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Kirk-Othmer encyclopedia on polyethers (doi 10.1002/0471238961.0118151323080920.a01): "The first aromatic sulfone polymer produced commercially was introduced as
Bakelite polysulfone ...under the trade name Udel. .. made by reaction of the disodium salt of bisphenol A (BPA) with 4,4′-dichlorodiphenyl
2350:
Thanks. Knowledge's willingness to use 'ppm' as a unit is a pet peeve of mine; probably somewhere between meaningless and uninterpretable for novice readers - in this case it also focuses attention on the smallness of the solubility, rather than the utter enormity of available solvent. I'd never
2351:
really thought of it as a green process but you are absolutely right, edits made to that effect. I did look at oxidation but I couldn't find a solid source and gave in, I suspect it biodegrades faster than any abiotic process. I expect photoxidation to be a path. I'll look again. --
2366:
There appears to be no properties section. melting, boiling solubility and flash are in the chembox. But two have no references. Solubility in other solvents may be significant. Also available is the crystal structure. I would guess spectrum info is also available, IR, MR.
2603:"In the industrial process, bisphenol A is always produced (Scheme 4) together with sizable quantities of o,p‘-bisphenol A (o,p‘-BPA/BPA molar ratios up to 1:2)"! The latter surprised me but makes sense. Apparently methods exist to reverse the o,p' stuff into isoprop
2084:
Yes, I agree with the gallery change, but I still have a feeling that a duplicate picture feels strange. Maybe put another picture with a caption, then add the information you added in the caption of the duplicate picture in the text, then remove the picture.
2222:
I've started responding to these comments on the same line you've written them, my additions in italics. Not the normal way of replying to things, but it might help to keep track of each point. If it's an issue I can revert my comments and try another way.
455:
1164:. I have not reviewed all of the sources, but from what I can see most look like review articles. Here are a few that may be primary research studies. I have not reviewed where these occur in the text, for example to see if they are appropriate or not.
2402:
I think I've addressed most of the comments raised so far. Outstanding are references for the density and water solubility in the chembox and a mechanism for abiotic decomposition. I'll continue to look for these. Additionally, this paper
2318:
C + water. And apparently very generalizable (all kinds of phenols and carbonyls), which is very cool. Its difficult to beat the price of acetone. Also, for chemists, the prep is cute because phenol and acetone are coproduced by the
2673:
Density of BPA from X-ray crystallography is 1.217 g/cm3 according to doi 10.1007/s10870-007-9207-8. Other details according to
Cambridge Xray database (to the extent that structures are reported to or collected by the database):
2465:
Secondary refs query list: I've addresses the points at that section. About half the questioned refs have been deleted. The others are either fine or have been reinforced. I remain unsure about the ERRγ binding study
1803:
Not to worry. I've also become derailed by real life, and probably wont be able to finish the next round of edits until next week. I'm still going to try and finish this process; I feel like it's close to the end.
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Would be nice to know: to what does BPA degrade? It is popular and to some, heartwarming, that pollutants are degraded by organisms, but my guess is that at neutral pH in air, BPA undergoes some sort of
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2707:
Thanks. I think the crystal structure is of limited interest, even to professional chemists. Its not a hard molecule to picture, so I agree that an Xray structure probably wouldn't add much. --
1960:
I've reworked this, the statement did not appear to be supported by the refs given. Somewhat predictably, there are a range of reported binding affinities. General range is about right though.
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2508:
As mentioned to
Praseodymium-141 on their talk-page. I feel that I've completed all of the improvements requested. It would be regrettable if the review stalled this late into the process.
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2600:"The ion-exchange-resin-catalyzed process requires a treatment of the resin with an aminomercaptan... the promoter carbonium ion, which .. alkylates the phenol ring more rapidly."
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However, I've realised that you've put your comments before the text on my signing, so please can you try to move your future comments after the ? That would be great.
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SciFinder leading me off in the wrong direction there. It's gratifying to see that most of those key points are already in the article but it leaves the question of
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A primary source but with over 200 citations. I can't find a good secondary ref but I've added some additional refs ones showing that it's common in dental cements.
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1906:), I can't seem to find the link to the URL you provide. Regardless ref 66 is weak and I've deleted it. The statement is still referenced by a direct link to ECHA
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In the "Pharmacology" section, the last image is merely a repeat of one of the chembox images, and does the one about "diethylstilbestrol" fit in this context?
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The article presents a readable description of a highly topical and sometimes controversial chemical. Some thoughts that occurred to me but are not crucial:
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Ref #32 (doi 10.1002/14356007.a21_449.pub4) is indeed a review of solid acid-catalyzed condensations from a ChemE perspective. BPA is mentioned 43x. --
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solubility of 300 g/ton of water (I like those practical units!) seems about right, in fact fairly high owing to the hydrophilic OH groups.
