483:
1048:
1056:
531:
895:
1307:
619:
248:) has been claimed, the report could not be reproduced and such a species from the removal of all electrons of the element beyond the preceding inert gas configuration (at least with iron in its +8 oxidation state) has been found to be improbable computationally. However, one form of anionic with iron in its +7 oxidation state, along with an iron(V)-peroxo isomer, has been detected by infrared spectroscopy at 4 K after cocondensation of laser-ablated Fe atoms with a mixture of O
1182:
422:
952:
467:
407:
1218:
1298:
444:
1466:
Fe(−4), Ru(−4), and Os(−4) have been observed in metal-rich compounds containing octahedral complexes ; Pt(−3) (as a dimeric anion ), Cu(−2), Zn(−2), Ag(−2), Cd(−2), Au(−2), and Hg(−2) have been observed (as dimeric and monomeric anions; dimeric ions were initially reported to be for Zn, Cd, Hg, but
2066:
James, B.D.; Bakalova, M.; Lieseganga, J.; Reiff, W.M.; Hockless, D.C.R.; Skelton, B.W.; White, A.H. (1996). "The hexachloroferrate(III) anion stabilized in hydrogen bonded packing arrangements. A comparison of the X-ray crystal structures and low temperature magnetism of tetrakis(methylammonium)
294:
Iron is the first of the transition metals that cannot reach its group oxidation state of +8, although its heavier congeners ruthenium and osmium can, with ruthenium having more difficulty than osmium. Ruthenium exhibits an aqueous cationic chemistry in its low oxidation states similar to that of
209:, that revolutionalized the latter field in the 1950s. Iron is sometimes considered as a prototype for the entire block of transition metals, due to its abundance and the immense role it has played in the technological progress of humanity. Its 26 electrons are arranged in the
1111:
Among the halide and pseudohalide complexes, fluoro complexes of iron(III) are the most stable, with the colorless being the most stable in aqueous solution. Chloro complexes are less stable and favor tetrahedral coordination as in ; and are reduced easily to iron(II).
915:
absorptions. Thus, all the above complexes are rather strongly colored, with the single exception of the hexaquo ion – and even that has a spectrum dominated by charge transfer in the near ultraviolet region. On the other hand, the pale green iron(II) hexaquo ion
910:
precipitates out of solution. Although Fe has a d configuration, its absorption spectrum is not like that of Mn with its weak, spin-forbidden d–d bands, because Fe has higher positive charge and is more polarizing, lowering the energy of its ligand-to-metal
1235:, is an old and well-known iron-cyanide complex, extensively used as pigment and in several other applications. Its formation can be used as a simple wet chemistry test to distinguish between aqueous solutions of Fe and Fe as they react (respectively) with
1991:
Nicholas A. Barnes, Stephen M.Godfrey, Nicholas Ho, Charles A.McAuliffe, Robin G.Pritchard; "Facile synthesis of a rare example of an iron(III) iodide complex, , from the reaction of Me3AsI2 with unactivated iron powder", Polyhedron (2013) 55, 67-72.
295:
iron, but osmium does not, favoring high oxidation states in which it forms anionic complexes. In the second half of the 3d transition series, vertical similarities down the groups compete with the horizontal similarities of iron with its neighbors
1581:
Changhoon Lee; Myung-Hwan
Whangbo; Jürgen Köhler (2010). "Analysis of Electronic Structures and Chemical Bonding of Metal-rich Compounds. 2. Presence of Dimer (T–T) and Isolated T Anions in the Polar Intermetallic
1124:. An example of a low-spin iron(III) complex is . The cyanide ligands may easily be detached in , and hence this complex is poisonous, unlike the iron(II) complex found in Prussian blue, which does not release
1142:(5 unpaired electrons). This value is always half the number of unpaired electrons. Complexes with zero to two unpaired electrons are considered low-spin and those with four or five are considered high-spin.
213:
3d4s, of which the 3d and 4s electrons are relatively close in energy, and thus it can lose a variable number of electrons and there is no clear point where further ionization becomes unprofitable.
1116:
is a common test for the presence of iron(III) as it forms the blood-red . Like manganese(II), most iron(III) complexes are high-spin, the exceptions being those with ligands that are high in the
983:
205:, namely the ability to form variable oxidation states differing by steps of one and a very large coordination and organometallic chemistry: indeed, it was the discovery of an iron compound,
1979:
Siegfried Pohl, Ulrich
Bierbach, Wolfgang Saak; "FeI3SC(NMe2)2, a Neutral Thiourea Complex of Iron(III) Iodide", Angewandte Chemie International Edition in English (1989) 28 (6), 776-777.
971:
1075:-donor ligands. The latter tend to be rather more unstable than iron(II) complexes and often dissociate in water. Many Fe–O complexes show intense colors and are used as tests for
2181:
Echigo, Takuya; Kimata, Mitsuyoshi (2008). "Single-crystal X-ray diffraction and spectroscopic studies on humboldtine and lindbergite: weak Jahn–Teller effect of Fe ion".
936:
being precipitated out. In excess carbon dioxide this forms the slightly soluble bicarbonate, which occurs commonly in groundwater, but it oxidises quickly in air to form
1044:
structure with co-planar oxalate ions bridging between iron centres with the water of crystallisation located forming the caps of each octahedron, as illustrated below.
1718:
Lu, Jun-Bo; Jian, Jiwen; Huang, Wei; Lin, Hailu; Li, Jun; Zhou, Mingfei (2016-11-16). "Experimental and theoretical identification of the Fe(VII) oxidation state in FeO
256:
compounds contain formal oxidation states of +1, 0, −1, or even −2. The oxidation states and other bonding properties are often assessed using the technique of
610:
and light at the temperature of −20 °C, with oxygen and water excluded. Complexes of ferric iodide with some soft bases are known to be stable compounds.
693:(VI) anion is such a strong oxidizing agent that it oxidizes nitrogen and ammonia at room temperature, and even water itself in acidic or neutral solutions:
3222:
2476:
2340:
3029:
3561:
3012:
2623:
2244:
2126:
1896:
1867:
1662:
1286:
90:
2566:
1342:, by Pauson and Kealy and independently by Miller and colleagues, whose surprising molecular structure was determined only a year later by
482:
2183:
1842:
582:
Ferric iodide is an exception, being thermodynamically unstable due to the oxidizing power of Fe and the high reducing power of I:
2308:
1051:
Crystal structure of iron(II) oxalate dihydrate, showing iron (gray), oxygen (red), carbon (black), and hydrogen (white) atoms.
3209:
3057:
1173:
is not. They have a tendency to be oxidized to iron(III) but this can be moderated by low pH and the specific ligands used.
