24:
245:
142:
719:
566:). It is a colorless odorless liquid although aged samples can appear yellowish. Owing to hydrolysis, samples have a weak alcohol-like odor. It is soluble in many organic solvents. Decomposition in water is not hazardous, and therefore titanium butoxide is often used as a liquid source of titanium dioxide, which allows deposition of TiO
754:
Titanium butoxide is a corrosive, flammable liquid which reacts violently with oxidizing materials. It is incompatible with sulfuric and nitric acids, inorganic hydroxides and peroxides, bases, amines, amides, isocyanates and boranes. It is irritating to skin and eyes, and causes nausea and vomiting
714:
Titanium butoxide reacts with alkylcyclosiloxanes. With ocatamethylcyclotetrasiloxane it produces dibutoxydimethylsilane, 1,5-dibutoxyhexamethyltrisiloxane, 1,7-dibutoxyoctamethyltetrasiloxane, 1,3-dibutoxytetramethyldisiloxane and polymers. With hexamethylcyclotrisiloxane it also produces
52:
Titanium(IV) butoxide, titanium n-butoxide, titanium tetrakis(butoxide), butyl titanate, tetrabutoxy titanium, titanium tetrabutoxide, tetrabutoxytitanium, tetrabutyltitanate, tetrabutyl orthotitanate, titanium tetrabutanolate, TYZOR
755:
if swallowed. LD50 is 3122 mg/kg (rat, oral) and 180 mg/kg (mouse, intravenal); flash point is 77 °C. When heated it emits irritating fumes, which form explosive mixtures with air at concentrations above 2 vol%.
938:
Qin, Qing; Zhao, Yun; Schmallegger, Max; Heil, Tobias; Schmidt, Johannes; Walczak, Ralf; Gescheidt-Demner, Georg; Jiao, Haijun; Oschatz, Martin (2019). "Enhanced
Electrocatalytic N
674:
Analogous to the alkoxide exchange, titanium butoxide hydrolyzes readily. The reaction details are complex, but the overall process can be summarized with this balanced equation.
1042:
Weymann-Schildknetch, Sandrine; Henry, Marc (2001). "Mechanistic
Aspects of the Hydrolysis and Condensation of Titanium Alkoxides Complexed by Tripodal Ligands".
1118:
284:
1297:
1065:
K. A. Andrianov; Sh. V. Pichkhadze; V. V. Komarova; Ts. N. Vardosanidze (1962). "Reactions of organocyclosiloxanes with tetrabutyl orthotitanate".
99:
582:
922:
831:
458:
259:
1111:
727:
1967:
1411:
523:
1834:
723:
192:
1862:
1535:
1104:
223:
23:
1848:
1820:
149:
1736:
1935:
1892:
1804:
1680:
1259:
137:
1780:
1375:
1367:
1347:
1238:
1230:
694:
Diverse oxo-alkoxo intermediates have been trapped and characterized. Pyrolysis also affords the dioxide:
609:
1927:
1583:
1495:
1325:
1276:
1222:
1200:
1141:
594:
40:
1644:
1455:
1395:
1387:
1355:
1246:
1178:
1157:
867:
1876:
1788:
1720:
1575:
1567:
1338:
1264:
1183:
1165:
240:
65:
1972:
1900:
1559:
1217:
1173:
1127:
977:
1939:
821:
1475:
1317:
1082:
1024:
969:
918:
893:
827:
602:
586:
119:
912:
1768:
1752:
1708:
1672:
1656:
1435:
1423:
1333:
1254:
1149:
1074:
1047:
1016:
959:
951:
883:
875:
739:
731:
539:
414:
389:
307:
201:
1931:
1636:
1543:
1403:
718:
581:
75:
244:
141:
879:
871:
888:
851:
517:
1961:
1908:
1884:
981:
964:
807:
439:
378:
368:
130:
1943:
1443:
573:
Titanium butoxide is often used to prepare titanium oxide materials and catalysts.
790:
181:
671:
etc. For this reason, titanium butoxide is not compatible with alcohol solvents.
1696:
503:
942:
Reduction via
Partial Anion Substitution in Titanium Oxide–Carbon Composites".
