1584:"What this means is, the time derivative of the free energy vanishes, signalling a stationary point. This derivative is usually called, for certain hisorical and technical reasons, the free energy change" What rubbish! he's quoting out of context. Even when one replaces the nonsensical time derivative by derivative with respect to the reaction coordinate it still does not make sense to equate a derivative with a free energy change. There's a real dilemma here: equilibrium is taught through kinetics in schools and through thermodynamics at University. I really object to schoollchildren being told "this theory is wrong but it gives the right answer".
2545:
than the reactants). The entropy of mixing is a curve with a minimum at 50%. When you add this curve to the straight line due to the free energy of reaction, the position of the minimum shifts depending on the magnitude of the free energy change. (As we discussed above, if the free energy change is large enough, the minimum can become negligible, resulting in a practically 100% equilibrium position.) In other words, the entropy of mixing "causes" equilibrium by discouraging having pure products, but it is indeed the free energy of reaction that determines the value of the equilibrium constant, as is apparent from the equation DeltaG = -RTlnK. --
2391:
mechanism would be easier because it is only one small barrier at a time instead of one huge barrier, but sadly that's not the case. Imagine you start from P, and "climb" one step to I5. Once you are in that state, you are faced with two possibilities: climbing one more step to I4, or going back to P. Unfortunately, going back to P is much more likely because the barrier in that direction is lower. Effectively what happens is that you are establishing an (unfavorable) equilibrium between P and I5 before you can even climb the second step. And so on, until you reach TS1 and finally "fall down" to R.
2519:
a circular argument: where do the equilibrium concentrations come from? Put another way, why are the dissociation constants for ethylacetate and propylacetate different? The entropy argument is the same for both, so it must be mainly the difference in standard free energy between reactants and products that makes equilibrium constants different and hence, determines the composition of an equilibrium mixture. I just don't like separating one entropy effect for all the others such as those involved in solvation/desolvation about which we know next to nothing.
2492:. The original article was totally useless, so I set about reading the papers by Guldberg and Waage and produced the version of 13.45, 24 June, based on these readings. Loon91 immediately reverted most of it without explanation. An issue here is that many textbooks give a definition of the law which is significantly different from the one developed by G&W, so it's no use citing those sources to support such a definition. I guess you would not want to get involved, but this guy is a loose cannon and I don't know how to deal with such hostility.
2373:. Once these radicals start flying around chain reactions will occur. The radicals involved will be the same as in the forward reaction, but it's easy to see how nitrogen atoms can be produced in the back-reaction without the need for a catalyst. I'm still troubled by the idea that at equilibrium the catalyst affects both overall reaction rates in such a way that the ratio remains constant. I can see it in principle for a reaction coordinate with a single maximum, whose height is affected by the catalyst, but not for multi-step systems.
83:, in which "New Basqueland" and "The Independent Basque Country" are listed. If we had this situation, we could add a note that said: "hey, in Spain the basque is also spoken". But since the basque-speaking peoples do not have an independent state, they do not appear as an independent section in the Ibero-America article, so we don't mention them. But as we already have a section for the catalan-speaking countries (Andorra), it's good to add the note I added. I'm not sure if you understand what I mean xD
3839:
2301:
don't know the mechanism well, the barrier is possibly even larger than that for the forward reaction, given that the formation of ammonia is slightly endothermic (DeltaHf = -10 kcal/mol). Ammonia is very stable (in the kinetic sense) at room temperature; one does not see it decomposing into N2 and H2. But if you put ammonia in a Haber reactor you should see it decompose until it reached equilibrium, and it would reach it faster thanks to the catalyst. --
2805:
1587:"The most basic approach is to manipulate the various equilibrium constants till the desired concentrations are expressed in terms of measured equilibrium constants (equivalent to measuring chemical potentials) and initial conditions" again rubbish as it stands. If we say manipulate various expressions relating to the equilibrium, that's getting nearer to being meaningful, but the idea of measuring chemical potentials in this context defeats me.
2777:
Theil desselben in 2 Theilen Wasser ... mit 2½ bis 3 Theilen
Manganhyperoxid... 3 Theile Schwefelsäure (1 part suggar in 2 parts water with 2½ to 3 parts Manganhyperoxide and 3 parts sulfuric acid at 60°C). There are no ants in this discription at all. The discription of furfural is small in this article and states: oil like substance smelling like almonds is a by product of the synthesis. I think we should change the article accordigly.--
2084:
reversibility. It is true that there could be side reactions involving NH and NH2, but that is true for both the forward and the reverse reactions. However, I don't imagine that these reactions will be of major importance, because they would presumably be reversible too and lead to species that are less stable than N2, H2, and NH3. The fact that the Haber process works leads me to think that, but I'm not an expert on it. --
3656:
864:
2481:. The forward reaction rate, in the absence of a catalyst, is slow. I agree that H atoms may well be present but the evidence suggests that they don't have enough energy to kick-start the reaction. Whilst the catalysed reaction may well obey the principle of microscopic reversibility it is likely that the catalyst has no effect on the dissociation process. That was my original concern. If NH
2950:". I disagree with the policy, but it's still likely to get deleted by someone else. The additions may be useful, but to pass by the more strict enforcers of the fair use rules you'll need to break it out of the gallery and add some notes about why each cover is worth mentioning. (Some notes on the history and differences between the books might be enough.) —
1685:
original I will quit editing it. Like you say, I put a lot of time and effort into the revised version. I did it because I wanted to get the science right and reverting to the original will mean that the science in the article is not right. There's no way I could put it right by an series of incremental edits such as I have done, for example, with
811:
2259:, 2nd ed. clearly states that enzymes also catalyze the reverse reaction. Although there is still some controversy regarding the best explanation for enzymatic catalysis, which can also vary from enzyme to enzyme, it is pretty clear that it is not by simply binding to the substrate as per the lock-and-key model. A more accepted explanation is
2276:
is mainly effective away from equilibrium. I find it difficult (but not impossible) to accept that at equilibrium the catalyst affects both reaction rates equally. It's also possible that at equilibrium the catalyst has no effect. The kinetics of multi-step reactions is not something that we should get into, is it! Let's leave it at that.
3460:
the nineteenth century. I suspect it was first used in the early or mid-twentieth century. I have always confidently assumed that the person who introduced it (whoever that was) chose the letter R to stand for "radical"; but that is, as I say, just an assumption. I'm sorry I am not able to give you a better answer to this question.
3236:, but the GA was put on hold with comments that are so vague as to be nearly useless. I say forget about GA and go straight for FA. At least the process is more open, with more people giving their opinion, and with more dialog where one can generally ask for specific, actionable items and ignore the objections that are not clarified. --
2529:
substances, but this is not true of solutes; I don't think that the argument can be applied to solutions because there are entropy factors that apply to the solvent itself, particularly in reactions where ions are involved. I conclude that it needs to be stated that the entropy of mixing idea does not apply universally.
1121:. Your constant input on the peer review, your support on the FAC, your solution to the solution problem, and your edits to the article itself are all greatly appreciated. If you ever have an article being peer reviewed (and I'm not already making comments there), let me know and I'll settle up the score. --
3459:
You asked on my talk page if I knew where the symbol "R" comes from, when used to symbolize any arbitrary hydrocarbon radical in a structural formula. I don't know the historical origin of this symbol, but I can tell you that it is either very rare or not found at all among chemical formulas used in
2748:
Can you explain why you redirected the article Energy (Chemistry) to energy. There was already a conflict with physchim62 regardingthe earlier redirect, in which
Jrefree has given some suggestions. From the above post I notice that you somehow specialize in such acts. I really feel concerned with the
2539:
I think it would be good to qualify that the entropy of mixing does not apply to heterogeneous systems, which are in some ways similar to phase equilibria. It is also true that the ideal entropy of mixing is not exact for non-ideal solutions, given the entropy changes in the solvent that you mention.
2518:
I have at last obtained pdf's of the two articles you cited, and have read the one by
Clugston carefully. There is no doubt that entropy maximisation and free energy minimisation are two sides of the same coin. In that sense Clugston's article is "trivial". Moreover I detect something that looks like
2275:
Many thanks for these comments. I'm still not completely convinced, but I don't want you to spend any more time on this discussion. I think there are two situations which need to be considered: at equilibrium forward and backward rates are equal, but away from equilibrium this is not so. The catalyst
379:
SuggestBot picks articles in a number of ways based on other articles you've edited, including straight text similarity, following wikilinks, and matching your editing patterns against those of other
Wikipedians. It tries to recommend only articles that other Wikipedians have marked as needing work.
4428:
Answer to
Plasmic Physics: Your group numbering may seem sensible to you, but it is not the numbering used by any chemistry book or article that I have ever seen, or that Itub has ever seen according to his answer above. Knowledge (XXG) policy is to summarize information which is accepted elsewhere,
4092:
Terminology! My mistake, I meant anion. Two atoms or ions that both have positive or negative oxidation states are not and cannot be bonded or ionically or otherwise. Negative to positive, neutral to neutral, or negative to neutral to positive, not negative to negative, or positive to positive. Just
2390:
I've made this sketch of a hypothetical six-step mechanism to illustrate a point. In this sketch, the rate in the forward direction is determined by the difference TS1-R, and in the reverse direction by TS1-P. The rate-determining step is the same in both directions. One could think that the reverse
2159:
The equilibrium constant depends on the energies of C and D independently of intermediate energies. The catalyst affects the energy of an intermediate state, but not the equilibrium composition of the mixture, so in this multi-step situation one reaction can be speeded up without affecting the final
2083:
I don't know the literature about the thermolysis of ammonia, but I'm pretty sure that the dissociation energies have been calculated. I don't see why the catalytic mechanism for the Haber process wouldn't speed up the reverse reaction, and I don't know any exceptions to the principle of microscopic
3049:
I'm done for now, but it would be good to know what format such a list should have, in case I need it in the future. Note that I'm not renaming categories, but in some cases removing categories that are too general, in others substituting them with a more specific category, and yet in others adding
2776:
Most of the literature points to 1873 not the original paper from 1870! But know I found a problem in furfural. The original publication of Döbereiner from 1832 states that he wants to introduce formic acid (Ameisensäure) for several medical issues and therefor introduces a synthesis from suggar. 1
2718:
Besides STR3DI32, there are only a few, if any, molecular mechanics based programs that can be described as quantitative versions of the VSEPR theory. Since the VSEPR theory is, and will remain, an invaluable tool in organic chemistry, an article on STR3DI32 is also valuable and important. None
2300:
It has to be affected, due to microscopic reversibility. I think you are focusing too much on the dissociation of N2, which admittedly is a highly unfavorable step which hinders the reaction. But the reverse reaction also faces quite a big barrier. Although I don't know exactly what it is because I
2254:
Enzymes can certainly catalyze the reverse reaction as well, and many reactions of metabolic interest are reversible and need the enzyme to catalyze it both directions (I think the hydrolysis of CO2 is a good example, due to its a role in the regulation of pH of the blood). At least the book I have
2237:
D. It is assumed that A and B are always in equilibrium with one another, and that C and D are not, because the barriers from C to A and from D to B are insurmountable under the reaction conditions (i.e., have a half-life longer than hours, months, years, or billions of years, etc. depending on the
1800:
I've looked at bit at J. Chem. Ed. and couldn't find an article with this type of calculation, but I wouldn't object to adding it as a footnote as it is a relatively straightforward derivation from the equations that are already in the article. However, when I tried to do this calculation I got 271
1580:
This last statement is fundamentally unsound and is one of the reasons why I undertook a re-write. In media of constant ionic strength there is no such approximation. Even Atkins may be unaware of this, but I can't say for sure as I only have the 1st. Edition (being the old inorganic chemist that I
2544:
contribution to the free energy that explains the existence of chemical equilibrium for ideal systems. If it is excluded, a plot of free energy vs advance of reaction has no minimum but is a straight line, and one would expect 100% conversion to the products (assuming they have a lower free energy
2247:
That's a common drawing convention used in physical organic chemistry to indicate that those states (reactant, product, or intermediate) are in fact minima in the (multi-dimensional) potential energy surface. However, it is just for illustration, and some authors choose to use other illustrations,
4350:
Thanks for removing "whistogen" and "dracogen" which I had wondered about as well. I also question the same editor's group numbers for the lanthanides: IC to VIIIC with seven (!) elements numbered VIIIC. Certainly
Mendeleev and Bohr would be surprised, but I would like your opinion. Have you ever
3529:
Such mass hysteria seems to be working. User BHG is one of the top-10 editors by edit count on
Knowledge (XXG) and has lots of friends. I can't imagine most WWI veteran articles surviving if this trend continues. I do urge everyone who considers tracking the oldest-old, whether WWI vets or no, to
1684:
It was for these reasons that I said his editing was irresponsible and wanted to start again from my original. It's hardly my job to correct his errors is it? I should be grateful if you would post some conciliatory remarks on the chemical equilibrium talk page - if the article is reverted to the
797:
I've just spoken to him (James) on the phone and he's informed me that his account has been re-infiltrated again by whoever keeps using his laptop, most likely his son. He's been away for 3 days on a trip, so it's unlikely any of the things that were added were from him directly, and he wanted to
2894:
If I may add, I started looking for real information on this molecule precisely in an attempt to demonstrate its notability in case someone nominated it for deletion. To my surprise, I couldn't find anything, which lead me to the conclusion that it should be deleted. I'm all from saving chemical
2502:
Unfortunately I don't know much about the history of the law of mass action, and I don't think I want to get involved at this point. The only thing I can suggest is to discuss the topic calmly and try to find good recent references about it. If the textbooks are wrong, I'm sure someone must have
3433:
Good catch on that AfD - I saw the very badly written article which was posted last night and reacted a bit too hastily. Thanks for taking the time to confirm that there was a worthwhile subject there. I've withdrawn the nom, and rewritten the article from scratch with the references you found.