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Abiotic degradation (from
Smokefoot): I've added a review ref which has a section on this. Did you want to know what it degraded into?
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Density: I still don't have a reference for this. I suspect it might be included in the crystal data refs, but I can't access those.
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The article is not about polyetherimides (why would it be?). It is about hydroxymethylations and a lot about BPA. Some tidbits:
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Hello there, I will be reviewing this article. Note that I won't come
Knowledge very often, so I might take a while to respond.
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Maybe you could add a bit more of the suggestions from Graeme
Bartlett (e.g. solubility in other solvents)? Also check
1862:
Yes. It's the website for the relevant
Australian statutory authority. I have modified the ref to try and clarify this.
119:
2680:
The crystal structure has been reported 5x (an indication of the compound's signficance, most are reported only once)
1882:
Yes. It's the website for the relevant
Canadian statutory authority. I have modified the ref to try and clarify this.
1789:
Sorry for the delay, but I might not come back on this for a while. By the way I changed my username from Bli231957.
2523:
2156:-Butylphenol. I would advise you to change "Para tertiary butyl phenol" to "4-tert-Butylphenol" in the piped link.
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In the "History" section, what does this sentence mean: "He found BPA to be 1 / 37,000 as effective as estradiol"?
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That's ok, any improvements might take a while to push through anyhow. Thanks for accepting the job! Editors at
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2597:"Two industrial processes are used ... hydrochloric acid or ion-exchange resins,23,24 mainly sulfonic resins."
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I've checked the source code, and I didn't find a way to do that. Please could you open a new line instead?
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unresolved. They clearly contain a BPA unit, and they have been made from BPA in the past, but are they
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In the "Production" section, how does "para selective" have to do with "Arene substitution pattern"?
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articles on environment-related topics, as well as to ensure that environment articles are properly
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on
Knowledge. If you would like to participate, please visit the project page, where you can join
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on
Knowledge. If you would like to participate, please visit the project page, where you can join
2683:
The structures of 20 solvates have been reported (further evidence of some intense interest, BTW)
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This article was the subject of a Wiki Education Foundation-supported course assignment, between
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I've made a start. I don't actually have access the the crystal data beyond what CCDC shows. --
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A fancy drawing of the Xray structure could be produced. It doesnt tell the reader much.
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The section "Toxicity" is too short. Maybe expand it or merge it with the main section?
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for more suggestions with the refs. The comments from Smokefoot might also be helpful.
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I don't feel like there's anything that could be added. I'll mark this as a pass.
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I hope that this helps a little! Congrats on all the hard work on this article!
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can you verify if this this secondary source supports synthesis being from BPA?
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2052:. I'll try and clarify with captions - but I'm also comfortable with deletion.
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I'll do this GA review quite quickly, so it'll hopefully finish before July.
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1332:. The edit link for this section can be used to add comments to the review.
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https://www.foodstandards.gov.au/consumer/chemicals/bpa/Pages/default.aspx
1208:- Primary but supporting a primary measurement (that's allowed isn't it?)
179:
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586:, a collaborative effort to improve the coverage of articles related to
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There is a doi for the article in Berichte: 10.1002/cber.18920250333 --
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This page gets quite a lot of pageviews, so I might be quite strict.
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I would say maybe remove the last picture, but keep the other two.
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https://www.jstage.jst.go.jp/article/jec1991/14/1/14_1_57/_article
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Many thanks... is it mentioned in relation to polyetherimides? --
705:. Please visit the project page for details or ask questions at
195:
1987:
I had though that straightforward but I have tried to clarify.
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but I don't have access to it. Are there any other issues? --
2152:-Butylpheol is a piped link, but the link is a redirect to 4-
697:, which recommends that medicine-related articles follow the
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https://laws-lois.justice.gc.ca/eng/acts/C-1.68/index.html
1818:
Yeah, I've also become derailed by real life. No worries!
1212:
Ref 66 is a news article about a study and would not meet
410:. To participate, help improve this article or visit the
203:
2070:
I've had a crack at improving it first. Any opinions? --
2797:
High-importance Occupational Safety and Health articles
2607:
ylphenol, which is recycled. Your faithful servant, --
2280:
I see you've straighten it all out. Thanks for that. --
59:
2323:. That information is probably beyond the readership.
