190:
adjusted from the molecular weight and functionality of isocyanate resins, prepolymers, and the exact combinations of diols, triols and polyols selected, with the rate of reaction being strongly influenced by catalysts and inhibitors; polyureas form virtually instantaneously when isocyanate resins are combined with long-chain amine functional polyether or polyester resins and short-chain diamine extenders – the amine-isocyanate nucleophilic addition reaction does not require catalysts. Polyureas also form when isocyanate resins come into contact with moisture;
31:
1169:
1175:
186:
formed and highly branched crosslinked structures develop, the rate of cure being influenced by the physical form and functionality of epoxy resins and curing agents – elevated temperature postcuring induces secondary crosslinking of backbone hydroxyl functionality which condense to form ether bonds;
256:
composites, which are used in the fabrication of factory-finished structural composite OEM or replacement parts, and as site-applied, cured and finished composite repair and protection materials. When used as the binder for aggregates and other solid fillers, they form particulate-reinforced polymer
243:
and re-shaped after they are cured. This usually prevents recycling for the same purpose, except as filler material. New developments involving thermoset epoxy resins which on controlled and contained heating form crosslinked networks permit repeatedly reshaping, like silica glass by reversible
185:
Epoxy functional resins can be homo-polymerized with anionic or cationic catalysts and heat, or copolymerised through nucleophilic addition reactions with multifunctional crosslinking agents which are also known as curing agents or hardeners. As reaction proceeds, larger and larger molecules are
189:
Polyurethanes form when isocyanate resins and prepolymers are combined with low- or high-molecular weight polyols, with strict stoichiometric ratios being essential to control nucleophilic addition polymerisation – the degree of crosslinking and resulting physical type (elastomer or plastic) is
231:
applications up to the decomposition temperature since they keep their shape as strong covalent bonds between polymer chains cannot be broken easily. The higher the crosslink density and aromatic content of a thermoset polymer, the higher the resistance to heat degradation and chemical attack.
204:
resins all cured by polycondensation involving the release of water and heat, with cure initiation and polymerisation exotherm control influenced by curing temperature, catalyst selection or loading and processing method or pressure – the degree of pre-polymerisation and level of residual
214:
Thermosetting polymer mixtures based on thermosetting resin monomers and pre-polymers can be formulated and applied and processed in a variety of ways to create distinctive cured properties that cannot be achieved with thermoplastic polymers or inorganic materials.
181:
diluents, with cure initiated by free radicals generated from ionizing radiation or by the photolytic or thermal decomposition of a radical initiator – the intensity of crosslinking is influenced by the degree of backbone unsaturation in the prepolymer;
309:: insulating foams, mattresses, coatings, adhesives, car parts, print rollers, shoe soles, flooring, synthetic fibers, etc. Polyurethane polymers are formed by combining two bi- or higher functional monomers/oligomers.
1776:
244:
covalent bond exchange reactions on reheating above the glass transition temperature. There are also thermoset polyurethanes shown to have transient properties and which can thus be reprocessed or recycled.
235:
Hard, plastic thermosets may undergo permanent or plastic deformation under load. Elastomers, which are soft and springy or rubbery and can be deformed and revert to their original shape on loading release.
1500:
573:
297:
or polycyanurates for electronics applications with need for dielectric properties and high glass temperature requirements in aerospace structural composite components.
377:, used alone or hybridised with epoxy and phenolic resins, for structural prepregs, liquid molding and film adhesives for composite construction, bonding and repair.
775:; Marc A. Hillmyer; William R. Dichtel (2015). "Mechanically Activated, Catalyst-Free Polyhydroxyurethane Vitrimers". Journal of the American Chemical Society.
833:
Guzman, Enrique; Cugnoni, Joël; Gmür, Thomas (2014). "Multi-Factorial Models of a Carbon Fibre/Epoxy
Composite Subjected to Accelerated Environmental Ageing".
651:
Reactive
Polymers Fundamentals and Applications: A Concise Guide to Industrial Polymers (Plastics Design Library), William Andrew Inc., 2nd edition, 2013,
303:
fiberglass systems: sheet molding compounds and bulk molding compounds; filament winding; wet lay-up lamination; repair compounds and protective coatings.
291:
used in printed circuit boards and in body parts of modern aircraft, aerospace composite structures, as a coating material and for glass reinforced pipes.
