127:
24:
459:
Hering, Florian; Berthel, Johannes H. J.; Lubitz, Katharina; Paul, Ursula S. D.; Schneider, Heidi; Härterich, Marcel; Radius, Udo (2016). "Synthesis and
Thermal Properties of Novel NHC-Stabilized Cobalt Carbonyl Nitrosyl Complexes".
364:(NO). It is a dark red volatile oil that is soluble in nonpolar solvents. The compound is one of the simplest metal nitrosyls. It is highly toxic, reminiscent of the same property for
206:
84:
181:
502:
447:
314:
341:
497:
492:
134:
122:
377:
357:
442:
King, R. B. "Organometallic
Synthesis, Volume 1: Transition-metal compounds" (1965) Academic Press.
365:
50:
420:
443:
104:
469:
229:
60:
126:
335:
486:
298:
288:
166:
115:
381:
473:
424:
257:
95:
278:
153:
135:
23:
334:
Except where otherwise noted, data are given for materials in their
419:
The complex undergoes substitution readily by Lewis bases such as
83:
73:
376:
Cobalt tricarbonyl nitrosyl is prepared by the treatment of
165:
59:
8:
293:−1.1 °C (30.0 °F; 272.0 K)
125:
103:
15:
416:Many other methods have been developed.
190:InChI=1S/3CO.Co.NO/c3*1-2;;1-2/q;;;+1;-1
435:
211:
186:
116:
303:50 °C (122 °F; 323 K)
193:Key: XDBBIZGDISXSEJ-UHFFFAOYSA-N
7:
156:
14:
244:
22:
427:, concomitant with loss of CO.
338:(at 25 °C , 100 kPa).
315:Occupational safety and health
247:
241:
235:
1:
474:10.1021/acs.organomet.6b00374
17:Cobalt tricarbonyl nitrosyl
354:Cobalt tricarbonyl nitrosyl
38:Cobalt nitrosyl tricarbonyl
519:
332:
312:
307:
222:
202:
177:
43:
35:
30:
21:
372:Synthesis and reactions
360:with the formula Co(CO)
503:Organocobalt compounds
378:dicobalt octacarbonyl
358:organocobalt compound
366:nickel tetracarbonyl
170: (charge error)
421:tertiary phosphines
265: g·mol
18:
498:Nitrosyl complexes
493:Carbonyl complexes
342:Infobox references
16:
468:(17): 2806–2821.
350:Chemical compound
348:
347:
85:Interactive image
510:
478:
477:
456:
450:
440:
411:
403:
399:
264:
249:
246:
243:
237:
230:Chemical formula
169:
158:
137:
129:
118:
107:
87:
63:
26:
19:
518:
517:
513:
512:
511:
509:
508:
507:
483:
482:
481:
462:Organometallics
458:
457:
453:
441:
437:
433:
409:
407:
401:
397:
395:
391:
374:
363:
351:
344:
339:
325:
262:
252:
240:
232:
218:
215:
210:
209:
198:
195:
194:
191:
185:
184:
173:
159:
147:
110:
90:
77:
66:
53:
39:
12:
11:
5:
516:
514:
506:
505:
500:
495:
485:
484:
480:
479:
451:
434:
432:
429:
414:
413:
405:
393:
389:
373:
370:
361:
349:
346:
345:
340:
336:standard state
333:
330:
329:
326:
323:
320:
319:
310:
309:
305:
304:
301:
295:
294:
291:
285:
284:
281:
275:
274:
271:
267:
266:
260:
254:
253:
250:
238:
233:
228:
225:
224:
220:
219:
217:
216:
214:=O.=O.=O.N(=O)
213:
205:
204:
203:
200:
199:
197:
196:
192:
189:
188:
180:
179:
178:
175:
174:
172:
171:
162:
160:
152:
149:
148:
146:
145:
141:
139:
131:
130:
120:
112:
111:
109:
108:
100:
98:
92:
91:
89:
88:
80:
78:
71:
68:
67:
65:
64:
56:
54:
49:
46:
45:
41:
40:
37:
33:
32:
28:
27:
13:
10:
9:
6:
4:
3:
2:
515:
504:
501:
499:
496:
494:
491:
490:
488:
475:
471:
467:
463:
455:
452:
449:
445:
439:
436:
430:
428:
426:
422:
417:
387:
386:
385:
383:
379:
371:
369:
367:
359:
355:
343:
337:
331:
327:
322:
321:
317:
316:
311:
306:
302:
300:
299:Boiling point
297:
296:
292:
290:
289:Melting point
287:
286:
282:
280:
277:
276:
272:
269:
268:
261:
259:
256:
255:
234:
231:
227:
226:
221:
212:
208:
201:
187:
183:
176:
168:
164:
163:
161:
155:
151:
150:
143:
142:
140:
138:
133:
132:
128:
124:
121:
119:
117:ECHA InfoCard
114:
113:
106:
102:
101:
99:
97:
94:
93:
86:
82:
81:
79:
75:
70:
69:
62:
58:
57:
55:
52:
48:
47:
42:
34:
29:
25:
20:
465:
461:
454:
438:
418:
415:
382:nitric oxide
375:
353:
352:
324:Main hazards
313:
44:Identifiers
36:Other names
425:isocyanides
318:(OHS/OSH):
270:Appearance
223:Properties
123:100.034.481
487:Categories
448:0124080502
431:References
283:1.47 g/cm
258:Molar mass
96:ChemSpider
72:3D model (
61:14096-82-3
51:CAS Number
144:237-945-5
136:EC Number
308:Hazards
273:red oil
167:13539873
105:21241479
356:is the
279:Density
263:172.969
154:PubChem
446:
410:
408:NO + 2
404:Co(CO)
402:
400:NO → 2
398:
328:toxic
207:SMILES
31:Names
380:with
182:InChI
74:JSmol
444:ISBN
423:and
392:(CO)
470:doi
396:+ 2
157:CID
489::
466:35
464:.
412:CO
388:Co
384::
368:.
242:Co
476:.
472::
406:3
394:8
390:2
362:3
251:4
248:O
245:N
239:3
236:C
76:)
Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.
