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as Glaxo
Professor of Organihttps://en.wikipedia.org/Wikipedia:Biographies_of_living_persons/Helpc Chemistry, Director of the Wolfson Centre for Organic Chemistry in Medical Science and Head of the Organic Section. He was appointed the Sir Derek Barton Professor of Synthetic Chemistry in 1999. Barrett has invented many reactions including novel glycosidations, atom-economic aromatic substitution reactions, metal-catalyzed oxidations and hydroaminations, reactions using ROMP-gel supported reagents and multi-component benzyne coupling reactions. He has contributed extensively to the synthesis of β-lactams using alkenyl anions, ynolates, novel isocyanates, iron vinylidines, heteroatom functionalized nitroalkenes, and ring closing alkene and enyne metathesis reactions. He has completed the total synthesis of diverse bioactive natural products including papulacandin D, papuamine, showdomycin, milbemycin β3, the palmarumycins and preussomerin G, (+)-calyculin A and the multiple cyclopropane CETP inhibitor U-106305 and structurally related cyclopropane nucleoside FR-900848 and coronanes. He has also published highly flexible methods for the biomimetic total syntheses of resorcylate and meroterpenoid natural products including 15G256β, aigialomycin D, LL-Z1640-2, cruentaren A, hericenone J and macrosporin, amorphastilbol, (+)-hongoquercin A and B, and austalides. Barrett, in collaboration with Brian Hoffman at Northwestern University, has published pioneering work on the synthesis of diverse porphyrazines bearing 8, 6, 4, and 2 thiols, amines or alcohols as peripheral macrocyclic ring substituents and the conversion of these polydentate ligands by the complexation of metal ions both within the macrocyclic cavity and at the periphery to produce diverse multimetallic complexes. Several such complexes are imaging agents for the highly selective detection of cancers in both cells and in vivo and as PDT agents. Additionally, Barrett in collaboration with Simak Ali and R. Charles Coombes in Medicine at Imperial College and Dennis Liotta and James P. Snyder in Emory University has made pioneering contributions to addressing unmet medical need with the invention of highly selective and bioavailable inhibitors of the Cyclin Dependent Kinases including CDK-7 inhibitor ICEC0942 (CT7001), which have been licensed by Carrick Therapeutics for clinical trials to treat Tamoxifen-resistant and other cancers.
1179:
P.; Liotta, Dennis C.; Freemont, Paul. S.; Aboagye, Eric O.; Coombes, R. Charles; Barrett, Anthony G. M.; Ali, Simak (23 December 2010). "A Novel
Pyrazolopyrimidine Is a Potent Inhibitor of Cyclin-Dependent Protein Kinases 1, 2, and 9, Which Demonstrates Antitumor Effects in Human Tumor Xenografts Following Oral Administration".
267:, 1994 Tilden Lectureship, 1996 Award in Synthetic Organic Chemistry, 2001 Award in Natural Products Chemistry, 2004 Pedler Lectureship, 2005 Simonsen Lectureship, 2010 Charles Rees Award), the American Chemical Society (1986 Cope Scholar Award), the Royal Society (2002 Royal Society Wolfson Research Merit Award
1178:
Heathcote, Dean A.; Patel, Hetal; Kroll, Sebastian H. B.; Hazel, Pascale; Periyasamy, Manikandan; Alikian, Mary; Kanneganti, Seshu K.; Jogalekar, Ashutosh S.; Scheiper, Bodo; Barbazanges, Marion; Blum, Andreas; Brackow, Jan; Siwicka, Alekasandra; Pace, Robert D. M.; Fuchter, Matthew J.; Snyder, James
277:
Wellcome (2000 Award for