232:
Mechanical strength and hardness also improve with crosslink density, although at the expense of brittleness. They normally decompose before melting.
893:
Roberto C. Dante, Diego A. Santamaría and Jesús Martín Gil (2009). "Crosslinking and thermal stability of thermosets based on novolak and melamine".
211:
are cured by an exothermal ring-opening polymerisation without releasing any chemical, which translates in near zero shrinkage upon polymerisation.
1493:
1376:
812:
796:
727:
616:
135:
polymers which are commonly produced and distributed in the form of pellets, and shaped into the final product form by melting, pressing, or
860:
Kulkarni, Romit; Wappler, Peter; Soltani, Mahdi; Haybat, Mehmet; Guenther, Thomas; Groezinger, Tobias; Zimmermann, André (1 February 2019).
257:
composites, which are used for factory-applied protective coating or component manufacture, and for site-applied and cured construction, or
1835:
1786:
1755:
690:
67:
1486:
993:
706:
656:
640:
386:
resins used in the manufacture of sustainable biocomposite construction, cements, adhesives, coatings and casting/foundry resins.
1882:
1018:
368:
Diallyl-phthalate (DAP) used in high temperature and mil-spec electrical connectors and other components. Usually glass filled.
823:
ISO 24817 Composite
Repairs for Pipework: Qualification and Design, Installation, Testing and Inspection, 2015, ICS: 75.180.20
1771:
1750:
1647:
1401:
632:
862:"An Assessment of Thermoset Injection Molding for Thin-Walled Conformal Encapsulation of Board-Level Electronic Packages"
1825:
1745:
701:
Industrial
Polymer Applications: Essential Chemistry and Technology, Royal Society of Chemistry, UK, 1st edition, 2016,
454:
90:. Heat is not necessarily applied externally, and is often generated by the reaction of the resin with a curing agent (
1818:
1740:
1556:
1153:
544:
278:
1877:
1083:
1058:
1858:
1592:
1478:
1391:
1216:
1033:
1023:
527:
371:
Epoxy novolac resins used for printed circuit boards, electrical encapsulation, adhesives and coatings for metal.
193:
1662:
1652:
1514:
1201:
1148:
1038:
549:
274:
253:
1252:
1143:
1128:
1108:
505:
450:
258:
668:
404:
resins used for wet lay-up laminating, molding and fast setting industrial protection and repair materials.
227:
materials due to the three-dimensional network of bonds (crosslinking), and are also better suited to high-
1667:
1545:
1300:
1028:
986:
509:
170:. Crosslink density varies depending on the monomer or prepolymer mix, and the mechanism of crosslinking:
1847:
1551:
772:
446:
281:; casting; electronics encapsulation; construction; protective coatings; adhesives; sealing and joining.
1567:
1562:
1535:
1453:
685:
Concise
Encyclopedia of Polymer Science and Engineering, ed. J.I. Kroschwitz, Wiley, New York, 1990,
177:
with unsaturated sites at the ends or on the backbone are generally linked by copolymerisation with
1697:
1458:
1381:
1295:
1247:
501:
178:
1712:
1630:
1371:
1345:
1315:
1275:
1257:
1206:
1158:
1138:
489:
147:
71:
921:
807:
PCC-2 Repair of
Pressure Equipment and Piping, American Society of Mechanical Engineers, 2015,
30:
1842:
1808:
1728:
1540:
1362:
1280:
979:
941:
808:
792:
723:
702:
686:
652:
636:
628:
612:
495:
422:
401:
395:
352:
174:
136:
124:
51:
1733:
1428:
1330:
1305:
1237:
1103:
1098:
1043:
959:
933:
902:
873:
842:
776:
756:
587:
474:
430:
208:
166:
or chain extension through the formation of covalent bonds between individual chains of the
791:
Polymer Matrix
Composites: Materials Usage, Design, and Analysis, SAE International, 2012,
1597:
1583:
1448:
1335:
1325:
1093:
300:
345:, light but strong material, similar to Bakelite formerly used in the manufacture of the
1168:
392:
used for thermoset polymer matrix composites and as ceramic matrix composite precursors.
1626:
1438:
1340:
1211:
389:
380:
Mold or mold runners (the black plastic part in integrated circuits or semiconductors).
362:
958:
T Malaba, J Wang, Journal of
Composites, vol. 2015, Article ID 707151, 8 pages, 2015.