2864:
I saw your prod. I'm not sure if this is entirely made up by the first editor to this page since it has been mentioned elsewhere. Some chemical compounds are also rather imaginatively named (what about cubane or prismane?), so that in itself is not sufficient reason to say this name is made up.
2528:
Re-read
Clugston's paper. He acknowledges that the argument does not apply to heterogeneous equilibria. That's solubility out of the window! The statement that standard free energy change refers to pure substances is not correct in general. For gases and liquids the standard states are the pure
2127:
but in any case for this particular figure the RDS for both directions is TS2. If you solve all the differential equations you'll see that the rate will change equally for both directions, regardless of which TS you modify. Also, if you could change the rate in only one direction, you would be
2037:
speeds up the reverse reaction or not not. Looking at the proposed mechanism, it seems very unlikely to me. One can imagine all sorts of free radical reactions occurring rapidly in the gas phase once the first N-H bond is thermally homolysed. I have two questions for you. 1) Do you know of any
542:
Sorry about the flub on the conversion rate. I saw "currently" without any indication how current "current" was, and wanted to insert a date (and felt the need to validate that the rate hadn't changed since whenever "current" was). In case you're curious how I messed up: I got 9¢ (US) per peso
4037:
The -1 oxidation state occurs in acetylene, in carbon 1 of ethanol, ethylamine, chloroethane, and all other similar compounds with a C(CH2)X substructure where X is an atom more electronegative than carbon. It also occurs in the central carbon of isobutane. And many, many more compounds. Read
2662:
I recently added a paragraph to the article on the anomeric effect, in which I pointed out that there are actually two conformations of the equatorial 2-tetrahydropyranyl ether that MUST show n-sigma* effects. Anyone with a molecular model of this molecule can see this. Yet you deleted my
37:
regarding the
Catalan-speaking population of Spain. This is of course correct, but I think that it is going to be problematic to try to classify the countries by language because several countries (including, but not limited to Spain) are multi-lingual. There's also Guarani, English, Nahuatl,
1692:
May I add that I declined to enter the entropy of mixing "debate" though in fact I initiated it with a remark I made to happy camper. You were, of course, right, but loom91 would not accept your arguments. His statement "Actually, it's more general to talk about entropy, because it is a more
626:
Either I've completely lost my mind, or I'm dealing with an invariably insulting editor who has an advanced degree in chemistry, yet really doesn't understand key parts of the physics of the subject. So, I'm asking for some badly needed RfC on the chem section of this article. I'm leaving an
2882:
in the sense that the name was not made up by the initial author of the article, but it is certainly a "made up" name in a more general sense. There are many imaginatively named molecules, such as cubane, where the names do get used in the "real world", and as such they will appear in real
424:
regarding the wording of the lyrics, and provided some sources at least I consider more important than the normal amateur site. It went unanswered for more than two weeks before I decided to take action and change the las phrase. You jumped to revert my edits, leaving no reference of the
2113:
O the catalyst affects the activation energy (TS1) for the forward reaction, but not neccessarily for the reverse (TS2). It will only affect the reverse reaction rate if it happens to be also the rate-determining step and if the reverse reaction must follow the same reaction path.
455:
I had reverted it because I guess something had gone wrong with the coding and the page was deleted. I tried refreshing the ñ page and it kept givnig me an error that it no longer existed, so I reverted it and it came back. Sorry, not hard feeling to whatever change you had made.
2677:
You really have NOT given me any reason for your desire to delete the article on STR3DI32. I can only assume that you are in opposition to any method of molecular modeling that is not orbital based. Am I correct? Is this move just another self-appointed censoring?
429:
version nor any message at the talk page. What's more, you claim that to be the "real" version, providing no sources. I feel like reverting back to my version, but will let you explain youractions and source your position. I'll past this also at the article's talk page.
2477:. If this is the case, then the dissociation of ammonia at the temperature and pressure of the Haber process can reach equilibrium rapidly without the aid of a catalyst because there will be a steady state concentration of nitrogen atoms and radicals, including NH, NH
2401:
N2H and so on. Also note that in the catalytic mechanism you are not really lowering any of these steps but rather undergoing a completely different mechanism, with more steps, the first of which is probably the adsorption of N2 and H2 on the surface of the catalyst.
1988:
Yes, I already have most of this typed up in a sub-section called "Heat and affinity" of a chapter called "Affinity and Free Energy" (chapter 11, pgs. 329-368) of a new 2007 textbook on Human
Chemistry publishing soon. I'll just give you the 7-page subsection here:
2920:
I see your point, and I agree. There are practically no limits on the number of chemicals which can and do exist, but not all are "important" in the sense of them having a practical use as a catalyst, building block, etc, or even being of academic interest.
2385:
1351:
1042:. And of course, you're always welcome to edit my templates. :-) By the way, if you have a picture of a particle in a box, that would be really nice...do you have access to a lab, where you could say, heat a cubic crystal of NaCl in some sodium vapor? --
2424:
suggests that both molecules are dissociated on the Fe surface. What is certain is that the activation energy for breaking the N-N bond is lowered. Now consider the reverse reaction. I can imagine that nitrogen atoms are produced by such reactions as
2138:. The only exception to this principle I know of is in the case of photochemically activated reactions; in those, after the excitation the system finds itself in a different potential energy surface, which usually goes downhill to the products. --
38:
Euskera, Gallego, etc... So I suggest getting rid of the language classification altogether (or at least try show the languages in a more general way that doesn't give the impression that there is only one language per country). What do you think?
4093:
because one book cites information doesn't mean its true. If Nitrogen in dinitrogen difluoride has a formal oxidation state of +1 then according to basic physical chemisty rules, the nitrogen cannot be bonded to the other, as I just explained.
3158:
Could you please respond to the question addressed in the RFC: whether the country is ambiguous or not? I would like to close that RFC with some conclusion and start a different one on the topic that people have been writing about. Thanks!
2285:
One last thought, after all. If the catalyst simply lowers the energy barrier to the point where the forward reaction proceeds at its "natural" rate equilibrium will be reached quickly. In the ammonia case the barrier is the dissociation of
1545:
3273:
Smokefoot and I have been working on this page, and from my limited experience it seems to cover most of the common techniques. Do you have any comments about the style, formatting, etc.? Or, any suggestions for inclusion? Thanks for your
2125:
3246:
Thanks Itub. I think for the moment I'm going to ask for clarification on the GA review. It can't hurt to see what the concerns might be. There's no hurry, after all. I was planning to take it through for FAC once the GA was passed. —
2248:
such as straight horizontal lines. The minima as plotted only have a strict meaning when the reaction coordinate is well-defined, which can only be plotted for very simple reactions. I'm using the same style as this book, for example:
4294:
I'm sorry, but I can't agree with those suggestions. I see no reason for excluding organic compounds and compounds with homonuclear bonds. There's nothing special about these compounds and nothing exotic about those oxidation states.
105:. That is how things are done. See the guidelines we agreed some weeks ago on the talk page. I have recommended deletion of the external link and keeping your excellent new addition. Please keep contributing to this page. Regards, --
568:
Thanks, I've commented about the figure in the article's talk page. The only thing I miss is the mention of the equivalent representation in terms of resonance structures. I may add it later, but it sorely needs a figure too. :)
2964:
Ok, I've move them out of the gallery, but I had put them there only in an attempt to improve the layout of the page (the floating images were screwing up the headings and stuff like that). I also expanded the history section.
2593:, 4144-4147 appears to have a proof of uniqueness. I suspect that these proofs might be difficult to convey to the general reader. Incidentally, the entropy of mixing for ideal gases is also discussed and cites M.W. Zermanski,
4467:
4310:
OK, so this is a matter of ego, since either way your oxidation states could be introduced into the article? Do we need to bring in someone more supperior, perhaps an auditor? Do you not want to put an end to this incessant
2719:
of the principles that you refer to, concerning articles in the Wiki, have been violated. Arev you simply trying to prevent other readers from knowing about the existence of a MM program that quantitates the VSEPR theory?
2399:
2N + 6H. Note: I don't think that's the real mechanism, but rather a free radical mechanism as you suggest. That means that you wouldn't need to fully dissociate N2 as the first step, you could have something like N2 + H -:
2136:
3342:
Physchim62 posted a bunch of evidence against me. I really didn't want to expand the case, but he's forced me to respond. I hope you understand that this isn't personal. Our conversations were going so nicely. Sigh. -
4123:
charge that an atom would have if the electrons were partitioned according to an arbitrary set of rules (the electrons in a bond are "counted" as belonging to the most electronegative atom). In any case, even atoms with
557:
Hi, I rewrote this article. I apologize if I seem to have lost some of your wording. You got this article off to a great start, and I could not resist. Feel free to revise what I put up. I will insert a figure soon.
807:
was similarly infiltrated and the password and email changed so he was unable to recover it. Regardless, i'll see him on saturday morning and speak to him then, but i just wanted to give you the "heads up". Cheers,
2133:
4273:
If you genuinely feel that you have a new oxidation state but, it does not comply with these rules, then add it to the main article not the info box. And state the conditions under which that oxidation state
2611:
article; I wouldn't be surprised if he had already considered its role in equilibrium in one of his famous papers published around 1870. But I haven't read any of Gibbs's papers so I can't tell for sure.
2249:
684:
actually deal with different topics. My opinion is that they don't, and therefore having two articles is redundant. I don't have a strong preference regarding the title of the resulting article, though.
4409:
Its acctually quite sensible to have seven VIIIC groups, it is no more senseless than having three VIIIB groups. Section A has one, if group 0 is concidered as group VIIIA, section B has three, section
2787:
As far as I'm concerned, please go ahead! I don't know anything about the history of furfural so I have no reason to object. It does sound more plausible that it was obtained from sugar than from ants.
1676:
3179:! Since you indicated that you agreed with item 3.1 (use common name) or 3.2 (use names shown on the Nobel site), could you please revisit the RFC and respond to the question in the section called
2241:
It is true that the equilibrium constant depends on the energies of C and D independently of intermediate energies. However, the equilibrium is dynamic, which means that for equilibrium C <-: -->
1181:
Ivan, let me clarify my position. It's not that I object to anyone editing the article, it's the fact that it has been done so badly. Let me give a few examples. You can still see the original at
2907:
and can conclude that there is something relevant to say other than that some people think it looks like a penguin, they are more than welcome to create a real article under the chemical name. --
4119:
You are confusing oxidation state with charge. Atoms with the same oxidation state can and do bond to each other. What part of the definition of oxidation state you don't understand? It is a
2367:
2166:
What about catalysis by enzymes? If you broadly accept the priciple that enzyme and substrate are like lock and key an enzyme will only speed up the forward reaction. As an example, consider
608:
Hi, I notice that you are interested in molecular orbitals. Thus, for you to note, I have just started the molecular orbital theory article if you are interested in contributing. Thanks: --
2503:
written an article on J. Chem. Ed. trying to clarify the issue. (Frankly, I don't even understand what the issue is. This is a historical topic about which I really know next to nothing.) --
1413:
3376:
3372:
699:
and although one could loosely merge these without to much difficulty, I reason that they should remain separate. Although I need to read more in this area, from what I understand so far
2837:" link (it is located at the very top of any Knowledge (XXG) page when you are logged in), and then selecting "Image" from the dropdown box. Note that any non-free images not used in any
3937:
This makes the 1+ simply a hypothetical average oxidation state if you were to isolate one nitrogen from the other. It is a calculated illusion, nothing more, it does not exist in the N
2242:
D, for example, C is being converted into D exactly at the same rate as D is being converted into C. From mass balance it follows that whatever happens to the overall rate for C -: -->
4429:
not to provide a forum for everyone's personal unpublished ideas on better ways to do things such as numbering the groups of the periodic table. For more details on this policy, see
2865:
Perhaps you might want to change it to a db-not notable, but that is a problem too because the non-chemist mafia uses such reasoning to attempt to delete many of our chemical stubs.