1071:
Wiki Education Foundation-supported course assignment
1892:
https://news.ncsu.edu/2012/09/wms-patisaul-amygdala/
1214:
https://news.ncsu.edu/2012/09/wms-patisaul-amygdala/
943:, a collaborative effort to improve the coverage of
600:
Knowledge:WikiProject Occupational Safety and Health
463:
This is a core article in the WikiProject Chemicals
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WikiProject Occupational Safety and Health articles
1894:(cite 66) a reliable source (it is a news article)?
603:
Template:WikiProject Occupational Safety and Health
2474:. I'm not a pharmacologist. It appears well cited.
2857:Articles copy edited by the Guild of Copy Editors
1654:and other media, where possible and appropriate:
1160:to identify sources that potentially do not meet
2792:GA-Class Occupational Safety and Health articles
517:, a project which is currently considered to be
404:, which aims to improve Knowledge's coverage of
87:for general discussion of the article's subject.
45:. If it no longer meets these criteria, you can
1904:https://www.ehn.org/bisphenol-a-2639174350.html
1227:- More of a binding study really. I'm not sure.
701:and that biomedical information in any article
1178:Ref #32 also may be a primary study from 1985
1664:(images are tagged and non-free content have
699:Manual of Style for medicine-related articles
251:
211:
8:
1747:might also be able to provide some input. --
1180:https://doi.org/10.1002%2Fpol.1985.170230616
1043:Knowledge:WikiProject Guild of Copy Editors
2313:the prep of BPA is a premier example of a
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1233:https://doi.org/10.5194%2Fdwes-9-27-2016
1170:https://pubmed.ncbi.nlm.nih.gov/19627357
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1128:Above undated message substituted from
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836:to improve Knowledge's coverage of the
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606:Occupational Safety and Health articles
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2852:Low-importance Science Policy articles
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2048:Looks like an attempt at showing the
1918:for some sources that might not meet
1223:https://doi.org/10.1093%2Fjb%2Fmvm158
237:
7:
2842:High-importance Environment articles
2099:I've redone it as a single image. --
957:Knowledge:WikiProject Science Policy
937:This article is within the scope of
691:This article is within the scope of
580:This article is within the scope of
513:This article is within the scope of
390:This article is within the scope of
326:
324:
2822:High-importance toxicology articles
1902:Ref 66 points to a different site (
960:Template:WikiProject Science Policy
708:Knowledge talk:WikiProject Medicine
343:It is of interest to the following
77:for discussing improvements to the
2782:High-importance chemicals articles
2184:I've restructured it a bit too. --
2140:are related to Bisphenol A in the
1085:
1081:
14:
2787:GA-Class WPChem worklist articles
868:Knowledge:WikiProject Environment
41:. If you can improve it further,
2847:GA-Class Science Policy articles
2812:Low-importance medicine articles
2481:
2413:Template:Chembox Thermochemistry
2411:) looks to have information for
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2050:structure–activity relationships
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1152:Hi, there was a request made by
1088:. Further details are available
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871:Template:WikiProject Environment
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703:use high-quality medical sources
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99:Click here to start a new topic.
19:
2238:I think it's fine, no problem.
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1370:for what the criteria are, and
977:This article has been rated as
888:This article has been rated as
737:This article has been rated as
620:This article has been rated as
440:This article has been rated as
420:Knowledge:WikiProject Chemicals
2832:All WikiProject Medicine pages
2827:Toxicology task force articles
2772:Natural sciences good articles
1393:(prose, spelling, and grammar)
1183:- I'm having difficulty here.
1049:Guild of Copy Editors articles
858:and leave any messages at the
717:Knowledge:WikiProject Medicine
597:Occupational Safety and Health
588:occupational safety and health
560:Occupational Safety and Health
529:Knowledge:WikiProject Polymers
423:Template:WikiProject Chemicals
33:Natural sciences good articles
29:has been listed as one of the
1:
2837:GA-Class Environment articles
1225:x-ray crystallography study
1197:10.1002/14356007.a21_449.pub4
951:and see a list of open tasks.
759:This article is supported by
720:Template:WikiProject Medicine
594:and see a list of open tasks.
532:Template:WikiProject Polymers
96:Put new text under old text.
2817:GA-Class toxicology articles
1874:(cite 63) a reliable source?
1854:(cite 60) a reliable source?
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2125:Maybe add a comment on how
414:for details on the project.
104:New to Knowledge? Welcome!