1871:
1813:
1620:
1406:
1396:
1386:
1290:
1191:
1113:
1063:
846:
583:
554:
523:
322:
294:
224:
132:
611:
Chemistry and
Technology of Epoxy Resins, ed. B. Ellis, Springer Netherlands, 1993,
602:
Unsaturated
Polyester Technology, ed. P.F. Bruins, Gordon and Breach, New York, 1976
105:
1433:
1423:
1285:
1133:
1078:
1053:
755:
D. Montarnal, M. Capelot, F. Tournilhac, L. Leibler, Science, 2011, 334, 965-968],
519:
515:
374:
336:
316:
306:
627:
Polyurethane Handbook, ed. G Oertel, Hanser, Munich, Germany, 2nd edition, 1994,
1616:
1588:
1523:
1443:
1242:
1123:
1118:
578:
228:
498:(used for making pipes, threads of fabric and insulation for electrical cables)
1692:
1320:
1310:
1174:
937:
922:"Migration of melamine and formaldehyde from tableware made of melamine resin"
466:
462:
284:
101:
75:
43:
591:
582:, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "
17:
1781:
1687:
1657:
1527:
1088:
1073:
1048:
760:
342:
288:
163:
155:
131:. Once hardened, a thermoset cannot be melted for reshaping, in contrast to
120:
109:
83:
963:
945:
1702:
780:
531:
478:
434:
418:
328:
312:
128:
96:
87:
878:
861:
1830:
1707:
1679:
1608:
1510:
1232:
1002:
470:
442:
438:
414:
356:
346:
240:
167:
151:
63:
906:
332:
205:
hydroxymethyl content in the resins determine the crosslink density.
159:
458:
426:
383:
270:
201:
197:
79:
29:
1068:
398:, an electrical insulating thermoset phenolic laminate material.
1482:
975:
744:
Design and Manufacture with Polymers: Introduction to Polymers
100:). Curing results in chemical reactions that create extensive
413:
Application/process uses and methods for thermosets include
971:
319:
hybrids used for abrasion resistant waterproofing coatings.
27:
Polymer obtained by irreversibly hardening (curing) a resin
920:
Ishiwata, Hajimu; Inoue, Takiko; Tanimura, Akio (1986).
239:
Conventional thermoset plastics or elastomers cannot be
252:
When compounded with fibers, thermosetting resins form
123:
or liquid prior to curing, and is often designed to be
534:, emblems as well as production and replacement parts)
86:
and may be promoted by high pressure or mixing with a
339:
resin used in electrical insulators and plasticware.
1801:
1764:
1721:
1678:
1640:
1607:
1576:
1522:
1471:
1416:
1361:
1354:
1266:
1225:
1182:
1009:
223:Thermosetting plastics are generally stronger than
866:Journal of Manufacturing and Materials Processing
365:used on worktop surfaces and some plastic dishes.
349:automobile, currently used for household objects
127:into the final shape. It may also be used as an
359:, particleboard and medium-density fibreboard.
1494:
987:
492:(used for objects such as milk bottle crates)
8:
746:, page 9. Milton Keynes: The Open University
484:Specific methods of molding thermosets are:
718:S.H. Goodman, H. Dodiuk-Kenig, ed. (2013).
150:a thermosetting resin transforms it into a
1501:
1487:
1479:
1358:
994:
980:
972:
877:
82:). Curing is induced by heat or suitable
566:
1084:Polyethylene terephthalate (PET, PETE)
1024:Cross-linked polyethylene (PEX, XLPE)
1019:Acrylonitrile butadiene styrene (ABS)
771:Fortman, David J.; Jacob P. Brutman;
742:The Open University (UK), 2000. T838
722:(3rd ed.). USA: William Andrew.