1932:
See answer on my TALK page. And, BTW, sorry for mistakenly posting this first on your user page, rather than properly your TALK page! A breach of wiki-ettiquette I know better than!
1977:. However, I'm not that familiar with this topic, and since the ancient history of chemistry seems to be one of your favorite topics I thought you might know more about it. Cheers,
4046:
by Greenwood and Earnshaw. You'll see that their table of oxidation states lists -4, -3, -2, -1, 0, 1, 2, 3, and 4 for carbon, and -3, -2, -1, 0, 1, 2, 3, 4, and 5 for nitrogen. --
3549:
Thanks for doing the right thing on that user page. I had forgotten about that page -- I had meant to mark it for deletion it weeks ago. Your prompting has reminded me to do that.
3427:
1884:
1762:
1222:
1707:
All right, but I'm going away for a few days and I won't have time to do that until Monday. Please be patient, the world won't end if the article is not perfect for a few days. --
1234:
4326:
It's a matter of not excluding perfectly well-known and well-documented oxidations states for arbitrary reasons that you haven't even cared to explain. I've created a thread at
3142:
I'm not wedded to this format. As long as I can understand what change you want to make, and the article titles you want to apply this change to, I can take care of the rest. --
2833:
If you have uploaded other unlicensed media, please check whether they're used in any articles or not. You can find a list of 'image' pages you have edited by clicking on the "
2576:
3633:, plus it looks like the template won't be deleted. Personally, I don't think the actual lame edit war for the "Nobel Prize in Economics" article is the one listed in
3368:
3358:
1784:
1194:"Despite the failure of this derivation, the equilibrium constant for a reaction is indeed a constant, independent of the activities of the various species involved "!
2063:
3913:
In the future, please resort to the discussion page, before you try to edit something you think is wrong. Or it could result in a wikiwar which is against the rules.
2578:
in the case of heterogeneous equilibria. I haven't given this any thought, as I'm not a thermodynamicist. Do you know if anything has been published on this subject?
2471:
2447:
2196:
1426:
2826:
if you think that that will be useful. However, please note that images for which a replacement could be created are not acceptable for use on Knowledge (XXG) (see
2635:
energy. I really see no alternative but to get him banned from editing the thing. Otherwise we're never going to be left alone to write it. I'm open to suggestions.
3444:
No problem, and you did a great job on the rewrite! The article originally didn't have much that was salvageable, so deleting it would have been understandable. --
4221:
Both arguments are non-sequiturs. Oxidation states can and are defined for atoms in molecules and don't need to be stable "by themselves", whatever that means. --
3968:
form compounds in the +1 oxidation state (FN=NF) and in the -1 oxidation state (HN=NH). I've reverted your edit accordingly. Please look at a decent book such as
2822:, meaning that it is not used in any articles on Knowledge (XXG). If the image was previously in an article, please go to the article and see why it was removed.
3192:
I don't know if this changes anything but wanted to let you know that I've discovered what the country data is supposed to be. You can find it under the point
2398:
N2, a step which might even be barrierless, but there had to be a large series of steps that had to be climbed starting from ammonia, something like 2NH3 -: -->
4007:
Why do you think that Carbon has a -1 oxidation state. If your trying to use the carbide ion as an example, I should point out that it is the same case as in N
2244:
C. Think about what would happen if you added a catalyst to a system that is already in equilibrium, and the catalyst only affected the rate in one direction.
2148:
I'm not expert in this field, so I'll accept what you say about microscopic reversibility. However there are a couple of matters that are still not clear.
3592:. When was the last time you saw even a mention of mathematical chemistry in a computational chemistry text or review? ;-) I've reverted the last edit. --
2730:
2132:
true that the rates in both directions are equal at equilibrium. Therefore if you changed one without changing the other you would affect the equilibrium.
1681:
He's pasted this in from the old article, but the notation is inconsistent with the notation given earlier. The same applies to the rest of the section.
3683:, which you created or substantially expanded. If you know of another interesting fact from a recently created article, then please suggest it on the
3637:-- there are others that could be put there, but I won't add them since the edit war isn't over and it would probably only exasperate the situation.
3508:
2206:
into close proximity of the O attached to Zn and c) having a basic site handy to accept the liberated proton. I don't see how the enzyme can adapt to
2842:
4158:
I know that oxidation state is related but not the same as charge. If your theory is correct, then why is the (I) only stable in the dimer form (N
1744:
Interesting point about reactions going to completion. I've done the maths and have come up with a semi-quantitative measure. For the reaction A+B
4366:
I have never heard of these group numbers, but I decided to give them the benefit of the doubt until I have time to look at it more carefully. --
2100:
4414:
has seven, and the g-block would have eleven. It would be like saying that Earth has one moon, why should Jupiter have more moons than Ganymede.
3526:
I find it incredulous that one would attack even the man who invented the term 'folklore' and started the field of 'supercentenarian tracking.'
1734:
Ok, I've turned it into a redirect. I hadn't noticed that the content was identical, so I thought that a more involved merge would be needed. --
3500:
Greetings, User Brown-Haired Girl has waged a campaign to wipe out the entire 'supercentenarians' field on Knowledge (XXG). This has included:
1161:
102:
4327:
3985:
3946:
440:
2834:
2263:, which means that the enzyme binds to the transition state better than to the substrate itself, thus lowering the effective barrier. --
672:
with the reason "non-covalent bonding is important in the field of supramolecular chemistry according to Lehn". I'm not questioning the
1021:. (Of course, most of these are not distinguished as X center, Y electron, but can be considered "types of bonds" to some extent.) --
3868:
it and make it go away, and no hard feelings; after all, it's just a small token of appreciation. If you like it, just add your name
2946:
covers into a gallery. Unfortunately book covers are only accepted under Knowledge (XXG)'s Fair Use guidelines. Most importantly, "
1814:
You are right, I forgot the 2.303. Please put this stuff in yourself if you want to, as I won't touch the article again for a while.
98:
4430:
2631:
As noted, Hallen, after totally screwing up the energy article, is now going to actively prevent anybody from writing a summary of
3919:
Take the permanganate ion for instance, in it, Manganese has a formal oxidation state of +7. There can be be no indiscrepencies.
587:
No problem, it's not like I own the article, I didn't even start it! The article is better now thanks to your contributions too.
4187:
is a formal oxidation state of oxygen then why does no molecule exist with that atom that doesn't contain the dioxygenyl cation?
2555:
Thanks for these comments. I, too have been away. To be perfectly general we also need to explain the existence of a minimum in
2231:
D. In this case, the first step has a barrier with the difference TS1−C. However, in the context of the system discussed in the
1787:
ca. 118 kJ mol. I doubt if this result is original. If we can find a citable source it might be worth adding it as footnote.
703:, the main founder of this field, who won the 1987 Nobel Prize for his work in SMC, defines “molecular chemistry”, as begun by
2904:
3558:
2069:? If not, would you like to amuse yourself with some juicy open-shell calculations? The point at issue is whether a catalyst
899:
131:
2814:. The image description page currently specifies that the image is non-free and may only be used on Knowledge (XXG) under a
4447:
Right, I will comply, but as a final note, it was not my own research, I just lack the ability to accurately refference it.
3039:, if you give me a list of what maps to what. So, would you like a hand? It would save you a lot of typing and clicking? --
1593:
3475:
3197:
3176:
3169:
3152:
3288:
Sorry about that! I have no idea what happened there, must have inadvertently highlighted your paragraph and overtyped it
2947:
2827:
2105:
for a multi-stage reaction. It clearly illustrates that, for example, in the carbonic anhydrase- catalysed reaction of CO
627:
identical message for user:smokefoot and everybody else with a chem degree I can think of. Gracias for the outside view.
2290:; once this process is speeded up by the Fe catalyst the reaction proceeds "normally". The back-reaction is unaffected.
1164:
to complement these two. My qualification for making such a bold proposal is more than 30 years experience in the field
3503:
3018:
514:
Thanks for your note. I'm not sure what the problem is either, but I'll put the word out for some help. Thanks again! -
4128:
of the same sign can form covalent bonds to each other too. Chemical bonds are not simple electrostatic attraction. --
3899:
3869:
3849:
3827:
3788:
http://en.wikipedia.org/Wikipedia:Administrators%27_noticeboard/3RR#User:Itub_reported_by_User:CyclePat_.28Result:_.29
3756:
2) You remove the same reference and sourced information, per the above example, and, this time, the second reference.
2810:
341:
260:
3930:
molecule, because the two nitrogen atoms are bonded together, they form a completely covalent radicle concisting of N
4380:
I decided to remove them too. They seem extremely dubious and I haven't found any plausible google hits for them. --
1144:
I'm pleased to see that you are following developments here. This is the broader picture: I am proposing to replace
1038:
I haven't decided what to put in that template yet, since I wanted to avoid duplicating the items that are found in
3684:
2585:
There are several proofs of the existence and uniqueness of chemical equilibrium cited in Van Zeggeren and Storey,
2314:
681:
466:
3504:
http://en.wikipedia.org/Wikipedia:Categories_for_discussion/Log/2007_November_1#Category:Supercentenarian_trackers
1368:
4452:
4419:
4316:
4279:
4192:
4098:
4024:
3950:
3022:
1169:
1039:
436:
292:
3618:
3607:
3483:
2868:
Anyway, I have no vested interest in this article, but I do not believe wp:made-up is an appropriate reason. --
2095:
1149:
986:
728:
715:
between supermolecules. Intermolecular forces, on the other had, is a more general term which may include the
711:. He contrasts this with the new field of “supramolecular chemistry” as related to the making and breaking of
696:
602:
399:
305:
2589:(1970). Unfortunately they are conference reports rather than publications. D.B. Shear, J. Chem. Phys. (1969)
2038:
literature on the thermolysis of ammonia? Have the dissociation energies (for loss of one hydrogen atom) of NH
1346:{\displaystyle K={\frac {k_{+}}{k_{-}}}={\frac {\{S\}^{\sigma }\{T\}^{\tau }}{\{A\}^{\alpha }\{B\}^{\beta }}}}
2396:
Back to the Haber process, let's assume for a moment that the first step is the dissociation of N2, N2 -: -->
1168:. However, I'm looking for some kind of consensus and your views will be most appreciated. Please respond at
3725:
the accronym you have provide does not meet the standards for inclusion)... I'm copying this message to the
3575:
1974:
951:
472:
Thanks for your message about this article. I've expanded it. Take a look and improve as necessary. Thanks,
315:
3895:
3655:
3568:
3004:
2983:
2955:
2597:(1957) so that idea is not very new, even if it has only recently crept into Atkins's Physical Chemistry.
1559:
1182:
757:
139:
3403:
84:
3978:
3838:
3671:
3629:. I'm pretty sure the complaints are less about the template and more about the article's inclusion in
3513:
2412:
Now we have come full circle. I agree that the catalytic mechanism probably involves the adsorption of N
1993:
with the 25-references included and I'll leave it to you to format (short on time presently). Later: --
1966:
1960:
1869:
1747:
1693:
fundamental and universal quantity than Gibbs energy" shows him to have a poor grasp of thermodynamics.
1207:
1130:
919:
875:
359:
220:
210:
3787:
2008:
Ivan: Per your request, I have added a couple of diagrams to the Polyurethane page. I hope these help.
1990:
676:
of non-covalent bonding. What I'm questioning is whether the Knowledge (XXG) articles currently titled
3881:
3877:
3509:
http://en.wikipedia.org/Wikipedia:Articles_for_deletion/Robert_Young_%28longevity_claims_researcher%29
2160:
outcome. The rate of reaction away from equilibrium conditions is not the same as that at equilibrium.
