Knowledge (XXG)

:Manual of Style/Chemistry/Safety - Knowledge (XXG)

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If a chemical is used as a pesticide, most likely its use is subject to extensive regulation, which will vary from country to country, and even depend on the province or state within many countries. Furthermore, most regulations change with time. Prudence must be exercised in covering such regulatory
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If a chemical is used as a pesticide, most likely its use is subject to extensive regulation, which will vary from country to country, and even depend on the province or state within many countries. Furthermore, most regulations change with time. Prudence must be exercised in covering such regulatory
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These are also published by the IPCS, but are much shorter than other IPCS publications (two pages!) and intended for a non-technical audience. They do not include citations to the original literature, but are peer-reviewed. They are particularly useful for providing basic chemical information (in
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There are noticeable differences between the MSDSs of different companies. In particular, MSDSs written for distribution in the United States are noticeably harsher on the perceived hazards of a given chemical than those written from distribution in Europe (this almost certainly stems from the
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News reports of spills or accidents associated with a chemical compound, even though they may be tragic, are usually not notable. The description of hazards should avoid anecdotes. The role of Knowledge (XXG) is to give balanced and accurate information, allowing readers to reach their own
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Descriptions of hazards should, as far as possible, be based on published, peer-reviewed sources, which should be cited at the appropriate point in the article. A list of resources for chemical safety information is given in the external links section of these guidelines.
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conclusions. Hazards should be peer reviewed, and not taken from newspaper accounts. If an event is potentially significant enough to warrant inclusion as a safety hazard, first post it to the discussion page and discuss it with the Knowledge (XXG) community.
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risks to humans which are very widely used around the world. Summary evaluations are available for all chemicals which have been classified as carcinogens by the IARC, and in some cases the full text of the monograph is available free of charge. These are a
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source of safety information for a particular chemical: indeed, they may be the only available source of basic chemical data such as melting points. If that is the case, a separate safety section is inappropriate. However the relevant summary data
736:(see above) are preferred as a source for carcinogenicity information, as they cover more substances in greater depth, but the NTP report is also reliable. The report also links to many other federal regulations concerning the substances listed. 400:) with the collaboration of many other national and international bodies. It publishes several series of documents which may be of use here: these are peer-reviewed reviews, but are often long and technical. The three main ones are 1092: 859:(CCID) according to the Hazardous Substances and New Organisms Regulations (HSNO regulations): contains over 5000 GHS classifications (some of these are multiple classifications for different concentrations of the same substance) 267:. Editors recognize that all chemical compounds could be abused and can be dangerous under diverse circumstances. In cases where the mechanism of toxicity is noteworthy in a chemical context, e.g., the inhibition of 540: 205: 928:, currently on its 11th edition (2004, 4860 pages). It is available in most university libraries and in many large public libraries, and some universities have local access to a CD-ROM version. In citing 971: 955: 275:, a separate section within the article is often desirable because it illuminates the chemical subject. In a few cases where the literature and lore on toxicity is extensive, such as 195: 180: 1014:
present several problems as sources: these problems are shared by the various collections of MSDSs kept and compiled by university chemistry departments and by data retrieved from
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Depending on the extent of the information, this content may be incorporated into the Safety section or it may be a separate section on its own. If the compound is a drug, follow
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Much of the regulation of occupation exposure to chemical substances in Canada is of provincial competence. There is a federal classification system, the
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When the safety section is warranted beyond the information in the Chembox, information should be succinctly presented. Pertinent information could be
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They are commercial documents, usually held on the supplier's website: why should we favour one supplier over another in linking to their sites?
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Safety sections should only be included when the information adds something to the article. They are not obligatory and often are inappropriate.
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In the usual encyclopedic way, the Project avoids serving either as a safety manual or a guide to regulation. We follow the advice in
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legally enforceable in the United States, although they have been cited in civil lawsuits as an example of industry best practice.
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The CDC promote public health in general, and most of their work on occupational health is conducted through NIOSH. However, their
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the absence of a more specific source), and in providing NFPA-ratings which have been peer-reviewed (otherwise difficult to find).
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The EPA is mostly concerned with pesticides and environmental polluants, information on which can be found through the
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on just over 300 substances. These are fairly long and technical, and often redundant to CICADs or similar documents.
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This page provides additional information about concepts in the page(s) it supplements. This page is not one of
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is a strong acid, it is not necessary to state that it should be stored away from bases and reactive metals.
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The EU-OSHA site contains information of a more general nature about the use of chemicals in the workplace.
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via GHSPictograms, GHSSignalWord, NFPA, or MainHazard parameters; further elaborated in H and P phrases.
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They are not peer-reviewed. Although they are usually competently complied, peer-reviewed sources are
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from using the primary literature (e.g. journal articles) as sources for chemical safety information.
