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Mixed-anion compounds

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159:, or substituting atoms in a structure by others, including by water, oxygen, fluorine, or nitrogen. Teflon pouches can be used to separate different formulations. Thin film deposits can yield strained layers. High pressures can be used to prevent evaporation of volatiles. High pressure can result in different crystal forms, perhaps with higher 146:
Many of the non-metals that could make mixed-anion compounds may have greatly varying volatilities. This makes it more difficult to combine the elements together. Compounds may be produced in a solid state reaction, by heating solids together, either in a vacuum or a gas. Common gases used include,
1937:
Shlyapnikov, Igor M.; Goreshnik, Evgeny A.; Mazej, Zoran (31 December 2018). "Guanidinium Perfluoridotitanate(IV) Compounds: Structural Determination of an Oligomeric 3– Anion, and an Example of a Mixed-Anion Salt Containing Two Different Fluoridotitanate(IV) Anions".
1630:
Maeda, Kazuhiko; Takeiri, Fumitaka; Kobayashi, Genki; Matsuishi, Satoru; Ogino, Hiraku; Ida, Shintaro; Mori, Takao; Uchimoto, Yoshiharu; Tanabe, Setsuhisa; Hasegawa, Tetsuya; Imanaka, Nobuhito; Kageyama, Hiroshi (15 January 2022).
1894:
Sun, Jun; Abudouwufu, Tushagu; Jin, Congcong; Guo, Zhiyong; Zhang, Min (17 December 2021). "K 6 (IO 6 H 4)(HI 2 O 6)(HIO 3) 2 (IO 3) 4 ·2H 2 O: A Case of Iodate with Coexisting and Units".
1810:
Ravnsbaek, Dorthe B.; Sørensen, Lise H.; Filinchuk, Yaroslav; Reed, Daniel; Book, David; Jakobsen, Hans J.; Besenbacher, Flemming; Skibsted, Jørgen; Jensen, Torben R. (April 2010).
1844:
Almoussawi, Batoul; Huvé, Marielle; Dupray, Valérie; Clevers, Simon; Duffort, Victor; Mentré, Olivier; Roussel, Pascal; Arevalo-Lopez, Angel M.; Kabbour, Houria (22 April 2020).
1672:
Li, Yan-Yan; Wang, Wen-Jing; Wang, Hui; Lin, Hua; Wu, Li-Ming (7 June 2019). "Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials".
61:
By having more than one anion, many more compounds can be made, and properties tuned to desirable values. In terms of optics, properties include
116: 78: 1573: 1433:
Some elements can form several kinds of anions, and compounds may exist with more than one. Examples include the iodate periodates,
1845: 1846:"Oxysulfide Ba5(VO2S2)2(S2)2 Combining Disulfide Channels and Mixed-Anion Tetrahedra and Its Third-Harmonic-Generation Properties" 1979: 93:. Mechanical properties can include ability to grow a large crystal, ability to form a thin layer, strength, or brittleness. 105: 1984: 1501:
Kageyama, Hiroshi; Hayashi, Katsuro; Maeda, Kazuhiko; Attfield, J. Paul; Hiroi, Zenji; Rondinelli, James M.;
