Knowledge (XXG)

Kegginite

Source 📝

466:
O contained within Kegginite, it defracts relatively weakly leading to being limited to 2θ < 40°. However, a defined structure has been identified and is broken into two distinct parts, a structural unit and an interstitial complex. The structural unit is a heteropolyanion composed of 12 distorted
308:
as the basis of the structural unit. It also recognizes the work of J.F. Keggin who first experimentally described the structure of the α-Keggin anions in 1934. At the time of its discovery it represented a new crystal structure type and was the first mineral discovered with a vanadyl-containing
445:
Kegginite has been found in the main tunnel level of the Packrat mine, near Gateway, Mesa County, Colorado, U.S.A. The Packrat Mine is near the northern end of the Uravan Mineral Belt. Kegginite is very rare, it has been found sparingly on only a few small samples but often in association with
483:
octahedra. Without the capping tetrahedron, the heteropolyanion is the ε-isomer of the Keggin anion. The formula of the interstitial unit is . The Pb site is located above each of the remaining cavities located in the mono-capped Keggin anion.
322:, with brittle tenacity, irregular fracture, and good cleavage on {001}. Due to the very limited amount of crystals available, their size, and dark color make it impossible to obtain reliable measurements of the indices of refraction. 317:
Crystals of kegginite are orange-red hexagonal tablets. The crystals are transparent vitreous and have a pinkish-orange streak. Kegginite is non-fluorescent in long wave and short wave ultraviolet light. It exhibits a 2 on the
515:
Anthony R. Kampf, John M. Hughes, Barbara P. Nash, and Joe Marty (2017) Kegginite, a new mineral with a novel ε-isomer of the Keggin anion. American Mineralogist, Volume 102, pages 461-465.
304:. This specific mineral is very rare, and has only been found in one specific level of the Packrat mine. Kegginite is named as such due to the presence of the ε-isomer of the 84: 175: 575: 565: 560: 454:, and sherwoodite. Kegginite forms from the oxidation of montroseite-corvusite assembleges in moist environments. 74: 570: 165: 155: 541:
Kondinski, A., Parac-Vogt, T. N., 2018, Keggin Structure, Quō Vādis?, Frontiers in Chemistry, v 6,
198: 188: 145: 542: 301: 116: 305: 226: 39: 122: 94: 554: 106: 261: 258: 248: 319: 271: 297: 32: 479:(vanadate) tetrahedron, which shares three of its four vertices with the VO 99: 61: 451: 208: 54: 447: 67: 527: 48: 543:
https://www.frontiersin.org/articles/10.3389/fchem.2018.00346
284: 270: 257: 247: 225: 217: 207: 197: 187: 174: 164: 154: 144: 136: 131: 115: 105: 93: 83: 73: 38: 28: 23: 18: 8: 475:(arsenate) tetrahedron and capped by a VO 523: 521: 329: 300:mineral discovered in Packrat mine near 280:O and soluble at room temperature in HCl 511: 509: 507: 505: 503: 501: 499: 497: 493: 537: 535: 15: 7: 471:octahedra surrounding a central AsO 14: 528:https://mindat.org/min-47606.html 313:Physical and optical properties 1: 462:Due to the high amounts of H 592: 309:polyoxometalate anion. 