456:
38:
217:
103:
253:
477:
315:
117:, the condensation process that converts low molecular weight oxides to polymers with M-O-M linkages. Olation often begins with the deprotonation of a metal-hydroxo complex. It is the basis for mineralization and the precipitation of metal oxides. For the oxides of d0 metals, V, Nb, Ta, Mo, and W, the olation process affords
330:
The oxo ligand (or analogous sulfido ligand) is nearly ubiquitous in molybdenum and tungsten chemistry, appearing in the ores containing these elements, throughout their synthetic chemistry, and also in their biological role (aside from nitrogenase). The biologically transported species and starting
443:
Ca centre with several bridging oxo ligands that participate in the oxidation of water to molecular oxygen. The OEC is proposed to utilize a terminal oxo intermediate as a part of the water oxidation reaction. This complex is responsible for the production of nearly all of earth's molecular oxygen.
347:
prosthetic group. The Mo/W centers generally cycle between hexavalent (M(VI)) and tetravalent (M(IV)) states. Although there is some variation among these enzymes, members from all three families involve oxygen atom transfer between the Mo/W center and the substrate. Representative reactions from
492:
3-8) are well known, whereas terminal oxo compounds for metals in the cobalt through zinc triads (Groups 9-12) are rare and invariably feature metals with coordination numbers lower than 6. This trend holds for other metal-ligand multiple bonds. Claimed exceptions to this rule have been retracted.
500:
may appear to be an exception to the oxo-wall rule, but it is not because the complex is non-octahedral. The trigonal symmetry reorders the metal d-orbitals below the degenerate MO π* pair. In three-fold symmetric complexes, multiple MO bonding is allowed for as many as 7 d-electrons.
480:
Qualitative molecular orbital diagram of a d metal-oxo fragment (empty metal d orbitals in an octahedral field on left, full oxygen p orbitals on right). Here it can be seen that d electrons fill a nonbonding orbital and electrons d fill anti-bonding orbitals, which destabilize the
1598:
Cao, Rui; Anderson, Travis M.; Piccoli, Paula M. B.; Schultz, Arthur J.; Koetzle, Thomas F.; Geletii, Yurii V.; Slonkina, Elena; Hedman, Britt; Hodgson, Keith O.; Hardcastle, Kenneth I.; Fang, Xikui (2007-09-01).
1504:
Anderson, Travis M.; Cao, Rui; Slonkina, Elena; Hedman, Britt; Hodgson, Keith O.; Hardcastle, Kenneth I.; Neiwert, Wade A.; Wu, Shaoxiong; Kirk, Martin L.; Knottenbelt, Sushilla; Depperman, Ezra C. (2005-08-01).
1405:
Anderson, Travis M.; Neiwert, Wade A.; Kirk, Martin L.; Piccoli, Paula M. B.; Schultz, Arthur J.; Koetzle, Thomas F.; Musaev, Djamaladdin G.; Morokuma, Keiji; Cao, Rui; Hill, Craig L. (2004-12-17).
305:(MMO) oxidizes methane to methanol via oxygen atom transfer from an iron-oxo intermediate at its non-heme diiron center. Much effort is aimed at reproducing reactions with synthetic catalysts.
485:
The term "oxo wall" is a theory used to describe the fact that no terminal oxo complexes are known for metal centers with octahedral symmetry and d-electron counts beyond 5.
2271:
2308:
504:
Terminal oxo ligands are also rather rare for the titanium triad, especially zirconium and hafnium and are unknown for group 3 metals (scandium, yttrium, and lanthanum).
1812:
326:
ligands attached to molybdenum. They are omitted from the figure for simplicity. The rest of the heterocycle is similar to what is shown for the other two cofactors.
2158:
1194:"Molybdenum and Vanadium Do not Replace Tungsten in the Catalytically Active Forms of the Three Tungstoenzymes in the Hyperthermophilic Archaeon Pyrococcus furiosus"
2338:
1781:
2375:
141:. Some metal-oxos are capable of transferring their oxo ligand to organic substrates. One such example of this type of reactivity is from the enzyme superfamily
109:, one of many polyoxometallate salts. The structure illustrates terminal oxo, doubly-bridging oxo, triply bridging oxo, and six-fold bridging oxo ligands.