3395:
2511:
2039:
1282:
123:
42:
2499:
2469:
2143:
1766:
1679:
Huang, Wei; Xu, Wen-Hua; Schwarz, W.H.E.; Li, Jun (2016-05-02). "On the
Highest Oxidation States of Metal Elements in MO
1047:
631:
3073:
2973:
383:
502:), also known as fool's gold owing to its golden luster. It is not an iron(IV) compound, but is actually an iron(II)
2037:
Clausen, C.A.; Good, M.L. (1968). "Stabilization of the hexachloroferrate(III) anion by the methylammonium cation".
1405:). The former is one of the most readily available sources of iron(II), but is less stable to aerial oxidation than
3363:
2841:
2685:
325:
when finely divided and dissolves easily in dilute acids, giving Fe. However, it does not react with concentrated
3226:
2767:
1129:
257:
594:
Ferric iodide, a black solid, is not stable in ordinary conditions, but can be prepared through the reaction of
1858:
Reiff, William
Michael; Long, Gary J. (1984). "Mössbauer Spectroscopy and the Coordination Chemistry of Iron".
1390:
1055:
329:
and other oxidizing acids due to the formation of an impervious oxide layer, which can nevertheless react with
906:
As pH rises above 0 the above yellow hydrolyzed species form and as it rises above 2–3, reddish-brown hydrous
3556:
3415:
3239:
2462:
2077:
1442:
1195:
912:
2554:
1366:
1267:
1240:
1236:
1211:
1117:
1017:
894:
261:
210:
2422:
2335:
2104:
Giannoccaro, P.; Sacco, A. (1977). "Bis[Ethylenebis(Diphenylphosphine)]-Hydridoiron
Complexes".
1654:
1343:
1263:
1198:
of iron, where carbon atoms are covalently bound to the metal atom. They are many and varied, including
618:
3137:
2713:
2615:
2272:
2192:
1731:
1562:
1553:
Changhoon Lee; Myung-Hwan
Whangbo (2008). "Late transition metal anions acting as p-metal elements".
1191:
1084:
797:
307:
and share similar chemistry. As such, iron, cobalt, and nickel are sometimes grouped together as the
253:
542:
are well-known. The ferrous halides typically arise from treating iron metal with the corresponding
3231:
2542:
2106:
2071:
and tetrakis(hexamethylenediammonium) hexachloroferrate(III) tetrachloroferrate(III) tetrachloride
1132:, including every possible spin quantum number value for a d-block element from 0 (diamagnetic) to
1025:
382:
also exists, though it is unstable at room temperature. Despite their names, they are actually all
948:
Due to its electronic structure, iron has a very large coordination and organometallic chemistry.
530:
3483:
3307:
3259:
3184:
3176:
3125:
2957:
2881:
2865:
2817:
2746:
2534:
2331:
2288:
2208:
2163:
1398:
1351:
1347:
1247:
1088:
997:
933:
595:
386:
whose compositions may vary. These oxides are the principal ores for the production of iron (see
355:
154:
80:
1932:
1362:
1306:
1884:
1181:
3504:
3335:
3323:
3197:
3168:
3104:
2873:
2853:
2797:
2792:
2705:
2697:
2440:
2389:
2240:
2122:
1892:
1863:
1838:
1789:
1747:
1700:
1658:
1322:
1207:
1005:
334:
330:
315:
233:
182:
1574:
3217:
3160:
2941:
2921:
2901:
2889:
2805:
2759:
2754:
2725:
2677:
2430:
2379:
2348:
2313:
2280:
2263:
2226:
2200:
2155:
2114:
2086:
2048:
1781:
1739:
1692:
1646:
1607:
1570:
1447:
1382:
1203:
1125:
1037:
975:
968:
964:
899:
470:
395:
391:
318:. As a result, mercury is traded in standardized 76 pound flasks (34 kg) made of iron.
304:
229:
202:
951:
562:
Iron reacts with fluorine, chlorine, and bromine to give the corresponding ferric halides,
3435:
3351:
3295:
2833:
2733:
2605:
1767:"High-Valent Iron(IV)–Oxo Complexes of Heme and Non-Heme Ligands in Oxygenation Reactions"
1551:; Au(–3) has been observed in ScAuSn and in other 18-electron half-Heusler compounds. See
1255:
937:
907:
603:
563:
543:
519:
466:
367:
217:
119:
105:
1285:, is a useful reagent for organic chemistry; it contains iron in the −2 oxidation state.
252:/Ar. Iron(IV) is a common intermediate in many biochemical oxidation reactions. Numerous
2276:
2196:
1735:
1566:
3516:
3275:
3192:
3109:
2741:
2236:
1928:
1406:
1199:
1029:
751:
The Fe ion has a large simple cationic chemistry, although the pale-violet hexaquo ion
421:
379:
2306:
Miller, S. A.; Tebboth, J. A.; Tremaine, J. F. (1952). "114. Dicyclopentadienyliron".
3550:
2090:
1259:
1225:
322:
269:
2212:
2167:
2657:
2292:
1145:
Iron(II) complexes are less stable than iron(III) complexes but the preference for
623:
1696:
967:. A typical six-coordinate anion is hexachloroferrate(III), , found in the mixed
2230:
1889:
Cyanotype: the history, science and art of photographic printing in
Prussian blue
1113:
1021:
503:
326:
244:), which contains iron in its +6 oxidation state. Although iron(VIII) oxide (FeO
2118:
1354:. Ferrocene is still one of the most important tools and models in this class.
1281:, a complex with a cluster of three iron atoms at its core. Collman's reagent,
3535:
2204:
1797:
956:
940:
that accounts for the brown deposits present in a sizeable number of streams.
351:
308:
2393:
1993:
1433:). Iron(II) compounds tend to be oxidized to iron(III) compounds in the air.
1128:
except when dilute acids are added. Iron shows a great variety of electronic
2996:
1325:
1321:
A landmark in this field was the discovery in 1951 of the remarkably stable
929:
928:
does not undergo appreciable hydrolysis. Carbon dioxide is not evolved when
406:
288:
265:
225:
206:
109:
2444:
2435:
2417:
2384:
2367:
1793:
1751:
1704:
1611:
1217:
2317:
1980:
1358:
1064:
1016:(delta) for the right-handed screw axis, in line with IUPAC conventions.
387:
221:
2352:
2261:
Kealy, T.J.; Pauson, P.L. (1951). "A New Type of Organo-Iron
Compound".
2052:
2159:
1743:
1121:
1041:
1033:
1001:
690:
2284:
2144:"Structure of trans-chlorohydridobis(diphenylphosphinoethane)iron(II)"
1785:
1297:
634:
in acidic aqueous solution for some common iron ions are given below:
1370:
1076:
607:
599:
539:
495:
300:
296:
1837:(in German) (91–100 ed.). Walter de Gruyter. pp. 1125–46.
1254:, in which a neutral iron atom is bound to the carbon atoms of five
963:
Many coordination compounds of iron are known, although few exhibit
2418:"An Iron Catalyst for Ketone Hydrogenations under Mild Conditions"
1216:
1180:
1054:
1046:
950:
893:
617:
529:
481:
465:
2454:
1381:
The iron compounds produced on the largest scale in industry are
763:
is very readily hydrolyzed when pH increases above 0 as follows:
337:, is considered to be resistant to rust, due to its oxide layer.