995:
Xiang, Quanjun; Yu, Jiaguo; Jaroniec, Mietek (2012). "Synergetic Effect of MoS
400:
330:
110:
1086:
1067:
Bulletin of the
Academy of Sciences of the USSR Division of Chemical Science
640:
Like other titanium alkoxides, titanium butoxide exchanges alkoxide groups:
212:
1028:
973:
955:
897:
1744:
1078:
613:
358:
168:
150:
1020:
1096:
1051:
406:
516:
Except where otherwise noted, data are given for materials in their
914:
Functional
Polymer Coatings: Principles, Methods, and Applications
751:
LD50 is 3122 mg/kg (rat, oral) and 180 mg/kg (mouse, intravenal).
717:
580:
547:
98:
88:
348:
1100:
570:
coatings of various shapes and sizes down to the nanoscale.
228:
856:
nanofibres with electron transition-based optical activity"
605:). Nonetheless it is often depicted as a simple monomer.
510:
3122 mg/kg (rat, oral) and 180 mg/kg (mouse, intravenal).
999:
and
Graphene as Cocatalysts for Enhanced Photocatalytic H
738:
nanofibers produced by depositing titanium butoxide on
268:
InChI=1S/4C4H9O.Ti/c4*1-2-3-4-5;/h4*2-4H2,1H3;/q4*-1;+4
632:
The reaction requires base to proceed to completion.
1044:
Journal of the
Chemical Society, Dalton Transactions
1920:
1629:
1310:
1292:
1210:
1195:
1134:
820:Pohanish, Richard P.; Greene, Stanley A. (2009).
180:
585:Structure of a typical titanium alkoxide, e.g.
74:
601:is not a monomer but exists as a cluster (see
1112:
8:
860:Science and Technology of Advanced Materials
589:(organic substituents removed for clarity).
1626:
1289:
1192:
1119:
1105:
1097:
243:
140:
118:
15:
963:
887:
823:Wiley Guide to Chemical Incompatibilities
593:Like most titanium alkoxides (exception:
200:
1869:
1865:
1855:
1851:
1841:
1837:
1827:
1823:
1009:Journal of the American Chemical Society
845:
843:
944:Angewandte Chemie International Edition
826:. John Wiley & Sons. p. 1010.
764:
742:. Carbon was removed by heating in air.
289:
264:
239:
131:
271:Key: YHWCPXVTRSHPNY-UHFFFAOYSA-N
7:
911:Wu, Limin; Baghdachi, Jamil (2015).
803:
801:
799:
786:
784:
782:
780:
778:
776:
774:
772:
770:
768:
171:
14:
343:COLORLESS TO LIGHT-YELLOW LIQUID
22:
520:(at 25 °C , 100 kPa).
852:"Hard-templating of chiral TiO
1:
1293:Organotitanium(III) compounds
880:10.1088/1468-6996/16/5/054206
538:is a metal alkoxide with the
405:most organic solvents except
1921:Organotitanium(IV) compounds
1196:Organotitanium(II) compounds
608:It is produced by treating
492:or concentration (LD, LC):
1989:
1003:Production Activity of TiO
793:. pubchem.ncbi.nlm.nih.gov
659:(OR) + HOR → Ti(OBu)
965:21.11116/0000-0004-023B-8
514:
488:
483:
432:
300:
280:
255:
58:
49:
39:
34:
21:
715:dibutoxydimethylsilane.
577:Structure and synthesis
335:340.32164
1968:Titanium(IV) compounds
956:10.1002/anie.201906056
743:
610:titanium tetrachloride
590:
917:. Wiley. p. 10.
721:
648:+ HOR → Ti(OBu)
595:titanium isopropoxide
584:
44:Titanium(IV) butoxide
624:+ 4 HOBu → Ti(OBu)
292:CCCC.CCCC.CCCC.CCCC.
950:(37): 13101–13106.
872:2015STAdM..16e4206W
808:Tetrabutyl titanate
730:(bottom) images of
390:Solubility in water
29:gas phase structure
18:
1630:Titanate compounds
1128:Titanium compounds
1079:10.1007/BF00905301
850:Wang, Cui (2015).
744:
591:
524:Infobox references
353:weak alcohol-like
17:Titanium butoxide
16:
1955:
1954:
1951:
1950:
1306:
1305:
1206:
1205:
1046:(16): 2425–2428.