1220: 1244: 1225: 1200: 1185: 1049: 951: 936: 156: 1319: 1287: 1210: 1205: 1195: 1180: 1175: 1029: 961: 956: 946: 931: 926: 674: 1426: 1291: 1283: 1215: 1190: 1165: 1160: 1150: 1039: 1024: 1009: 1004: 941: 916: 911: 901: 810: 795: 747: 732: 684: 669: 664: 520: 249: 177: 1273: 1230: 1155: 1132: 1019: 994: 989: 906: 878: 815: 805: 790: 785: 727: 722: 679: 654: 649: 639: 616: 611: 573: 510: 495: 482: 245: 1812:"Mixed-Anion and Mixed-Cation Borohydride KZn(BH4)Cl2: Synthesis, Structure and Thermal Decomposition" 1410: 1390: 1112: 984: 921: 888: 873: 858: 853: 775: 770: 737: 707: 644: 626: 596: 586: 568: 563: 500: 472: 434: 317: 313: 258: 241: 1766: 1602: 1518: 1502: 1478: 1122: 1107: 1092: 1087: 868: 843: 828: 765: 702: 659: 591: 553: 548: 538: 462: 429: 383: 305: 254: 1473: 1345: 1127: 1102: 833: 606: 543: 477: 444: 378: 360: 342: 309: 301: 267: 1811: 1450: 1442: 1299: 1261: 1067: 1014: 848: 558: 236: 198: 160: 135: 131: 1082: 296: 1955: 1919: 1876: 1756: 1689: 1654: 1279: 1269: 1265: 1034: 966: 621: 525: 406: 282: 401: 1911: 1868: 1792: 1569: 1546: 1454: 1438: 1397: 1044: 979: 863: 742: 505: 321: 262: 101: 42: 1745:"Crystal, magnetic and electronic structures and properties of new BaMnPnF (Pn = As, Sb, Bi)" 1947: 1903: 1860: 1826: 1782: 1774: 1723: 1712:"A review of the structural chemistry and physical properties of metal chalcogenide halides" 1681: 1644: 1610: 1536: 1526: 1385: 1381: 1340: 1328: 1170: 1137: 1097: 883: 800: 760: 712: 697: 601: 467: 457: 439: 424: 275: 148: 119: 70: 1710:
Xiao, Jin-Rong; Yang, Si-Han; Feng, Fang; Xue, Huai-Guo; Guo, Sheng-Ping (September 2017).
1743:
Saparov, Bayrammurad; Singh, David J.; Garlea, Vasile O.; Sefat, Athena S. (8 July 2013).
1446: 1434: 1402: 1306: 1303: 1117: 999: 838: 515: 373: 355: 271: 123: 62: 1770: 1606: 1522: 1787: 1744: 1541: 1506: 1363: 1336: 1332: 1323: 1310: 1077: 1072: 1062: 780: 717: 127: 66: 1973: 1959: 1923: 1880: 1693: 1658: 1367: 1359: 1314: 202: 152: 97: 90: 86: 74: 17: 1371: 1355: 209: 190: 1907: 1864: 1419: 1351: 286: 223: 219: 194: 182: 82: 1531: 1728: 1711: 411: 396: 291: 227: 186: 1507:"Expanding frontiers in materials chemistry and physics with multiple anions" 1685: 231: 215: 1951: 1915: 1872: 1830: 1796: 1550: 1649: 1632: 1615: 1590: 1461: 1254: 112: 1778: 46: 1564:
Kageyama, Hiroshi; Ogino, Hiraku; Hasegawa, Tetsuya (26 June 2023).
53:. The compounds contain a single phase, rather than just a mixture. 1761: 1633:"Recent Progress on Mixed-Anion Materials for Energy Applications" 50: 1591:"Mixed-Anion Compounds: A New Trend in Solid State Chemistry" 1464:
forms such as phosphates or fluorotitanates, such as and .
1589:
Takeiri, Fumitaka; Kageyama, Hiroshi (15 December 2018).