1833:
Holleman, Arnold F.; Wiberg, Egon; Wiberg, Nils (1985). "Iron".
1104:
1080:
989:
443:
198:
2458:
986:
complex is used as a starting material for compounds with the
321:
Iron is by far the most reactive element in its group; it is
390:
and blast furnace). They are also used in the production of
984:
chlorohydridobis(bis-1,2-(diphenylphosphino)ethane)iron(II)
314:
Unlike many other metals, iron does not form amalgams with
972:
tetrakis(methylammonium) hexachloroferrate(III) chloride
622:
Comparison of colors of solutions of ferrate (left) and
1067:(III) with the exception of iron(III)'s preference for
303:
in the periodic table, which are also ferromagnetic at
2338:(1952). "The Structure of Iron Bis-Cyclopentadienyl".
1860:
Mössbauer spectroscopy applied to inorganic chemistry
1315:
Structural formula of ferrocene and a powdered sample
264:
contain both iron(II) and iron(III) centers, such as
1091:
reacts with a phenol to form a deep violet complex:
201:
shows the characteristic chemical properties of the
3528:
3497:
3476:
3388:
3153:
3118:
3097:
2989:
2670:
2650:
2614:
2598:
2527:
2492:
1149:-donor ligands is less marked, so that for example
287:). The latter is used as the traditional "blue" in
1939:. Vol. 6. Cavendish Society. pp. 128–29.
1600:Zeitschrift für Anorganische und Allgemeine Chemie
1063:Iron(III) complexes are quite similar to those of
1008:with its two non-superposable geometries labelled
1357:Iron-centered organometallic species are used as
1262:powder, a highly reactive form of metallic iron.
1246:Another old example of an organoiron compound is
1059:Blood-red positive thiocyanate test for iron(III)
1032:applied in old-style photographic processes. The
974:. Complexes with multiple bidentate ligands have
932:anions are added, which instead results in white
2023:
2021:
2019:
2009:
2007:
2005:
2003:
2001:
1966:
1964:
1962:
1960:
1950:
1948:
1946:
1914:
1912:
1910:
1908:
1467:later shown to be for all these elements) in La
1632:
1630:
1289:contains iron in the rare +1 oxidation state.
2470:
1683:Molecules (M = Fe, Ru, Os, Hs, Sm, and Pu)".
1087:, used to determine the presence of phenols,
534:Hydrated iron(III) chloride (ferric chloride)
8:
1828:
1826:
1824:
1822:
1820:
1818:
1258:molecules. The compound can be used to make
1012:(lambda) for the left-handed screw axis and
3385:
2986:
2611:
2477:
2463:
2455:
1994:https://doi.org/10.1016/j.poly.2013.02.066
546:to give the corresponding hydrated salts.
2434:
2383:
3486:
1598:(AE = Ca, Sr; T = Au, Ag, Hg, Cd, Zn)".
1575:10.1016/j.solidstatesciences.2007.12.001
1424:
1420:
1416:
1412:
1338:
1334:
1330:
1277:
1273:
1168:
1164:
1156:
1152:
993:
923:
919:
878:
865:
861:
851:
847:
830:
826:
822:
812:
808:
789:
785:
775:
771:
758:
754:
456:
452:
434:
430:
283:
279:
275:
18:
2372:European Journal of Inorganic Chemistry
1459:
1981:https://doi.org/10.1002/anie.198907761
2142:Lee, J.; Jung, G.; Lee, S.W. (1998).
1287:Cyclopentadienyliron dicarbonyl dimer
91:Cyclopentadienyliron dicarbonyl dimer
7:
1891:. NMSI Trading Ltd. pp. 11–19.
449:Ferrosoferric or iron(II,III) oxide
2416:Bullock, R.M. (11 September 2007).
2027:Greenwood and Earnshaw, pp. 1091–97
2013:Greenwood and Earnshaw, pp. 1088–91
1970:Greenwood and Earnshaw, pp. 1082–84
1918:Greenwood and Earnshaw, pp. 1075–79
216:Iron forms compounds mainly in the
1004:ligands (shown at right) displays
1000:. The ferrioxalate ion with three
398:media in computers, and pigments.
16:Chemical compounds containing iron
14:
2334:; Rosenblum, M.; Whiting, M. C.;
1835:Lehrbuch der Anorganischen Chemie
228:, "ferric"). Iron also occurs in
2067:hexachloroferrate(III) chloride
1305:
1296:
442:
420:
405:
2406:Greenwood and Earnshaw, p. 1104
1954:Greenwood and Earnshaw, p. 1079
1885:"An introduction in monochrome"
1636:Greenwood and Earnshaw, p. 1070
1624:Greenwood and Earnshaw, p. 905
538:The binary ferrous and ferric
1:
3562:Chemical compounds by element
1862:. Springer. pp. 245–83.
1774:Accounts of Chemical Research
1697:10.1021/acs.inorgchem.6b00442
1283:disodium tetracarbonylferrate
632:standard reduction potentials
352:oxide and hydroxide compounds
124:ferrocenium tetrafluoroborate
43:Disodium tetracarbonylferrate
2368:"Ferrocene – 65 Years After"
2091:10.1016/0020-1693(95)04955-X
1266:of iron pentacarbonyl gives
1228:or "ferric ferrocyanide", Fe
384:non-stoichiometric compounds
689:The red-purple tetrahedral
412:Ferrous or iron(II) oxide,
333:. High purity iron, called
3578:
2119:10.1002/9780470132487.ch19
494:The best known sulfide is
427:Ferric or iron(III) oxide
3389:Organoiron(III) compounds
2366:Okuda, Jun (2016-12-28).
2232:Chemistry of the Elements
2229:; Earnshaw, Alan (1984).
2205:10.1007/s00269-008-0241-7
1651:Chemistry of the Elements
1649:; Earnshaw, Alan (1997).
2990:Organoiron(II) compounds
1196:organometallic compounds
1177:Organometallic compounds
27:Representative compound
2078:Inorganica Chimica Acta
1443:Category:Iron compounds
1243:to form Prussian blue.
1212:half-sandwich compounds
959:of the ferrioxalate ion
566:being the most common.
262:mixed valence compounds
230:higher oxidation states
192:(matrix isolation, 4K)
2436:10.1002/anie.200703053
2385:10.1002/ejic.201601323
2148:Bull. Korean Chem. Soc
1937:Hand-book of chemistry
1724:Phys. Chem. Chem. Phys
1612:10.1002/zaac.200900421
1367:transfer hydrogenation
1268:triiron dodecacarbonyl
1241:potassium ferrocyanide
1237:potassium ferricyanide
1222:
1188:
1118:spectrochemical series
1083:. For example, in the
1060:
1052:
1018:Potassium ferrioxalate
960:
944:Coordination compounds
903:
627:
535:
491:
474:
354:; the most common are
258:Mössbauer spectroscopy
2423:Angew. Chem. Int. Ed.