1191:
The expression for forward reaction rate has been separated from the defining equilibrium expression.
457:
4475:
4448:
4415:
4312:
4275:
4188:
4162:), why does this collapse into a different state outside of the dimer? You don't get the NF molecule.
4094:
4020:
3678:
3418:
3298:
1721:
1153:
1145:
677:
669:
431:
388:
333:
4246:
Its time to reach common ground, here is my suggestion When we add new oxidation states, they must:
3721:. Surelly you can explain in better details and provide some sources for your mis-information. (per
3626:
3603:
2896:
2846:
1010:
732:
364:
235:
76:
72:
48:
3119:
3094:
3069:
3065:
2879:
2819:
2733:, where other Knowledge (XXG) editors with no part in this dispute will help reach a consensus. --
1063:
Nope, I'm a theoretical/computational chemist. I tend to break things when I go into a lab. ;-) --
3873:
3813:
3795:
3776:
3734:
3554:
3479:
3264:
3218:
2720:
2679:
2664:
2489:
2167:
1686:
1157:
981:
Depending on how specific you want the template to be, others you might want to consider include
893:
195:
185:
4260:
Occur unbonded to another atom of the same element with the same oxidation state in the example.
3916:
There are two kinds of oxidation states: Formal oxiodation sates and averaged oxidation states.
3589:
3136:
3131:
3111:
3106:
3086:
3081:
2759:
Ok, I've followed one of Jreferee's suggestions and nominated the article for deletion. Cheers,
2128:
changing the position of equilibrium. While it is true that K=k1/k-1 is not generally valid, it
1540:{\displaystyle K{\stackrel {\mathrm {def} }{=}}{\frac {\left^{c}\left^{d}}{\left^{a}\left^{b}}}}
3060:
I'll have to key it into AWB myself anyway, so it doesn't matter. You can have something like:
4438:
4400:
4356:
3982:
3697:
3387:
3383:
3371:. Please add any evidence you may wish the Arbitrators to consider to the evidence sub-page,
2979:
2951:
2009:
1764:
AB, if one starts with 1 mol of A and 1 mol of B reaction "goes to completion" when Lg K : -->
1563:
1551:
762:
421:
287:
135:
3861:
3857:
3745:
3634:
3630:
3622:
2823:
2705:
2701:
2697:
2558:
3970:
3805:
3275:
3252:
3143:
3040:
2922:
2869:
2804:
1994:
1970:
1769:
1126:
1123:
1095:
1043:
955:
913:
736:
704:
609:
494:
473:
240:
64:
60:
56:
52:
3768:
3578:? I think it is wrong, but I do not really have time until tomorrow to address it again. --
3233:
3214:
2693:
2048:
4471:
4039:
3808:. I've left a reply on the talk page for you. Best regards, in all humility, Thank you. --
3291:
2099:
804:
700:
403:
270:
215:
205:
200:
169:
80:
3865:
3718:
2815:
2456:
2432:
2181:
950:
Do you have a list of all X-center, Y-electron bonds somewhere? I made a new template at
879:
4328:
Knowledge (XXG) talk:WikiProject Elements#Oxidation_states_of_the_elements_and_infoboxes
4385:
4371:
4335:
4300:
4226:
4133:
4125:
4075:
4051:
3997:
3853:
3614:
3534:
3344:
3313:
2608:
2598:
2579:
2530:
2520:
2493:
2374:
2291:
2277:
2232:
2215:
2115:
2074:
1919:
1856:
1788:
1725:
1696:
1172:
1018:
1014:
846:
819:
579:
559:
544:
392:
297:
230:
17:
3722:
2689:
2073:
speeds up both forward and backward reactions when the mixture is not at equilibrium.
3809:
3791:
3772:
3730:
3550:
3036:
2750:
2649:
2646:
2641:
2636:
2485:
or an intermediate is adsorbed by the catalyst that would be yet another mechanism.
2421:
2202:+ H. It works by a) polarising a water molecule by coordination to Zn, b) bringing CO
2034:
1946:
1943:
1938:
1933:
1002:
998:
990:
889:
716:
655:
641:
638:
633:
628:
369:
323:
245:
156:
44:
34:
2895:
articles from "non-chemistry mafia" deletionists, which is why I worked on rescuing
4466:
Hi there, I've made some chages to the article and replied to your comments on the
4434:
4396:
4352:
3726:
3714:
3707:
3694:
3487:
3461:
1090:
1006:
775:
529:
417:
4351:
seen these numbers before, or are they equally nonsense which should be deleted?
2384:
1855:=1 and =1/N, the result follows. Footnote or mini section? I have no preference.
1724:, so I am happy to replace the content by a redirect, or you do it if you agree.
3662:
3435:
3248:
2260:
982:
863:
501:
328:
225:
3872:, but again, there's no need to feel upset if you don't. Love and best wishes,
3312:
I really like your point about Jekyll/Hyde. That issue is worth clarifying. -
2124:
It's not that simple. The concept of rate-determining step has its limitations,
798:
explain also that he's looked at his page and will change it when he gets back.
4479:
4456:
4442:
4423:
4404:
4389:
4375:
4360:
4339:
4320:
4304:
4283:
4230:
4196:
4137:
4102:
4079:
4055:
4028:
4001:
3954:
3903:
3817:
3799:
3780:
3738:
3700:
3641:
3638:
3596:
3582:
3579:
3562:
3539:
3490:
3464:
3448:
3438:
3421:
3390:
3347:
3329:
3316:
3306:
3278:
3258:
3240:
3221:
3204:
3201:
3187:
3184:
3163:
3160:
3146:
3054:
3043:
3025:
3007:
2986:
2969:
2958:
2925:
2911:
2900:
2887:
2872:
2855:
2849:
2792:
2781:
2778:
2763:
2753:
2737:
2723:
2712:
2682:
2667:
2652:
2616:
2601:
2549:
2540:
That said, I still think the entropy of mixing is important because it is the
2533:
2523:
2507:
2496:
2406:
2377:
2305:
2294:
2280:
2267:
2218:
2142:
2118:
2088:
2077:
2022:
2012:
1997:
1981:
1949:
1922:
1859:
1805:
1791:
1738:
1728:
1711:
1699:
1175:
1134:
1098:
1067:
1046:
1025:
994:
972:
965:
958:
937:
927:
904:
849:
832:
815:
782:
768:
739:
724:
689:
658:
644:
612:
591:
582:
573:
562:
547:
532:
518:
504:
486:
476:
460:
445:
406:
346:
159:
142:
119:
109:
106:
87:
3934:. In this radicle the 2+ oxidation state is shared between the participants.
3713:
I would like to invite you to take a look at the discussion happening on the
2883:
publications and indexed by CAS. But that is not the case with penguinone. --
2369:. The energy of this dissociation is much less than for the dissociation of N
1558:. Often (conditions are given below) these activities can be approximated by
4381:
4367:
4331:
4296:
4222:
4129:
4071:
4047:
3993:
3593:
3445:
3326:
3237:
3126:
3101:
3076:
3051:
2966:
2908:
2884:
2789:
2760:
2734:
2709:
2708:. If after that you still don't understand the reason, I cannot help you. --
2613:
2546:
2504:
2403:
2302:
2264:
2163:
Why are the energies of C and D shown as minima rather than constant values?
2139:
2085:
2019:
1978:
1802:
1735:
1708:
1064:
1022:
969:
934:
829:
779:
686:
588:
570:
483:
351:
255:
190:
116:
2135:
For more information about the principle of microscopic reversibility, see
2607:
Well, the entropy of mixing was known by Gibbs, at least according to the
1969:(salt, sulphur, mercury) would be useful to add to the history section of
2770:
1118:
515:
275:
2243:
D has to be compensated by an equivalent change in the rate for D -: -->
172:
predicts that you will enjoy editing some of these articles. Have fun!
810:
380:
Your contributions make Knowledge (XXG) better -- thanks for helping.
4015:
in Nitrogen. The "-1" state does not occur anywhere out side of the C
2903:
is a joke. If anyone has the inclination to read the 11 papers about
2624:
619:
265:
4470:. Could you have a look and see if I have dealt with your concerns?
3804:
Hello Itub, I would first like to apologize for all the comotion at
3514:
http://en.wikipedia.org/Louis_Epstein_%28supercentenarian_tracker%29
1765:
2 lg N, where N is Avagadro's constant: for this reaction lg K : -->
398:
P.S. You received these suggestions because your name was listed on
75:
would not fit in what I did, because we don't have a section called
2948:
Fair use images may never be included as part of a photo gallery...
3486:
which seems the best place to discuss it, so please reply there.
2397:
N + N. The reverse step would be the formation of N2, N + N -: -->
933:
Hey, thanks for the star, and for all the work you did. Cheers! --
578:
Thank you for your patience (with my invasiveness) and guidance.--
310:
250:
68:
3375:. You may also contribute to the case on the workshop sub-page,
3035:
I see you're recatting a lot of stuff right now. I can help with
3666:
3000:
1801:
kJ/mol. Are you sure you didn't mix up the log10 with the ln? --
3521:
3482:
contradicts itself and says both C3v and D3h! I left a note on
2033:
I'm currently trying to puzzle out whether the catalyst in the
695:
While I appreciate your effort to organize, I have interest in
3748:
I have noticed that you violated the 3R rule. This is because:
3170:
Talk:Nobel Prize in Chemistry#RFC: Country data in Nobel lists
793:
Just thought i'd mirror what i posted to MessedRocker's page;
3417:
Hello Itub! Thank you for some userful information. Regards,
3377:
Knowledge (XXG):Requests for arbitration/Sadi Carnot/Workshop
3373:
Knowledge (XXG):Requests for arbitration/Sadi Carnot/Evidence
3153:
Talk:Nobel Prize in Chemistry#RFC: Country – ambiguous or not
1165:
101:
and put that and the new addition you added up for debate on
3367:
An Arbitration case in which you commented has been opened:
4070:
is not a radical (let alone a radicle!). It is an anion. --
2799:
Orphaned non-free image (Image:Players handbook 2nd ed.jpg)
2749:
wikipedia future, if people like you are given a free hand
2152:
I think the activation energy for the first step is not ΔG
1188:
Introduction: Adding a catalyst will fasten the reaction!
4395:
Good decision, and your edit summary is well expressed.
3574:
Good work on this article. Have you seen the new lead to
3428:
Knowledge (XXG):Articles for deletion/Alka Seltzer Rocket
43:
I did so because there are three sections in the article
1873:
1751:
1387:
1211:
3762:
3757:
3752:
2939:
2228:
I'm assuming you are talking about the process C -: -->
751:
720:
528:
Thanks for point that out. (Was late at night :-( ) --
402:. If this was in error, sorry about the confusion. --
1671:{\displaystyle G=U+PV-TS=\sum _{i=1}^{m}\mu _{i}N_{i}}
2561:
2459:
2435:
2317:
2184:
2051:
1872:
1772:
1750:
1596:
1429:
1371:
1237:
1210:
3369:
Knowledge (XXG):Requests for arbitration/Sadi Carnot
3359:
Knowledge (XXG):Requests for arbitration/Sadi Carnot
387:
on how to make SuggestBot better, please tell me on
59:. I thought it was good to add the note next to the
3852:by placing a heart icon in the top-right corner of
3761:
3) Despite the changes, you remove both references.
3717:. You and I are heading towards a slipery slope of
3181:
Clarification & Questions related to 3.1 or 3.2
2420:on the surface of the catalyst. The article on the
654:Thanks for the help with the missing topics page -
2841:will be deleted after seven days, as described on
2570:
2465:
2441:
2361:
2190:
2057:
1878:
1778:
1756:
1670:
1566:, giving the easier to measure and use constants K
1539:
1407:
1345:
1216:
719:if fashioned so. If you don’t believe me, look at
707:in 1828, as related to the making and breaking of
668:I'm puzzled by your removal of the merge tag from
130:Heyas, thanks for your limitations section to the
2488:P.S. An edit war has broken out in regard to the
2210:a bicarbonate molecule and a proton rather than
1866:The result can be somewhat generalised. For A+nB
165:Articles you might like to edit, from SuggestBot
152:was what I wanted to say about bismuth. Thanks =
3215:WP:ANI#user:panda possible breach of good faith
1965:Hi, I was thinking that some discussion of the
1574:encountered in high-school chemistry courses.