111:For electrical properties, electric conductivity, 147:oxygen, hydrogen, ammonia, chlorine, fluorine, 8: 1496: 1494: 1786: 1760: 1727: 1648: 1637:Bulletin of the Chemical Society of Japan 1614: 1540: 1530: 328: 1940:European Journal of Inorganic Chemistry 1819:European Journal of Inorganic Chemistry 1490: 1705: 1703: 117:superconducting transition temperature 7: 1460:These kinds also include different 155:approaches to manufacture include 25: 104:, phase transition temperatures, 96:Thermal properties can include 1716:Coordination Chemistry Reviews 1568:. Royal Society of Chemistry. 1: 1908:10.1021/acs.inorgchem.1c03436 1865:10.1021/acs.inorgchem.9b03674 1249:disulfide dithioorthovanadate 106:thermal expansion coefficient 138:transition can be adjusted. 1674:Crystal Growth & Design 27:Class of chemical compounds 2001: 1532:10.1038/s41467-018-02838-4 69:, laser damage threshold, 49:and more than one kind of 1729:10.1016/j.ccr.2017.06.010 1503:Poeppelmeier, Kenneth R. 212:or chalcogenide halides 57:Use in materials science 1686:10.1021/acs.cgd.9b00358 151:, or carbon disulfide. 35:heteroanionic materials 1952:10.1002/ejic.201801207 1831:10.1002/ejic.201000119 1595:Nihon Kessho Gakkaishi 1278:phosphates, including 157:solvothermal synthesis 1980:Mixed anion compounds 1650:10.1246/bcsj.20210351 1566:Mixed Anion Compounds 1511:Nature Communications 39:mixed-anion materials 31:Mixed-anion compounds 1616:10.5940/jcrsj.60.240 1505:(22 February 2018). 1451:phosphate phosphites 1443:tellurite tellurates 1320:chalcogenide borates 1288:phosphate molybdates 1245:borohydride-chloride 81:particularly in the 18:Mixed anion compound 1896:Inorganic Chemistry 1853:Inorganic Chemistry 1771:2013NatSR...3E2154S 1607:2018NKG....60..240T 1523:2018NatCo...9..772K 1350:Condensed borates: 1292:phosphate arsenates 1280:fluoride phosphates 1270:carbonate chlorides 1266:carbonate fluorides 250:telluride chlorides 178:pnictochalcogenides 161:coordination number 136:charge-density wave 132:dielectric constant 1985:Physical chemistry 1749:Scientific Reports 1455:arsenate arsenites 1439:selenate selenites 1398:selenite fluorides 1284:chloride phosphate 1274:carbonate bromides 322:arsenide chlorides 263:telluride bromides 246:selenide chlorides 43:chemical compounds 1946:(48): 5246–5257. 1825:(11): 1608–1612. 1779:10.1038/srep02154 1411:sulfide silicates 1386:sulfate chlorides 1382:sulfate fluorides 1341:borate phosphates 1329:borate carbonates 1236: 1235: 318:fluorobismuthides 314:fluoroantimonides 276:telluride iodides 259:selenide bromides 242:sulfide chlorides 102:thermal stability 16:(Redirected from 1992: 1964: 1963: 1934: 1928: 1927: 1891: 1885: 1884: 1859:(9): 5907–5917. 1850: 1841: 1835: 1834: 1816: 1807: 1801: 1800: 1790: 1764: 1740: 1734: 1733: 1731: 1707: 1698: 1697: 1680:(7): 4172–4192. 1669: 1663: 1662: 1652: 1627: 1621: 1620: 1618: 1601:(5–6): 240–245. 