2394:
271:
1370:
Larson, Virginia A.; Battistella, Beatrice; Ray, Kallol; Lehnert, Nicolai; Nam, Wonwoo (2020). "Iron and manganese oxo complexes, oxo wall and beyond".
2465:
2189:
1655:
1563:
455:
419:
The three different classes of molybdenum cofactors are shown in the adjacent figure. The biological use of tungsten mirrors that of molybdenum.
2330:
2138:
2009:
1354:
2444:
2295:
2216:
2163:
1805:
2181:
2133:
1757:
207:(PDC). Metal oxo species are capable of catalytic, including asymmetric oxidations of various types. Some metal-oxo complexes promote
2456:
2411:
2367:
2351:
2153:
2120:
2110:
1997:
648:
Meunier, Bernard; de Visser, Samuël P.; Shaik, Sason (2004). "Mechanism of
Oxidation Reactions Catalyzed by Cytochrome P450 Enzymes".
404:
1690:
O’Halloran, Kevin P.; Zhao, Chongchao; Ando, Nicole S.; Schultz, Arthur J.; Koetzle, Thomas F.; Piccoli, Paula M. B.; Hedman, Britt;
948:"Epoxidation of olefins by cytochrome P450: Evidence from site-specific mutagenesis for hydroperoxo-iron as an electrophilic oxidant"
2497:
2406:
2263:
2062:
1248:
2533:
2359:
2322:
2317:
2283:
2125:
2074:
2039:
2022:
2014:
1950:
1890:
2168:
1941:
1929:
1900:
1895:
1798:
766:; Hussain-Bates, Bilquis; Hursthouse, Michael B. (1993). "Synthesis and X-ray Crystal Structure of Oxotrimesityl-Iridium(V)".
61:. Formally O, an oxo ligand can be bound to one or more metal centers, i.e. it can exist as a terminal or (most commonly) as
2244:
2148:
2102:
1985:
1905:
1859:
1469:
1005:
Farinas, Edgardo T; Alcalde, Miguel; Arnold, Frances (2004). "Alkene epoxidation catalyzed by cytochrome P450 BM-3 139-3".
1917:
1696:
1085:
1694:; et al. (2012). "Revisiting the Polyoxometalate-Based Late-Transition-Metal-Oxo Complexes: The "Oxo Wall" Stands".
1508:"A Palladium-Oxo Complex. Stabilization of This Proposed Catalytic Intermediate by an Encapsulating Polytungstate Ligand"
2436:
1972:
319:
513:
1081:"Synthetic Iron-Oxo 'Diamond Core' Mimics Structure of Key IIntermediate in Methane Monooxygenase Catalytic Cycle"
693:
200:
149:
142:
2420:
1980:
1835:
846:
Hausinger, R. P. (January–February 2004). "Fe(II)/α-Ketoglutarate-Dependent
Hydroxylases and Related Enzymes".
256:
1732:
691:
Du, G.; Abu-Omar, M. M. (2008). "Oxo and Imido
Complexes of Rhenium and Molybdenum in Catalytic Reductions".
73:
and in many iron-containing enzymes. One of the earliest synthetic compounds to incorporate an oxo ligand is
2208:
1326:
428:
296:
2303:
2115:
1044:; Spangler, Dale; Loew, Gilda (1985). "Cytochrome P450 mediated aromatic oxidation: a theoretical study".
489:
177:
2143:
302:
204:
168:
contains a high-valent iron-oxo which is capable of abstracting hydrogen atoms from strong C–H bonds.
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1821:
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959:
768:
54:
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318:
Three structural families of molybdenum cofactors: a) xanthine oxidase, b) sulfite oxidase, and c)
208:
193:
130:
70:
37:
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199:
and alcohols to ketones or carboxylic acids. More selective or gentler oxidizing reagents include
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1572:
1486:
1478:
1442:
1387:
1295:
1174:
871:
763:
563:
Nugent, W. A., Mayer, J. M. "Metal-Ligand
Multiple Bonds." John Wiley & Sons, New York, 1988.
382:
299:, insert ferryl oxygen into saturated C–H bonds, epoxidize olefins, and oxidize aromatic groups.