277:such as glass-reinforced plastic and
273:used as the matrix component in many
104:between polymer chains to produce an
7:
1836:List of environmental health hazards
1756:List of environmental health hazards
46:to give a rigid 3D thermoset polymer
1641:Miscellaneous additives incl. PHCs
895:Journal of Applied Polymer Science
579:Compendium of Chemical Terminology
74:") a soft solid or viscous liquid
37:: individual linear polymer chains
25:
115:The starting material for making
42:: Polymer chains which have been
1173:
1167:
1059:Polybutylene terephthalate (PBT)
1034:Poly(methyl methacrylate) (PMMA)
847:10.1016/j.compstruct.2013.12.028
1039:Poly(ethyl methacrylate) (PEMA)
926:Food Additives and Contaminants
173:Acrylic resins, polyesters and
1402:Category:Plastics applications
1149:Styrene maleic anhydride (SMA)
1144:Polyvinylidene chloride (PVDC)
1129:Polytetrafluoroethylene (PTFE)
720:Handbook of Thermoset Plastics
1:
1109:Poly(p-phenylene oxide) (PPO)
1826:Persistent organic pollutant
1787:Toxic Substances Control Act
1746:Persistent organic pollutant
1029:Ethylene vinyl acetate (EVA)
429:for jointing and injection,
1819:Great Pacific garbage patch
1741:Great Pacific garbage patch
1154:Styrene-acrylonitrile (SAN)
1069:Polyetheretherketone (PEEK)
673:Polymer Properties Database
545:Fusion bonded epoxy coating
279:graphite-reinforced plastic
1899:
1782:Japan Toxic Substances Law
1577:Miscellaneous plasticizers
248:Fiber-reinforced materials
1856:
1777:European REACH regulation
1772:California Proposition 65
1515:polyhalogenated compounds
1392:High-performance plastics
1217:High-performance plastics
1165:
938:10.1080/02652038609373566
275:fiber reinforced plastics
1202:Fibre-reinforced plastic
1139:Polyvinyl chloride (PVC)
592:10.1351/goldbook.TT07168
550:Thermoset polymer matrix
254:fiber-reinforced polymer
1253:Biodegradable additives
761:10.1126/science.1212648
512:thermosetting plastics)
1883:Thermosetting plastics
1668:Perfluorooctanoic acid
1104:Polyphenyl ether (PPE)
1099:Polyoxymethylene (POM)
1044:Polyacrylic acid (PAA)
47:
1848:Biodegradable plastic
1197:Thermosetting polymer
1094:Polylactic acid (PLA)
773:Christopher J. Cramer
584:thermosetting polymer
451:electrical insulation
56:thermosetting polymer
33:
1859:Identification codes
1459:Foam food containers
1382:Engineering plastics
835:Composite Structures
781:10.1021/jacs.5b08084
518:(used for producing
66:that is obtained by
1698:Endocrine disruptor
1296:Compression molding
1248:Polymer stabilizers
964:10.1155/2015/707151
879:10.3390/jmmp3010018
502:Compression molding
179:unsaturated monomer
1713:Polymer fume fever
1372:Commodity plastics
1346:Rotational molding
1316:Fiberglass molding
1276:Injection moulding
1258:Filler (materials)
1207:Corrugated plastic
1159:Tritan copolyester
1114:Polypropylene (PP)
1064:Polycarbonate (PC)
669:"Polybenzoxazines"
490:injection moulding
415:protective coating
48:
1878:Polymer chemistry
1865:
1864:
1843:Plastic recycling
1809:Plastic pollution
1795:
1794:
1729:Plastic pollution
1509:Health issues of
1467:
1466:
1363:Plastics industry
1281:Plastic extrusion
1134:Polyurethane (PU)
1124:Polysulfone (PES)
1079:Polyethylene (PE)
1054:Polybutylene (PB)
907:10.1002/app.31114
813:978-0-7918-6959-8
797:978-0-7680-7813-8
729:978-1-4557-3107-7
617:978-94-010-5302-0
528:gaming miniatures
496:Extrusion molding
433:, foundry sands,
423:civil engineering
419:seamless flooring
353:Urea-formaldehyde
323:Vulcanized rubber
137:injection molding
112:polymer network.
58:, often called a
52:materials science
16:(Redirected from
1890:
1734:Rubber pollution
1584:Organophosphates
1503:
1496:
1489:
1480:
1359:
1331:Filament winding
1306:Transfer molding
1233:Polymer additive
1177:
1171:
1119:Polystyrene (PS)
996:
989:
982:
973:
966:
956:
950:
949:
917:
911:
910:
901:(6): 4059–4065.
