308:882 °C (1,620 °F; 1,155 K)
203:
110:
15:
1258:
1105:
1064:
170:
2139:
2135:
2126:
1575:
1571:
1561:
1557:
1468:
1377:
1373:
985:Journal of the American Chemical Society
709:
639: + 2 KSCN → SnS + K
246:
224:
199:
1646:
101:
2509:
1162:
1160:
929:
927:
659:. Tin(II) sulfide is insoluble in (NH
7:
1632:
141:
14:
1088:Ginley, D.; Green, M.A. (2008).
1001:(Excerpted from a PhD thesis at
777:Zeitschrift für Kristallographie
697:as a solar cell absorber layer.
509:
505:(at 25 °C , 100 kPa).
954:Journal of Materials Chemistry
686:copper indium gallium selenide
411:Occupational safety and health
1:
789:10.1524/zkri.1978.148.3-4.295
833:10.1021/acs.nanolett.5b00209
1047:Brent; et al. (2015).
694:power conversion efficiency
280:150.775 g/mol
2865:
2511:
1648:
1629:
1135:10.1007/s10854-015-3050-z
1020:Chemistry of the Elements
1018:; Earnshaw, Alan (1997).
762:10.1107/s0567740881007528
724:GESTIS Substance Database
672:Photovoltaic applications
499:
428:
408:
403:
347:GeS type (orthorhombic),
334:
257:
237:
215:
48:
36:
26:
21:
952:with hydrogen sulfide".
730:, accessed on 4/9/2007.
1169:Physica Status Solidi A
1189:10.1002/pssa.201532426
378: = 11.18 Å,
1024:Butterworth-Heinemann
1016:Greenwood, Norman N.
678:thin-film solar cells
621:potassium thiocyanate
474:Germanium monosulfide
394:Coordination geometry
382: = 3.98 Å,
2849:IV-VI semiconductors
1066:10.1021/jacs.5b08236
605:dissolves in liquid
494:Tributyl tin sulfide
1181:2016PSSAR.213..170N
1059:(39): 12689–12696.
997:10.1021/ja01678a014
876:2016RSCAd...6.5848A
825:2015NanoL..15.2174R
754:1981AcCrB..37.1903D
742:Acta Crystallogr. B
470:Silicon monosulfide
386: = 4.32 Å
325:Solubility in water
18:
1107:10.1557/mrs2008.71
1003:Iowa State College
884:10.1039/c5ra23092f
680:. Currently, both
532:Infobox references
466:Carbon monosulfide
429:Related compounds
16:
2834:Tin(II) compounds
2821:
2820:
2815:
2814:
1586:
1585:
1033:978-0-08-037941-8
682:cadmium telluride
657:hydrochloric acid
629:potassium sulfide
623:reliably reduces
603:stannous chloride
548:chemical compound
540:Chemical compound
538:
537:
485:Related compounds
342:Crystal structure
288:dark brown solid
184:CompTox Dashboard
90:Interactive image
2856:
2345:
2344:
2343:
2142:
2129:
1960:
1954:
1944:
1938:
1792:
1791:
1774:
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1471:
1426:
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1262:
1234:
1228:
1227:
1215:
1209:
1208:
1164:
1155:
1154:
1129:(7): 4541–4556.
1118:
1112:
1111:
1109:
1085:
1079:
1078:
1068:
1053:J. Am. Chem. Soc
1044:
1038:
1037:
1026:. p. 1233.
1022:(2nd ed.).
1012:
1006:
1000:
980:
974:
973:
966:10.1039/a907939d
943:
942:
931:
922:
921:
905:
896:
895:
870:(7): 5848–5855.
859:
853:
852:
819:(3): 2174–2179.
807:
801:
800:
783:(3–4): 295–303.
772:
766:
765:
737:
731:
714:
643:S + 2CO + N
607:hydrogen sulfide
522:
516:
513:
512:
478:Lead(II) sulfide
369:Lattice constant
265:Chemical formula
208:
207:
192:
190:
174:
154:
143:
122:
114:
103:
92:
68:
19:
17:Tin(II) sulfide
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2857:
2855:
2854:
2853:
2844:Reducing agents
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2255:
2239:
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2212:
2202:
2200:
2195:
2188:
2184:
2170:
2157:
2153:
2141:
2137:
2133:
2131:
2128:
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2119:
2114:
2112:
2104:
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2069:
2066:
2048:
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2036:
2034:
2030:
2025:
2023:
2019:
2009:
2007:
2002:
1995:
1991:
1986:
1972:
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1961:
1958:
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1311:
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1231:
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1212:
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1120:
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1115:
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1041:
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1009:
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899:
861:
860:
856:
809:
808:
804:
774:
773:
769:
739:
738:
734:
719:Tin(II) sulfide
715:
711:
707:
690:direct band gap
674:
666:
662:
653:
646:
642:
638:
568:
561:
544:Tin(II) sulfide
541:
534:
529:
528:
527: ?)