263:
enzymes for oxidation of aliphatic groups to alcohols by the action of
Compound I (adapted from
1139:
Schwarz, G.; Mendel, R. R.; Ribbe, M. W. (2009). "Molybdenum
Cofactors, Enzymes and Pathways".
1775:
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967:
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902:
855:
818:
808:
797:"Beyond Ferryl‑Mediated Hydroxylation: 40 Years of the rebound mechanism and C–H activation"
777:
733:
702:
657:
630:
586:
538:
394:
221:
185:
118:
1407:"A Late-Transition Metal Oxo Complex: K7Na9[O=PtIV(H2O)L2], L = [PW9O34]9-"
1338:
523:
352:
289:
260:
229:
176:
Some of the longest known and most widely used oxo compounds are oxidizing agents such as
165:
66:
62:
42:
65:. Oxo ligands stabilize high oxidation states of a metal. They are also found in several
1267:
1154:
1097:
963:
2253:
1967:
1318:
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1080:
923:
890:
823:
796:
432:
370:
164:
Transition metal-oxo's are also capable of abstracting strong C–H, N–H, and O–H bonds.
1406:
1221:
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1962:
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31:
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449:
445:
225:
138:
106:
102:
1211:
723:
Gunay, A.; Theopold, K. H. (2010). "C-H Bond
Activations by Metal Oxo Compounds".
467:
Ca core of the oxygen evolving complex of
Photosystem II at a resolution of 1.9 Å.
17:
2027:
476:
340:
216:
706:
1383:
1249:"Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å"
1018:
859:
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252:
1661:. If this is an intentional citation to a retracted paper, please replace
1569:. If this is an intentional citation to a retracted paper, please replace
1475:. If this is an intentional citation to a retracted paper, please replace
1247:
Umena, Yasufumi; Kawakami, Keisuke; Shen, Jian-Ren; Kamiya, Nobuo (2011).
1230:
991:
314:
1790:
1346:
1275:
1162:
1057:
634:
267:
Iron(IV)-oxo compounds are intermediates in many biological oxidations:
152:, metal oxo complexes are intermediates in the conversion of water to O
114:
1709:
1643:
1616:
1551:
1524:
906:
737:
661:
590:
192:). Compounds such as these are widely used for converting alkenes to
620:
Holm, R. H. (1987). "Metal-centered oxygen atom transfer reactions".
133:. Oxygen-atom transfer is common reaction of particular interest in
1600:
1507:
574:
331:
point for biosynthesis is generally accepted to be oxometallates MoO
518:
475:
454:
313:
251:
215:
101:
36:
293:
196:
1794:
1335:
Molecular
Electronic Structures of Transition Metal Complexes I
575:"A Novel Oxidizing Reagent Based on Potassium Ferrate(VI)1"
30:"Oxide complex" redirects here. Not to be confused with
286:, that hydroxylate a variety of hydrocarbon substrates.
1325:(2012). "Electronic Structures of Oxo-Metal Ions". In
891:"Hydrocarbon Hydroxylation by Cytochrome P450 Enzymes"
113:
A common reaction exhibited by metal-oxo compounds is
1758:"Oxo wall still stands as inorganic papers retracted"
1313:
1311:
1309:
228:(d), (d), simplified view of compound I (a state of
1242:
1240:
488:
Oxo compounds for the vanadium through iron triads (
2477:
2387:
2228:
2201:
2087:
2055:
1883:
1852:
1828:
1506:
220:Selection of molecular metal oxides. From left,
952:Proceedings of the National Academy of Sciences
573:Delaude, Lionel; Laszlo, Pierre (1996-01-01).
129:Metal oxo complexes are intermediates in many
1806:
27:Coordination complex containing an oxo ligand
8:
1756:Hadlington2012-06-14T00:00:00+01:00, Simon.
1780:: CS1 maint: numeric names: authors list (
559:
557:
555:
553:
121:, a large class of molecular metal oxides.
1813:
1799:
1791:
1675:|...|intentional=yes}}
1583:|...|intentional=yes}}
1489:|...|intentional=yes}}
718:
716:
348:each of the three structural classes are:
272:Alpha-ketoglutarate-dependent hydroxylases
1220:
1210:
1115:
1105:
981:
971:
922:
822:
812:
1605:Journal of the American Chemical Society
1513:Journal of the American Chemical Society
1337:. Structure and Bonding. Vol. 142.