1586: 1580: 1579: 1561: 1555: 1554: 1544: 1534: 1498: 1447:nitrate nitrites 1435:sulfite sulfates 1403:iodate fluorides 1391:sulfate arsenate 1307:borate chlorides 1304:fluoride borates 1239:Molecular anions 329: 306:fluorophosphides 272:selenide iodides 255:sulfide bromides 149:hydrogen sulfide 120:piezoelectricity 71:refractive index 21: 2000: 1999: 1995: 1994: 1993: 1991: 1990: 1989: 1970: 1969: 1968: 1967: 1936: 1935: 1931: 1893: 1892: 1888: 1848: 1843: 1842: 1838: 1814: 1809: 1808: 1804: 1742: 1741: 1737: 1709: 1708: 1701: 1671: 1670: 1666: 1629: 1628: 1624: 1588: 1587: 1583: 1576: 1563: 1562: 1558: 1500: 1499: 1492: 1487: 1479:oxalate formate 1470: 1431: 1423: 1364:boroantimonates 1346:borate acetates 1337:borate sulfates 1333:borate nitrates 1324:sulfide borates 1311:borate bromides 1258: 1241: 310:fluoroarsenides 302:fluoropnictides 268:sulfide iodides 174: 169: 144: 124:pyroelectricity 63:phosphorescence 59: 28: 23: 22: 15: 12: 11: 5: 1998: 1996: 1988: 1987: 1982: 1972: 1971: 1966: 1965: 1929: 1902:(1): 688–692. 1886: 1836: 1802: 1735: 1699: 1664: 1622: 1581: 1575:978-1839165122 1574: 1556: 1489: 1488: 1486: 1483: 1482: 1481: 1476: 1474:borate acetate 1469: 1466: 1430: 1424: 1422: 1417: 1416: 1415: 1414: 1413: 1405: 1400: 1395: 1394: 1393: 1388: 1376: 1375: 1374: 1368:borophosphates 1360:borotellurates 1348: 1343: 1326: 1317: 1315:borate iodides 1300:halide borates 1294: 1276: 1262:halocarbonates 1257: 1252: 1251: 1250: 1247: 1240: 1237: 1234: 1233: 1228: 1223: 1218: 1213: 1208: 1203: 1198: 1193: 1188: 1183: 1178: 1173: 1168: 1163: 1158: 1153: 1148: 1144: 1143: 1140: 1135: 1130: 1125: 1120: 1115: 1110: 1105: 1100: 1095: 1090: 1085: 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199:oxyantimonides 173: 170: 168: 165: 143: 140: 128:ferromagnetism 67:photocatalysis 58: 55: 26: 24: 14: 13: 10: 9: 6: 4: 3: 2: 1997: 1986: 1983: 1981: 1978: 1977: 1975: 1961: 1957: 1953: 1949: 1945: 1941: 1933: 1930: 1925: 1921: 1917: 1913: 1909: 1905: 1901: 1897: 1890: 1887: 1882: 1878: 1874: 1870: 1866: 1862: 1858: 1854: 1847: 1840: 1837: 1832: 1828: 1824: 1820: 1813: 1806: 1803: 1798: 1794: 1789: 1784: 1780: 1776: 1772: 1768: 1763: 1758: 1754: 1750: 1746: 1739: 1736: 1730: 1725: 1721: 1717: 1713: 1706: 1704: 1700: 1695: 1691: 1687: 1683: 1679: 1675: 1668: 1665: 1660: 1656: 1651: 1646: 1642: 1638: 1634: 1626: 1623: 1617: 1612: 1608: 1604: 1600: 1596: 1592: 1585: 1582: 1577: 1571: 1567: 1560: 1557: 1552: 1548: 1543: 1538: 1533: 1528: 1524: 1520: 1516: 1512: 1508: 1504: 1497: 1495: 1491: 1484: 1480: 1477: 1475: 1472: 1471: 1467: 1465: 1463: 1458: 1456: 1452: 1448: 1444: 1440: 1436: 1429:and oligomers 1428: 1427:Mixed valency 1425: 1421: 1418: 1412: 1409: 1408: 1406: 1404: 1401: 1399: 1396: 1392: 1389: 1387: 1383: 1380: 1379: 1377: 1373: 1372:boroselenites 1369: 1365: 1361: 1357: 1356:boroselenates 1353: 1349: 1347: 1344: 1342: 1338: 1334: 1330: 1327: 1325: 1321: 1318: 1316: 1312: 1308: 1305: 1301: 1298: 1297: 1295: 1293: 1289: 1285: 1281: 