1021:10.1021/ja302846n
1015:(15): 6575–6578.
924:978-1-118-88303-7
833:978-0-470-52330-8
740:carbon nanofibers
603:titanium ethoxide
587:titanium ethoxide
536:Titanium butoxide
532:Chemical compound
530:
529:
224:CompTox Dashboard
100:Interactive image
1980:
1872:
1858:
1844:
1830:
1627:
1621:
1620:
1619:
1611:
1610:
1602:
1601:
1593:
1592:
1290:
1193:
1121:
1114:
1107:
1098:
1091:
1090:
1062:
1056:
1055:
1052:10.1039/b103398k
1039:
1033:
1032:
1007:Nanoparticles".
992:
986:
985:
967:
935:
929:
928:
908:
902:
901:
891:
847:
838:
837:
817:
811:
805:
794:
788:
475:
448:
433:Thermochemistry
415:Refractive index
308:Chemical formula
248:
247:
232:
230:
204:
184:
173:
152:
144:
133:
122:
102:
78:
26:
19:
1988:
1987:
1983:
1982:
1981:
1979:
1978:
1977:
1958:
1957:
1956:
1947:
1916:
1912:
1904:
1896:
1888:
1880:
1871:
1867:
1863:
1857:
1853:
1849:
1843:
1839:
1835:
1829:
1825:
1821:
1816:
1812:
1808:
1800:
1796:
1792:
1784:
1776:
1772:
1764:
1760:
1756:
1748:
1740:
1732:
1728:
1724:
1716:
1712:
1704:
1700:
1692:
1688:
1684:
1676:
1668:
1664:
1660:
1652:
1648:
1640:
1625:
1618:
1615:
1614:
1613:
1609:
1606:
1605:
1604:
1600:
1597:
1596:
1595:
1591:
1588:
1587:
1586:
1584:
1579:
1571:
1563:
1555:
1551:
1547:
1539:
1531:
1527:
1523:
1519:
1515:
1507:
1503:
1499:
1491:
1487:
1483:
1479:
1471:
1467:
1463:
1459:
1451:
1447:
1439:
1431:
1427:
1419:
1415:
1407:
1399:
1391:
1383:
1379:
1371:
1363:
1359:
1351:
1342:
1329:
1321:
1302:
1300:
1288:
1284:
1280:
1272:
1268:
1250:
1242:
1234:
1226:
1202:
1191:
1187:
1169:
1161:
1153:
1145:
1130:
1125:
1095:
1094:
1064:
1063:
1059:
1041:
1040:
1036:
1006:
1002:
998:
994:
993:
989:
941:
937:
936:
932:
925:
910:
909:
905:
855:
849:
848:
841:
834:
819:
818:
814:
806:
797:
789:
766:
761:
749:
737:
709:
705:
701:
689:
685:
681:
666:
662:
658:
651:
647:
638:
627:
623:
600:
579:
569:
565:
561:
557:
553:
545:
533:
526:
521:
507:
501:
476:
473:
467:
463:
460:
459:Std enthalpy of
449:
442:
425:
423:
392:
324:
320:
316:
310:
296:
293:
288:
287:
276:
273:
272:
269:
263:
262:
251:
233:
226:
207:
187:
174:
162:
125:
105:
92:
81:
68:
54:
45:
30:
27:
12:
11:
5:
1986:
1984:
1976:
1975:
1970:
1960:
1959:
1953:
1952:
1949:
1948:
1946:
1945:
1941:
1937:
1933:
1929:
1924:
1922:
1918:
1917:
1915:
1914:
1910:
1906:
1902:
1898:
1894:
1890:
1886:
1882:
1878:
1874:
1860:
1846:
1832:
1818:
1814:
1810:
1806:
1802:
1798:
1794:
1790:
1786:
1782:
1778:
1774:
1770:
1766:
1762:
1758:
1754:
1750:
1746:
1742:
1738:
1734:
1730:
1726:
1722:
1718:
1714:
1710:
1706:
1702:
1698:
1694:
1690:
1686:
1682:
1678:
1674:
1670:
1666:
1662:
1658:
1654:
1650:
1646:
1642:
1638:
1633:
1631:
1624:
1623:
1616:
1607:
1598:
1589:
1581:
1577:
1573:
1569:
1565:
1561:
1557:
1553:
1549:
1545:
1541:
1537:
1533:
1529:
1525:
1521:
1517:
1513:
1509:
1505:
1501:
1497:
1493:
1489:
1485:
1481:
1477:
1473:
1469:
1465:
1461:
1457:
1453:
1449:
1445:
1441:
1437:
1433:
1429:
1425:
1421:
1417:
1413:
1409:
1405:
1401:
1397:
1393:
1389:
1385:
1381:
1377:
1373:
1369:
1365:
1361:
1357:
1353:
1349:
1345:
1340:
1336:
1331:
1327:
1323:
1319:
1314:
1312:
1308:
1307:
1304:
1303:
1298:
1296:
1294:
1287:
1286:
1282:
1278:
1274:
1270:
1266:
1262:
1257:
1252:
1248:
1244:
1240:
1236:
1232:
1228:
1224:
1220:
1214:
1212:
1208:
1207:
1204:
1203:
1199:
1197:
1190:
1189:
1185:
1181:
1176:
1171:
1167:
1163:
1159:
1155:
1151:
1147:
1143:
1138:
1136:
1132:
1131:
1126:
1124:
1123:
1116:
1109:
1101:
1093:
1092:
1073:(5): 776–779.
1057:
1034:
1004:
1000:
996:
987:
939:
930:
923:
903:
853:
839:
832:
812:
795:
791:Butyl titanate
763:
762:
760:
757:
748:
745:
735:
712:
711:
707:
703:
699:
692:
691:
687:
683:
679:
669:
668:
664:
660:
656:
653:
649:
645:
637:
634:
630:
629:
625:
621:
598:
578:
575:
567:
563:
559:
555:
551:
543:
531:
528:
527:
522:
518:standard state
515:
512:
511:
508:
499:
497:
494:
493:
486:
485:
481:
480:
477:
471:
465:
457:
454:
453:
452:711 J/(mol·K)
450:
438:
435:
434:
430:
429:
426:
421:
413:
410:
409:
403:
397:
396:
393:
388:
385:
384:
381:
375:
374:
371:
365:
364:
361:
355:
354:
351:
345:
344:
341:
337:
336:
333:
327:
326:
322:
318:
314:
311:
306:
303:
302:
298:
297:
295:
294:
291:
283:
282:
281:
278:
277:
275:
274:
270:
267:
266:
258:
257:
256:
253:
252:
250:
249:
236:
234:
222:
219:
218:
215:
209:
208:
206:
205:
197:
195:
189:
188:
186:
185:
177:
175:
167:
164:
163:
161:
160:
156:
154:
146:
145:
135:
127:
126:
124:
123:
115:
113:
107:
106:
104:
103:
95:
93:
86:
83:
82:
80:
79:
71:
69:
64:
61:
60:
56:
55:
51:
47:
46:
43:
37:
36:
32:
31:
28:
13:
10:
9:
6:
4:
3:
2:
1985:
1974:
1971:
1969:
1966:
1965:
1963:
1944:
1942:
1940:
1938:
1936:
1934:
1932:
1930:
1928:
1926:
1925:
1923:
1919:
1913:
1907:
1905:
1899:
1897:
1891:
1889:
1883:
1881:
1875:
1873:
1861:
1859:
1847:
1845:
1833:
1831:
1819:
1817:
1803:
1801:
1787:
1785:
1779:
1777:
1767:
1765:
1751:
1749:
1743:
1741:
1735:
1733:
1719:
1717:
1707:
1705:
1695:
1693:
1679:
1677:
1671:
1669:
1655:
1653:
1643:
1641:
1635:
1634:
1632:
1628:
1622:
1582:
1580:
1574:
1572:
1566:
1564:
1558:
1556:
1542:
1540:
1534:
1532:
1510:
1508:
1494:
1492:
1474:
1472:
1454:
1452:
1442:
1440:
1434:
1432:
1422:
1420:
1410:
1408:
1402:
1400:
1394:
1392:
1386:
1384:
1374:
1372:
1366:
1364:
1354:
1352:
1346:
1344:
1337:
1335:
1332:
1330:
1324:
1322:
1316:
1315:
1313:
1309:
1301:
1295:
1291:
1285:
1275:
1273:
1263:
1261:
1258:
1256:
1253:
1251:
1245:
1243:
1237:
1235:
1229:
1227:
1221:
1219:
1216:
1215:
1213:
1211:Titanium(III)
1209:
1201:
1198:
1194:
1188:
1182:
1180:
1177:
1175:
1172:
1170:
1164:
1162:
1156:
1154:
1148:
1146:
1140:
1139:
1137:
1133:
1129:
1122:
1117:
1115:
1110:
1108:
1103:
1102:
1099:
1088:
1084:
1080:
1076:
1072:
1068:
1061:
1058:
1053:
1049:
1045:
1038:
1035:
1030:
1026:
1022:
1018:
1014:
1010:
991:
988:
983:
979:
975:
971:
966:
961:
957:
953:
949:
945:
934:
931:
926:
920:
916:
915:
907:
904:
899:
895:
890:
885:
881:
877:
873:
869:
866:(5): 054206.