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The standard reference work for chemical safety, other than the sites and monographs given above, is
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NIOSH is a federal agency concerned more with research and training rather than with regulation. Its
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be described by a long list of potential hazards as well as H&P phrases. Knowledge (XXG) does
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The HSE is responsible for promotion and enforcement of health and safety regulations in the UK.
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different legal frameworks for these documents). Which version should we choose as our source?
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The hazards associated with most chemical compounds are adequately described in the Chembox
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from the National Industrial Chemicals Notification and Assessment Scheme (NICNAS) at the
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Knowledge (XXG) talk:WikiProject Chemicals/Archive 2011#Recommend New Template or Project
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is a useful secondary source of information on some more exotic compounds, such as
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Other IPCS publications which might be of use in specific circumstances include:
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is a widely used summary of basic safety information, but mostly redundant to
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are the legally enforceable standards for workplace contamination in the U.S.
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be included in the chembox, with the MSDS as a reference or included in the
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provides a variety of general publications about various chemical hazards.
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The ECHA is the main site for EU-related chemical safety concerning e.g.
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Knowledge (XXG) essays and information pages about the Manual of Style
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As a counterbalance to these problems, MSDSs or IUCLID are often the
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values (for "Immediately Dangerous to Life and Health", available
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Explanatory essay about Knowledge (XXG):Manual of Style/Chemistry
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Monographs on the Evaluation of Carcinogenic Risks to Humans
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WHMIS site also provides a small amount of information on
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The IARC (CIRC in its French acronym) is an agency of the
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American Conference of Governmental Industrial Hygienists
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American Conference of Governmental Industrial Hygienists
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The FDA is the source for U.S.-related information about
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Regulations, when noteworthy, should not be enumerated.
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Institut national de recherche et de sécurité (France)
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National Institute for Occupational Safety and Health
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Concise International Chemical Assessment Documents
939:Sax's Dangerous Properties of Industrial Materials 925:Sax's Dangerous Properties of Industrial Materials 792:Canadian Centre for Occupational Health and Safety 784:Workplace Hazardous Materials Information System 702:Agency for Toxic Substances and Disease Registry 649:Prevention, Pesticides and Toxic Substances site 891:National Institute of Technology and Evaluation 810:list substances which are regulated under the 708:The ATSDR is a federal agency which publishes 812:Canadian Environmental Protection Act of 1999 586:Occupational Safety and Health Administration 574:European Agency for Safety and Health at Work 563:European Agency for Safety and Health at Work 551:, i.e. in the European market are available. 