1046:Journal of the American Chemical Society
795:Huang, Xiongyi; Groves, John T. (2017).
757:
755:
549:
211:, converting hydrocarbons to alcohols.
1773:
496:The iridium oxo complex Ir(O)(mesityl)
889:Ortiz de Montellano, Paul R. (2010).
7:
1731:Ritter, Stephen K. (June 12, 2012).
1192:Mukund, S.; Adams, M. W. W. (1996).
1040:Korzekwa, Kenneth; Trager, William;
282:, generating Fe(IV)=O centers, i.e.
322:. The DMSO reductase features two
131:metal-catalyzed oxidation reactions
405:Aldehyde ferredoxin oxidoreductase
339:. All Mo/W enzymes, again except
224:(d), a tungsten oxo carbonyl (d),
25:
459:X-ray Crystal structure of the Mn
579:The Journal of Organic Chemistry
278:by oxidative decarboxylation of
85:), which was likely prepared by
310:Molybdenum/tungsten oxo species
98:Olation and acid-base reactions
1458:10.1126/science.337.6092.290-a
1:
1601:"Terminal Gold-Oxo Complexes"
1212:10.1128/jb.178.1.163-167.1996
1086:Proc. Natl. Acad. Sci. U.S.A.
848:Crit. Rev. Biochem. Mol. Biol
782:10.1016/S0277-5387(00)81474-6
448:is necessary for much of the
1733:"Metal-Oxo Papers Retracted"
51:transition metal oxo complex
1333:; Dahl, Jens Peder (eds.).
343:, are bound to one or more
45:and b) terminal oxo ligands
2550:
946:Coon, M. J. (1998-01-20).
762:Hay-Motherwell, Robyn S.;
707:10.2174/138527208785740238
514:Metal-ligand multiple bond
29:
1384:10.1038/s41570-020-0197-9
1019:10.1016/j.tet.2003.10.099
860:10.1080/10409230490440541
814:10.1007/s00775-016-1414-3
694:Current Organic Chemistry
201:pyridinium chlorochromate
160:Hydrogen-atom abstraction
150:water oxidation catalysis
143:molybdenum oxotransferase
1372:Nature Reviews Chemistry
1327:Mingos, David Michael P.
427:The active site for the
257:Oxygen rebound mechanism
232:, d), and Ir(O)(mesityl)
2534:Transition metal oxides
1423:10.1126/science.1104696
1107:10.1073/pnas.0710734105
429:oxygen-evolving complex
423:Oxygen-evolving complex
1822:Coordination complexes
1079:Brunold, T.C. (2007).
973:10.1073/pnas.95.7.3555
482:
468:
327:
264:
237:
178:potassium permanganate
110:
46:
1667:|...}}
1638:(Retracted, see
1575:|...}}
1546:(Retracted, see
1481:|...}}
1452:(Retracted, see
479:
458:
444:This key link in the
317:
303:Methane monooxygenase
255:
219:
205:pyridinium dichromate
105:
40:
248:Iron(IV)-oxo species
125:Oxygen-atom transfer
71:molybdenum cofactors
55:coordination complex
1697:Inorganic Chemistry
1611:(36): 11118–11133.
1519:(34): 11948–11949.
1417:(5704): 2074–2077.
1347:10.1007/430_2011_55
1276:10.1038/nature09913
1268:2011Natur.473...55U
1163:10.1038/nature08302
1155:2009Natur.460..839S
1098:2007PNAS..10420641B
1092:(52): 20641–20642.
1058:10.1021/ja00300a033
964:1998PNAS...95.3555V
764:Wilkinson, Geoffrey
635:10.1021/cr00082a005
209:C-H bond activation
107:Sodium decavanadate
1341:. pp. 17–28.
483:
469:
452:present on earth.
328:
265:
238:
111:
47:
2516:
2515:
1710:10.1021/ic2008914
1704:(13): 7025–7031.
1692:Hodgson, Keith O.
1644:10.1021/ja207909y
1617:10.1021/ja072456n
1552:10.1021/ja207910h
1525:10.1021/ja054131h
1356:978-3-642-27369-8
1149:(7257): 839–847.
