63:
669:
54:. A novel aspect of the method is the ability to determine the 3D-trajectory of iron atoms within vibrational modes, providing a unique appraisal of DFT-prediction accuracy. Other names for this method include nuclear inelastic scattering (NIS), nuclear inelastic absorption (NIA), nuclear resonant inelastic x-ray scattering (NRIXS), and phonon assisted Mössbauer effect.
681:
70:
In the experimental setup, X-rays are released from the particle beam by an undulator; a high-resolution monochromator produces a beam with small energy dispersion (typically 1.0 meV). The sample is irradiated with photons chosen around the resonance of the Mössbauer isotope and further information
42:, most commonly iron. The method exploits the high resolution offered by synchrotron light sources, which enables the resolution of vibrational fine structure, especially those vibrations that are coupled to the position of the Fe centre(s). The method is popularly applied to problems in
79:. The resulting raw spectrum contains a high-intensity resonance that corresponds to the nuclear excited state of the probed nucleus. For bulk samples, the technique detects natural abundance Fe. For many dilute or biological samples, the sample is often enriched in Fe.
104:
Alp, E. E.; Sturhahn, W.; Toellner, T. S.; Zhao, J.; Hu, M.; Brown, D. E., "Vibrational
Dynamics Studies by Nuclear Resonant Inelastic X-Ray Scattering," in Mössbauer Spectroscopy, P. Gütlich, B. W. Fitzsimmons, R. Rüffer and H. Spiering, Eds. 2003, Springer Netherlands.
137:
J. W. Pavlik, A. Barabanschikov, A. G. Oliver, E. E. Alp, W. Sturhahn, J. Zhao, J. T. Sage, W. R. Scheidt, "Probing
Vibrational Anisotropy with Nuclear Resonance Vibrational Spectroscopy" , Angew. Chem. Int. Ed. 2010, volume 49, pp. 4400-4404.
71:
is provided for the specific isotope. Typical parameters for the experimental scan are –20 meV below recoil-free resonance energy to +100 meV above it. The number of scans (often recorded for 5 seconds every 0.2 meV) depends on the amount of
95:
E. E. Alp, W. Sturhahn, T. S. Toellner, J. Zhoa, M.Hu, D. E. Brown. "Vibrational
Dynamics Studies by Nuclear Resonant Inelastic X-Ray Scattering" Hyperfine Interactions 144/145: 3–20, 2002.
75:-active nuclei in the sample. The number of photons absorbed by the sample at any wavelength are measured by detecting the fluorescence emitted from the excited atom with an avalanche
500:
173:
391:
324:
269:
238:
606:
424:
286:
555:
374:
218:
495:
297:
198:
441:
419:
166:
17:
507:
429:
259:
364:
309:
121:
W. R. Scheidt, S. M. Durbin, J. T. Sage, "Nuclear resonance vibrational spectroscopy – NRVS", J. Inorg. Biochem. 2005, vol. 99, 60-71.
707:
591:
343:
159:
596:
414:
611:
581:
512:
446:
712:
540:
331:
228:
338:
243:
472:
319:
208:
628:
467:
436:
369:
618:
560:
409:
281:
644:
623:
386:
264:
39:
685:
517:
213:
62:
304:
43:
673:
545:
276:
190:
601:
314:
223:
72:
31:
649:
586:
565:
381:
359:
292:
203:
550:
477:
451:
47:
139:
122:
106:
76:
66:
Schematic of a synchrotron, which provides the incident X-ray beams for this technique.
701:
126:
182:
16:"NRVS" redirects here. For the advocacy group in New South Wales, Australia, see
110:
27:
51:
143:
61:
155:
151:
38:, is specific for samples that contain nuclei that respond to
637:
574:
533:
526:
488:
460:
402:
352:
252:
189:
167:
8:
239:Vibrational spectroscopy of linear molecules
530:
234:Nuclear resonance vibrational spectroscopy
174:
160:
152:
24:Nuclear resonance vibrational spectroscopy
607:Inelastic electron tunneling spectroscopy
287:Resonance-enhanced multiphoton ionization
375:Extended X-ray absorption fine structure
88:
18:Northern Rivers Vaccination Supporters
7:
680:
14:
592:Deep-level transient spectroscopy
344:Saturated absorption spectroscopy
679:
668:
667:
597:Dual-polarization interferometry
612:Scanning tunneling spectroscopy
587:Circular dichroism spectroscopy
582:Acoustic resonance spectroscopy
127:10.1016/j.jinorgbio.2004.11.004
34:. The technique, often called
541:Fourier-transform spectroscopy
229:Vibrational circular dichroism
1:
339:Cavity ring-down spectroscopy
244:Thermal infrared spectroscopy
