136:). The main drawback of pentacene OFET is degradation upon exposure to light and air. On the other hand, phenacenes, an isomeric form of acenes, has been known as a stable compound in which the benzene rings are fused in a zigzag structure. For the past several years, there is renewed interest in synthesis of phenacene derivatives associated with electronic applications in emissive and semi- or superconducting materials.
65:
82:
111:
97:
281:
Ionkin, A. S.; Marshall, W. J.; Fish, B. M.; Bryman, L. M.; Wang, Y. (2008). "A tetra-substituted chrysene: orientation of multiple electrophilic substitution and use of a tetra-substituted chrysene as a blue emitter for OLEDs".
308:
Mitsuhashi, R.; Suzuki, Y.; Yamanari, Y.; Mitamura, H.; Kambe, T.; Ikeda, N.; Okamoto, H.; Fujiwara, A.; Yamaji, M.; Kawasaki, N.; Maniwa, Y.; Kubozono, Y. (2010). "Superconductivity in alkali-metal-doped picene".
246:
Komura, N.; Goto, H.; He, X.; Mitamura, H.; Eguchi, R.; Kaji, Y.; Okamoto, H.; Sugawara, Y.; Gohda, S.; Sato, K.; Kubozono, Y. (2012). "Characteristics of phenacene thin film field-effect transistor".
157: ā 18 K. Thus, phenacenes and their derivatives may play an important role in future fabrication of stable and high-performance electronic devices such as OFET,
146:Ī¼ = 5 cm/(Vā
s). Phenacene FET shows Ī¼ = 0.75 cm/(Vā
s) and no sensitivity to air. Furthermore, picene doped with potassium and rubidium exhibit
352:
Okamoto, H.; Kawasaki, N.; Kaji, Y.; Kubozono, Y.; Fujiwara, A.; Yamaji, M. (2008). "Air-assisted high-performance field-effect transistor with thin films of picene".
837:
430:
133:
27:
421:
132:. Of academic interest, pentacene has been widely used as an active layer in organic thin-film field-effect transistors (
739:
124:
Aromatic compounds with extended Ļ-conjugated system have attracted attention because of their potential use in
572:
142:(phenacene) can serve as an active layer of a high-performance p-channel organic thin-film FET with very high
633:
628:
143:
129:
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125:
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23:
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775:
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582:
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223:
182:
831:
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720:
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399:
64:
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679:
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454:
81:
623:
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480:
214:
806:
801:
730:
638:
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232:
811:
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58:
35:
330:
110:
96:
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365:
267:
648:
541:
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139:
75:
796:
31:
158:
403:
38:
from which they differ by the arrangement of the fused rings.
183:"Organic semiconductors for organic field-effect transistors"
165:. Substituted picenes may serve as an active layer of OFETs.
789:
708:
662:
565:
504:
463:
437:
26:consisting of fused aromatic rings. They are
415:
8:
303:
301:
187:Science and Technology of Advanced Materials
422:
408:
400:
222:
120:Relevance to organic electronic materials
40:
173:
7:
386:Nakano, Y.; Saito, M.; Nakamura, H.
150:with a maximum critical temperature
14:
838:Polycyclic aromatic hydrocarbons
431:Polycyclic aromatic hydrocarbons
109:
95:
80:
63:
28:polycyclic aromatic hydrocarbons
1:
207:10.1088/1468-6996/10/2/024313
181:Yamashita, Yoshiro (2009).
16:Group of chemical compounds
854:
388:WO 2010016511 A1 20100211
597:-Benzopyrene(Olympicene)
130:organic semiconductors
573:Benzacephenanthrylene
144:field-effect mobility
557:Tricyclobutabenzene
360:(32): 10470ā10471.