Innovative Chemistry), Institute of Applied Catalysis (2001 Award for Innovation in Applied Catalysis), and the Specialised Organic Sector Association (2000 Innovation Award). In 2017 he received the Imperial College President's Medal for Excellence in Research: Excellence in
373:
Anderson, Oren P; Barrett, Anthony GM; Edmunds, Jeremy J; Hachiya, Shun-Ichiro; Hendrix, James A; Horita, Kiyoshi; Malecha, James W; Parkinson, Christopher J; VanSickle, Andrew (1 November 2001). "Applications of crotyldiisopinocampheylboranes in synthesis: a formal total synthesis of (+)-calyculin
230:
Barrett was appointed lecturer in organic chemistry (1975) at IC and senior lecturer (1982). In 1983, he was appointed full professor of
Chemistry at Northwestern University in Evanston, Illinois, and in 1990 moved to Colorado State University. After ten years research in the US, he returned to IC
1128:
Patel, Hetal; Periyasamy, Manikandan; Sava, Georgina P.; Bondke, Alexander; Slafer, Brian W.; Kroll, Sebastian H. B.; Barbazanges, Marion; Starkey, Richard; Ottaviani, Silvia; Harrod, Alison; Aboagye, Eric O.; Buluwela, Laki; Fuchter, Matthew J.; Barrett, Anthony G. M.; Coombes, R. Charles; Ali,
669:
Ma, Tsz-Kan; White, Andrew J.P.; Barrett, Anthony G.M. (July 2017). "Meroterpenoid total synthesis: Conversion of geraniol and farnesol into amorphastilbol, grifolin and grifolic acid by dioxinone- β -keto-acylation, palladium catalyzed decarboxylative allylic rearrangement and aromatization".
433:
Navarro, Ismael; Basset, Jean-François; Hebbe, Séverine; Major, Sarah M.; Werner, Thomas; Howsham, Catherine; Bräckow, Jan; Barrett, Anthony G. M. (1 August 2008). "Biomimetic
Synthesis of Resorcylate Natural Products Utilizing Late Stage Aromatization: Concise Total Syntheses of the Marine
1226:; Liotta, Dennis C.; Snyder, James P.; Kanneganti, Seshu K.; Tolhurst, Robert S.; Periyasamy, Manikandan; Fuchter, Matthew J.; Siwicka, Alekasandra; Brackow, Jan; Patel, Hetal; Scheiper, Bodo; Jogalekar, Ashutosh S.; Kroll, Sebastian H. B.; Heathcote, Dean A.; Ali, Simak (1 August 2009).
329:
Barrett, Anthony G. M.; Blaney, Frank; Campbell, Andrew D.; Hamprecht, Dieter; Meyer, Thorsten; White, Andrew J. P.; Witty, David; Williams, David J. (1 May 2002). "Unified Route to the
Palmarumycin and Preussomerin Natural Products. Enantioselective Synthesis of (−)-Preussomerin G".
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Barrett, Anthony G. M.; Doubleday, Wendel W.; Hamprecht, Dieter; Kasdorf, Krista; Tustin, Gary J.; White, Andrew J. P.; Williams, David J. (1997). "Assembly of the antifungal agent FR-900848 and the CETP inhibitor U-106305: studies on remarkable multicyclopropane natural products".
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Cordes, Jens; Calo, Frederick; Anderson, Katie; Pfaffeneder, Toni; Laclef, Sylvain; White, Andrew J. P.; Barrett, Anthony G. M. (6 January 2012). "Total
Syntheses of Angelicoin A, Hericenone J, and Hericenol A via Migratory Prenyl- and Geranylation–Aromatization Sequences".
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Trivedi, Evan R.; Vesper, Benjamin J.; Weitman, Hana; Ehrenberg, Benjamin; Barrett, Anthony G. M.; Radosevich, James A.; Hoffman, Brian M. (2010). "Chiral bis-Acetal
Porphyrazines as Near-infrared Optical Agents for Detection and Treatment of Cancer".
1421:
Riedel, René; Seel, Andrew G.; Malko, Daniel; Miller, Daniel P.; Sperling, Brendan T.; Choi, Heungjae; Headen, Thomas F.; Zurek, Eva; Porch, Adrian; Kucernak, Anthony; Pyper, Nicholas C.; Edwards, Peter P.; Barrett, Anthony G. M. (2021).