30:-based technique that probes
473:Inelastic neutron scattering
534:Data collection, processing
410:Photoelectron/photoemission
111:10.1007/978-94-010-0045-1_1
729:
619:Photoacoustic spectroscopy
561:Time-resolved spectroscopy
15:
663:
645:Astronomical spectroscopy
624:Photothermal spectroscopy
32:vibrational energy levels
708:Vibrational spectroscopy
629:Pump–probe spectroscopy
518:Ferromagnetic resonance
310:Laser-induced breakdown
325:Glow-discharge optical
305:Raman optical activity
219:Rotational–vibrational
144:10.1002/anie.201000928
67:
44:bioinorganic chemistry
40:Mössbauer spectroscopy
713:Scientific techniques
546:Hyperspectral imaging
65:
298:Coherent anti-Stokes
253:UV–Vis–NIR "Optical"
602:Hadron spectroscopy
392:Conversion electron
353:X-ray and Gamma ray
260:Ultraviolet–visible
77:photodiode detector
58:Experimental set-up
650:Force spectroscopy
575:Measured phenomena
566:Video spectroscopy
270:Cold vapour atomic
68:
695:
694:
659:
658:
551:Spectrophotometry
478:Neutron spin echo
452:Beta spectroscopy
365:Energy-dispersive
48:materials science
720:
683:
682:
671:
670:
531:
442:phenomenological
191:Vibrational (IR)
176:
169:
162:
153:
146:
135:
129:
119:
113:
102:
96:
93:
728:
727:
723:
722:
721:
719:
718:
717:
698:
697:
696:
691:
655:
633:
570:
522:
484:
456:
398:
348:
248:
209:Resonance Raman
185:
180:
150:
149:
136:
132:
120:
116:
103:
99:
94:
90:
85:
60:
21:
12:
11:
5:
726:
724:
716:
715:
710:
700:
699:
693:
692:
690:
689:
677:
664:
661:
660:
657:
656:
654:
653:
647:
641:
639:
635:
634:
632:
631:
626:
621:
616:
615:
614:
604:
599:
594:
589:
584:
578:
576:
572:
571:
569:
568:
563:
558:
553:
548:
543:
537:
535:
528:
524:
523:
521:
520:
515:
510:
505:
504:
503:
492:
490:
486:
485:
483:
482:
481:
480:
470:
464:
462:
458:
457:
455:
454:
449:
444:
439:
434:
433:
432:
427:
425:Angle-resolved
422:
417:
406:
404:
400:
399:
397:
396:
395:
394:
384:
379:
378:
377:
372:
367:
356:
354:
350:
349:
347:
346:
341:
336:
335:
334:
329:
328:
327:
312:
307:
302:
301:
300:
290:
284:
279:
274:
273:
272:
262:
256:
254:
250:
249:
247:
246:
241:
236:
231:
226:
221:
216:
211:
206:
201:
195:
193:
187:
186:
181:
179:
178:
171:
164:
156:
148:
147:
130:
114:
97:
87:
86:
84:
81:
59:
56:
13:
10:
9:
6:
4:
3:
2:
725:
714:
711:
709:
706:
705:
703:
688:
687:
678:
676:
675:
666:
665:
662:
651:
648:
646:
643:
642:
640:
636:
630:
627:
625:
622:
620:
617:
613:
610:
609:
608:
605:
603:
600:
598:
595:
593:
590:
588:
585:
583:
580:
579:
577:
573:
567:
564:
562:
559:
557:
554:
552:
549:
547:
544:
542:
539:
538:
536:
532:
529:
525:
519:
516:
514:
511:
509:
506:
502:
499:
498:
497:
494:
493:
491:
487:
479:
476:
475:
474:
471:
469:
466:
465:
463:
459:
453:
450:
448:
445:
443:
440:
438:
435:
431:
428:
426:
423:
421:
418:
416:
413:
412:
411:
408:
407:
405:
401:
393:
390:
389:
388:
385:
383:
380:
376:
373:
371:
368:
366:
363:
362:
361:
358:
357:
355:
351:
345:
342:
340:
337:
333:
330:
326:
323:
322:
321:
318:
317:
316:
313:
311:
308:
306:
303:
299:
296:
295:
294:
291:
288:
285:
283:
282:Near-infrared
280:
278:
275:
271:
268:
267:
266:
263:
261:
258:
257:
255:
251:
245:
242:
240:
237:
235:
232:
230:
227:
225:
222:
220:
217:
215:
212:
210:
207:
205:
202:
200:
197:
196:
194:
192:
188:
184:
177:
172:
170:
165:
163:
158:
157:
154:
145:
141:
134:
131:
128:
124:
118:
115:
112:
108:
101:
98:
92:
89:
82:
80:
78:
74:
64:
57:
55:
53:
49:
45:
41:
37:
33:
29:
25:
19:
684:
672:
652:(a misnomer)
638:Applications
556:Time-stretch
447:paramagnetic
265:Fluorescence
233:
183:Spectroscopy
133:
117:
100:
91:
69:
35:
23:
22:
224:Vibrational
28:synchrotron
702:Categories
430:Two-photon
332:absorption
214:Rotational
83:References
52:geophysics
508:Terahertz
489:Radiowave
387:Mössbauer
73:Mössbauer
674:Category
403:Electron
370:Emission
320:emission
277:Vibronic
686:Commons
513:ESR/EPR
461:Nucleon
289:(REMPI)
527:Others
315:Atomic
50:, and
468:Alpha
437:Auger
415:X-ray
382:Gamma
360:X-ray
293:Raman
204:Raman
199:FT-IR
26:is a
36:NRVS
496:NMR
140:doi
123:doi
107:doi
704::
501:2D
420:UV
46:,
175:e
168:t
161:v
142::
125::
109::
20:.
Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.