518:
514:
510:
506:
492:
490:Tin(IV) sulfide
486:
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472:
468:
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439:
421:
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371:
359:
344:
327:
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201:DTXSID401014321
193:
186:
177:
157:
144:
132:
95:
82:
71:
58:
44:
40:
39:Tin monosulfide
32:
31:Tin(II) sulfide
12:
11:
5:
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2860:
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2851:
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2841:
2836:
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1313:
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1307:
1305:
1304:
1297:
1290:
1282:
1275:
1274:
1245:(99): e52705.
1229:
1210:
1175:(1): 170–177.
1156:
1113:
1100:(4): 355–364.
1080:
1039:
1032:
1007:
975:
949:
945:
939:
923:
897:
854:
802:
767:
732:
708:
706:
703:
673:
670:
664:
660:
652:
649:
648:
647:
644:
640:
636:
601:temperatures,
584:liquid ammonia
576:
575:
567:
564:
559:
539:
536:
535:
530:
508:
507:
503:standard state
500:
497:
496:
487:
484:
481:
480:
463:
457:
454:
453:
440:
434:
431:
430:
426:
425:
422:
419:
416:
415:
406:
405:
401:
400:
397:
392:
389:
388:
374:
372:
367:
364:
363:
360:
355:
352:
351:
345:
340:
337:
336:
332:
331:
328:
323:
320:
319:
318:about 1230 ˚C
316:
310:
309:
306:
300:
299:
296:
290:
289:
286:
282:
281:
278:
272:
271:
268:
263:
260:
259:
255:
254:
252:
251:
248:
240:
239:
238:
235:
234:
232:
231:
227:
226:
218:
217:
216:
213:
212:
210:
209:
196:
194:
182:
179:
178:
176:
175:
167:
165:
159:
158:
156:
155:
147:
145:
137:
134:
133:
131:
130:
126:
124:
116:
115:
105:
97:
96:
94:
93:
85:
83:
76:
73:
72:
70:
69:
61:
59:
54:
51:
50:
46:
45:
38:
34:
33:
30:
24:
23:
13:
10:
9:
6:
4:
3:
2:
2861:
2850:
2847:
2845:
2842:
2840:
2837:
2835:
2832:
2831:
2829:
2810:
2807:
2804:
2801:
2798:
2795:
2792:
2789:
2786:
2783:
2781:
2774:
2771:
2768:
2766:
2760:
2758:
2748:
2745:
2744:
2741:
2730:
2727:
2725:
2714:
2711:
2709:
2698:
2695:
2693:
2682:
2679:
2677:
2666:
2663:
2661:
2650:
2647:
2645:
2634:
2631:
2629:
2618:
2615:
2613:
2602:
2599:
2597:
2586:
2583:
2581:
2570:
2567:
2565:
2554:
2551:
2549:
2538:
2535:
2533:
2522:
2519:
2516:
2515:
2508:
2504:
2501:
2498:
2495:
2492:
2489:
2486:
2483:
2480:
2477:
2474:
2471:
2468:
2465:
2462:
2459:
2456:
2453:
2450:
2449:
2445:
2442:
2440:
2437:
2435:
2425:
2423:
2416:
2413:
2411:
2404:
2402:
2399:
2397:
2386:
2379:
2377:
2370:
2367:
2365:
2358:
2348:
2346:
2333:
2331:
2320:
2314:
2312:
2305:
2299:
2297:
2291:
2289:
2283:
2281:
2270:
2267:
2264:
2262:
2259:
2257:
2250:
2249:
2245:
2242:
2240:
2234:
2232:
2228:
2217:
2207:
2205:
2201:
2194:
2191:
2189:
2179:
2177:
2174:
2172:
2165:
2163:
2160:
2158:
2148:
2145:
2143:
2130:
2122:
2120:
2113:
2107:
2105:
2099:
2097:
2091:
2089:
2079:
2077:
2075:
2072:
2070:
2061:
2060:
2056:
2053:
2051:
2047:
2041:
2039:
2035:
2024:
2014:
2012:
2008:
2001:
1998:
1996:
1985:
1982:
1980:
1977:
1975:
1971:
1964:
1962:
1948:
1946:
1932:
1930:
1919:
1916:
1914:
1907:
1904:
1902:
1891:
1888:
1886:
1875:
1868:
1865:
1863:
1856:
1845:
1838:
1835:
1833:
1822:
1819:
1817:
1815:
1812:
1810:
1803:
1802:
1798:
1795:
1793:
1782:
1780:
1776:
1762:
1760:
1756:
1749:
1746:
1744:
1734:
1732:
1729:
1727:
1720:
1719:
1715:
1712:
1709:
1707:
1700:
1698:
1694:
1688:
1686:
1679:
1669:
1667:
1664:
1662:
1655:
1654:
1650:
1644:
1642:
1635:
1634:
1628:
1621:
1614:
1609:
1607:
1602:
1600:
1595:
1594:
1591:
1578:
1567:
1564:
1553:
1551:
1541:
1539:
1533:
1531:
1525:
1523:
1517:
1515:
1509:
1507:
1501:
1499:
1493:
1491:
1485:
1484:
1482:
1478:
1472:
1464:
1462:
1459:
1457:
1454:
1452:
1449:
1447:
1437:
1435:
1429:
1427:
1396:
1394:
1388:
1386:
1383:
1380:
1369:
1367:
1361:
1359:
1353:
1351:
1337:
1335:
1329:
1327:
1321:
1320:
1318:
1314:
1310:
1309:Tin compounds
1303:
1298:
1296:
1291:
1289:
1284:
1283:
1280:
1270:
1266:
1261:
1256:
1252:
1251:10.3791/52705
1248:
1244:
1240:
1233:
1230:
1225:
1221:
1214:
1211:
1206:
1202:
1198:
1194:
1190:
1186:
1182:
1178:
1174:
1170:
1163:
1161:
1157:
1152:
1148:
1144:
1140:
1136:
1132:
1128:
1124:
1117:
1114:
1108:
1103:
1099:
1095:
1091:
1084:
1081:
1076:
1072:
1067:
1062:
1058:
1054:
1050:
1043:
1040:
1035:
1029:
1025:
1021:
1017:
1011:
1008:
1004:
998:
994:
990:
986:
979:
976:
971:
967:
963:
959:
955:
930:
928:
924:
919:
915:
911:
904:
902:
898:
893:
889:
885:
881:
877:
873:
869:
865:
858:
855:
850:
846:
842:
838:
834:
830:
826:
822:
818:
814:
806:
803:
798:
794:
790:
786:
782:
778:
771:
768:
763:
759:
755:
751:
747:
743:
736:
733:
729:
725:
721:
720:
713:
710:
704:
702:
698:
695:
691:
687:
683:
679:
671:
669:
658:
650:
634:
633:
632:
630:
626:
625:stannic oxide
622:
619:
615:
610:
608:
604:
600:
595:
593:
589:
585:
581:
580:stoichiometry
573:
572:
571:
565:
563:
562:3, No. 198).
557:
553:
549:
545:
533:
526:
521:
504:
498:
495:
491:
488:
483:
482:
479:
475:
471:
467:
464:
461:
456:
455:
452:
451:Tin telluride
448:
444:
443:Tin(II) oxide
441:
438:
433:
432:
427:
423:
418:
417:
413:
412:
407:
402:
398:
395:
391:
390:
385:
381:
377:
373:
370:
366:
365:
362:Pnma, No. 62
361:
358:
354:
353:
350:
346:
343:
339:
338:
333:
329:
326:
322:
321:
317:
315:
314:Boiling point
312:
311:
307:
305:
304:Melting point
302:
301:
297:
295:
292:
291:
287:
284:
283:
279:
277:
274:
273:
269:
266:
262:
261:
256:
247:
243:
236:
228:InChI=1S/S.Sn
225:
221:
214:
206:
202:
198:
197:
195:
185:
181:
180:
173:
169:
168:
166:
164:
161:
160:
153:
149:
148:
146:
140:
136:
135:
128:
127:
125:
123:
118:
117:
113:
109:
106:
104:
102:ECHA InfoCard
99:
98:
91:
87:
86:
84:
80:
75:
74:
67:
63:
62:
60:
57:
53:
52:
47:
43:
42:Herzenbergite
35:
29:
25:
20:
2839:Monosulfides
2192:
1460:
1243:J. Vis. Exp.
1242:
1232:
1223:
1219:
1213:
1172:
1168:
1126:
1122:
1116:
1097:
1094:MRS Bulletin
1093:
1083:
1056:
1052:
1042:
1019:
1010:
988:
984:
978:
968:– via
957:
953:
909:
867:
864:RSC Advances
863:
857:
816:
813:Nano Letters
812:
805:
780:
776:
770:
748:(10): 1903.
