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are no longer truly uncorrelated. By asserting that it was acceptable to ignore these correlations in the population at times after the initial time, Boltzmann had introduced an element of time asymmetry through the formalism of his calculation.
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is usually understood as a physically grounded hypothesis, it was recently highlighted that it could also be interpreted as a heuristic hypothesis. This interpretation allows using the
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248:"Illustrations of the dynamical theory of gases. Part II. On the process of diffusion of two or more kinds of moving particles among one another,"
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Gyenis, Balazs (2017). "Maxwell and the normal distribution: A colored story of probability, independence, and tendency towards equilibrium".
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Brown, Harvey R.; Myrvold, Wayne (2008-09-08). "Boltzmann's H-theorem, its limitations, and the birth of (fully) statistical mechanics".
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The assumption of molecular chaos is the key ingredient that allows proceeding from the
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Boltzmann, L. (2003). "Further
Studies on the Thermal Equilibrium of Gas Molecules".
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333:. History of Modern Physical Sciences. Vol. 1. pp. 262–349.
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Conceptual Foundations of the Statistical Approach in Mechanics
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Weitere
Studien über das Wärmegleichgewicht unter Gasmolekülen
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Maxwell, J. C. (1867). "On the
Dynamical Theory of Gases".
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Chliamovitch, G.; Malaspinas, O.; Chopard, B. (2017).
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Studies in
History and Philosophy of Modern Physics
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51:and probability for finding another velocity
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147:Ehrenfest, Paul; Ehrenfest, Tatiana (2002).
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