1655:Butterworth-Heinemann
1647:Greenwood, Norman N.
1220:
1184:
1058:
1050:
954:
897:
621:
533:
485:
469:
346:Oxides and hydroxides
224:, "ferrous") and +3 (
3536:Hemolithin (protein)
2318:10.1039/JR9520000632
2239:. pp. 1282–86.
2227:Greenwood, Norman N.
2184:Phys. Chem. Minerals
1765:Nam, Wonwoo (2007).
1555:Solid State Sciences
1365:, for example, is a
1192:Organoiron chemistry
1085:ferric chloride test
1020:is used in chemical
590:+ 2 Fe (E = +0.23 V)
518:ions in a distorted
45:(Collman's reagent)
2353:10.1021/ja01128a527
2277:1951Natur.168.1039K
2197:2008PCM....35..467E
2053:10.1021/ic50070a047
2040:Inorganic Chemistry
1883:Ware, Mike (1999).
1736:2016PCCP...1831125L
1730:(45): 31125–31131.
1685:Inorganic Chemistry
1567:2008SSSci..10..444K
1024:and along with its
978:. For example, the
606:in the presence of
350:Iron forms various
2160:10.1007/BF02698412
1933:"Mercury and Iron"
1744:10.1039/c6cp06753k
1590:-Type Compounds AE
1399:iron(III) chloride
1248:iron pentacarbonyl
1223:
1204:carbonyl complexes
1189:
1089:iron(III) chloride
1071:-donor instead of
1061:
1053:
961:
934:iron(II) carbonate
904:
628:
614:Solution chemistry
596:iron pentacarbonyl
558:(X = F, Cl, Br, I)
536:
506:containing Fe and
492:
475:
356:iron(II,III) oxide
232:, e.g. the purple
155:iron tetrafluoride
81:Iron pentacarbonyl
3544:
3543:
3472:
3471:
3093:
3092:
2646:
2645:
2341:J. Am. Chem. Soc.
2285:10.1038/1681039b0
2271:(4285): 1039–40.
2246:978-0-08-022057-4
2128:978-0-470-13248-7
1898:978-1-900747-07-3
1869:978-0-306-41647-7
1786:10.1021/ar700027f
1664:978-0-08-037941-8
1323:sandwich compound
1200:cyanide complexes
1006:helical chirality
976:geometric isomers
892:
891:
687:
686:
335:electrolytic iron
331:hydrochloric acid
234:potassium ferrate
203:transition metals
196:
195:
183:Potassium ferrate
3569:
3489:
3464:
3463:
3462:
3454:
3453:
3445:
3444:
3386:
2987:
2612:
2479:
2472:
2465:
2456:
2449:
2448:
2438:
2413:
2407:
2404:
2398:
2397:
2387:
2363:
2357:
2356:
2347:(8): 2125–2126.
2328:
2322:
2321:
2303:
2297:
2296:
2258:
2252:
2250:
2223:
2217:
2216:
2178:
2172:
2171:
2139:
2133:
2132:
2101:
2095:
2094:
2063:
2057:
2056:
2034:
2028:
2025:
2014:
2011:
1996:
1989:
1983:
1977:
1971:
1968:
1955:
1952:
1941:
1940:
1925:
1919:
1916:
1903:
1902:
1880:
1874:
1873:
1855:
1849:
1848:
1830:
1813:
1812:
1810:
1808:
1802:
1796:. Archived from
1771:
1762:
1756:
1755:
1715:
1709:
1708:
1676:
1670:
1668:
1653:(2nd ed.).
1643:
1637:
1634:
1625:
1622:
1616:
1615:
1578:
1464:
1448:Cobalt compounds
1432:
1383:iron(II) sulfate
1341:
1309:
1300:
1280:
1194:is the study of
1172:
1160:
1141:
1140:
1136:
1126:hydrogen cyanide
1038:iron(II) oxalate
996:
965:high-valent iron
927:
900:iron(II) sulfate
882:
876:
875:
872:
855:
834:
816:
793:
779:
766:
765:
762:
743:
742:
741:
732:
731:
730:
721:
719:
718:
708:
707:
706:
672:
671:
670:
637:
636:
517:
516:
515:
471:Pourbaix diagram
459:
446:
437:
424:
415:
409:
396:magnetic storage
341:Binary compounds
305:room temperature
286:
218:oxidation states
174:
173:
172:
152:
151:
150:
142:
141:
72:
71:
70:
62:
61:
19:
3577:
3576:
3572:
3571:
3570:
3568:
3567:
3566:
3547:
3546:
3545:
3540:
3524:
3520:
3512:
3508:
3493:
3488:
3484:
3468:
3461:
3458:
3457:
3456:
3452:
3449:
3448:
3447:
3443:
3440:
3439:
3438:
3436:
3431:
3427:
3423:
3419:
3411:
3407:
3403:
3399:
3384:
3379:
3375:
3371:
3367:
3359:
3355:
3347:
3343:
3339:
3331:
3327:
3319:
3315:
3311:
3303:
3299:
3291:
3287:
3283:
3279:
3271:
3267:
3263:
3255:
3251:
3247:
3243:
3235:
3213:
3205:
3201:
3188:
3180:
3172:
3164:
3149:
3145:
3141:
3133:
3129:
3114:
3089:
3085:
3081:
3077:
3069:
3065:
3061:
3053:
3049:
3045:
3041:
3037:
3033:
3024:
3020:
3016:
3008:
3004:
3000:
2985:
2981:
2977:
2969:
2965:
2961:
2953:
2949:
2945:
2937:
2933:
2929:
2925:
2917:
2913:
2909:
2905:
2897:
2893:
2885:
2877:
2869:
2861:
2857:
2849:
2845:
2837:
2829:
2825:
2821:
2813:
2809:
2801:
2787:
2783:
2779:
2775:
2771:
2763:
2750:
2737:
2729:
2721:
2717:
2709:
2701:
2693:
2689:
2681:
2666:
2661:
2642:
2639:
2635:
2631:
2627:
2610:
2594:
2590:
2586:
2582:
2578:
2574:
2570:
2562:
2558:
2550:
2546:
2538:
2523:
2519:
2515:
2507:
2503:
2488:
2483:
2453:
2452:
2429:(39): 7360–63.
2415:
2414:
2410:
2405:
2401:
2365:
2364:
2360:
2336:Woodward, R. B.
2330:
2329:
2325:
2305:
2304:
2300:
2260:
2259:
2255:
2247:
2225:
2224:
2220:
2180:
2179:
2175:
2141:
2140:
2136:
2129:
2103:
2102:
2098:
2065:
2064:
2060:
2047:(12): 2662–63.