1277: 1275: 1271: 1267: 1263: 1260: 1259: 1256: 1253: 1248: 1246: 1243: 1242: 1238: 1232: 1229: 1227: 1224: 1222: 1219: 1217: 1214: 1212: 1209: 1207: 1204: 1202: 1199: 1197: 1194: 1192: 1189: 1187: 1184: 1182: 1179: 1177: 1174: 1172: 1169: 1167: 1164: 1162: 1159: 1157: 1154: 1152: 1149: 1146: 1145: 1141: 1139: 1136: 1134: 1131: 1129: 1126: 1124: 1121: 1119: 1116: 1114: 1111: 1109: 1106: 1104: 1101: 1099: 1096: 1094: 1091: 1089: 1086: 1084: 1081: 1079: 1076: 1074: 1071: 1069: 1066: 1064: 1061: 1058: 1057: 1053: 1051: 1048: 1046: 1043: 1041: 1038: 1036: 1033: 1031: 1028: 1026: 1023: 1021: 1018: 1016: 1013: 1011: 1008: 1006: 1003: 1001: 998: 996: 993: 991: 988: 986: 983: 981: 978: 975: 974: 970: 968: 965: 963: 960: 958: 955: 953: 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446: 443: 441: 438: 436: 433: 431: 428: 426: 423: 420: 419: 415: 413: 410: 408: 405: 403: 400: 398: 395: 392: 391: 387: 385: 382: 380: 377: 375: 372: 369: 368: 364: 362: 359: 357: 354: 351: 350: 346: 344: 341: 338: 337: 333: 331: 330: 323: 319: 315: 311: 307: 303: 300: 299: 298: 297:halopnictides 295: 293: 290: 288: 284: 281: 277: 273: 269: 266: 264: 260: 256: 253: 251: 247: 243: 240: 238: 235: 233: 229: 225: 221: 217: 214: 213: 211: 210:chalcohalides 208: 204: 200: 196: 192: 191:oxyphosphides 188: 184: 181: 180: 179: 176: 175: 171: 166: 164: 162: 158: 154: 153:Soft chemical 150: 141: 139: 137: 133: 129: 125: 121: 118: 114: 109: 107: 103: 99: 98:melting point 94: 92: 91:non-linearity 88: 87:near infrared 84: 80: 76: 75:birefringence 72: 68: 64: 56: 54: 52: 48: 44: 40: 36: 32: 19: 1943: 1939: 1932: 1899: 1895: 1889: 1856: 1852: 1839: 1822: 1818: 1805: 1752: 1748: 1738: 1719: 1715: 1677: 1673: 1667: 1643:(1): 26–37. 1640: 1636: 1625: 1598: 1594: 1584: 1565: 1559: 1514: 1510: 1459: 1432: 1420:Fluoroanions 1352:borosulfates 1322:, including 1302:, including 1264:, including 304:, including 287:oxyselenides 224:oxychlorides 220:oxyfluorides 218:, including 195:oxyarsenides 185:, including 183:oxypnictides 145: 110: 95: 60: 38: 34: 30: 29: 1755:(1): 2154. 292:oxyhydrides 283:oxysulfides 228:oxybromides 187:oxynitrides 83:ultraviolet 45:containing 1974:Categories 1517:(1): 772. 1485:References 1462:oligomeric 1407:Silicates 232:oxyiodides 216:oxohalides 142:Production 79:absorption 1960:104344701 1924:245278633 1881:216073355 1762:1306.5182 1722:: 23–47. 1694:197213596 1659:244141502 1378:sulfates 1255:Oxyanions 172:Elemental 1916:34919392 1873:32319754 1797:23831607 1551:29472526 1296:borates 113:band gap 1788:6504822 1767:Bibcode 1603:Bibcode 1542:5823932 1519:Bibcode 1468:Organic 47:cations 1958:  1922:  1914:  1879:  1871:  1795:  1785:  1692:  1657:  1572:  1549:  1539:  1453:, and 1956:S2CID 1920:S2CID 1877:S2CID 1849:(PDF) 1815:(PDF) 1757:arXiv 1690:S2CID 1655:S2CID 167:Kinds 51:anion 1944:2018 1912:PMID 1869:PMID 1823:2010 1793:PMID 1570:ISBN 1547:PMID 1226:BiTe 1221:BiSb 1216:BiBr 1211:BiSe 1206:BiAs 1201:BiGe 