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2807:GA-Class medicine articles
2529:18:33, 2 August 2022 (UTC)
2518:12:18, 2 August 2022 (UTC)
1253:12:37, 31 March 2022 (UTC)
983:project's importance scale
940:WikiProject Science Policy
894:project's importance scale
856:Knowledge:Contributing FAQ
743:project's importance scale
626:project's importance scale
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2317:process: A + 2B --: -->
1666:non-free use rationales
1381:reasonably well written
963:Science Policy articles
833:WikiProject Environment
830:article is part of the
2742:Cheers (ref 25 btw) --
2677:its CSD code is CEGYOC
1374:for what they are not)
840:. The aim is to write
755:
458:
333:This article is rated
129:avoid personal attacks
1648:It is illustrated by
1590:neutral point of view
1539:broad in its coverage
1092:. Student editor(s):
1040:Guild of Copy Editors
1034:Guild of Copy Editors
1006:Guild of Copy Editors
754:
457:
401:WikiProject Chemistry
394:WikiProject Chemicals
288:Auto-archiving period
177:Find medical sources:
154:Neutral point of view
39:good article criteria
1330:Talk:Bisphenol A/GA1
1199:(sorry for the ping)
874:Environment articles
694:WikiProject Medicine
515:WikiProject Polymers
159:No original research
828:environment-related
57:: August 2, 2022. (
2127:Dinitrobisphenol A
1846:Reliable sources:
1632:No edit wars, etc.
1447:factually accurate
1112:. Peer reviewers:
1090:on the course page
1031:, a member of the
821:Environment portal
756:
459:
426:chemicals articles
339:content assessment
183:
140:dispute resolution
101:
2633:made that way? --
2472:10.1093/jb/mvm158
2451:Solubility (from
2409:10.1021/jp503567c
2198:Looks great now.
1686:suitable captions
1467:reference section
1320:
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1148:Secondary sources
1082:23 September 2019
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2138:-Butylphenol
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73:This is the
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43:please do so
31:
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2648:sulfone".--
2398:Checking in
1419:word choice
1326:transcluded
1098:Lexjennifer
1025:copy edited
865:Environment
850:categorized
838:environment
790:Environment
85:not a forum
79:Bisphenol A
27:Bisphenol A
2761:Categories
2142:"See also"
1519:plagiarism
1452:verifiable
1279:Authorship
1265:GA toolbox
1168:Ref # 30-
1110:Lucy H Ahn
654:Toxicology
37:under the
2694:Smokefoot
2650:Smokefoot
2609:Smokefoot
2576:Smokefoot
2548:Smokefoot
2436:Bli231957
2337:Smokefoot
2268:Bli231957
2254:Bli231957
2240:Bli231957
2200:Bli231957
2158:Bli231957
2087:Bli231957
2058:Bli231957
2031:Bli231957
1997:Bli231957
1970:Bli231957
1943:Bli231957
1937:Others:
1924:Bli231957
1777:Bli231957
1763:Bli231957
1730:Bli231957
1711:Pass/Fail
1341:Bli231957
1338:Reviewer:
1302:Templates
1293:Reviewing
1258:GA Review
1245:JenOttawa
1236:- Removed
1221:Ref # 67
1217:- Removed
1187:Smokefoot
1118:Chang2021
417:Chemicals
407:chemicals
364:Chemicals
142:if needed
125:Be polite
75:talk page
2218:Response
1920:WP:MEDRS
1842:Comments
1351:contribs
1307:Criteria
1231:Ref #73
1162:WP:MEDRS
1134:PrimeBOT
1102:Amunoz18
714:Medicine
649:Medicine
526:Polymers
520:inactive
494:inactive
489:Polymers
465:worklist
335:GA-class
263:Archives
232:Springer
197:Cochrane
110:get help
83:This is
81:article.
47:reassess
2668:Density
2448:OK:...
1745:WP:Chem
1705:Overall
1569:focused
1515:copyvio
1423:fiction
1203:Ref 45
1122:Jsodhi1
1106:Ebang21
981:on the
892:on the
842:neutral
741:on the
624:on the
444:on the
292:90 days
2723:Ref 24
2631:mostly
2541:Ref 32
1651:images
1621:stable
1619:It is
1592:policy
1537:It is
1445:It is
1425:, and
1415:layout
1379:It is
1364:review
1114:Ghuynh
1094:Hbhat3
341:scale.
220:OpenMD
190:PubMed
54:Review
2729:Stone
1684:with
1427:lists
1366:(see
1328:from
854:Read
826:This
268:Index
246:Wiley
138:Seek
2748:talk
2733:talk
2713:talk
2698:talk
2654:talk
2639:talk
2613:talk
2580:talk
2566:talk
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2440:talk
2432:here
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2286:talk
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2190:talk
2181:Done
2162:talk
2154:tert
2150:tert
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2129:and
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2020:Done
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1084:and
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844:and
616:High
436:High
369:Core
239:Trip
213:Gale
205:DOAJ
127:and
2468:doi
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1890:Is
1870:Is
1850:Is
1407:MoS
1193:doi
1132:by
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253:TWL
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