331:10.1038/nature08859
323:2010Natur.464...76M
260:2012ApPhL.101h3301K
199:2009STAdM..10b4313Y
163:organic solar cells
126:organic electronics
825:
824:
736:Hexabenzocoronene
619:Benzofluoranthene
614:Benzofluoranthene
609:Benzofluoranthene
604:Benzofluoranthene
527:Benzophenanthrene
366:10.1021/ja803291a
268:10.1063/1.4747201
148:superconductivity
117:
116:
24:organic compounds
845:
726:Diindenoperylene
634:Dibenzanthracene
629:Dibenzanthracene
624:trans-Bicalicene
424:
417:
410:
401:
395:
389:
384:
378:
377:
354:J. Am. Chem. Soc
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343:
342:
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292:10.1039/b715386d
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248:Appl. Phys. Lett
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113:
99:
84:
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41:
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848:
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828:
827:
826:
821:
790:General classes
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704:
658:
561:
500:
459:
433:
428:
398:
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351:
350:
346:
317:(7285): 76ā79.
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306:
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22:are a class of
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12:
11:
5:
851:
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823:
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820:
819:
814:
809:
804:
799:
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786:
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776:Trinaphthylene
773:
771:Superphenalene
768:
763:
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753:
748:
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733:
728:
723:
718:
712:
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685:Dibenzopyrenes
682:
677:
672:
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664:
660:
659:
657:
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654:Tetraphenylene
651:
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631:
626:
621:
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569:
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512:Benzanthracene
508:
506:
502:
501:
499:
498:
493:
488:
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478:
476:Acenaphthylene
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344:
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121:
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107:
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100:
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78:
73:
69:
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61:
56:
52:
51:
48:
45:
15:
13:
10:
9:
6:
4:
3:
2:
850:
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749:
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724:
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719:
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707:
701:
698:
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693:
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688:
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681:
678:
676:
675:Benzoperylene
673:
671:
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558:
555:
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550:
548:
545:
543:
540:
538:
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530:
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523:
522:Benzofluorene
520:
518:
517:Benzofluorene
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509:
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503:
497:
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284:Chem. Commun.
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254:(8): 083301.
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200:
196:
193:(2): 024313.
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137:
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30:, related to
29:
25:
21:
816:
721:Dicoronylene
670:Anthanthrene
594:
552:Triphenylene
537:Fluoranthene
496:Phenanthrene
471:Acenaphthene
391:
382:
357:
353:
347:
314:
310:
286:(20): 2319.
283:
276:
251:
247:
241:
190:
186:
176:
151:
138:
123:
47:Common name
19:
18:
695:Triangulene
680:Corannulene
588:Benzopyrene
583:Benzopyrene
578:Benzopyrene
455:Naphthalene
740:Hexa-cata-
481:Anthracene
169:References
104:phenacene
92:Fulminene
89:phenacene
72:phenacene
55:phenacene
50:Structure
44:Phenacene
20:Phenacenes
817:Phenacene
807:Cyclacene
802:Circulene
731:Heptacene
639:Pentacene
547:Tetracene
491:Phenalene
215:1468-6996
36:helicenes
832:Category
812:Helicene
766:Sumanene
756:Rubicene
746:Kekulene
716:Coronene
709:7+ rings
700:Zethrene
690:Hexacene
644:Perylene
532:Chrysene
486:Fluorene
445:Butalene
374:18627146
339:20203605
233:27877286
59:Chrysene
781:Truxene
761:Rubrene
751:Ovalene
663:6 rings
566:5 rings
505:4 rings
464:3 rings
450:Azulene
438:2 rings
319:Bibcode
256:Bibcode
224:5090443
195:Bibcode
649:Picene
542:Pyrene
372:
337:
311:Nature
231:
221:
213:
140:Picene
76:Picene
32:acenes
797:Acene
392:2010
370:PMID
335:PMID
229:PMID
211:ISSN
161:and
159:OLED
134:OFET
34:and
362:doi
358:130
327:doi
315:464
288:doi
264:doi
252:101
219:PMC
203:doi
128:as
834::
390:,
368:.
356:.
333:.
325:.
313:.
300:^
262:.
250:.
227:.
217:.
209:.
201:.
191:10
189:.
185:.
742:)
738:(
595:H
593:6
423:e
416:t
409:v
394:.
376:.
364::
341:.
329::
321::
294:.
290::
270:.
266::
258::
235:.
205::
197::
155:C
152:T
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