745:
741:
735:
718:
712:
699:
675:
654:
611:
596:
577:
574:Sn + S → SnS
569:
543:
542:
447:Tin selenide
420:Main hazards
409:
383:
379:
375:
49:Identifiers
37:Other names
991:: 105–106.
631:coproduct:
592:pyrolysates
414:(OHS/OSH):
357:Space group
285:Appearance
258:Properties
108:100.013.863
2828:Categories
960:(2): 527.
717:Record of
705:References
684:and CIGS (
651:Properties
588:triaryltin
335:Structure
330:Insoluble
298:5.22 g/cm
276:Molar mass
270:SnS
172:J4580W867H
77:3D model (
56:CAS Number
28:IUPAC name
1205:124780995
1197:1862-6319
1151:137524157
1143:0957-4522
970:CiteSeerX
892:2046-2069
841:1530-6984
618:anhydrous
612:Instead,
599:cryogenic
566:Synthesis
424:Irritant
129:215-248-7
121:EC Number
66:1314-95-0
1620:Sulfides
1269:26067454
1075:26352047
918:63-14307
849:25710674
797:53314748
616:, pure,
590:sulfide
404:Hazards
2512:
1260:4542955
1177:Bibcode
872:Bibcode
821:Bibcode
750:Bibcode
726:of the
722:in the
525:what is
523: (
460:cations
294:Density
139:PubChem
1480:Sn(IV)
1390:Sn(OH)
1316:Sn(II)
1267:
1257:
1203:
1195:
1149:
1141:
1073:
1030:
916:
890:
847:
839:
795:
614:molten
556:sulfur
520:verify
517:
458:Other
437:anions
435:Other
242:SMILES
152:426379
22:Names
1570:Sn(IO
1556:Sn(NO
1543:Sn(CH
1439:Sn(CH
1201:S2CID
1147:S2CID
793:S2CID
546:is a
220:InChI
79:JSmol
1547:COO)
1495:SnCl
1487:SnBr
1456:SnTe
1451:SnSe
1443:COO)
1431:SnSO
1339:Sn(C
1331:SnCl
1323:SnBr
1265:PMID
1193:ISSN
1139:ISSN
1071:PMID
1028:ISBN
914:LCCN
888:ISSN
845:PMID
837:ISSN
594:.
554:and
163:UNII
2811:No
2808:Md
2805:Fm
2802:Es
2799:Cf
2796:Bk
2793:Cm
2790:Am
2787:Pu
2784:Np
2769:Pa
2762:ThS
2746:**
2729:YbS
2713:TmS
2697:ErS
2681:HoS
2665:DyS
2649:TbS
2633:GdS
2617:EuS
2601:SmS
2585:PmS
2569:NdS
2553:PrS
2537:CeS
2521:LaS
2505:Og
2502:Ts
2499:Lv
2496:Mc
2493:Fl
2490:Nh
2487:Cn
2484:Rg
2481:Ds
2478:Mt
2475:Hs
2472:Bh
2469:Sg
2466:Db
2463:Rf
2460:Lr
2457:**
2454:Ra
2451:Fr
2446:Rn
2443:At
2439:PoS
2419:PbS
2415:PbS
2401:HgS
2373:PtS
2369:PtS
2361:IrS
2336:OsS
2316:ReS
2293:TaS
2285:HfS
2269:LuS
2261:BaS
2246:Xe
2236:TeS
2231:-Sb
2204:-Sn
2197:SnS
2193:SnS
2176:CdS
2162:PdS
2146:Ru
2125:TcS
2116:MoS
2109:MoS
2101:NbS
2093:ZrS
2074:SrS
2057:Kr
2054:Br
2050:+Se
2043:SeS
2038:-As
2011:-Ge
2004:GeS
2000:GeS
1984:GaS
1979:ZnS
1974:CuS
1918:FeS
1910:MnS
1906:MnS
1890:CrS
1859:TiS
1841:TiS
1837:TiS
1821:ScS
1814:CaS
1799:Ar
1796:Cl
1759:-Si
1752:SiS
1748:SiS
1731:MgS
1716:Ne
1706:)SH
1702:(NH
1697:COS
1682:+BO
1666:BeS
1651:He
1623:(S)
1535:SnS
1527:SnO
1519:SnI
1511:SnH
1503:SnF
1467:SnP
1461:SnS
1417:SnO
1385:SnO
1372:SnC
1363:SnI
1355:SnF
1255:PMC
1247:doi
1185:doi
1173:213
1131:doi
1102:doi
1061:doi
1057:137
993:doi
962:doi
948:CCF
944:SnO
880:doi
829:doi
785:doi
781:148
758:doi
635:SnO
597:At
552:tin
550:of
349:oP8
189:EPA
142:CID
2830::
2777:US
2773:US
2750:Ac
2733:Yb
2717:Tm
2701:Er
2685:Ho
2669:Dy
2653:Tb
2637:Gd
2621:Eu
2605:Sm
2589:Pm
2573:Nd
2557:Pr
2541:Ce
2525:La
2517:*
2427:Bi
2406:Tl
2389:Au
2381:Au
2350:Ir
2323:Re
2308:WS
2301:WS
2273:Lu
2265:*
2252:Cs
2243:I
2220:Sb
2209:Sb
2181:In
2167:Ag
2150:Rh
2134:Tc
2063:Rb
2027:As
2016:As
1988:Ga
1966:Cu
1950:Ni
1934:Co
1922:Fe
1894:Cr
1871:VS
1867:VS
1848:Ti
1825:Sc
1784:-S
1779:-P
1736:Al
1722:Na
1713:F
1710:O
1690:CS
1657:Li
1413:36
1404:18
1263:.