1196:BiCl 1181:BiSi 1050:TeSb 1045:TeBr 1040:TeSe 1035:TeAs 1030:TeGe 1025:TeCl 1010:TeSi 967:SbBr 962:SbSe 957:SbAs 952:SbGe 947:SbCl 932:SbSi 889:BrSe 884:BrAs 879:BrGe 874:BrCl 859:BrSi 816:SeAs 811:SeGe 806:SeCl 791:SeSi 748:AsGe 743:AsCl 728:AsSi 685:GeCl 670:GeSi 617:ClSi 41:are 1948:doi 1904:doi 1861:doi 1827:doi 1783:PMC 1775:doi 1724:doi 1720:347 1682:doi 1645:doi 1611:doi 1537:PMC 1527:doi 1231:BiI 1191:BiS 1186:BiP 1176:BiF 1171:BiO 1166:BiN 1161:BiC 1156:BiB 1151:BiH 1147:Bi 1138:ITe 1133:ISb 1128:IBr 1123:ISe 1118:IAs 1113:IGe 1108:ICl 1093:ISi 1054:Te 1020:TeS 1015:TeP 1005:TeF 1000:TeO 995:TeN 990:TeC 985:TeB 980:TeH 976:Te 971:Sb 942:SbS 937:SbP 927:SbF 922:SbO 917:SbN 912:SbC 907:SbB 902:SbH 898:Sb 893:Br 869:BrS 864:BrP 854:BrF 849:BrO 844:BrN 839:BrC 834:BrB 829:BrH 825:Br 820:Se 801:SeS 796:SeP 786:SeF 781:SeO 776:SeN 771:SeC 766:SeB 761:SeH 757:Se 752:As 738:AsS 733:AsP 723:AsF 718:AsO 713:AsN 708:AsC 703:AsB 698:AsH 694:As 689:Ge 680:GeS 675:GeP 665:GeF 660:GeO 655:GeN 650:GeC 645:GeB 640:GeH 636:Ge 631:Cl 627:ClS 622:ClP 612:ClF 607:ClO 602:ClN 597:ClC 592:ClB 587:ClH 583:Cl 569:SSi 526:PSi 487:Si 483:SiF 478:SiO 473:SiN 468:SiC 463:SiB 458:SiH 454:Si 85:or 37:or 1976:: 1954:. 1942:. 1918:. 1910:. 1900:61 1898:. 1875:. 1867:. 1857:59 1855:. 1851:. 1821:. 1817:. 1791:. 1781:. 1773:. 1765:. 1751:. 1747:. 1718:. 1714:. 1702:^ 1688:. 1678:19 1676:. 1653:. 1641:95 1639:. 1635:. 1609:. 1599:60 1597:. 1593:. 1545:. 1535:. 1525:. 1513:. 1509:. 1493:^ 1457:. 1449:, 1445:, 1441:, 1437:, 1384:, 1370:, 1366:, 1362:, 1358:, 1354:, 1339:, 1335:, 1331:, 1313:, 1309:, 1290:, 1286:, 1282:, 1272:, 1268:, 1142:I 1103:IS 1098:IP 1088:IF 1083:IO 1078:IN 1073:IC 1068:IB 1063:IH 1059:I 578:S 574:SP 564:SF 559:SO 554:SN 549:SC 544:SB 539:SH 535:S 530:P 521:PF 516:PO 511:PN 506:PC 501:PB 496:PH 492:P 449:F 445:FO 440:FN 435:FC 430:FB 425:FH 421:F 416:O 412:ON 407:OC 402:OB 397:OH 393:O 388:N 384:NC 379:NB 374:NH 370:N 365:C 361:CB 356:CH 352:C 347:B 343:BH 339:B 334:H 320:, 316:, 312:, 308:, 285:, 274:, 270:, 261:, 257:, 248:, 244:, 230:, 226:, 222:, 201:, 197:, 193:, 189:, 163:. 134:, 130:, 126:, 122:, 115:, 108:. 100:, 89:, 77:, 73:, 65:, 33:, 1962:. 1950:: 1926:. 1906:: 1883:. 1863:: 1833:. 1829:: 1799:. 1777:: 1769:: 1759:: 1753:3 1732:. 1726:: 1696:. 1684:: 1661:. 1647:: 1619:. 1613:: 1605:: 1578:. 1553:. 1529:: 1521:: 1515:9 20:)

Index

Mixed anion compound
chemical compounds
cations
anion
phosphorescence
photocatalysis
refractive index
birefringence
absorption
ultraviolet
near infrared
non-linearity
melting point
thermal stability
thermal expansion coefficient
band gap
superconducting transition temperature
piezoelectricity
pyroelectricity
ferromagnetism
dielectric constant
charge-density wave
hydrogen sulfide
Soft chemical
solvothermal synthesis
coordination number
pnictochalcogenides
oxypnictides
oxynitrides
oxyphosphides

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