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It must be stressed that standard reduction potentials are not additive values. They cannot be directly summed up, or subtracted, from the values in volt indicated in a
Latimer diagram. If needed, their calculation must be performed via the difference in Gibbs free energies. The easiest way to
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and the sign minus simplifies on both side of the equation. So, the values of E in volt must be simply multiplied by the number (n) of electron transferred in the considered half-reaction. Since the
Faraday constant can disappear from the equation, no need to calculate
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in solution under the conditions for which the electrode potentials are given: if the potential to the right of the species is higher than the potential on the left, it will disproportionate. Therefore,
188:, the electrode potential is a representation of the Gibbs energy change for the given reduction. The sum of the Gibbs energy changes for subsequent reductions (e.g. from O
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Atkins, Peter; Overton, Tina (2010). "5. Oxidation and
Reduction: The diagrammatic presentation of potential data ยง5.12 Latimer diagrams".
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224:. This can be used to find the electrode potential for non-adjacent species, which gives all the information necessary for the
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to the right side. The species are connected by arrows, and the numerical value of the standard potential (in
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O) is the same as the Gibbs energy change for the overall reduction (i.e. from O
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A simple examination of a
Latimer diagram can also indicate if a species will
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Representation of the standard electrode potential data of an element
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proceed is simply to use energies (nE) directly expressed in
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of the element is on the left side, with successively lower
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reactions are shown in the direction of reduction (gain of
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data of that element. This type of diagram is named after
344:"ยง1.3 Some Uses of Standard Potentials: Latimer Diagrams"
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has a value +0.68 V over it, it indicates that the
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Latimer diagrams can be used in the construction of
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54:In a Latimer diagram, because by convention
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324:Shriver and Atkins' Inorganic Chemistry
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236:(eV), because the Faraday constant
389:. You can help Knowledge (XXG) by
46:(1893โ1955), an American chemist.
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327:. OUP Oxford. pp. 162โ163.
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130:standard electrode potential
40:standard electrode potential
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350:. Springer. p. 18.
144:) + 2 H + 2
44:Wendell Mitchell Latimer
220:O), in accordance with
446:Electrochemistry stubs
385:-related article is a
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342:Rieger, P.H. (1993).
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249:expressed in joule.
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308:Ellingham diagram
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292:See also
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182:G = -n
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