8: 857:Chemical Classification Information Database 592:The OSHA is the federal agency charged with 1088:Knowledge (XXG) Manual of Style (chemistry) 728:: the most recent available version is the 462:International Agency for Research on Cancer 248:aspire to be a surrogate for MSDS and does 1050:field (label the link as "External MSDS", 828:Australian Safety and Compensation Council 691:Emergency Preparedness & Response site 683:Centers for Disease Control and Prevention 378:International Programme on Chemical Safety 143: 48:Knowledge (XXG):Manual of Style/Chemistry 413:Environmental Health Criteria Monographs 56:Knowledge (XXG)'s policies or guidelines 1057: 849:Environmental Risk Management Authority 824:Hazardous Substances Information System 722:Department of Health and Human Services 720:The National Toxicology Program of the 489:when discussing human carcinogenicity. 455:IPCS/CEC Evaluation of Antidotes Series 384:The IPCS is a joint programme of three 215: 155: 252:provide advice as a matter of policy. 910:(Chemical Risk Information Platform) 7: 1006:Material Safety Data Sheets (MSDSs) 522:Secondary sources (EU and national) 516:International Chemical Safety Cards 504:International Chemical Safety Cards 476:, France. It publishes a series of 386:United Nations specialized agencies 1083:Knowledge (XXG) supplemental pages 880:(click on "Fiches toxicologiques") 863:New Zealand Inventory of Chemicals 440:JECFA Monographs & Evaluations 60:thoroughly vetted by the community 28: 918:Secondary sources (encyclopedias) 621:Pocket Guide to Chemical Hazards 101: 33: 937:Lewis, Richard J., ed. (2004), 837:Department of Health and Ageing 786:(WHMIS), which can be searched 641:Environmental Protection Agency 600:provides several useful links. 372:Secondary sources (UN agencies) 18:Knowledge (XXG):Manual of Style 741:Hazardous Substances Data Bank 653:Acute Exposure Guidance Levels 594:occupational safety and health 449:Poisons Information Monographs 1: 598:Safety and Health Topics site 421:IPCS Health and Safety Guides 367:Sources of safety information 126:in writing a safety section. 1064:An illustrative discussion: 749:National Library of Medicine 660:Food and Drug Administration 1012:Material Safety Data Sheets 978:, Cincinnati, Ohio: ACGIH, 941:(11th ed.), London: Wiley, 833:Chemical Assessment Reports 804:CEPA Environmental Registry 800:"Substance-Specific Issues" 764:Health and Safety Executive 716:National Toxicology Program 602:Permissible Exposure Limits 348:What Knowledge (XXG) is not 1109: 294: 240:The majority of compounds 67: 901:of about 1500 substances 556:European Chemicals Agency 549:European Community number 533:European Chemicals Agency 470:World Health Organization 285:hexafluorophosphoric acid 1054:with the company name). 958:(ACGIH) in establishing 336:WikiProject Pharmacology 119:almost never appropriate 109:This page in a nutshell: 310:Coverage of regulations 133:should be used instead. 960:Threshold Limit Values 954:The monographs of the 710:Toxicological Profiles 726:Report on Carcinogens 434:Pesticide Data Sheets 999:strongly discouraged 724:publishes a regular 790:at the site of the 58:as it has not been 976:2009 TLVs and BEIs 899:GHS classfications 808:Environment Canada 84:WP:Chemical safety 596:regulations. Its 281:cyanide poisoning 238: 237: 196:Structure drawing 142: 141: 131:secondary sources 93: 92: 44:explanatory essay 1100: 1068: 1062: 1049: 987: 950: 913: 904: 879: 826:(HSIS) from the 751:, available via 695:chemical weapons 487:preferred source 345:As indicated by 232: 181:Compound classes 144: 105: 104: 98: 80: 37: 36: 30: 1108: 1107: 1103: 1102: 1101: 1099: 1098: 1097: 1073: 1072: 1071: 1063: 1059: 1047: 1008: 994: 992:Primary sources 985: 970: 948: 936: 920: 911: 902: 887: 877: 871: 845: 820: 780: 760: 674:questions. Its 582: 529: 524: 374: 369: 357: 340:recommendations 332: 312: 299: 293: 273:carbon monoxide 226: 149:Manual of Style 124:primary sources 102: 96: 89: 88: 78:WP:MOSCHEM/SAFE 76: 72: 64: 63: 34: 26: 25: 24: 12: 11: 5: 1106: 1104: 1096: 1095: 1090: 1085: 1075: 1074: 1070: 1069: 1056: 1039:only available 1035: 1034: 1031: 1027: 1007: 1004: 993: 990: 989: 988: 983: 952: 951: 946: 919: 916: 915: 914: 905: 895: 894: 886: 883: 882: 881: 870: 867: 866: 865: 860: 853: 852: 844: 841: 840: 839: 830: 819: 816: 779: 776: 768: 767: 759: 758:United Kingdom 756: 745: 744: 718: 717: 706: 705: 687: 686: 676:EAFUS database 664: 663: 645: 644: 616: 615: 590: 589: 581: 578: 577: 576: 567: 