803:He also informed me that his previous account,
3474:Are you sure it is C3v as you have stated for
2731:Knowledge (XXG):Articles for deletion/STR3DI32
2362:{\displaystyle NH_{3}\to NH_{2}\cdot +H\cdot }
1766:ca. 47.5/mols of reactant. This translates to
1917:it comes out that the criterion is Lg K : -->
1408:{\displaystyle aA+bB\rightleftharpoons cC+dD}
8:
3232:My opinion is that the article is ready for
2235:article, the "first" step is either A -: -->
1331:
1324:
1315:
1308:
1297:
1290:
1281:
1274:
855:Thanks for the help on Timeline of chemistry
4330:so other people can give their opinions. --
3864:If you don't really like it, feel free to
3833:
3650:
968:, which were missing from the template. --
754:the numerous contributions made by James?
3992:before deleting more oxidation states. --
3675:was updated with a fact from the article
2560:
2458:
2434:
2341:
2325:
2316:
2225:I'll use the same numbering for clarity.
2183:
2050:
1871:
1771:
1749:
1662:
1652:
1642:
1631:
1595:
1528:
1510:
1490:
1472:
1457:
1442:
1441:
1436:
1434:
1433:
1428:
1420:The equilibrium constant K is defined as
1370:
1334:
1318:
1300:
1284:
1271:
1260:
1250:
1244:
1236:
1209:
3706:I invite you to have your discussion on
3496:Are the Oldest-Old or Final Few notable?
3382:On behalf of the Arbitration Committee,
2905:3,4,4,5-Tetramethyl-2,5-cyclohexadienone
2383:
3617:your original reason for including the
3395:
2156:, but the difference between C and TS1.
861:
3518:And, even, a man dead over 100 years:
2587:The computation of chemical equilibria
2257:Lehninger's Principles of Biochemistry
1720:The content is identical with that of
1162:Determination of equilibrium constants
964:I don't have a list, but I just added
103:Talk:List of publications in chemistry
3860:but simply a small way to spread the
3825:
3522:http://en.wikipedia.org/William_Thoms
3325:I'm glad we agree about something! --
2311:The reverse reaction must begin with
7:
4254:Provide an refference to an example.
954:and would like to add them to it. --
750:Hi there! Just curious, why did you
3289:
1879:{\displaystyle \rightleftharpoons }
1757:{\displaystyle \rightleftharpoons }
1217:{\displaystyle \rightleftharpoons }
731:is defined by the use of the term “
727:, in which the intro definition of
622:and the last two edits by Hallenrm?
79:. We neither have a section called
3751:1) You remove sourced information.
2818:. However, the image is currently
2562:
1773:
1449:
1446:
1443:
24:
2811:Image:Players handbook 2nd ed.jpg
2663:contribution. Please explain.
482:Wow, that was a great expansion!
174:
99:List of publications in chemistry
97:I have reverted your deletion on
93:List of publications in chemistry
3837:
3744:After looking at the history of
3654:
3198:RFC: Country data in Nobel lists
3177:RFC: Country data in Nobel lists
3175:Thanks for participating in the
2995:OpenBabel: expert system or not?
2803:
2098:
1094:? Thanks for the chuckle. :-) --
862:
809:
3545:User:Karlhahn/ethanol2006-12-08
3299:
3292:
2238:interests of the experimenter).
2094:I've located this diagram from
3613:Perhaps you should explain to
3188:04:37, 30 September 2007 (UTC)
3164:06:01, 14 September 2007 (UTC)
2729:Please take your arguments to
2460:
2436:
2331:
2185:
828:Thanks for letting me know. --
487:23:02, 21 September 2006 (UTC)
477:22:05, 21 September 2006 (UTC)
461:23:17, 19 September 2006 (UTC)
446:08:29, 14 September 2006 (UTC)
132:Henderson-Hasselbalch equation
33:Hi, I see you added a note to
1:
4480:10:45, 21 December 2007 (UTC)
4457:08:03, 13 December 2007 (UTC)
4443:01:57, 13 December 2007 (UTC)
4424:23:02, 12 December 2007 (UTC)
4405:20:11, 12 December 2007 (UTC)
4390:17:14, 12 December 2007 (UTC)
4376:17:08, 12 December 2007 (UTC)
4361:16:04, 12 December 2007 (UTC)
4340:11:53, 13 December 2007 (UTC)
4321:10:25, 13 December 2007 (UTC)
4305:09:15, 13 December 2007 (UTC)
4284:22:40, 12 December 2007 (UTC)
4257:Occur in inorganic compounds.
4231:10:51, 12 December 2007 (UTC)
4197:10:09, 12 December 2007 (UTC)
4138:08:41, 11 December 2007 (UTC)
4103:07:57, 11 December 2007 (UTC)
4080:07:16, 11 December 2007 (UTC)
4056:07:14, 11 December 2007 (UTC)
4029:21:22, 10 December 2007 (UTC)
4002:12:29, 10 December 2007 (UTC)
3955:21:02, 10 December 2007 (UTC)
3904:11:30, 10 December 2007 (UTC)
3882:19:47, 21 November 2007 (UTC)
3818:19:09, 21 November 2007 (UTC)
3800:20:31, 19 November 2007 (UTC)
3781:18:52, 19 November 2007 (UTC)
3739:18:42, 19 November 2007 (UTC)
3701:18:56, 17 November 2007 (UTC)
3642:15:05, 15 November 2007 (UTC)
3597:10:08, 13 November 2007 (UTC)
3583:09:39, 13 November 2007 (UTC)
3563:16:28, 12 November 2007 (UTC)
3476:Octahedral molecular geometry
3386:19:27, 29 October 2007 (UTC)
3147:09:46, 6 September 2007 (UTC)
3055:09:33, 6 September 2007 (UTC)
3044:09:26, 6 September 2007 (UTC)
2828:our policy for non-free media
760:, your friendly neighborhood
659:10:11, 16 February 2007 (UTC)
618:Could you have a look at the
592:21:12, 28 December 2006 (UTC)
583:20:42, 28 December 2006 (UTC)
574:20:33, 28 December 2006 (UTC)
563:18:14, 28 December 2006 (UTC)
548:18:51, 12 December 2006 (UTC)
533:07:49, 10 November 2006 (UTC)
134:article. Most informative. -
3894:Thanks for the correction.--
3540:17:08, 9 November 2007 (UTC)
3491:17:41, 7 November 2007 (UTC)
3465:16:21, 7 November 2007 (UTC)
3449:10:11, 7 November 2007 (UTC)
3439:17:49, 6 November 2007 (UTC)
3422:02:59, 3 November 2007 (UTC)
3391:19:27, 29 October 2007 (UTC)
3348:17:16, 1 November 2007 (UTC)
3330:08:45, 24 October 2007 (UTC)
3317:14:18, 23 October 2007 (UTC)
3307:14:09, 23 October 2007 (UTC)
3279:15:00, 18 October 2007 (UTC)
3259:14:43, 18 October 2007 (UTC)
3241:08:21, 18 October 2007 (UTC)
3222:19:02, 10 October 2007 (UTC)
3205:14:55, 10 October 2007 (UTC)
2843:criteria for speedy deletion
1117:Thanks for all your help on
845:From the left, of course!:-)
789:User:James.Spudeman's edits.
774:I've detailed my reasons in
645:09:34, 19 January 2007 (UTC)
120:22:39, 6 February 2006 (UTC)
110:22:15, 6 February 2006 (UTC)
3530:chime in on these debates.
3026:17:14, 18 August 2007 (UTC)
2744:Energy (chemistry) redirect
2582:18:06, 11 June 2007 (UTC)
1358:
650:Missing topics in chemistry
613:23:16, 2 January 2007 (UTC)
519:21:57, 8 October 2006 (UTC)
505:20:58, 6 October 2006 (UTC)
407:13:36, 13 August 2006 (UTC)
400:the SuggestBot request page
342:Probability interpretations
261:Law of multiple proportions
4495:
3786:You may see the report at
3455:"R" in structural formulas
1928:Xe and SF6 mixing in lungs
1918:n+1 lg N for 1 mole of B.
1556:at equilibrium composition
1197:Contradictory definitions
1135:18:21, 29 April 2007 (UTC)
1099:18:26, 24 April 2007 (UTC)
1068:17:48, 23 April 2007 (UTC)
1047:17:27, 23 April 2007 (UTC)
1026:12:37, 16 April 2007 (UTC)
973:12:30, 16 April 2007 (UTC)
959:12:27, 16 April 2007 (UTC)
946:X-center, Y-electron bonds
938:06:27, 18 April 2007 (UTC)
928:21:02, 17 April 2007 (UTC)
905:01:40, 14 April 2007 (UTC)
833:19:19, 15 March 2007 (UTC)
820:16:08, 15 March 2007 (UTC)
783:12:31, 15 March 2007 (UTC)
769:11:10, 15 March 2007 (UTC)
740:00:26, 13 March 2007 (UTC)
690:12:33, 12 March 2007 (UTC)
682:intermolecular interaction
467:Beta-methylamino L-alanine
427:"las dos patitas de atras"
395:, SuggestBot's caretaker.
177:
88:17:20, 13 April 2007 (UTC)
71:. Other languages such as
4044:Chemistry of the Elements
3975:Chemistry of the Elements
3973:; Earnshaw, Alan (1997).
3588:It is wrong, or at least
3210:your comments are invited
3008:19:00, 12 July 2007 (UTC)
2987:01:48, 13 July 2007 (UTC)
2970:08:06, 12 July 2007 (UTC)
2959:01:52, 12 July 2007 (UTC)
2926:10:36, 11 July 2007 (UTC)
2912:09:39, 11 July 2007 (UTC)
2888:09:20, 11 July 2007 (UTC)
2873:09:15, 11 July 2007 (UTC)
2850:21:50, 10 July 2007 (UTC)
2793:12:15, 28 June 2007 (UTC)
2782:16:57, 27 June 2007 (UTC)
2764:08:03, 20 June 2007 (UTC)
2754:04:11, 20 June 2007 (UTC)
2738:12:05, 14 June 2007 (UTC)
2724:11:57, 14 June 2007 (UTC)
2713:11:48, 14 June 2007 (UTC)
2683:11:38, 14 June 2007 (UTC)
2668:11:38, 14 June 2007 (UTC)
2653:21:50, 11 June 2007 (UTC)
2617:14:29, 13 June 2007 (UTC)
2602:14:21, 13 June 2007 (UTC)
2508:12:22, 25 June 2007 (UTC)
2497:11:46, 25 June 2007 (UTC)
2407:18:47, 23 June 2007 (UTC)
2378:18:44, 22 June 2007 (UTC)
2306:11:16, 22 June 2007 (UTC)
2295:09:46, 22 June 2007 (UTC)
2281:14:25, 21 June 2007 (UTC)
2268:11:06, 20 June 2007 (UTC)
2219:20:06, 19 June 2007 (UTC)
2143:09:07, 17 June 2007 (UTC)
2119:18:17, 16 June 2007 (UTC)
1361:
1170:talk:chemical equilibrium
1150:user talk:petergans/draft
1040:Category:Chemical bonding
868:
850:21:25, 6 April 2007 (UTC)
293:Gas-liquid chromatography
281:
160:04:10, 23 June 2006 (UTC)
3619:Nobel Prize in Economics
3608:Nobel Prize in Economics
3484:Talk:Hexamethyl tungsten
3017:It is currently under a
2571:{\displaystyle \Delta G}
2550:06:58, 5 June 2007 (UTC)
2534:10:18, 1 June 2007 (UTC)
2524:21:06, 31 May 2007 (UTC)
2096:Curtin-Hammett principle
2089:07:13, 5 June 2007 (UTC)
2078:16:44, 28 May 2007 (UTC)
2065:and NH: been calculated
2023:07:05, 5 June 2007 (UTC)
2013:13:01, 28 May 2007 (UTC)
1998:11:02, 24 May 2007 (UTC)
1982:08:01, 24 May 2007 (UTC)
1950:21:25, 14 May 2007 (UTC)
1923:08:01, 24 May 2007 (UTC)
1860:19:24, 23 May 2007 (UTC)
1806:17:23, 23 May 2007 (UTC)
1792:14:15, 23 May 2007 (UTC)
1739:12:37, 22 May 2007 (UTC)
1729:10:08, 22 May 2007 (UTC)
1712:06:47, 18 May 2007 (UTC)
1700:21:02, 17 May 2007 (UTC)
1577:_______________________
987:coordinate covalent bond
869:The Chemistry Bond Star
735:. I hope this helps? --
729:supramolecular chemistry
697:supermolecular chemistry
603:Molecular orbital theory
416:I left a message at the
306:Deposition (meteorology)
143:19:03, 18 May 2006 (UTC)
4431:WP:No original research
3767:I am reporting this to
3685:Did you know? talk page
3576:computational chemistry
3533:Sincerely, Robert Young
2595:Heat and Thermodynamics
2035:Haber process#catalysts
1975:history of the molecule
1818:Here is my derivation.