217:
Barrett was educated at Heles
Grammar School in Exeter. He attended Imperial College, London (1st Class Honours BSc in 1973 and DIC and PhD in 1975). He carried out his Ph.D. working under the direction of Sir
642:
Cordes, Jens; Barrett, Anthony G. M. (March 2013). "Synthesis of
Macrosporin and Related 9,10-Anthraquinones by Biomimetic Polyketide Aromatization and Cyclization of 6-Benzylresorcylates".
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Michel, Sarah L. J.; Hoffman, Brian M.; Baum, Sven M.; Barrett, Anthony G. M. (2002). "Peripherally Functionalized Porphyrazines: Novel Metallomacrocycles with Broad, Untapped Potential".
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Miyatake-Ondozabal, Hideki; Barrett, Anthony G. M. (3 December 2010). "Total Synthesis of TAK-Kinase Inhibitor LL-Z1640-2 via Consecutive Macrocyclization and Transannular Aromatization".
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Calo, Frederick; Richardson, Jeffery; Barrett, Anthony G. M. (5 November 2009). "Total Synthesis of Aigialomycin D using a One-Pot Ketene Generation−Trapping−Aromatization Sequence".
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Barrett, Anthony G. M.; Hoffman, Brian M.; Zong, Hong; Zhong, Chang; Fuchter, Matthew J. (19 May 2008). "Porphyrazines: Designer Macrocycles by Peripheral Substituent Change".
717:"Meroterpenoid Synthesis via Sequential Polyketide Aromatization and Cationic Polyene Cyclization: Total Syntheses of (+)-Hongoquercin A and B and Related Meroterpenoids"
774:"Meroterpenoid Synthesis via Sequential Polyketide Aromatization and Radical Anion Cascade Triene Cyclization: Biomimetic Total Syntheses of Austalide Natural Products"
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Trivedi, Evan R.; Ma, Zhidong; Waters, Emily A.; Macrenaris, Keith W.; Subramanian, Rohit; Barrett, Anthony G. M.; Meade, Thomas J.; Hoffman, Brian M. (July 2014).
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Kandela, Irawati K.; McAuliffe, Katherine J.; Cochran, Lauren E.; Barrett, Anthony G. M.; Hoffman, Brian M.; Mazar, Andrew P.; Trivedi, Evan R. (13 July 2017).
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Fouché, Marianne; Rooney, Lisa; Barrett, Anthony G. M. (15 March 2012). "Biomimetic Total Synthesis of Cruentaren A via Aromatization of Diketodioxinones".
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Barrett has received numerous awards for his contributions to research from the Royal Society of Chemistry (1980 Meldola Medal, 1982 Harrison Medal
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Ma, Tsz-Kan; Elliott, Daniel C.; Reid, Stephanie; White, Andrew J. P.; Parsons, Philip J.; Barrett, Anthony G. M. (2 November 2018).
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1032:"Synthesis and characterization of a porphyrazine-Gd(III) MRI contrast agent and imaging of a breast cancer xenograft model"
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analogues under dissolving metal reduction conditions. This not only triggered the development of thermally stable solid
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1081:"Discovery of the Antitumor Effects of a Porphyrazine Diol (Pz 285) in MDA-MB-231 Breast Tumor Xenograft Models in Mice"
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1314:"Synthesis and structures of two thermally stable sodides with the macrocyclic complexant hexamethyl hexacyclen"
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201:. He is Director of the Wolfson Centre for Organic Chemistry in Medical Science. He was elected a fellow of the
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in 2003. He obtained a BSc as well as PhD from Imperial College London in 1973 and 1975 respectively.
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Redko, M. Y.; Vlassa, M.; Jackson, J. E.; Misiolek, A. W.; Huang, R. H.; Dye, J. L. (2002).