320:Mohs Scale of Hardness 150:Distinct/Good on {001} 85:Strunz classification 218:Optical properties 127:c = 15.846 Å; 576:Trigonal minerals 566:Arsenate minerals 561:Vanadate minerals 436: 435: 326:Chemical analysis 302:Gateway, Colorado 291: 290: 583: 545: 539: 530: 525: 516: 513: 330: 227:Refractive index 203:Pinkish - Orange 180: 160:Irregular/Uneven 121:a = 14.936  45: 44:(repeating unit) 16: 591: 590: 586: 585: 584: 582: 581: 580: 551: 550: 549: 548: 540: 533: 526: 519: 514: 495: 490: 482: 478: 474: 470: 465: 460: 443: 416: 402: 398: 384: 380: 328: 315: 279: 266:Not Fluorescent 242: 238: 234: 178: 126: 66: 59: 53: 43: 42: 12: 11: 5: 589: 587: 579: 578: 573: 568: 563: 553: 552: 547: 546: 531: 517: 492: 491: 489: 486: 480: 476: 472: 468: 463: 459: 456: 442: 439: 434: 433: 431: 428: 424: 423: 421: 418: 414: 410: 409: 406: 403: 400: 396: 392: 391: 388: 385: 382: 378: 374: 373: 370: 367: 363: 362: 359: 356: 352: 351: 348: 345: 341: 340: 337: 334: 327: 324: 314: 311: 289: 288: 286: 282: 281: 277: 276:Insoluble in H 274: 268: 267: 264: 255: 254: 251: 245: 244: 240: 236: 232: 229: 223: 222: 219: 215: 214: 211: 205: 204: 201: 195: 194: 191: 185: 184: 181: 172: 171: 168: 162: 161: 158: 152: 151: 148: 142: 141: 138: 134: 133: 132:Identification 129: 128: 119: 113: 112: 109: 103: 102: 97: 95:Crystal system 91: 90: 87: 81: 80: 77: 71: 70: 64: 57: 51: 46: 36: 35: 30: 26: 25: 21: 20: 13: 10: 9: 6: 4: 3: 2: 588: 577: 574: 572: 571:Lead minerals 569: 567: 564: 562: 559: 558: 556: 544: 538: 536: 532: 529: 524: 522: 518: 512: 510: 508: 506: 504: 502: 500: 498: 494: 487: 485: 457: 455: 453: 449: 446:ansermetite, 440: 438: 432: 429: 426: 425: 422: 419: 412: 411: 407: 404: 394: 393: 389: 386: 376: 375: 371: 368: 365: 364: 360: 357: 354: 353: 349: 346: 343: 342: 338: 335: 332: 331: 325: 323: 321: 312: 310: 307: 303: 299: 295: 287: 283: 275: 273: 269: 265: 263: 260: 256: 252: 250: 246: 230: 228: 224: 220: 216: 212: 210: 206: 202: 200: 196: 192: 190: 186: 182: 177: 173: 169: 167: 163: 159: 157: 153: 149: 147: 143: 139: 135: 130: 124: 120: 118: 114: 111:3 - Pyramidal 110: 108: 107:Crystal class 104: 101: 98: 96: 92: 88: 86: 82: 78: 76: 72: 69: 63: 56: 50: 47: 41: 37: 34: 31: 27: 22: 17: 461: 444: 437: 390:49.01-51.30 350:26.98-29.27 316: 306:Keggin anion 293: 292: 262:fluorescence 259:Ultraviolet 249:Pleochroism 555:Categories 488:References 441:Occurrence 408:4.38-4.80 372:0.93-0.99 361:5.59-5.75 285:References 272:Solubility 176:Mohs scale 140:Orange-Red 75:IMA symbol 458:Structure 298:phosphate 294:Kegginite 239:= 2.040 n 235:= 2.035 n 213:2.69 g/cm 117:Unit cell 33:Phosphate 19:Kegginite 221:Uniaxial 193:Vitreous 179:hardness 166:Tenacity 156:Fracture 146:Cleavage 100:Trigonal 29:Category 452:mesaite 430:100.01 253:Visible 243:= 2.085 209:Density 170:Brittle 89:8.FD.10 40:Formula 24:General 448:gypsum 427:Total 420:14.59 387:47.87 347:26.82 339:Range 333:Oxide 199:Streak 189:Luster 405:4.42 369:0.92 358:5.39 296:is a 137:Color 60:* 20 366:MgO 355:CaO 344:PbO 336:wt% 79:Kgn 557:: 534:^ 520:^ 496:^ 467:VO 450:, 417:O 395:As 125:, 55:Ca 49:Pb 481:6 477:4 473:4 469:6 464:2 415:2 413:H 401:5 399:O 397:2 383:5 381:O 379:2 377:V 278:2 241:γ 237:β 233:α 231:n 183:2 123:Å 68:O 65:2 62:H 58:3 52:3

Index

Phosphate
Formula
Pb
Ca
H
O
IMA symbol
Strunz classification
Crystal system
Trigonal
Crystal class
Unit cell
Å
Cleavage
Fracture
Tenacity
Mohs scale
Luster
Streak
Density
Refractive index
Pleochroism
Ultraviolet
fluorescence
Solubility
phosphate
Gateway, Colorado
Keggin anion
Mohs Scale of Hardness
gypsum

Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.