1779:{\displaystyle \Delta }
1200:______________________
1176:09:19, 7 May 2007 (UTC)
952:Template:Chemical bonds
316:List of stable isotopes
4346:Group (periodic table)
3856:Don't worry, it's not
3569:Mathematical chemistry
3013:Spells in Harry potter
2999:Please comment on the
2934:Fair use and galleries
2572:
2467:
2443:
2388:
2363:
2192:
2059:
2058:{\displaystyle \cdot }
1880:
1780:
1758:
1672:
1647:
1550:where represents the
1541:
1409:
1347:
1218:
1183:user:petergans/sandbox
788:
543:backwards in my head.
389:SuggestBot's talk page
4462:Review of NAD article
3979:Butterworth-Heinemann
3971:Greenwood, Norman N.
2878:Maybe I extrapolated
2808:Thanks for uploading
2573:
2468:
2444:
2387:
2364:
2193:
2060:
2029:Ammonia and catalysis
1967:alchemical principles
1961:User talk:Sadi Carnot
1881:
1781:
1759:
1673:
1627:
1542:
1410:
1348:
1219:
876:Timeline of chemistry
360:Orbital hybridisation
221:Pinacol rearrangement
211:Rate-determining step
126:Henderson-Hasselbalch
3679:Mercury(IV) fluoride
3194:Country data defined
3023:Therequiembellishere
2942:you put two D&D
2559:
2466:{\displaystyle \to }
2457:
2442:{\displaystyle \to }
2433:
2315:
2191:{\displaystyle \to }
2182:
2049:
2004:Polyurethane diagram
1870:
1770:
1748:
1722:equilibrium constant
1594:
1560:molar concentrations
1427:
1369:
1235:
1208:
1154:equilibrium constant
1146:Chemical equilibrium
678:non-covalent bonding
670:non-covalent bonding
664:Non-covalent bonding
500:Good idea:) Thanks!
334:Reducing environment
115:No problem, thanks.
63:one to say that the
3402:Link redacted, per
3001:Openbabel talk page
2897:caesium perchlorate
2824:You may add it back
2658:The Anomeric Effect
1955:Chemical principles
1011:noncovalent bonding
733:noncovalent bonding
493:Note in History of
365:Pesticide poisoning
236:Ammonium persulfate
49:Portuguese-speaking
3480:Hexamethyltungsten
3470:Hexamethyltungsten
3265:Air-free technique
2978:Nice additions! —
2568:
2490:Law of Mass Action
2463:
2439:
2389:
2359:
2188:
2168:carbonic anhydrase
2055:
1963:
1876:
1776:
1754:
1687:solubility product
1668:
1537:
1405:
1343:
1214:
1158:stability constant
1140:Stability constant
713:non-covalent bonds
530:Gary van der Merwe
196:Plum pudding model
186:Physical chemistry
67:is also spoken in
47:, as you can see:
3987:978-0-08-037941-8
3896:Environnement2100
3890:Methane chemistry
3887:
3886:
3691:
3690:
2944:Player's Handbook
2816:claim of fair use
2514:Entropy of mixing
1991:Heat and affinity
1958:
1851:Since . Putting T
1564:partial pressures
1554:of the species A
1552:chemical activity
1535:
1454:
1418:
1417:
1341:
1266:
1160:. I have written
902:
896:
886:
885:
553:3-center-4e thing
444:
377:
376:
288:Inert pair effect
4486:
3991:
3841:
3834:
3806:talk:millisecond
3658:
3651:
3627:user's talk page
3537:
3407:
3400:
3305:
3303:
3296:
2835:my contributions
2807:
2644:
2639:
2577:
2575:
2574:
2569:
2472:
2470:
2469:
2464:
2448:
2446:
2445:
2440:
2368:
2366:
2365:
2360:
2346:
2345:
2330:
2329:
2197:
2195:
2194:
2189:
2102:
2064:
2062:
2061:
2056:
1973:, or perhaps to
1971:chemical element
1941:
1936:
1885:
1883:
1882:
1877:
1785:
1783:
1782:
1777:
1763:
1761:
1760:
1755:
1677:
1675:
1674:
1669:
1667:
1666:
1657:
1656:
1646:
1641:
1546:
1544:
1543:
1538:
1536:
1534:
1533:
1532:
1527:
1515:
1514:
1509:
1496:
1495:
1494:
1489:
1477:
1476:
1471:
1458:
1456:
1455:
1453:
1452:
1440:
1435:
1414:
1412:
1411:
1406:
1359:
1352:
1350:
1349:
1344:
1342:
1340:
1339:
1338:
1323:
1322:
1306:
1305:
1304:
1289:
1288:
1272:
1267:
1265:
1264:
1255:
1254:
1245:
1223:
1221:
1220:
1215:
926:
900:
894:
874:For helping get
866:
859:
858:
818:
813:
767:
705:Friedrich Wohler
636:
631:
510:Visible spectrum
495:Water (molecule)
434:
241:Pseudomonadaceae
175:
77:Guaraní-speaking
61:Catalan-speaking
57:Catalan-speaking
53:Spanish-speaking
4494:
4493:
4489:
4488:
4487:
4485:
4484:
4483:
4464:
4449:Plasmic Physics
4416:Plasmic Physics
4348:
4313:Plasmic Physics
4276:Plasmic Physics
4189:Plasmic Physics
4186:
4161:
4126:partial charges
4095:Plasmic Physics
4069:
4042:. And read the
4040:oxidation state
4021:Plasmic Physics
4018:
4014:
4010:
3988:
3969:
3962:
3947:222.153.150.124
3944:
3940:
3933:
3929:
3925:
3922:Now, take the N
3911:
3892:
3832:
3711:
3649:
3611:
3572:
3547:
3535:
3498:
3472:
3457:
3431:
3419:Masterpiece2000
3415:
3410:
3401:
3397:
3362:
3286:
3268:
3229:
3212:
3173:
3156:
3033:
3019:deletion review
3015:
2997:
2936:
2859:
2801:
2774:
2746:
2675:
2660:
2642:
2637:
2629:
2557:
2556:
2516:
2484:
2480:
2476:
2455:
2454:
2452:
2431:
2430:
2428:
2419:
2415:
2372:
2337:
2321:
2313:
2312:
2289:
2205:
2201:
2180:
2179:
2177:
2173:
2155:
2112:
2108:
2047:
2046:
2045:
2041:
2031:
2006:
1957:
1939:
1934:
1930:
1916:
1912:
1909:Assuming that T
1904:
1897:
1889:
1868:
1867:
1854:
1847:
1843:
1839:
1832:
1825:
1768:
1767:
1746:
1745:
1658:
1648:
1592:
1591:
1573:
1569:
1517:
1516:
1499:
1498:
1497:
1479:
1478:
1461:
1460:
1459:
1425:
1424:
1367:
1366:
1330:
1314:
1307:
1296:
1280:
1273:
1256:
1246:
1233:
1232:
1206:
1205:
1152:and to replace
1142:
1115:
948:
911:
857:
843:
814:
805:User:J.Spudeman
791:
755:
748:
701:Jean-Marie Lehn
666:
652:
634:
629:
624:
606:
555:
540:
526:
524:Circulene image
512:
498:
470:
453:
414:
412:Re:La Cucaracha
391:. Thanks from
271:Oxidizing agent
216:Dihydrogen bond
206:Benzimidazoline
201:Cyclopentadiene
167:
154:
128:
95:
81:Basque-speaking
29:
22:
21:
20:
12:
11:
5:
4492:
4490:
4463:
4460:
4393:
4392:
4378:
4347:
4344:
4343:
4342:
4311:argumentation?
4308:
4307:
4291:
4290:
4289:
4288:
4287:
4286:
4266:
4265:
4264:
4263:
4262:
4261:
4258:
4255:
4244:
4243:
4242:
4241:
4240:
4239:
4238:
4237:
4236:
4235:
4234:
4233:
4208:
4207:
4206:
4205:
4204:
4203:
4202:
4201:
4200:
4199:
4184:
4172:
4171:
4170:
4169:
4168:
4167:
4166:
4165:
4164:
4163:
4159:
4147:
4146:
4145:
4144:
4143:
4142:
4141:
4140:
4110:
4109:
4108:
4107:
4106:
4105:
4085:
4084:
4083:
4082:
4067:
4061:
4060:
4059:
4058:
4032:
4031:
4016:
4012:
4008:
3986:
3961:
3958:
3942:
3938:
3931:
3927:
3923:
3910:
3907:
3891:
3888:
3885:
3884:
3854:your userpage.