2036:
2035:
2031:
2026:
2017:
2012:
1999:
1990:
1986:
1978:
1974:
1969:
1958:
1953:
1944:
1929:Gmelin, Leopold
1927:
1926:
1922:
1917:
1906:
1899:
1882:
1881:
1877:
1870:
1857:
1856:
1852:
1845:
1832:
1831:
1816:
1806:
1804:
1803:on 15 June 2021
1800:
1769:
1764:
1763:
1759:
1721:
1717:
1716:
1712:
1682:
1678:
1677:
1673:
1665:
1645:
1644:
1640:
1635:
1628:
1623:
1619:
1597:
1593:
1589:
1585:
1580:
1552:
1550:
1546:
1542:
1538:
1534:
1530:
1526:
1523:(structure (AE)
1522:
1518:
1514:
1510:
1506:
1502:
1498:
1494:
1490:
1486:
1482:
1478:
1474:
1470:
1465:
1461:
1456:
1439:
1430:
1426:
1422:
1418:
1414:
1410:
1404:
1394:
1388:
1379:
1377:Industrial uses
1363:Knölker complex
1340:
1336:
1332:
1328:
1319:
1318:
1317:
1316:
1312:
1311:
1310:
1302:
1301:
1279:
1275:
1271:
1256:carbon monoxide
1253:
1234:
1231:
1186:
1179:
1170:
1166:
1162:
1161:is known while
1158:
1154:
1150:
1138:
1134:
1133:
1102:
1098:
995:
987:
946:
938:iron(III) oxide
925:
921:
917:
913:charge transfer
908:iron(III) oxide
880:
873:
870:
869:
867:
863:
859:
853:
849:
845:
832:
828:
824:
820:
814:
810:
806:
791:
787:
783:
777:
773:
769:
760:
756:
752:
747:
740:
738:
737:
736:
734:
729:
727:
726:
725:
723:
717:
714:
713:
712:
710:
705:
702:
701:
700:
698:
679:
669:
666:
665:
664:
662:
616:
604:carbon monoxide
589:
578:(X = F, Cl, Br)
577:
573:
564:ferric chloride
557:
553:
550:Fe + 2 HX → FeX
544:hydrohalic acid
528:
520:sodium chloride
514:
511:
510:
509:
507:
501:
489:
480:
464:
463:
462:
461:
460:
458:
454:
450:
447:
439:
438:
436:
432:
428:
425:
417:
416:
413:
410:
377:
373:
368:iron(III) oxide
365:
361:
348:
343:
285:
281:
277:
273:
251:
247:
243:
239:
171:
168:
167:
166:
164:
149:
146:
145:
144:
140:
137:
136:
135:
133:
120:Ferric chloride
106:Ferrous sulfate
96:
69:
66:
65:
64:
60:
57:
56:
55:
53:
23:
17:
12:
11:
5:
3575:
3573:
3565:
3564:
3559:
3557:Iron compounds
3549:
3548:
3542:
3541:
3539:
3538:
3532:
3530:
3526:
3525:
3523:
3522:
3518:
3514:
3510:
3506:
3501:
3499:
3495:
3494:
3492:
3491:
3480:
3478:
3474:
3473:
3470:
3469:
3467:
3466:
3459:
3450:
3441:
3433:
3429:
3425:
3421:
3417:
3413:
3409:
3405:
3401:
3397:
3392:
3390:
3383:
3382:
3377:
3373:
3369:
3365:
3361:
3357:
3353:
3349:
3345:
3341:
3337:
3333:
3329:
3325:
3321:
3317:
3313:
3309:
3305:
3301:
3297:
3293:
3289:
3285:
3281:
3277:
3273:
3269:
3265:
3261:
3257:
3253:
3249:
3245:
3241:
3237:
3233:
3229:
3224:
3220:
3215:
3211:
3207:
3203:
3199:
3195:
3190:
3186:
3182:
3178:
3174:
3170:
3166:
3162:
3157:
3155:
3151:
3150:
3148:
3147:
3143:
3139:
3135:
3131:
3127:
3122:
3120:
3116:
3115:
3113:
3112:
3107:
3101:
3099:
3095:
3094:
3091:
3090:
3088:
3087:
3083:
3079:
3075:
3071:
3067:
3063:
3059:
3055:
3051:
3047:
3043:
3039:
3035:
3031:
3027:
3022:
3018:
3014:
3010:
3006:
3002:
2998:
2993:
2991:
2984:
2983:
2979:
2975:
2971:
2967:
2963:
2959:
2955:
2951:
2947:
2943:
2939:
2935:
2931:
2927:
2923:
2919:
2915:
2911:
2907:
2903:
2899:
2895:
2891:
2887:
2883:
2879:
2875:
2871:
2867:
2863:
2859:
2855:
2851:
2847:
2843:
2839:
2835:
2831:
2827:
2823:
2819:
2815:
2811:
2807:
2803:
2799:
2795:
2790:
2785:
2781:
2777:
2773:
2769:
2765:
2761:
2757:
2752:
2748:
2744:
2739:
2735:
2731:
2727:
2723:
2719:
2715:
2711:
2707:
2703:
2699:
2695:
2691:
2687:
2683:
2679:
2674:
2672:
2668:
2667:
2665:
2664:
2659:
2654:
2652:
2648:
2647:
2644:
2643:
2641:
2637:
2633:
2629:
2625:
2621:
2619:
2609:
2608:
2602:
2600:
2596:
2595:
2593:
2592:
2588:
2584:
2580:
2576:
2572:
2568:
2564:
2560:
2556:
2552:
2548:
2544:
2540:
2536:
2531:
2529:
2525:
2524:
2522:
2521:
2517:
2513:
2509:
2505:
2501:
2496:
2494:
2490:
2489:
2486:Iron compounds
2484:
2482:
2481:
2474:
2467:
2459:
2451:
2450:
2408:
2399:
2378:(2): 217–219.
2358:
2323:
2298:
2253:
2245:
2237:Pergamon Press
2218:
2173:
2134:
2127:
2096:
2058:
2029:
2015:
1997:
1984:
1972:
1956:
1942:
1920:
1904:
1897:
1875:
1868:
1850:
1843:
1814:
1780:(7): 522–531.
1757:
1719:
1710:
1691:(9): 4616–25.
1680:
1671:
1663:
1638:
1626:
1617:
1595:
1591:
1587:
1583:
1561:(4): 444–449.