865:
861:
857:
846:
844:
840:
835:
829:
825:
824:
816:
813:
809:
804:
802:
800:
796:
792:
787:
785:
783:
781:
779:
777:
775:
773:
771:
769:
765:
758:
756:
752:
746:
741:
733:
729:
725:
720:
716:
697:
696:
695:
677:
676:
675:
672:
654:
652:(OR) + HOBu
643:
642:
641:
635:
633:
619:
618:
617:
615:
611:
606:
604:
596:
588:
583:
576:
574:
571:
549:
541:
537:
525:
519:
513:
509:
505:
496:
495:
491:
487:
482:
479:-1670 kJ/mol
478:
470:
462:
456:
455:
451:
446:
441:
440:Heat capacity
437:
436:
431:
427:
420:
416:
412:
411:
408:
404:
402:
399:
398:
394:
391:
387:
386:
382:
380:
379:Boiling point
377:
376:
372:
370:
369:Melting point
367:
366:
362:
360:
357:
356:
352:
350:
347:
346:
342:
339:
338:
334:
332:
329:
328:
312:
309:
305:
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1311:Titanium(IV)
1135:Titanium(II)
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686:O → TiO
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59:Identifiers
50:Other names
1552:·20TiO
1544:NiO·Sb
504:median dose
490:Lethal dose
395:decomposes
363:0.998 g/cm
340:Appearance
301:Properties
138:100.024.552
1962:Categories
1893:Pb(Zr,Ti)O
810:. nist.gov
759:References
726:(top) and
597:), Ti(OBu)
401:Solubility
331:Molar mass
202:FJS8Q2MX9I
111:ChemSpider
87:3D model (
66:CAS Number
41:IUPAC name
1973:Alkoxides
1496:Ti(OCH(CH
1087:0568-5230
982:195760017
690:+ 4 HOBu
636:Reactions
461:formation
325:Ti
213:UN number
159:227-006-8
151:EC Number
76:5593-70-4
1029:22458309
974:31257671
898:27877835
702:→ TiO
628:+ 4 HCl
484:Hazards
120:13836735
1737:EuBaTiO
889:5070021
868:Bibcode
706:+ 2 Bu
698:Ti(OBu)
678:Ti(OBu)
667:+ HOBu
655:Ti(OBu)
644:Ti(OBu)
614:butanol
542:Ti(OBu)
540:formula
407:ketones
383:312 °C
373:-55 °C
359:Density
169:PubChem
1697:CaZrTi
1536:KTiOPO
1512:Ti(OCH
1412:Ti(NMe
1356:Ti(ClO
1085:
1027:
980:
972:
921:
896:
886:
830:
747:Safety
732:chiral
682:+ 2 H
428:1.486
285:SMILES
35:Names
1909:ZnTiO
1901:SrTiO
1885:PbTiO
1877:NiTiO
1781:MnTiO
1745:FeTiO
1673:CaTiO
1637:BaTiO
1424:Ti(NO
1404:TiOSO
1339:TiS(S
978:S2CID
612:with
550:= –CH
260:InChI
217:2920
182:21801
89:JSmol
1681:CaCu
1585:Ti(C
1576:TiSi
1568:TiSe
1480:(OCH
1456:Ti(C
1348:TiCl
1326:TiBr
1231:TiCl
1223:TiBr
1218:TiAl
1184:TiSi