1052:(14): 4273–4279.
1042:Gouterman, Martin
907:10.1021/cr9002193
801:J Biol Inorg Chem
776:(16): 2009–2012.
738:10.1021/cr900269x
701:(14): 1185–1198.
662:10.1021/cr020443g
591:10.1021/jo960633p
585:(18): 6360–6370.
385:) + 2 H + 2 e → H
135:organic chemistry
119:polyoxometallates
75:potassium ferrate
69:, for example in
18:Metal oxo complex
16:(Redirected from
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650:Chemical Reviews
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539:Dioxygen complex
320:(DMSO) reductase
222:vanadyl chloride
186:osmium tetroxide
172:Molecular oxides
63:bridging ligands
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290:Cytochrome P450
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230:cytochrome P450
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2320:
2315:
2310:
2306:
2301:
2297:
2293:
2289:
2285:
2281:
2277:
2273:
2269:
2265:
2261:
2256:
2251:
2246:
2242:
2237:
2232:
2230:
2226:
2225:
2223:
2222:
2218:
2214:
2210:
2205:
2203:
2199:
2198:
2196:
2195:
2187:
2183:
2179:
2174:
2170:
2166:
2161:
2156:
2151:
2146:
2141:
2136:
2131:
2127:
2123:
2118:
2113:
2108:
2104:
2100:
2096:
2091:
2089:
2085:
2084:
2082:
2081:
2076:
2072:
2068:
2064:
2059:
2057:
2053:
2052:
2050:
2049:
2045:
2041:
2037:
2033:
2029:
2025:
2020:
2016:
2012:
2007:
2003:
1999:
1995:
1991:
1987:
1983:
1978:
1974:
1970:
1965:
1960:
1956:
1952:
1948:
1943:
1939:
1935:
1931:
1927:
1923:
1919:
1915:
1911:
1907:
1903:
1898:
1893:
1887:
1885:
1881:
1880:
1878:
1877:
1873:
1869:
1865:
1861:
1856:
1854:
1850:
1849:
1847:
1846:
1842:
1838:
1832:
1830:
1826:
1825:
1820:
1818:
1817:
1810:
1803:
1795:
1788:
1787:
1748:
1723:
1682:
1590:
1496:
1397:
1378:(8): 404–419.
1362:
1355:
1323:Gray, Harry B.
1305:
1236:
1205:(1): 163–167.
1184:
1131:
1071:
1032:
1013:(3): 525–528.
997:
958:(7): 3555–60.
938:
901:(2): 932–948.
881:
838:
787:
751:
712:
683:
640:
612:
565:
548:
546:
543:
542:
541:
536:
531:
526:
521:
516:
509:
506:
497:
473:
472:The "oxo wall"
470:
464:
460:
440:
436:
435:(PSII) is a Mn
433:photosystem II
424:
421:
417:
416:
412:
408:
402:
398:
390:
386:
378:
374:
371:DMSO reductase
368:
364:
360:
356:
336:
332:
311:
308:
307:
306:
300:
287:
275:
249:
246:
244:
243:Metalloenzymes
241:
240:
239:
233:
189:
181:
173:
170:
161:
158:
153:
126:
123:
99:
96:
94:
91:
87:Georg E. Stahl
82:
78:
57:containing an
26:
24:
14:
13:
10:
9:
6:
4:
3:
2:
2546:
2535:
2532:
2530:
2527:
2526:
2524:
2509:
2506:
2504:
2501:
2499:
2496:
2494:
2488:
2486:
2483:
2482:
2480:
2476:
2470:
2469:
2464:
2462:
2455:
2453:
2443:
2441:
2435:
2433:
2419:
2417:
2410:
2408:
2405:
2403:
2393:
2392:
2390:
2386:
2380:
2374:
2372:
2366:
2364:
2358:
2356:
2350:
2348:
2337:
2335:
2329:
2327:
2321:
2319:
2316:
2314:
2307:
2305:
2302:
2300:
2294:
2292:
2282:
2280:
2270:
2268:
2262:
2260:
2257:
2255:
2252:
2250:
2243:
2241:
2234:
2233:
2231:
2227:
2221:
2215:
2213:
2207:
2206:
2204:
2200:
2194:
2192:
2188:
2186:
2180:
2178:
2167:
2165:
2162:
2160:
2157:
2155:
2152:
2150:
2147:
2145:
2142:
2140:
2137:
2135:
2132:
2130:
2124:
2122:
2119:
2117:
2114:
2112:
2109:
2107:
2101:
2099:
2093:
2092:
2090:
2086:
2080:
2073:
2071:
2061:
2060:
2058:
2054:
2048:
2038:
2036:
2026:
2024:
2021:
2019:
2013:
2011:
2008:
2006:
1996:
1994:
1984:
1982:
1979:
1977:
1971:
1969:
1966:
1964:
1961:
1959:
1949:
1947:
1940:
1938:
1928:
1926:
1916:
1914:
1904:
1902:
1899:
1897:
1894:
1892:
1889:
1888:
1886:
1882:
1876:
1866:
1864:
1858:
1857:
1855:
1851:
1845:
1839:
1837:
1834:
1833:
1831:
1827:
1823:
1816:
1811:
1809:
1804:
1802:
1797:
1796:
1793:
1783:
1777:
1763:
1759:
1752:
1749:
1738:
1734:
1727:
1724:
1719:
1715:
1711:
1707:
1703:
1699:
1698:
1693:
1686:
1683:
1674:
1666:
1659:
1658:
1653:
1649:
1645:
1641:
1634:
1630:
1626:
1622:
1618:
1614:
1610:
1606:
1602:
1594:
1591:
1582:
1574:
1567:
1566:
1561:
1557:
1553:
1549:
1542:
1538:
1534:
1530:
1526:
1522:
1518:
1514:
1509:
1500:
1497:
1488:
1480:
1473:
1472:
1467:
1463:
1459:
1455:
1448:
1444:
1440:
1436:
1432:
1428:
1424:
1420:
1416:
1412:
1408:
1401:
1398:
1393:
1389:
1385:
1381:
1377:
1373:
1366:
1363:
1358:
1352:
1348:
1344:
1340:
1336:
1332:
1328:
1324:
1320:
1314:
1312:
1310:
1306:
1301:
1297:
1293:
1289:
1285:
1281:
1277:
1273:
1269:
1265:
1261:
1257:
1250:
1243:
1241:
1237:
1232:
1228:
1223:
1218:
1213:
1208:
1204:
1201:
1200:
1199:J. Bacteriol.
1195:
1188:
1185:
1180:
1176:
1172:
1168:
1164:
1160:
1156:
1152:
1148:
1144:
1143:
1135:
1132:
1127:
1123:
1118:
1113:
1108:
1103:
1099:
1095:
1091:
1088:
1087:
1082:
1075:
1072:
1067:
1063:
1059:
1055:
1051:
1047:
1043:
1036:
1033:
1028:
1024:
1020:
1016:
1012:
1008:
1001:
998:
993:
989:
984:
979:
974:
969:
965:
961:
957:
953:
949:
942:
939:
934:
930:
925:
920:
916:
912:
908:
904:
900:
896:
892:
885:
882:
877:
873:
869:
865:
861:
857:
853:
849:
842:
839:
834:
830:
825:
820:
815:
810:
806:
802:
798:
791:
788:
783:
779:
775:
771:
770:
765:
758:
756:
752:
747:
743:
739:
735:
731:
728:
727:
719:
717:
713:
708:
704:
700:
696:
695:
687:
684:
679:
675:
671:
667:
663:
659:
655:
651:
644:
641:
636:
632:
628:
625:
624:
616:
613:
608:
604:
600:
596:
592:
588:
584:
580:
576:
569:
566:
560:
558:
556:
554:
550:
544:
540:
537:
535:
532:
530:
527:
525:
522:
520:
517:
515:
512:
511:
507:
505:
502:
494:
491:
486:
478:
471:
457:
453:
451:
447:
434:
430:
422:
420:
415:H + 2 H + 2 e
406:
403:
396:
384:
372:
369:
354:
351:
350:
349:
346:
345:molybdopterin
342:
325:
324:molybdopterin
321:
316:
309:
304:
301:
298:
295:
291:
288:
285:
281:
280:ketoglutarate
273:
270:
269:
268:
262:
258:
254:
247:
242:
231:
227:
223:
218:
214:
213:
212:
210:
206:
202:
198:
195:
187:
179:
171:
169:
167:
159:
157:
151:
146:
144:
140:
136:
132:
124:
122:
120:
116:
108:
104:
97:
92:
90:
88:
76:
72:
68:
64:
60:
56:
52:
44:
39:
33:
32:complex oxide
19:
2467:
2258:
2190:
1765:. Retrieved
1761:
1751:
1740:. Retrieved
1736:
1726:
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649:
643:
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615:
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503:
495:
487:
484:
450:biodiversity
446:oxygen cycle
426:
418:
329:
283:
266:
226:permanganate
175:
163:
147:
139:biochemistry
128:
112:
58:
50:
48:
1737:cen.acs.org
1007:Tetrahedron
407:: R–CHO + H
367:+ 2 H + 2 e
341:nitrogenase
2523:Categories
2139:amino acid
2056:Si donors:
1767:2021-05-15
1742:2021-05-15
1331:Day, Peter
769:Polyhedron
726:Chem. Rev.