1548:
1544:
1540:
1536:
1532:
1528:
1527:(T–T)T⋅4e), Yb
1524:
1520:
1516:
1512:
1508:
1504:
1500:
1496:
1492:
1488:
1484:
1480:
1476:
1472:
1468:
1458:
1457:
1455:
1452:
1451:
1450:
1445:
1438:
1435:
1428:
1402:
1392:
1386:
1378:
1375:
1314:
1313:
1304:
1303:
1295:
1294:
1293:
1292:
1291:
1251:
1232:
1229:
1178:
1175:
1109:
1108:
1103:+ 3 HCl (Ar =
1100:
1096:
1030:photoreduction
945:
942:
890:
889:
883:
856:
842:
841:
835:
817:
803:
802:
794:
780:
749:
748:
745:
739:
728:
715:
703:
685:
684:
681:
677:
674:
667:
659:
658:
655:
652:
648:
647:
644:
641:
615:
612:
592:
591:
587:
586:2 I + 2 Fe → I
580:
579:
575:
571:
560:
559:
555:
551:
527:
524:
512:
499:
487:
479:
476:
448:
441:
440:
426:
419:
418:
411:
404:
403:
402:
401:
400:
380:Iron(II) oxide
375:
371:
363:
359:
347:
344:
342:
339:
249:
245:
241:
237:
194:
193:
190:
186:
185:
180:
176:
175:
169:
162:
158:
157:
147:
138:
131:
127:
126:
117:
113:
112:
103:
99:
98:
94:
88:
84:
83:
78:
74:
73:
67:
58:
51:
47:
46:
40:
36:
35:
33:
29:
28:
25:
15:
13:
10:
9:
6:
4:
3:
2:
3574:
3563:
3560:
3558:
3555:
3554:
3552:
3537:
3534:
3533:
3531:
3527:
3521:
3515:
3513:
3503:
3502:
3500:
3496:
3490:
3482:
3481:
3479:
3475:
3465:
3434:
3432:
3414:
3412:
3394:
3393:
3391:
3387:
3381:
3362:
3360:
3350:
3348:
3334:
3332:
3322:
3320:
3306:
3304:
3294:
3292:
3274:
3272:
3258:
3256:
3238:
3236:
3230:
3228:
3225:
3223:
3221:
3219:
3216:
3214:
3208:
3206:
3196:
3194:
3191:
3189:
3183:
3181:
3175:
3173:
3167:
3165:
3159:
3158:
3156:
3152:
3146:
3136:
3134:
3124:
3123:
3121:
3117:
3111:
3108:
3106:
3103:
3102:
3100:
3096:
3086:
3072:
3070:
3056:
3054:
3028:
3026:
3011:
3009:
2995:
2994:
2992:
2988:
2982:
2972:
2970:
2956:
2954:
2940:
2938:
2920:
2918:
2900:
2898:
2888:
2886:
2880:
2878:
2872:
2870:
2864:
2862:
2852:
2850:
2840:
2838:
2832:
2830:
2816:
2814:
2804:
2802:
2796:
2794:
2791:
2789:
2766:
2764:
2758:
2756:
2753:
2751:
2745:
2743:
2740:
2738:
2732:
2730:
2724:
2722:
2712:
2710:
2704:
2702:
2696:
2694:
2684:
2682:
2676:
2675:
2673:
2669:
2663:
2656:
2655:
2653:
2649:
2640:
2622:
2620:
2618:(I) compounds
2617:
2613:
2607:
2604:
2603:
2601:
2597:
2591:
2565:
2563:
2553:
2551:
2541:
2539:
2533:
2532:
2530:
2526:
2520:
2510:
2508:
2498:
2497:
2495:
2491:
2487:
2480:
2475:
2473:
2468:
2466:
2461:
2460:
2457:
2446:
2442:
2437:
2432:
2428:
2425:
2424:
2419:
2412:
2409:
2403:
2400:
2395:
2391:
2386:
2381:
2377:
2373:
2369:
2362:
2359:
2354:
2350:
2346:
2343:
2342:
2337:
2333:
2332:Wilkinson, G.
2327:
2324:
2319:
2315:
2311:
2310:
2309:J. Chem. Soc.
2302:
2299:
2294:
2290:
2286:
2282:
2278:
2274:
2270:
2266:
2265:
2257:
2254:
2248:
2242:
2238:
2234:
2233:
2228:
2222:
2219:
2214:
2210:
2206:
2202:
2198:
2194:
2191:(8): 467–75.
2190:
2186:
2185:
2177:
2174:
2169:
2165:
2161:
2157:
2154:(2): 267–69.
2153:
2149:
2145:
2138:
2135:
2130:
2124:
2120:
2116:
2112:
2109:
2108:
2107:Inorg. Synth.
2100:
2097:
2092:
2088:
2085:(2): 169–74.
2084:
2080:
2079:
2074:
2070:
2062:
2059:
2054:
2050:
2046:
2042:
2041:
2033:
2030:
2024:
2022:
2020:
2016:
2010:
2008:
2006:
2004:
2002:
1998:
1995:
1988:
1985:
1982:
1976:
1973:
1967:
1965:
1963:
1961:
1957:
1951:
1949:
1947:
1943:
1938:
1934:
1930:
1924:
1921:
1915:
1913:
1911:
1909:
1905:
1900:
1894:
1890:
1886:
1879:
1876:
1871:
1865:
1861:
1854:
1851:
1846:
1844:3-11-007511-3
1840:
1836:
1829:
1827:
1825:
1823:
1821:
1819:
1815:
1799:
1795:
1791:
1787:
1783:
1779:
1775:
1768:
1761:
1758:
1753:
1749:
1745:
1741:
1737:
1733:
1729:
1725:
1714:
1711:
1706:
1702:
1698:
1694:
1690:
1686:
1675:
1672:
1666:
1660:
1656:
1652:
1648:
1642:
1639:
1633:
1631:
1627:
1621:
1618:
1613:
1609:
1605:
1601:
1576:
1572:
1568:
1564:
1560:
1556:
1463:
1460:
1453:
1449:
1446:
1444:
1441:
1440:
1436:
1434:
1408:
1400:
1396:
1384:
1376:
1374:
1372:
1369:catalyst for
1368:
1364:
1360:
1355:
1353:
1349:
1345:
1327:
1324:
1308:
1299:
1290:
1288:
1284:
1269:
1265:
1261:
1260:carbonyl iron
1257:
1249:
1244:
1242:
1238:
1227:
1226:Prussian blue
1221:Prussian blue
1219:
1215:
1213:
1209:
1205:
1201:
1197:
1193:
1183:
1176:
1174:
1148:
1143:
1131:
1127:
1123:
1119:
1115:
1106:
1095:3 ArOH + FeCl
1094:
1093:
1092:
1090:
1086:
1082:
1078:
1074:
1070:
1066:
1057:
1049:
1045:
1043:
1039:
1035:
1031:
1027:
1023:
1019:
1015:
1011:
1007:
1003:
999:
991:
985:
981:
977:
973:
970:
966:
958:
957:enantiomorphs
953:
949:
943:
941:
939:
935:
931:
914:
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901:
896:
887:
884:
857:
844:
843:
839:
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805:
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799:
795:
781:
768:
767:
764:
696:
695:
694:
692:
682:
675:
661:
660:
657:E = −0.037 V
656:
653:
650:
649:
646:E = −0.447 V
645:
642:
639:
638:
635:
633:
625:
620:
613:
611:
609:
605:
601:
597:
585:
584:
583:
569:
568:
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549:
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541:
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338:
336:
332:
328:
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319:
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310:
306:
302:
298:
292:
290:
271:
270:Prussian blue
267:
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255:
235:
231:
227:
223:
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211:configuration
208:
204:
200:
191:
188:
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163:
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156:
132:
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118:
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114:
111:
107:
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100:
92:
89:
86:
85:
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79:
76:
75:
52:
49:
48:
44:
41:
38:
37:
34:
31:
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26:
21:
20:
2485:
2426:
2421:
2411:
2402:
2375:
2371:
2361:
2344:
2339:
2326:
2307:
2301:
2268:
2262:
2256:
2231:
2221:
2188:
2182:
2176:
2151:
2147:
2137:
2110:
2105:
2099:
2082:
2076:
2072:
2068:
2061:
2044:
2038:
2032:
1987:
1975:
1936:
1923:
1888:
1878:
1859:
1853:
1834:
1805:. Retrieved
1798:the original
1777:
1773:
1760:
1727:
1723:
1713:
1688:
1684:
1674:
1650:
1641:
1620:
1606:(1): 36–40.