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Barrett was the first to demonstrate the increased stability of per-alkylated
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Redko, Mikhail Y.; Jackson, James E.; Huang, Rui H.; Dye, James L. (2005).
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Ma, Tsz-Kan; Parsons, Philip J.; Barrett, Anthony G. M. (2019-04-02).
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1384:"Design and Synthesis of a Thermally Stable Organic Electride"
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Hoffman, Brian M.; Meade, Thomas J.; Barrett, Anthony G. M.;
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784:(9). American Chemical Society (ACS): 4961–4970.
917:Proceedings of the National Academy of Sciences
1312:Kuchenmeister, Mark E.; Dye, James L. (1989).
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1388:Journal of the American Chemical Society
1349:Journal of the American Chemical Society
1318:Journal of the American Chemical Society
436:Journal of the American Chemical Society
434:Antifungal Agents 15G256ι and 15G256β".
843:. John Wiley & Sons, Ltd: 473–590.
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1036:Contrast Media & Molecular Imaging
19:For the Canadian football player, see
644:European Journal of Organic Chemistry
7:
1897:Academics of Imperial College London
21:Anthony Barrett (Canadian football)
14:
1526:"Simonsen Award Previous Winners"
1293:. Perkin Transactions (1): 1501.
1544:"Charles Rees Award 2010 Winner"
993:10.1111/j.1751-1097.2009.00681.x
778:The Journal of Organic Chemistry
721:The Journal of Organic Chemistry
601:The Journal of Organic Chemistry
565:The Journal of Organic Chemistry
332:The Journal of Organic Chemistry
278:Innovation and Entrepreneurship
253:in solution for the first time.
1508:"Pedler Award Previous Winners"
1490:"Tilden Prize Previous Winners"
1291:Journal of the Chemical Society
1085:ACS Medicinal Chemistry Letters
981:Photochemistry and Photobiology
874:Australian Journal of Chemistry
841:Progress in Inorganic Chemistry
1181:Journal of Medicinal Chemistry
1097:10.1021/acsmedchemlett.7b00063
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1245:10.1158/0008-5472.CAN-09-0301
1147:10.1158/1535-7163.MCT-16-0847
1135:Molecular Cancer Therapeutics
376:Canadian Journal of Chemistry
184:Anthony Gerard Martin Barrett
61:Anthony Gerard Martin Barrett
30:Anthony Gerard Martin Barrett
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1472:"RSC Harrison-Meldola Prize"
684:10.1016/j.tetlet.2017.05.096
317:Fellows of the Royal Society
264:, 1986 Corday-Morgan Medal
207:Academy of Medical Sciences
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1530:Royal Society of Chemistry
1512:Royal Society of Chemistry
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1476:Royal Society of Chemistry
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1285:Barrett, Anthony (1981).
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791:10.1021/acs.joc.9b00142
733:10.1021/acs.joc.8b02095
412:Chemical Communications
303:Imperial College London
199:Imperial College London
126:Imperial College London
118:Northwestern University
101:Imperial College London
1819:Robert Williamson
1814:Peter M. Williams
1735:John G. McWhirter
849:10.1002/0471227110.ch8
656:10.1002/ejoc.201201480
1760:John G. Shepherd
1647:John Brian Clegg
299:"AGM Barrett Webpage"
1776:Alfred G. Sykes
1714:John Paul Maier
1708:Peter L. Knight
1440:10.1021/jacs.1c00115
1299:10.1039/p19810001501
1850:G. Ledyard Stebbins
1787:John F. Toland
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257:Awards and honors
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114:Institutions
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71:2 March 1952
1907:1952 births
1765:Joseph Silk
1740:John Mollon
1658:David Delpy
92:British, US
89:Nationality
1881:Categories
285:References
243:electrides
67:1952-03-02
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1698:Ron Grigg
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273:), Glaxo
251:ion pairs
239:alkalides
213:Education
165:.imperial
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175:.barrett
1833:Foreign
1604:Fellows
1597:in 1999
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925:Bibcode
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195:chemist
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