1253:.
1241:.
1222:.
1199:.
1191:.
1183:.
1171:.
1159:^
1145:.
1137:.
1127:26
1125:.
1098:33
1096:.
1092:.
1069:.
1055:.
1051:.
989:47
987:.
958:10
956:.
935:Bu
926:^
900:^
886:.
878:.
866:.
843:.
835:.
827:.
817:15
815:.
791:.
779:.
756:.
746:37
744:.
249:S=
2779:2
2764:2
2756:3
2754:S
2752:2
2739:3
2737:S
2735:2
2723:3
2721:S
2719:2
2707:3
2705:S
2703:2
2691:3
2689:S
2687:2
2675:3
2673:S
2671:2
2659:3
2657:S
2655:2
2643:3
2641:S
2639:2
2627:3
2625:S
2623:2
2611:3
2609:S
2607:2
2595:3
2593:S
2591:2
2579:3
2577:S
2575:2
2563:3
2561:S
2559:2
2547:3
2545:S
2543:2
2531:3
2529:S
2527:2
2433:3
2431:S
2429:2
2421:2
2410:S
2408:2
2395:3
2393:S
2391:2
2385:S
2383:2
2375:2
2363:2
2356:3
2354:S
2352:2
2341:4
2329:7
2327:S
2325:2
2318:2
2310:3
2303:2
2295:2
2287:2
2279:3
2277:S
2275:2
2256:S
2254:2
2238:2
2226:5
2224:S
2222:2
2215:3
2213:S
2211:2
2199:2
2187:3
2185:S
2183:2
2171:S
2169:2
2156:3
2154:S
2152:2
2140:7
2138:S
2136:2
2127:2
2118:3
2111:2
2103:2
2095:2
2087:3
2085:S
2083:2
2081:Y
2067:S
2065:2
2045:2
2033:3
2031:S
2029:4
2022:3
2020:S
2018:2
2006:2
1994:3
1992:S
1990:2
1970:S
1968:2
1959:y
1956:S
1953:x
1943:y
1940:S
1937:x
1928:4
1926:S
1924:3
1912:2
1900:3
1898:S
1896:2
1884:3
1882:S
1880:2
1878:V
1873:2
1861:3
1854:3
1852:S
1850:2
1843:2
1831:3
1829:S
1827:2
1809:S
1807:2
1805:K
1789:2
1773:y
1770:S
1767:x
1764:P
1754:2
1742:3
1740:S
1738:2
1726:S
1724:2
1704:4
1692:2
1684:3
1677:3
1675:S
1673:2
1671:B
1661:S
1659:2
1641:S
1639:2
1637:H
1612:e
1605:t
1598:v
1576:4
1574:)
1572:3
1562:4
1560:)
1558:3
1549:4
1545:3
1537:2
1529:2
1521:4
1513:4
1505:4
1497:4
1489:4
1469:3
1445:2
1441:3
1433:4
1422:2
1408:H
1399:C
1392:2
1378:4
1376:O
1374:2
1365:2
1357:2
1349:2
1347:)
1345:5
1343:H
1341:5
1333:2
1325:2
1301:e
1294:t
1287:v
1271:.
1249::
1226:.
1224:A
1207:.
1187::
1179::
1153:.
1133::
1110:.
1104::
1077:.
1063::
1036:.
999:.
995::
972:.
964::
950:3
946:2
940:3
920:.
894:.
882::
874::
868:6
851:.
831::
823::
799:.
787::
764:.
760::
752::
665:2
663:)
661:4
645:2
641:2
637:2
560:1
515:N
384:c
380:b
376:a
191:)
187:(
81:)
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