890:
884:
883:
881:
857:
851:
850:
830:
824:
821:
815:
805:
799:
789:
783:
769:
763:
753:
747:
740:
734:
733:
715:
709:
699:
693:
683:
677:
676:
665:
659:
649:
643:
625:
619:
609:
603:
600:
594:
571:
475:filament winding
209:Polybenzoxazines
143:Chemical process
21:
1898:
1897:
1893:
1892:
1891:
1889:
1888:
1887:
1868:
1867:
1866:
1861:
1852:
1797:
1796:
1791:
1760:
1717:
1674:
1636:
1603:
1572:
1518:
1507:
1473:
1463:
1412:
1350:
1336:Solvent bonding
1326:Plastic welding
1268:
1262:
1221:
1184:
1178:
1172:
1163:
1074:Polyester (PEs)
1011:
1005:
1000:
970:
969:
957:
953:
919:
918:
914:
892:
891:
887:
859:
858:
854:
832:
831:
827:
822:
818:
806:
802:
790:
786:
770:
766:
754:
750:
741:
737:
730:
717:
716:
712:
700:
696:
684:
680:
667:
666:
662:
650:
646:
626:
622:
610:
606:
601:
597:
572:
568:
563:
541:
504:(used to shape
481:, and molding.
411:
390:Silicone resins
301:Polyester resin
267:
250:
221:
145:
38:
28:
23:
22:
15:
12:
11:
5:
1896:
1894:
1886:
1885:
1880:
1870:
1869:
1863:
1862:
1857:
1854:
1853:
1851:
1850:
1845:
1840:
1839:
1838:
1833:
1828:
1823:
1822:
1821:
1805:
1803:
1799:
1798:
1793:
1792:
1790:
1789:
1784:
1779:
1774:
1768:
1766:
1762:
1761:
1759:
1758:
1753:
1748:
1743:
1738:
1737:
1736:
1725:
1723:
1719:
1718:
1716:
1715:
1710:
1705:
1700:
1695:
1690:
1684:
1682:
1676:
1675:
1673:
1672:
1671:
1670:
1660:
1655:
1650:
1644:
1642:
1638:
1637:
1635:
1634:
1627:Vinyl chloride
1624:
1621:Polycarbonates
1613:
1611:
1605:
1604:
1602:
1601:
1595:
1586:
1580:
1578:
1574:
1573:
1571:
1570:
1565:
1560:
1554:
1549:
1543:
1538:
1532:
1530:
1520:
1519:
1508:
1506:
1505:
1498:
1491:
1483:
1477:
1475:
1469:
1468:
1465:
1464:
1462:
1461:
1456:
1451:
1446:
1441:
1436:
1434:Packaging film
1431:
1426:
1420:
1418:
1417:Specific goods
1414:
1413:
1411:
1410:
1404:
1399:
1394:
1389:
1384:
1379:
1374:
1368:
1366:
1356:
1352:
1351:
1349:
1348:
1343:
1341:Vacuum forming
1338:
1333:
1328:
1323:
1318:
1313:
1308:
1303:
1298:
1293:
1288:
1283:
1278:
1272:
1270:
1264:
1263:
1261:
1260:
1255:
1250:
1245:
1240:
1235:
1229:
1227:
1223:
1222:
1220:
1219:
1214:
1212:Polymeric foam
1209:
1204:
1199:
1194:
1188:
1186:
1180:
1179:
1166:
1164:
1162:
1161:
1156:
1151:
1146:
1141:
1136:
1131:
1126:
1121:
1116:
1111:
1106:
1101:
1096:
1091:
1089:Polyimide (PI)
1086:
1081:
1076:
1071:
1066:
1061:
1056:
1051:
1049:Polyamide (PA)
1046:
1041:
1036:
1031:
1026:
1021:
1015:
1013:
1007:
1006:
1001:
999:
998:
991:
984:
976:
968:
967:
951:
912:
885:
852:
841:(4): 179–192.