3842:
3831:
3824:
3823:
3822:
3821:
3820:
3765:
3764:
3759:
3754:
3749:
3710:
3704:
3689:
3688:
3659:
3648:
3645:
3615:User:NYScholar
3610:
3601:
3600:
3599:
3571:
3566:
3546:
3543:
3497:
3494:
3478:? The page on
3471:
3468:
3456:
3453:
3452:
3451:
3430:
3425:
3414:
3411:
3409:
3408:
3394:
3361:
3356:
3355:
3354:
3353:
3352:
3351:
3350:
3335:
3334:
3333:
3332:
3320:
3319:
3285:
3282:
3267:
3262:
3244:
3243:
3228:
3225:
3211:
3208:
3172:
3167:
3155:
3150:
3140:
3139:
3134:
3129:
3123:
3122:
3115:
3114:
3109:
3104:
3098:
3097:
3090:
3089:
3084:
3079:
3073:
3072:
3058:
3057:
3050:categories. --
3032:
3029:
3014:
3011:
2996:
2993:
2992:
2991:
2990:
2989:
2973:
2972:
2935:
2932:
2931:
2930:
2929:
2928:
2915:
2914:
2891:
2890:
2858:
2853:
2847:BetacommandBot
2800:
2797:
2796:
2795:
2773:
2768:
2767:
2766:
2745:
2742:
2741:
2740:
2716:
2715:
2674:
2671:
2659:
2656:
2628:
2621:
2620:
2619:
2609:mixing paradox
2567:
2564:
2553:
2552:
2515:
2512:
2511:
2510:
2482:
2478:
2474:
2462:
2450:
2438:
2426:
2417:
2413:
2410:
2409:
2393:
2392:
2370:
2358:
2355:
2352:
2349:
2344:
2340:
2336:
2333:
2328:
2324:
2320:
2309:
2308:
2287:
2273:
2272:
2271:
2270:
2252:
2245:
2239:
2233:Curtin-Hammett
2222:
2221:
2203:
2199:
2187:
2175:
2171:
2164:
2161:
2157:
2153:
2146:
2145:
2110:
2106:
2092:
2091:
2054:
2043:
2039:
2030:
2027:
2026:
2025:
2005:
2002:
2001:
2000:
1956:
1953:
1929:
1926:
1914:
1910:
1907:
1906:
1902:
1899:
1895:
1891:
1890:
1887:
1875:
1863:
1862:
1852:
1849:
1845:
1841:
1837:
1834:
1830:
1827:
1823:
1816:
1815:
1811:
1810:
1809:
1808:
1795:
1794:
1775:
1753:
1732:
1731:
1717:
1716:
1715:
1714:
1679:
1678:
1665:
1661:
1655:
1651:
1645:
1640:
1637:
1634:
1630:
1626:
1623:
1620:
1617:
1614:
1611:
1608:
1605:
1602:
1599:
1571:
1567:
1548:
1547:
1531:
1526:
1523:
1520:
1513:
1508:
1505:
1502:
1493:
1488:
1485:
1482:
1475:
1470:
1467:
1464:
1451:
1448:
1445:
1439:
1432:
1416:
1415:
1404:
1401:
1398:
1395:
1392:
1389:
1386:
1383:
1380:
1377:
1374:
1363:
1362:
1354:
1353:
1337:
1333:
1329:
1326:
1321:
1317:
1313:
1310:
1303:
1299:
1295:
1292:
1287:
1283:
1279:
1276:
1270:
1263:
1259:
1253:
1249:
1243:
1240:
1226:
1225:
1213:
1186:
1185:
1141:
1138:
1114:
1111:
1110:
1109:
1108:
1107:
1106:
1105:
1104:
1103:
1102:
1101:
1077:
1076:
1075:
1074:
1073:
1072:
1071:
1070:
1054:
1053:
1052:
1051:
1050:
1049:
1031:
1030:
1029:
1028:
1019:quintuple bond
1015:quadruple bond
976:
975:
947:
944:
943:
942:
941:
940:
884:
883:
878:promoted as a
871:
870:
867:
856:
853:
842:
839:
838:
837:
836:
835:
823:
822:
800:
799:
790:
787:
786:
785:
747:
744:
743:
742:
709:covalent bonds
665:
662:
651:
648:
623:
616:
605:
600:
599:
598:
597:
596:
595:
594:
554:
551:
539:
536:
525:
522:
511:
508:
497:
491:
490:
489:
469:
464:
452:
449:
413:
410:
375:
374:
373:
372:
367:
362:
357:
354:
349:
344:
339:
336:
331:
326:
321:
318:
313:
308:
303:
300:
298:Cumene process
295:
290:
285:
280:
279:
278:
273:
268:
263:
258:
253:
248:
243:
238:
233:
231:Petrochemistry
228:
223:
218:
213:
208:
203:
198:
193:
188:
183:
181:
166:
163:
153:
146:
127:
124:
123:
122:
94:
91:
85:Onofre Bouvila
28:
27:Ibero-American
25:
23:
18:User talk:Itub
15:
14:
13:
10:
9:
6:
4:
3:
2:
4491:
4482:
4481:
4477:
4473:
4469:
4461:
4459:
4458:
4454:
4450:
4445:
4444:
4440:
4436:
4432:
4426:
4425:
4421:
4417:
4413:
4407:
4406:
4402:
4398:
4391:
4387:
4383:
4379:
4377:
4373:
4369:
4365:
4364:
4363:
4362:
4358:
4354:
4345:
4341:
4337:
4333:
4329:
4325:
4324:
4323:
4322:
4318:
4314:
4306:
4302:
4298:
4293:
4292:
4285:
4281:
4277:
4272:
4271:
4270:
4269:
4268:
4267:
4259:
4256:
4253:
4252:
4251:
4250:
4249:
4248:
4247:
4232:
4228:
4224:
4220:
4219:
4218:
4217:
4216:
4215:
4214:
4213:
4212:
4211:
4210:
4209:
4198:
4194:
4190:
4182:
4181:
4180:
4179:
4178:
4177:
4176:
4175:
4174:
4173:
4157:
4156:
4155:
4154:
4153:
4152:
4151:
4150:
4149:
4148:
4139:
4135:
4131:
4127:
4122:
4118:
4117:
4116:
4115:
4114:
4113:
4112:
4111:
4104:
4100:
4096:
4091:
4090:
4089:
4088:
4087:
4086:
4081:
4077:
4073:
4065:
4064:
4063:
4062:
4057:
4053:
4049:
4045:
4041:
4036:
4035:
4034:
4033:
4030:
4026:
4022:
4006:
4005:
4004:
4003:
3999:
3995:
3989:
3984:
3980:
3976:
3972:
3967:
3959:
3957:
3956:
3952:
3948:
3935:
3920:
3917:
3914:
3908:
3906:
3905:
3901:
3897:
3889:
3883:
3879:
3875:
3874:Master Redyva
3871:
3867:
3863:
3859:
3855:
3851:
3847:
3843:
3840:
3836:
3835:
3829:
3819:
3815:
3811:
3807:
3803:
3802:
3801:
3797:
3793:
3789:
3785:
3784:
3783:
3782:
3778:
3774:
3770:
3763:
3760:
3758:
3755:
3753:
3750:
3747:
3743:
3742:
3741:
3740:
3736:
3732:
3728:
3724:
3720:
3716:
3709:
3705:
3703:
3702:
3699:
3696:
3686:
3682:
3681:
3680:
3674:
3673:
3672:Did you know?
3668:
3664:
3660:
3657:
3653:
3652:
3646:
3644:
3643:
3640:
3636:
3632:
3628:
3624:
3620:
3616:
3609:
3605:
3604:Template:Lame
3602:
3598:
3595:
3591:
3587:
3586:
3585:
3584:
3581:
3577:
3570:
3567:
3565:
3564:
3560:
3556:
3552:
3544:
3542:
3541:
3538:
3531:
3527:
3524:
3523:
3519:
3516:
3515:
3511:
3510:
3506:
3505:
3501:
3495:
3493:
3492:
3489:
3485:
3481:
3477:
3469:
3467:
3466:
3463:
3454:
3450:
3447:
3443:
3442:
3441:
3440:
3437:
3429:
3426:
3424:
3423:
3420:
3412:
3405:
3399:
3396:
3393:
3392:
3389:
3385:
3380:
3378:
3374:
3370:
3365:
3360:
3357:
3349:
3346:
3341:
3340:
3339:
3338:
3337:
3336:
3331:
3328:
3324:
3323:
3322:
3321:
3318:
3315:
3311:
3310:
3309:
3308:
3304:
3302:
3297:
3295:
3283:
3281:
3280:
3277:
3271:
3266:
3263:
3261:
3260:
3256:
3255:
3250:
3242:
3239:
3235:
3231:
3230:
3226:
3224:
3223:
3220:
3216:
3209:
3207:
3206:
3203:
3199:
3195:
3190:
3189:
3186:
3182:
3178:
3171:
3168:
3166:
3165:
3162:
3154:
3151:
3149:
3148:
3145:
3138:
3135:
3133:
3130:
3128:
3125:
3124:
3121:
3117:
3116:
3113:
3110:
3108:
3105:
3103:
3100:
3099:
3096:
3092:
3091:
3088:
3085:
3083:
3080:
3078:
3075:
3074:
3071:
3067:
3063:
3062:
3061:
3056:
3053:
3048:
3047:
3046:
3045:
3042:
3038:
3037:User:Chem-awb
3030:
3028:
3027:
3024:
3020:
3012:
3010:
3009:
3006:
3002:
2994:
2988:
2985:
2981:
2977:
2976:
2975:
2974:
2971:
2968:
2963:
2962:
2961:
2960:
2957:
2953:
2949:
2945:
2941:
2933:
2927:
2924:
2919:
2918:
2917:
2916:
2913:
2910:
2906:
2902:
2898:
2893:
2892:
2889:
2886:
2881:
2877:
2876:
2875:
2874:
2871:
2866:
2862:
2857:
2854:
2852:
2851:
2848:
2845:. Thank you.
2844:
2840:
2836:
2831:
2829:
2825:
2821:
2817:
2813:
2812:
2806:
2798:
2794:
2791:
2786:
2785:
2784:
2783:
2780:
2772:
2769:
2765:
2762:
2758:
2757:
2756:
2755:
2752:
2743:
2739:
2736:
2732:
2728:
2727:
2726:
2725:
2722:
2714:
2711:
2707:
2703:
2699:
2695:
2691:
2687:
2686:
2685:
2684:
2681:
2672:
2670:
2669:
2666:
2657:
2655:
2654:
2651:
2648:
2645:
2640:
2634:
2633:science-based
2626:
2622:
2618:
2615:
2610:
2606:
2605:
2604:
2603:
2600:
2596:
2592:
2588:
2583:
2581:
2565:
2551:
2548:
2543:
2538:
2537:
2536:
2535:
2532:
2526:
2525:
2522:
2513:
2509:
2506:
2501:
2500:
2499:
2498:
2495:
2491:
2486:
2423:
2422:Haber process
2408:
2405:
2395:
2394:
2386:
2382:
2381:
2380:
2379:
2376:
2356:
2353:
2350:
2347:
2342:
2338:
2334:
2326:
2322:
2318:
2307:
2304:
2299:
2298:
2297:
2296:
2293:
2283:
2282:
2279:
2269:
2266:
2262:
2258:
2253:
2250:
2246:
2240:
2236:C or B -: -->
2234:
2227:
2226:
2224:
2223:
2220:
2217:
2213:
2209:
2169:
2165:
2162:
2158:
2151:
2150:
2149:
2144:
2141:
2137:
2134:
2131:
2126:
2123:
2122:
2121:
2120:
2117:
2103:
2101:
2097:
2090:
2087:
2082:
2081:
2080:
2079:
2076:
2072:
2068:
2052:
2036:
2028:
2024:
2021:
2017:
2016:
2015:
2014:
2011:
2003:
1999:
1996:
1992:
1987:
1986:
1985:
1983:
1980:
1976:
1972:
1968:
1962:
1954:
1952:
1951:
1948:
1945:
1942:
1937:
1927:
1925:
1924:
1921:
1900:
1893:
1892:
1865:
1864:
1861:
1858:
1850:
1835:
1828:
1821:
1820:
1819:
1813:
1812:
1807:
1804:
1799:
1798:
1797:
1796:
1793:
1790:
1743:
1742:
1741:
1740:
1737:
1730:
1727:
1723:
1719:
1718:
1713:
1710:
1706:
1705:
1704:
1703:
1702:
1701:
1698:
1694:
1690:
1688:
1682:
1663:
1659:
1653:
1649:
1643:
1638:
1635:
1632:
1628:
1624:
1621:
1618:
1615:
1612:
1609:
1606:
1603:
1600:
1597:
1590:
1589:
1588:
1585:
1582:
1578:
1575:
1565:
1561:
1557:
1553:
1529:
1524:
1521:
1518:
1511:
1506:
1503:
1500:
1491:
1486:
1483:
1480:
1473:
1468:
1465:
1462:
1437:
1430:
1423:
1422:
1421:
1402:
1399:
1396:
1393:
1390:
1384:
1381:
1378:
1375:
1372:
1365:
1364:
1360:
1357:
1335:
1327:
1319:
1311:
1301:
1293:
1285:
1277:
1268:
1261:
1257:
1251:
1247:
1241:
1238:
1231:
1230:
1229:
1203:
1202:
1201:
1198:
1195:
1192:
1189:
1184:
1180:
1179:
1178:
1177:
1174:
1171:
1167:
1163:
1159:
1155:
1151:
1147:
1139:
1137:
1136:
1133:
1132:
1128:
1125:
1120:
1112:
1100:
1097:
1093:
1092:
1087:
1086:
1085:
1084:
1083:
1082:
1081:
1080:
1079:
1078:
1069:
1066:
1062:
1061:
1060:
1059:
1058:
1057:
1056:
1055:
1048:
1045:
1041:
1037:
1036:
1035:
1034:
1033:
1032:
1027:
1024:
1020:
1016:
1012:
1008:
1004:
1003:metallic bond
1000:
999:covalent bond
996:
992:
991:hydrogen bond
988:
984:
980:
979:
978:
977:
974:
971:
967:
963:
962:
961:
960:
957:
953:
945:
939:
936:
932:
931:
929:
925:
923:
922:
917:
916:
914:Wim van Dorst
910:Fully agree!