1603:
1599:
1558:
1554:
1462:
1380:
1356:
1320:
1245:
1224:
1190:
1146:
1144:
1110:
1072:
1068:
1062:
1013:
1009:
979:
962:
947:
905:
902:heptahydrate
888:= 10 mol dm
885:
840:= 10 mol dm
837:
801:= 10 mol dm
796:
750:
688:
683:E = +2.20 V
629:
624:permanganate
593:
581:
561:
537:
493:
349:
320:
313:
293:
215:
197:
2312:: 632–635.
1807:22 February
1407:Mohr's salt
1264:Thermolysis
1185:Iron penta-
1130:spin states
1114:Thiocyanate
1026:sodium salt
1022:actinometry
898:Blue-green
673:+ 8 H + 3 e
522:structure.
504:polysulfide
486:Pyrite (FeS
327:nitric acid
278:(Fe[CN]
3551:Categories
3119:Fe(II,III)
2616:Organoiron
2235:. Oxford:
1669:(p. 1074).
1454:References
1163:[Fe(NH
1151:[Fe(NH
1028:undergoes
846:2[Fe(H
676:⇌ Fe + 4 H
570:2 Fe + 3 X
323:pyrophoric
309:iron triad
289:blueprints
254:organoiron
22:Oxidation
3529:Purported
3098:Fe(0,III)
2394:1434-1948
2113:: 69–72.
1359:catalysts
1348:Wilkinson
1326:ferrocene
1099:→ Fe(OAr)
1042:polymeric
1034:dihydrate
930:carbonate
918:[Fe(H
877:+ 2H + 2H
860:[Fe(H
821:[Fe(H
807:[Fe(H
792:(OH)] + H
784:[Fe(H
770:[Fe(H
753:[Fe(H
394:, useful
266:magnetite
226:iron(III)
207:ferrocene
134:Fe(diars)
110:ferrocene
3428:⋅xFe⋅yNH
3210:Fe(acac)
2651:Fe(0,II)
2445:17847139
2213:98739882
2168:35665289
1931:(1852).
1794:17469792
1752:27812577
1705:27074099
1543:, and Ca
1437:See also
1427:·6H
1344:Woodward
1250:, Fe(CO)
1208:sandwich
1187:carbonyl
1120:such as
1065:chromium
955:The two
651:Fe + 3 e
640:Fe + 2 e
478:Sulfides
392:ferrites
388:bloomery
222:iron(II)
3227:FeO(OH)
3154:Fe(III)
2493:Fe(-II)
2293:4181383
2273:Bibcode
2193:Bibcode
1732:Bibcode
1563:Bibcode
1371:ketones
1352:Fischer
1137:⁄
1122:cyanide
1077:phenols
1002:oxalate
691:ferrate
626:(right)
574:→ 2 FeX
540:halides
526:Halides
473:of iron
366:), and
316:mercury
260:. Many
32:−4 (ds)
3498:Fe(VI)
3477:Fe(IV)
3082:Fe(CO)
3066:Fe(CO)
2747:Fe(OH)
2714:Fe(ClO
2671:Fe(II)
2567:Fe(CO)
2535:Fe(CO)
2516:Fe(CO)
2504:Fe(CO)
2443:
2392:
2291:
2264:Nature
2243:
2211:
2166:
2125:
1895:
1866:
1841:
1792:
1750:
1703:
1661:
1483:In, Ca
1475:In, La
1397:) and
1361:. The
1040:has a
998:moiety
608:hexane
600:iodine
496:pyrite
301:nickel
297:cobalt
189:7 (d)
50:−1 (d)
39:−2 (d)
3517:BaFeO
3368:Fe(SO
3218:FeOCl
3198:Fe(NO
3021:)(CO)
2874:FeTiO
2866:FeMoO
2842:Fe(BF
2806:Fe(NO
2798:FeSeO
2776:Fe(SO
2632:FeCO)
2599:Fe(I)
2528:Fe(0)
2289:S2CID
2209:S2CID
2164:S2CID
1801:(PDF)
1770:(PDF)
1419:Fe(SO
1401:(FeCl
1385:(FeSO
1081:enols
980:trans
868:(OH)]
833:] + H
815:(OH)]
744:+ 3 O
733:+ 20
709:+ 10
598:with
179:6 (d)
161:5 (d)
130:4 (d)
116:3 (d)
102:2 (d)
87:1 (d)
77:0 (d)
24:state
3396:Fe(C
3376:·12H
3352:Fe(N
3312:(SeO
3264:(CrO
3232:FePO
3177:FeCl
3169:FeBr
3110:FeGe
3105:FeSi
3030:Fe(C
3013:Fe(C
2997:Fe(C
2978:(CO)
2922:Fe(C
2902:Fe(C
2882:FeCO
2854:FeCr
2834:FeSi
2793:FeSe
2760:FeSO
2726:FeBr
2706:FeCl
2636:(CO)
2559:(CO)
2547:(CO)
2441:PMID
2390:ISSN
2376:2017
2241:ISBN
2123:ISBN
2073:(II)
1893:ISBN
1864:ISBN
1839:ISBN
1809:2022
1790:PMID
1748:PMID
1701:PMID
1659:ISBN
1579:and
1535:, Ca
1515:, Ca
1507:, Sr
1499:, Ca
1491:, Ca
1350:and
1346:and
1329:Fe(C
1276:(CO)
1239:and
1210:and
1105:aryl
990:dppe
969:salt
829:(OH)
722:→ 4
654:⇌ Fe
643:⇌ Fe
630:The
602:and
498:(FeS
299:and
268:and
220:+2 (
199:Iron
93:("Fp
63:(CO)
3509:FeO
3485:FeF
3455:FeO
3451:105
3340:(SO
3193:FeP
3185:FeF
3161:FeI
3038:P(C
2974:FeI
2958:FeC
2942:FeC
2890:FeC
2822:(PO
2784:·6H
2768:(NH
2755:FeS
2742:FeO
2734:FeI
2698:FeF
2690:FeH
2678:FeH
2606:FeH
2575:COC
2431:doi
2380:doi
2349:doi
2314:doi
2281:doi
2269:168
2201:doi
2156:doi
2115:doi
2087:doi
2083:247
2075:".