825:
816:
800:
784:
764:
748:
735:
728:
710:
707:978-1782628149
694:
691:0-471-5 1253-2
678:
660:
657:978-1455731497
644:
641:978-1569901571
620:
604:
595:
565:
564:
562:
559:
558:
557:
552:
547:
540:
537:
536:
535:
513:
499:
493:
410:
407:
406:
405:
399:
393:
387:
381:
378:
372:
369:
366:
363:Melamine resin
360:
350:
340:
326:
320:
310:
304:
298:
295:Cyanate esters
292:
282:
266:
263:
249:
246:
220:
217:
144:
141:
26:
24:
14:
13:
10:
9:
6:
4:
3:
2:
1895:
1884:
1881:
1879:
1876:
1875:
1873:
1860:
1855:
1849:
1846:
1844:
1841:
1837:
1834:
1832:
1829:
1827:
1824:
1820:
1817:
1816:
1815:
1814:Garbage patch
1812:
1811:
1810:
1807:
1806:
1804:
1800:
1788:
1785:
1783:
1780:
1778:
1775:
1773:
1770:
1769:
1767:
1763:
1757:
1754:
1752:
1749:
1747:
1744:
1742:
1739:
1735:
1732:
1731:
1730:
1727:
1726:
1724:
1720:
1714:
1711:
1709:
1706:
1704:
1701:
1699:
1696:
1694:
1691:
1689:
1686:
1685:
1683:
1681:
1680:Health issues
1677:
1669:
1666:
1665:
1664:
1661:
1659:
1656:
1654:
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520:fishing lures
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354:
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307:Polyurethanes
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225:thermoplastic
218:
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133:thermoplastic
130:
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102:cross-linking
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61:
57:
53:
45:
41:
36:
32:
19:
18:Thermosetting
1524:Plasticizers
1472:Environment
1424:Blister pack
1377:Construction
1286:Blow molding
1196:
954:
932:(1): 63–69.
929:
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713:
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623:
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569:
516:Spin casting
483:
465:laminating,
412:
409:Applications
375:Benzoxazines
337:formaldehyde
317:polyurethane
251:
238:
234:
222:
213:
207:
192:
188:
184:
175:vinyl esters
172:
164:crosslinking
146:
116:
114:
95:
91:
70:hardening ("
68:irreversibly
59:
55:
49:
44:cross linked
39:
34:
1765:Regulations
1617:Bisphenol A
1301:Calendering
1243:Plasticizer
1183:Mechanical
402:Vinyl ester
271:Epoxy resin
259:maintenance
229:temperature
119:is usually
1872:Categories
1693:Carcinogen
1658:Organotins
1528:Phthalates
1474:and health
1321:Pultrusion
1311:Laminating
1269:processing
633:1569901570
561:References
467:pultrusion
463:wet lay-up
285:Polyimides
261:purposes.
219:Properties
117:thermosets
76:prepolymer
1722:Pollution
1688:Teratogen
1619:(BPA, in
1267:Plastics
1238:Colorants
1226:Additives
1010:Chemical
872:(1): 18.
532:figurines
488:Reactive
479:pre-pregs
435:adhesives
343:Duroplast
265:Materials
156:elastomer
121:malleable
110:insoluble
106:infusible
84:radiation
60:thermoset
1703:Diabetes
1609:Monomers
1589:Adipates
1511:plastics
1365:segments
1355:Products
1003:Plastics
539:See also
471:gelcoats
457:, solid
443:castings
439:sealants
396:Thiolyte
329:Bakelite
313:Polyurea
194:Phenolic
129:adhesive
97:hardener
92:catalyst
88:catalyst
1831:Dioxins
1751:Dioxins
1708:Obesity
1449:Cutlery
1439:Bottles
946:3956795
447:potting
431:mortars
357:plywood
347:Trabant
168:polymer
152:plastic
64:polymer
62:, is a
1548:(BBzP)
1517:(PHCs)
1429:Chairs
1397:Nurdle
944:
811:
795:
726:
705:
689:
655:
639:
631:
615:
427:grouts
333:phenol
241:melted
200:, and
160:rubber
148:Curing
125:molded
72:curing
1802:Waste
1648:PBDEs
1559:(DOP)
1185:types
1012:types
574:IUPAC
459:foams
384:Furan
202:furan
198:amino
162:) by
154:, or
80:resin
40:Right
1663:PFCs
1653:PCBs
1629:(in
1593:DEHA
1568:DINP
1563:DIDP
1557:DEHP
1552:DIHP
1536:DIBP
1513:and
1444:Bags
942:PMID
809:ISBN
793:ISBN
724:ISBN
703:ISBN
687:ISBN
653:ISBN
637:ISBN
629:ISBN
613:ISBN
524:jigs
522:and
508:and
331:, a
287:and
108:and
54:, a
35:Left
1631:PVC
1598:DOA
1546:BBP
1541:DBP
960:doi
934:doi
903:doi
899:114
874:doi
843:doi
839:111
777:doi
757:doi
588:doi
586:".
510:BMC
506:SMC
50:In
1874::
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940:.
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870:3
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732:.
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335:-
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315:/
158:(
78:(
20:)
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