566: 559: 558: 545:CLP Regulation 537: 536: 528: 527:European Union 525: 523: 520: 519: 518: 508: 507: 500: 499: 466: 465: 458: 457: 452: 446: 444:food additives 437: 427: 426: 418: 410: 382: 381: 373: 370: 368: 365: 363: 356: 353: 331: 328: 311: 308: 292: 289: 236: 235: 234: 233: 218: 217: 213: 212: 211: 210: 208:external links 207: 206:References and 203: 198: 193: 188: 183: 178: 173: 168: 166:Article titles 160: 159: 153: 152: 140: 139: 138: 137: 134: 114: 106: 94: 91: 90: 87: 86: 81: 73: 68: 65: 53: 52: 40: 38: 27: 15: 14: 13: 10: 9: 6: 4: 3: 2: 1105: 1094: 1091: 1089: 1086: 1084: 1081: 1080: 1078: 1067: 1061: 1058: 1055: 1053: 1045: 1040: 1032: 1028: 1025: 1021: 1020: 1019: 1017: 1013: 1005: 1003: 1001: 1000: 991: 986: 981: 977: 973: 969: 968: 967: 965: 961: 957: 949: 944: 940: 935: 934: 933: 931: 927: 926: 917: 909: 906: 900: 897: 896: 892: 889: 888: 884: 876: 873: 872: 868: 864: 861: 858: 855: 854: 850: 847: 846: 842: 838: 834: 831: 829: 825: 822: 821: 817: 815: 814:(CEPA 1999). 813: 809: 805: 801: 797: 796:Health Canada 794:(CCOHS). The 793: 789: 785: 777: 775: 773: 765: 762: 761: 757: 755: 754: 750: 742: 739: 738: 737: 735: 731: 727: 723: 715: 714: 713: 711: 703: 700: 699: 698: 696: 692: 684: 681: 680: 679: 677: 673: 669: 661: 658: 657: 656: 654: 650: 642: 639: 638: 637: 635: 631: 628:(see above). 627: 623: 622: 613: 610: 609: 608: 606: 603: 599: 595: 587: 584: 583: 580:United States 579: 575: 572: 571: 570: 564: 561: 560: 557: 554: 553: 552: 550: 546: 542: 534: 531: 530: 526: 521: 517: 514: 513: 512: 505: 502: 501: 498: 497: 492: 491: 490: 488: 483: 479: 475: 471: 463: 460: 459: 456: 453: 450: 447: 445: 441: 438: 435: 432: 431: 430: 425: 422: 419: 417: 414: 411: 409: 406: 403: 402: 401: 399: 395: 391: 387: 379: 376: 375: 371: 366: 364: 361: 354: 352: 350: 349: 343: 341: 337: 329: 327: 323: 321: 317: 309: 307: 303: 298: 290: 288: 286: 282: 278: 274: 270: 266: 262: 257: 255: 251: 247: 243: 230: 225: 222: 221: 220: 219: 214: 209: 204: 202: 199: 197: 194: 192: 189: 187: 184: 182: 179: 177: 174: 172: 169: 167: 164: 163: 162: 161: 158: 154: 151: 150: 146: 145: 135: 132: 129: 125: 121: 120: 115: 112: 111: 110: 107: 100: 99: 85: 82: 79: 75: 74: 71: 66: 61: 57: 50: 49: 45: 39: 32: 31: 23: 19: 1060: 1051: 1048:ExternalMSDS 1043: 1038: 1036: 1023: 1009: 998: 997: 996:Editors are 995: 975: 963: 953: 938: 929: 923: 921: 912:(in English) 908:CHRIP search 903:(in English) 781: 769: 746: 733: 725: 719: 707: 688: 665: 646: 620: 617: 591: 568: 538: 509: 495: 486: 482:carcinogenic 477: 467: 428: 383: 362: 358: 347: 344: 333: 324: 320:WP:NOTMANUAL 313: 304: 300: 258: 253: 249: 245: 241: 239: 191:Nomenclature 147: 118: 117: 108: 41: 1010:Commercial 878:(in French) 843:New Zealand 464:(IARC/CIRC) 355:Regulations 316:WP:NOTGUIDE 42:This is an 1077:Categories 984:188241795X 947:0471476625 734:Monographs 478:Monographs 330:Toxicology 297:WP:NOTNEWS 295:See also: 216:Categories 818:Australia 772:This page 747:From the 732:The IARC 672:cosmetics 565:(EU-OSHA) 472:based in 407:(CICADs) 291:Anecdotes 269:myoglobin 224:Templates 176:Chemicals 171:Chemboxes 157:Chemistry 70:Shortcuts 22:Chemistry 974:(2009), 730:11th ed. 360:topics. 326:topics. 229:citation 128:Reliable 20:‎ | 1026:better. 802:. The 704:(ATSDR) 651:. Its 614:(NIOSH) 604:(PELs) 506:(ICSCs) 423:(HSGs) 415:(EHCs) 277:cyanide 122:to use 1024:always 1016:IUCLID 893:(NITE) 869:France 851:(ERMA) 778:Canada 753:TOXNET 743:(HSDB) 588:(OSHA) 535:(ECHA) 451:(PIMs) 436:(PDSs) 380:(IPCS) 201:Safety 116:It is 46:about 930:Sax's 885:Japan 766:(HSE) 685:(CDC) 662:(FDA) 643:(EPA) 626:ICSCs 541:REACH 494:IARC 242:could 186:InChI 16:< 980:ISBN 943:ISBN 788:here 670:and 668:food 634:here 630:IDLH 543:and 474:Lyon 398:UNEP 322:. 318:and 263:and 261:LD50 1052:not 1044:may 964:not 806:of 480:on 442:on 394:ILO 390:WHO 338:'s 271:by 265:TLV 250:not 246:not 1079:: 1018:. 396:, 392:, 342:. 51:. 388:( 231:) 227:( 62:.

Index

Knowledge (XXG):Manual of Style
Chemistry
explanatory essay
Knowledge (XXG):Manual of Style/Chemistry
Knowledge (XXG)'s policies or guidelines
thoroughly vetted by the community
Shortcuts
WP:MOSCHEM/SAFE
WP:Chemical safety
primary sources
Reliable
secondary sources
Manual of Style
Chemistry
Article titles
Chemboxes
Chemicals
Compound classes
InChI
Nomenclature
Structure drawing
Safety
References and
external links

Templates
citation
LD50
TLV
myoglobin
carbon monoxide
cyanide

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