2069:(I)
2049:doi
1782:doi
1740:doi
1722:".
1693:doi
1608:doi
1604:636
1571:doi
1411:(NH
1079:or
1036:of
988:Fe(
699:FeO
663:FeO
554:+ H
414:FeO
378:).
370:(Fe
358:(Fe
240:FeO
165:FeO
97:")
3553::
3442:54
3408:BF
3364:NH
3336:Fe
3324:Fe
3308:Fe
3296:Fe
3280:(C
3276:Fe
3260:Fe
3244:(P
3240:Fe
3138:Fe
3126:Fe
2968:14
2964:22
2960:12
2818:Fe
2686:Mg
2658:Fe
2624:(C
2571:CH
2561:12
2555:Fe
2543:Fe
2512:Na
2439:.
2427:46
2420:.
2388:.
2374:.
2370:.
2345:74
2287:.
2279:.
2267:.
2207:.
2199:.
2189:35
2187:.
2162:.
2152:19
2150:.
2146:.
2121:.
2111:17
2081:.
2043:.
2018:^
2000:^
1959:^
1945:^
1935:.
1907:^
1887:.
1817:^
1788:.
1778:40
1776:.
1772:.
1746:.
1738:.
1728:18
1726:.
1699:.
1689:55
1687:.
1657:.
1629:^
1602:.
1582:Cr
1569:.
1559:10
1557:.
1547:Hg
1539:Au
1531:Ag
1519:Zn
1511:Cd
1503:Hg
1495:Ag
1487:Au
1479:Cu
1471:Pt
1389:·7
1373:.
1278:12
1272:Fe
1270:,
1214:.
1206:,
1202:,
922:O)
871:4+
864:O)
858:⇌
850:O)
825:O)
819:⇌
811:O)
788:O)
782:⇌
774:O)
757:O)
735:OH
724:Fe
697:4
451:Fe
429:Fe
311:.
291:.
274:Fe
236:(K
153:,
143:Cl
122:,
108:,
54:Fe
3519:4
3511:4
3507:2
3505:K
3487:4
3460:6
3446:H
3437:C
3430:3
3426:7
3424:O
3422:8
3420:H
3418:6
3416:C
3410:4
3406:2
3404:)
3402:5
3400:H
3398:5
3380:O
3378:2
3374:2
3372:)
3370:4
3366:4
3358:3
3356:)
3354:3
3346:3
3344:)
3342:4
3338:2
3330:3
3328:S
3326:2
3318:3
3316:)
3314:3
3310:2
3302:3
3300:O
3298:2
3290:3
3288:)
3286:4
3284:O
3282:2
3278:2
3270:3
3268:)
3266:4
3262:2
3254:3
3252:)
3250:7
3248:O
3246:2
3242:4
3234:4
3212:3
3204:3
3202:)
3200:3
3187:3
3179:3
3171:3
3163:3
3144:4
3142:S
3140:3
3132:4
3130:O
3128:3
3084:3
3080:6
3078:H
3076:4
3074:C
3068:3
3064:4
3062:H
3060:4
3058:C
3052:2
3050:)
3048:2
3046:)
3044:5
3042:H
3040:6
3036:4
3034:H
3032:5
3025:I
3023:2
3019:5
3017:H
3015:5
3007:2
3005:)
3003:5
3001:H
2999:5
2980:4
2976:2
2966:O
2962:H
2952:7
2950:O
2948:6
2946:H
2944:6
2936:2
2934:)
2932:3
2930:O
2928:5
2926:H
2924:3
2916:2
2914:)
2912:2
2910:O
2908:3
2906:H
2904:2
2896:4
2894:O
2892:2
2884:3
2876:3
2868:4
2860:4
2858:O
2856:2
2848:2
2846:)
2844:4
2836:2
2828:2
2826:)
2824:4
2820:3
2812:2
2810:)
2808:3
2800:4
2788:O
2786:2
2782:2
2780:)
2778:4
2774:2
2772:)
2770:4
2762:4
2749:2
2736:2
2728:2
2720:2
2718:)
2716:4
2708:2
2700:2
2692:6
2688:2
2680:2
2662:C
2660:3
2638:2
2634:2
2630:5
2628:H
2626:5
2589:6
2587:H
2585:6
2583:C
2581:2
2579:H
2577:2
2573:3
2569:3
2557:3
2549:9
2545:2
2537:5
2518:4
2514:2
2506:4
2502:2
2500:H
2478:e
2471:t
2464:v
2447:.
2433::
2396:.
2382::
2355:.
2351::
2320:.
2316::
2295:.
2283::
2275::
2251:.
2249:.
2215:.
2203::
2195::
2170:.
2158::
2131:.
2117::
2093:.
2089::
2055:.
2051::
2045:7
1901:.
1872:.
1847:.
1811:.
1784::
1754:.
1742::
1734::
1720:4
1707:.
1695::
1681:4
1667:.
1614:.
1610::
1596:3
1594:T
1592:5
1588:3
1586:B
1584:5
1577:.
1573::
1565::
1549:2
1545:3
1541:4
1537:5
1533:2
1529:3
1525:5
1521:3
1517:5
1513:3
1509:5
1505:3
1501:5
1497:3
1493:5
1489:3
1485:5
1481:2
1477:2
1473:2
1469:2
1431:O
1429:2
1425:2
1423:)
1421:4
1417:2
1415:)
1413:4
1409:(
1403:3
1395:O
1393:2
1391:H
1387:4
1339:2
1337:)
1335:5
1333:H
1331:5
1274:3
1252:5
1233:3
1230:4
1171:]
1169:6
1167:)
1165:3
1159:]
1157:6
1155:)
1153:3
1147:O
1139:2
1135:5
1107:)
1101:3
1097:3
1073:N
1069:O
1014:Δ
1010:Λ
994:2
992:)
982:-
926:]
924:6
920:2
886:K
881:O
879:2
874:2
866:4
862:2
854:]
852:6
848:2
838:K
831:2
827:4
823:2
813:5
809:2
798:K
790:5
786:2
778:]
776:6
772:2
761:]
759:6
755:2
746:2
720:O
716:2
711:H
704:4
680:O
678:2
668:4
588:2
576:3
572:2
556:2
552:2
513:2
508:S
500:2
490:)
488:2
457:4
455:O
453:3
435:3
433:O
431:2
376:3
374:O
372:2
364:4
362:O
360:3
284:3
282:)
280:6
276:4
272:(
250:2
246:4
242:4
238:2
170:4
148:2
139:2
95:2
68:8
59:2
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