623:Chem. Rev.
545:References
274:activate O
203:(PCC) and
93:Reactivity
59:oxo ligand
41:a) Doubly
2388:S donors:
2229:O donors:
2202:P donors:
2164:porphyrin
2111:imidazole
2088:N donors:
1884:C donors:
1853:B donors:
1829:H donors:
1673:retracted
1665:retracted
1625:0002-7863
1581:retracted
1573:retracted
1533:0002-7863
1487:retracted
1479:retracted
1431:0036-8075
1392:220295993
1300:205224374
1284:0028-0836
1179:205217953
1066:0002-7863
1027:0040-4020
915:0009-2665
670:0009-2665
599:0022-3263
534:Oxophilic
529:Metallate
431:(OEC) of
377:C–S(O)–CH
89:in 1702.
1776:cite web
1718:22694272
1652:22873776
1633:17711276
1560:22873777
1541:16117527
1466:22822129
1447:41123922
1439:15564312
1292:21499260
1171:19675644
1126:18093936
933:19769330
876:85784668
868:15121720
833:27909920
746:20143877
678:15352783
607:11667478
508:See also
481:complex.
411:O → R–CO
297:cofactor
259:used by
43:bridging
2529:Ligands
2002:& C
1411:Science
1264:Bibcode
1231:8550411
1151:Bibcode
1117:2409203
1094:Bibcode
992:9520404
960:Bibcode
924:2820140
824:5350257
194:vicinal
115:olation
1910:＝CH-CH
1716:
1650:
1646:,
1631:
1623:
1558:
1554:,
1539:
1531:
1464:
1460:,
1445:
1437:
1429:
1390:
1353:
1298:
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1282:
1256:Nature
1229:
1222:177634
1219:
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1169:
1142:Nature
1124:
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990:
980:
931:
921:
913:
874:
866:
831:
821:
744:
676:
668:
605:
597:
490:Groups
389:C–S–CH
363:O → SO
284:ferryl
184:) and
1901:HC(O)
1896:RC(O)
1669:with
1577:with
1483:with
1443:S2CID
1388:S2CID
1296:S2CID
1252:(PDF)
1175:S2CID
983:19874
872:S2CID
519:Oxide
397:) + H
335:or WO
197:diols
180:(KMnO
53:is a
2304:acac
2276:/HCO
2159:bipy
1918:C(CH
1782:link
1714:PMID
1648:PMID
1629:PMID
1621:ISSN
1556:PMID
1537:PMID
1529:ISSN
1462:PMID
1435:PMID
1427:ISSN
1351:ISBN
1288:PMID
1280:ISSN
1227:PMID
1167:PMID
1122:PMID
1062:ISSN
1023:ISSN
988:PMID
929:PMID
911:ISSN
864:PMID
829:PMID
742:PMID
674:PMID
666:ISSN
603:PMID
595:ISSN
383:DMSO
355:: SO
294:heme
236:(d).