1158:TiBr
1142:TiCl
1083:ISSN
1025:PMID
970:PMID
919:ISBN
894:PMID
828:ISBN
722:left
663:(OR)
620:TiCl
349:Odor
193:UNII
1868:TiF
1854:TiF
1840:TiF
1826:TiF
1813:TiO
1811:0.5
1807:0.5
1773:TiO
1713:TiO
1649:TiO
1560:TiS
1448:TiO
1436:TiO
1396:TiI
1388:TiH
1380:TiF
1368:TiF
1334:TiC
1318:TiB
1260:TiP
1255:TiN
1247:TiI
1239:TiF
1179:TiS
1174:TiO
1166:TiI
1150:TiH
1075:doi
1048:doi
1017:doi
1013:134
960:hdl
952:doi
884:PMC
876:doi
734:TiO
728:TEM
724:SEM
472:298
229:EPA
172:CID
53:TBT
1964::
1864:Rb
1850:Li
1822:Na
1809:Bi
1805:Na
1793:Ti
1789:Na
1769:Li
1757:Ti
1753:Ho
1725:Ti
1721:Dy
1709:Cs
1691:12
1685:Ti
1667:12
1661:Ti
1657:Bi
1645:Ba
1524:CH
1520:CH
1516:CH
1490:16
1484:CH
1476:Ti
1277:Ti
1265:Ti
1081:.
1071:11
1069:.
1023:.
1011:.
976:.
968:.
958:.
948:58
946:.
892:.
882:.
874:.
864:16
862:.
858:.
842:^
798:^
767:^
616::
562:CH
558:CH
554:CH
548:Bu
500:50
498:LD
464:(Δ
319:36
315:16
1911:3
1903:3
1895:3
1887:3
1879:3
1870:6
1866:2
1856:6
1852:2
1842:6
1838:2
1836:K
1828:6
1824:2
1815:3
1799:7
1797:O
1795:3
1791:2
1783:3
1775:3
1771:2
1763:7
1761:O
1759:2
1755:2
1747:3
1739:4
1731:7
1729:O
1727:2
1723:2
1715:3
1711:2
1703:7
1701:O
1699:2
1689:O
1687:4
1683:3
1675:3
1665:O
1663:3
1659:4
1651:4
1647:2
1639:3
1617:4
1612:)
1608:3
1603:O
1599:5
1594:H
1590:3
1578:2
1570:2
1562:2
1554:2
1550:3
1548:O
1546:2
1538:4
1530:4
1528:)
1526:3
1522:2
1518:2
1514:2
1506:4
1504:)
1502:2
1500:)
1498:3
1488:)
1486:3
1482:2
1478:4
1470:4
1468:)
1466:2
1464:O
1462:3
1460:H
1458:2
1450:4
1446:4
1444:H
1438:2
1430:4
1428:)
1426:3
1418:4
1416:)
1414:2
1406:4
1398:4
1390:4
1382:6
1378:2
1376:H
1370:4
1362:4
1360:)
1358:4
1350:4
1343:)
1341:2
1328:4
1320:2
1299:2
1283:3
1281:S
1279:2
1271:3
1269:O
1267:2
1249:3
1241:3
1233:3
1225:3
1186:2
1168:2
1160:2
1152:2
1144:2
1120:e
1113:t
1106:v
1089:.
1077::
1054:.
1050::
1031:.
1019::
1005:2
1001:2
997:2
984:.
962::
954::
940:2
927:.
900:.
878::
870::
854:2
836:.
736:2
710:O
708:2
704:2
700:4
688:2
684:2
680:4
665:2
661:2
657:3
650:3
646:4
626:4
622:4
599:4
568:2
564:3
560:2
556:2
552:2
546:(
544:4
506:)
502:(
474:)
469:H
466:f
447:)
445:C
443:(
424:)
422:D
419:n
417:(
323:4
321:O
317:H
313:C
231:)
227:(
91:)
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