909:
908:
907:
906:
903:
897:
891:
881:
880:featured list
877:
873:
872:
865:
860:
854:
852:
851:
848:
840:
834:
831:
827:
826:
825:
824:
821:
817:
812:
806:
802:
801:
796:
795:
794:
784:
781:
777:
773:
772:
771:
770:
765:
764:
759:
753:
745:
741:
738:
734:
730:
726:
722:
718:
717:covalent bond
714:
710:
706:
702:
698:
694:
693:
692:
691:
688:
683:
679:
675:
671:
663:
661:
660:
657:
649:
647:
646:
643:
640:
637:
632:
621:
617:
615:
614:
611:
604:
601:
593:
590:
586:
585:
584:
581:
577:
576:
575:
572:
567:
566:
565:
564:
561:
552:
550:
549:
546:
537:
535:
534:
531:
523:
521:
520:
517:
509:
507:
506:
503:
496:
492:
488:
485:
481:
480:
479:
478:
475:
468:
465:
463:
462:
459:
450:
448:
447:
442:
438:
433:
428:
423:
419:
411:
409:
408:
405:
401:
396:
394:
390:
386:
381:
371:
370:Haber process
368:
366:
363:
361:
358:
355:
353:
350:
348:
345:
343:
340:
337:
335:
332:
330:
327:
325:
324:Atomic theory
322:
319:
317:
314:
312:
309:
307:
304:
301:
299:
296:
294:
291:
289:
286:
283:
282:
277:
274:
272:
269:
267:
264:
262:
259:
257:
254:
252:
249:
247:
246:Deprotonation
244:
242:
239:
237:
234:
232:
229:
227:
224:
222:
219:
217:
214:
212:
209:
207:
204:
202:
199:
197:
194:
192:
189:
187:
184:
182:
179:
178:
176:
173:
171:
164:
162:
161:
158:
151:
147:
145:
144:
141:
137:
133:
125:
121:
118:
114:
113:
112:
111:
108:
104:
100:
92:
90:
89:
86:
82:
78:
74:
70:
66:
62:
58:
54:
50:
46:
45:Ibero-America
41:
39:
36:
35:Ibero-America
26:
19:
4465:
4446:
4427:
4411:
4408:
4394:
4349:
4309:
4245:
4121:hypothetical
4120:
4043:
3974:
3965:
3963:
3936:
3921:
3918:
3915:
3912:
3893:
3845:
3826:You've been
3766:
3727:talk:1 E-3 s
3715:Talk:1 E-3 s
3712:
3708:Talk:1 E-3 s
3692:
3677:
3676:
3670:
3612:
3573:
3548:
3532:
3528:
3525:
3520:
3517:
3512:
3507:
3502:
3499:
3473:
3458:
3432:
3416:
3404:WP:BLACKLIST
3398:
3388:David Mestel
3384:David Mestel
3381:
3366:
3363:
3300:
3293:
3287:
3272:
3269:
3253:
3245:
3213:
3193:
3191:
3180:
3174:
3157:
3141:
3120:category:yyy
3095:category:xxx
3070:category:yyy
3066:category:xxx
3059:
3034:
3031:Need a hand?
3016:
2998:
2980:Alan De Smet
2952:Alan De Smet
2943:
2937:
2867:
2863:
2860:
2838:
2832:
2809:
2802:
2775:
2747:
2717:
2688:Please read
2676:
2661:
2632:
2630:
2594:
2590:
2586:
2584:
2554:
2541:
2527:
2517:
2487:
2411:
2310:
2284:
2274:
2256:
2211:
2207:
2147:
2129:
2104:
2093:
2070:
2066:
2032:
2010:P Cottontail
2007:
1964:
1931:
1908:
1817:
1733:
1695:
1691:
1683:
1680:
1586:
1583:
1579:
1576:
1555:
1549:
1419:
1355:
1227:
1199:
1196:
1193:
1190:
1187:
1166:my home page
1143:
1122:
1116:
1091:Pauli effect
1089:
1007:peptide bond
949:
920:
915:
912:
887:
844:
841:Peeling eggs
816:J O R D A N
792:
776:Talk:Halogen
763:MessedRocker
761:
749:
712:
708:
673:
667:
653:
625:
607:
556:
541:
538:Mexican Peso
527:
513:
499:
471:
454:
426:
418:La Cucaracha
415:
397:
384:
383:If you have
382:
378:
168:
155:
149:
136:SocratesJedi
129:
96:
42:
32:
30:
4472:Tim Vickers
3977:(2nd ed.).
3945:molecule.--
3844:Hey there!
3663:17 November
3621:article in
3284:Sadi Carnot
3276:Rifleman 82
3183:? Thanks!
3144:Rifleman 82
3041:Rifleman 82
2923:Rifleman 82
2870:Rifleman 82
2261:induced fit
2255:available,
1995:Sadi Carnot
1959:Paste from
1096:HappyCamper
1044:HappyCamper
983:banana bond
966:delta bonds
956:HappyCamper
882:. Thanks!
737:Sadi Carnot
610:Sadi Carnot
474:Scientizzle
458:Speakslowly
329:Monochromat
320:Add Sources
226:Amino group
4019:radicle.--
3858:vandalism,
3413:Thank you!
3274:comments--
3137:blah blah3
3132:blah blah2
3112:blah blah3
3107:blah blah2
3087:blah blah3
3082:blah blah2
2901:penguinone
2856:Penguinone
2018:Thanks! --
1088:Heh, à la
995:ionic bond
725:User:V8rik
674:importance
404:SuggestBot
347:Dithiolene
170:SuggestBot
3964:Nitrogen
3862:WikiLove.
3850:loved you
3830:by Redyva
3551:Karl Hahn
3536:Ryoung122
3345:Jehochman
3314:Jehochman
3127:blah blah
3102:blah blah
3077:blah blah
2940:this edit
2880:WP:MADEUP
2623:The poor
2599:Petergans
2580:Petergans
2531:Petergans
2521:Petergans
2494:Petergans
2375:Petergans
2292:Petergans
2278:Petergans
2216:Petergans
2116:Petergans
2075:Petergans
2067:ab initio
1920:Petergans
1857:Petergans
1789:Petergans
1726:Petergans
1697:Petergans
1173:Petergans
721:this edit
580:Smokefoot
560:Smokefoot
545:AdamRoach
422:talk page
393:ForteTuba
352:Flat feet
256:Lone pair
191:Hydroxide
4468:FAC page
3909:Nitrogen
3810:CyclePat
3792:CyclePat
3773:CyclePat
3731:CyclePat
3625:on that
3590:WP:UNDUE
3270:Hi Itub
3219:emerson7
2861:Hi Itub
2839:articles
2820:orphaned
2771:Furfural
2751:Hallenrm
2673:STR3DI32
2453:and NH+H
2230:B -: -->
2229:A -: -->
1204:αA + βB
1119:Francium
1113:Francium
901:contribs
890:Jayron32
656:Skysmith
451:Revert ñ
385:feedback
276:Up quark
4435:Dirac66
4397:Dirac66
4353:Dirac66
4274:occurs.
3746:1 e-3 s
3695:Zzyzx11
3635:WP:LAME
3631:WP:LAME
3623:WP:LAME
3488:Dirac66
3462:Ajrocke
3364:Hello,
3118:Remove
3064:Change
2706:WP:TEND
2702:WP:SOAP
2698:WP:NPOV
2627:article
1844:=, so T
1786:G : -->
1224:σS + τT
1124:Cryptic
746:Halogen
432:Mariano
284:Cleanup
73:Guaraní
65:Catalan
4183:If a /
4066:BTW, C
3960:Carbon
3866:revert
3846:Redyva
3769:WP:ANI
3698:(Talk)
3639:–panda
3436:Iain99
3234:WP:FAC
3202:–panda
3185:–panda
2899:. But
2721:Vgsbox
2704:, and
2694:WP:COI
2680:Vgsbox
2665:Vgsbox
2625:energy
2214:them.
2208:accept
2109:with H
2071:always
1836:When T
1581:am).
758:Signed
752:revert
620:energy
502:DMacks
356:Expand
338:Wikify
266:Allene
3828:loved
3719:WP:3R
3580:Bduke
3301:scent
3294:iride
3227:Xenon
3161:panda
2779:Stone
2650:arris
2416:and H
2212:expel
1947:arris
1570:and K
642:arris
311:Redox
302:Merge
251:Aldol
180:Stubs
157:Steve
148:Yep,
107:Bduke
69:Spain
16:<
4476:talk
4453:talk
4439:talk
4420:talk
4401:talk
4386:talk
4382:Itub
4372:talk
4368:Itub
4357:talk
4336:talk
4332:Itub
4317:talk
4301:talk
4297:Itub
4280:talk
4227:talk
4223:Itub
4193:talk
4134:talk
4130:Itub
4099:talk
4076:talk
4072:Itub
4052:talk
4048:Itub
4025:talk
3998:talk
3994:Itub
3983:ISBN
3966:does
3951:talk
3900:talk
3878:talk
3870:here
3848:has
3814:talk
3796:talk
3777:talk
3771:. --
3735:talk
3729:. --
3723:WP:V
3667:2007
3606:and
3594:Itub
3446:Itub
3406:~~~~
3327:Itub
3254:talk
3238:Itub
3093:Add
3052:Itub
2984:Talk
2967:Itub
2956:Talk
2909:Itub
2885:Itub
2790:Itub
2761:Itub
2735:Itub
2710:Itub
2690:WP:N
2614:Itub
2547:Itub
2542:only
2505:Itub
2449:NH+H
2404:Itub
2303:Itub
2265:Itub
2170:, CO
2140:Itub
2086:Itub
2042:, NH
2020:Itub
1979:Itub
1905:=+nK
1803:Itub
1736:Itub
1709:Itub
1356:...
1228:...
1131:Talk
1065:Itub
1023:Itub
970:Itub
935:Itub
921:Talk
895:talk
847:dick
830:Itub
780:Itub
778:. --
687:Itub
680:and
589:Itub
571:Itub
484:Itub
150:that
140:Talk
117:Itub
55:and
4433:.
3661:On
3647:DYK
3557:) (
3290:—
3249:RJH
3196:in
3068:to
3005:JKW
2938:In
2830:).
2473:N+H
2400:-->
2198:HCO
2174:+ H
1913:=nT
1898:=+K
1848:=+K
1833:=+K
1826:=+K
1689:.
1562:or
1156:by
1148:by
1127:C62
723:by
516:AED
420:'s
4478:)
4455:)
4441:)
4422:)
4403:)
4388:)
4374:)
4359:)
4338:)
4319:)
4303:)
4295:--
4282:)
4229:)
4195:)
4136:)
4101:)
4078:)
4054:)
4027:)
4000:)
3981:.
3953:)
3902:)
3880:)
3816:)
3798:)
3790:--
3779:)
3737:)
3693:--
3687:.
3669:,
3665:,
3561:)
3379:.
3257:)
3217:--
3200:.
3021:.
3003:.
2982:|
2965:--
2954:|
2921:--
2788:--
2700:,
2696:,
2692:,
2612:--
2591:48
2563:Δ
2461:→
2437:→
2429:+H
2425:NH
2402:--
2357:⋅
2348:⋅
2332:→
2186:→
2178:O
2130:is
2053:⋅
1984:.
1886:AB
1874:⇌
1840:=T
1774:Δ
1752:⇌
1650:μ
1629:∑
1616:−
1388:⇌
1336:β
1320:α
1302:τ
1286:σ
1262:−
1212:⇌
1129:·
1017:,
1013:,
1009:,
1005:,
1001:,
997:,
993:,
989:,
985:,
930:.
888:--
685:--
558:--
456:--
138:|
51:,
40:"
4474:(
4451:(
4437:(
4418:(
4412:C
4399:(
4384:(
4370:(
4355:(
4334:(
4315:(
4299:(
4278:(
4225:(
4191:(
4185:2
4160:2
4132:(
4097:(
4074:(
4068:2
4050:(
4023:(
4017:2
4013:2
4011:F
4009:2
3996:(
3990:.
3949:(
3943:2
3941:F
3939:2
3932:2
3928:2
3926:F
3924:2
3898:(
3876:(
3812:(
3794:(
3775:(
3733:(
3559:C
3555:T
3553:(
3251:(
2647:H
2643:B
2638:S
2566:G
2483:3
2479:2
2475:2
2451:2
2427:2
2418:2
2414:2
2371:2
2354:H
2351:+
2343:2
2339:H
2335:N
2327:3
2323:H
2319:N
2288:2
2286:N
2251:.
2204:2
2200:3
2176:2
2172:2
2154:1
2111:2
2107:2
2044:2
2040:3
1944:H
1940:B
1935:S
1915:A
1911:B
1903:B
1901:T
1896:A
1894:T
1888:n
1853:A
1846:A
1842:B
1838:A
1831:B
1829:T
1824:A
1822:T
1664:i
1660:N
1654:i
1644:m
1639:1
1636:=
1633:i
1625:=
1622:S
1619:T
1613:V
1610:P
1607:+
1604:U
1601:=
1598:G
1572:p
1568:c
1530:b
1525:]
1522:B
1519:[
1512:a
1507:]
1504:A
1501:[
1492:d
1487:]
1484:D
1481:[
1474:c
1469:]
1466:C
1463:[
1450:f
1447:e
1444:d
1438:=
1431:K
1403:D
1400:d
1397:+
1394:C
1391:c
1385:B
1382:b
1379:+
1376:A
1373:a
1332:}
1328:B
1325:{
1316:}
1312:A
1309:{
1298:}
1294:T
1291:{
1282:}
1278:S
1275:{
1269:=
1258:k
1252:+
1248:k
1242:=
1239:K
924:)
918:(
898:|
892:|
766:.
756:—
639:H
635:B
630:S
443:)
441:c
439:/
437:t
435:(
31:"
Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.