188:(OsO
137:and
2399:NCS
2376:OPR
2352:OSR
2331:ClO
2318:ONO
2296:RCO
2173:Si)
2169:(Me
2154:RCN
2121:RNO
2069:4−n
2067:SiR
2023:≡CR
2015:=CR
2010:RNC
1934:＝CH
1706:doi
1640:doi
1613:doi
1609:129
1548:doi
1521:doi
1517:127
1454:doi
1419:doi
1415:306
1380:doi
1343:doi
1272:doi
1260:473
1217:PMC
1207:doi
1203:178
1159:doi
1147:460
1112:PMC
1102:doi
1090:104
1054:doi
1050:107
1015:doi
978:PMC
968:doi
919:PMC
903:doi
899:110
856:doi
819:PMC
809:doi
778:doi
734:doi
730:110
703:doi
658:doi
654:104
631:doi
587:doi
395:DMS
373:: H
359:+ H
148:In
81:FeO
2525::
2503:Br
2498:Cl
2466:NC
2457:SR
2437:SO
2407:RS
2368:PO
2360:SO
2347:NO
2323:NO
2313:CO
2272:CO
2254:RO
2217:PR
2209:PR
2193:CS
2149:RN
2134:py
2126:NO
2116:NO
2095:NH
2079:Si
2004:70
2000:60
1973:CO
1968:CO
1963:CN
1942:RC
1930:CH
1906:CH
1860:BR
1778:}}
1774:{{
1760:.
1735:.
1712:.
1702:51
1700:.
1627:.
1619:.
1607:.
1603:.
1535:.
1527:.
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1511:.
1441:.
1433:.
1425:.
1413:.
1409:.
1386:.
1374:.
1349:.
1329:;
1321:;
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1294:.
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1239:^
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1145:.
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1100:.
1083:.
1060:.
1048:.
1021:.
1011:60
1009:.
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976:.
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956:95
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950:.
927:.
917:.
909:.
897:.
893:.
870:.
862:.
852:39
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827:.
817:.
805:22
803:.
799:.
774:12
772:.
754:^
740:.
715:^
699:12
697:.
672:.
664:.
652:.
627:87
601:.
593:.
583:61
581:.
577:.
552:^
156:.
145:.
77:(K
49:A
2508:I
2492:2
2490:F
2485:F
2468:S
2461:O
2459:2
2451:3
2449:O
2447:2
2445:S
2439:2
2431:2
2429:S
2427:2
2425:C
2423:2
2421:R
2416:S
2414:2
2412:R
2401:2
2397:2
2395:R
2378:3
2370:4
2362:4
2354:2
2345:5
2343:H
2341:5
2339:C
2333:4
2325:3
2311:2
2309:R
2298:2
2290:4
2288:O
2286:2
2284:C
2278:3
2274:3
2266:2
2264:O
2259:O
2249:O
2247:2
2245:R
2240:O
2238:2
2236:H
2219:2
2211:3
2191:N
2184:2
2182:N
2177:N
2175:2
2171:3
2144:N
2128:2
2105:3
2103:N
2097:3
2077:3
2075:R
2065:n
2063:H
2046:7
2044:H
2042:9
2040:C
2034:5
2032:H
2030:5
2028:C
2017:2
1998:C
1992:6
1990:R
1988:6
1986:C
1981:C
1975:2
1957:4
1955:H
1953:6
1951:C
1946:R
1944:2
1936:2
1932:2
1924:3
1922:)
1920:2
1912:2
1908:2
1891:R
1874:n
1872:H
1870:m
1868:B
1862:2
1843:2
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1836:H
1814:e
1807:t
1800:v
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1770:.
1745:.
1720:.
1708::
1679:)
1677:.
1642::
1635:.
1615::
1587:)
1585:.
1550::
1543:.
1523::
1493:)
1491:.
1456::
1449:.
1421::
1394:.
1382::
1376:4
1359:.
1345::
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1274::
1266::
1233:.
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1181:.
1161::
1153::
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1104::
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1056::
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1017::
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970::
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780::
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736::
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705::
680:.
660::
637:.
633::
609:.
589::
498:3
465:5
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441:5
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409:2
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393:(
391:3
387:3
381:(
379:3
375:3
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361:2
357:3
337:4
333:4
276:2
234:3
190:4
182:4
154:2
83:4
79:2
34:.
20:)
Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.
