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Premixed flame

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processes are much faster than the physical processes such as vortex motion in the flow and, hence, the inner structure of a laminar flame remains intact in most circumstances. The constitutive layers of the inner structure correspond to specified intervals over which the temperature increases from the specified unburned mixture up to as high as the
930: 64:(or burning velocity) which depends on the convection-diffusion-reaction balance within the flame, i.e. on its inner chemical structure. The premixed flame is characterised as laminar or turbulent depending on the velocity distribution in the unburned pre-mixture (which provides the medium of propagation for the flame). 2086:. If the flow rate is equal to the flame speed, we would expect a stationary flat flame front normal to the flow direction. If the flow rate is above the flame speed, the flame front will become conical such that the component of the velocity vector normal to the flame front is equal to the flame speed. 1617:
Variations in local propagation speed of a laminar flame arise due to what is called flame stretch. Flame stretch can happen due to the straining by outer flow velocity field or the curvature of flame; the difference in the propagation speed from the corresponding laminar speed is a function of these
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premixed charge, the combustion process once initiated sustains itself by way of its own heat release. The majority of the chemical transformation in such a combustion process occurs primarily in a thin interfacial region which separates the unburned and the burned gases. The premixed flame interface
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Under contrasting conditions, however, the inner structure of the premixed flame may be entirely disrupted causing the flame to extinguish either locally (known as local extinction) or globally (known as global extinction or blow-off). Such opposing cases govern the operation of practical combustion
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A turbulent premixed flame can be assumed to propagate as a surface composed of an ensemble of laminar flames so long as the processes that determine the inner structure of the flame are not affected. Under such conditions, the flame surface is wrinkled by virtue of turbulent motion in the premixed
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Under controlled conditions (typically in a laboratory) a laminar flame may be formed in one of several possible flame configurations. The inner structure of a laminar premixed flame is composed of layers over which the decomposition, reaction and complete oxidation of fuel occurs. These chemical
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In practical scenarios, turbulence is inevitable and, under moderate conditions, turbulence aids the premixed burning process as it enhances the mixing process of fuel and oxidiser. If the premixed charge of gases is not homogeneously mixed, the variations on equivalence ratio may affect the
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In this configuration, the flame is typically initiated by way of a spark within a homogeneous pre-mixture. The subsequent propagation of the developed premixed flame occurs as a spherical front until the mixture is transformed entirely or the walls of the combustion vessel are reached.
410: 1323:{\displaystyle S_{L}=\left\{{\frac {2B\lambda _{b}\rho _{b}^{m+n}\nu _{F}^{m}Y_{O_{2},u}^{m+n-1}G(n,m,a)}{c_{p,b}\rho _{u}^{2}\nu _{O_{2}}W_{O_{2}}^{m+n-1}\beta ^{m+n+1}\mathrm {Le} _{O_{2}}^{-n}\mathrm {Le} _{F}^{-m}}}\right\}^{1/2}e^{-E_{a}/2RT_{b}}+O(\beta ^{-1}),} 892: 2081:
In a Bunsen flame, a steady flow rate is provided which matches the flame speed so as to stabilize the flame. If the flow rate is below the flame speed, the flame will move upstream until the fuel is consumed or until it encounters a
2028: 188: 2061:. This, however, is typically not the case as the propagation speed of the interface (with resect to unburned mixture) varies from point to point due to the aerodynamic stretch induced due to gradients in the velocity field. 1624: 1898: 1434: 253: 2227:
Chelliah, H. K., & Williams, F. A. (1987). Asymptotic analysis of two-reactant flames with variable properties and Stefan-Maxwell transport. Combustion science and technology, 51(4-6), 129-144.
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devices such as SI engines as well as aero-engine afterburners. The prediction of the extent to which the inner structure of flame is affected in turbulent flow is a topic of extensive research.
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Rogg, B., & Williams, F. A. (1985). Asymptotic analysis of laminar flame propagation with variable transport coefficients. Combustion science and technology, 42(5-6), 301-316.
2122:, soot formation is mitigated as well. Premixed combustion has therefore gained significance in recent times. The uses involve lean-premixed-prevaporized (LPP) gas turbines and 1917:
gases increasing the surface area of the flame. The wrinkling process increases the burning velocity of the turbulent premixed flame in comparison to its laminar counterpart.
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Clavin, Paul, and Geoff Searby. Combustion Waves and Fronts in Flows: Flames, Shocks, Detonations, Ablation Fronts and Explosion of Stars. Cambridge University Press, 2016.
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mixtures. This result is first obtained by T. Mitani in 1980. Second order correction to this formula with more complicated transport properties were derived by
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Since the equivalence ratio of the premixed gases may be controlled, premixed combustion offers a means to attain low temperatures and, thereby, reduce
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Rogg, B. (1986). On the accuracy of asymptotic flame speed predictions for two-reactant flames. Combustion science and technology, 45(5-6), 317-329.
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Clavin, P., & Graña-Otero, J. C. (2011). Curved and stretched flames: the two Markstein numbers. Journal of Fluid Mechanics, 686, 187-217.
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Williams, F. A. (1985). Turbulent combustion. In The mathematics of combustion (pp. 97-131). Society for Industrial and Applied Mathematics.
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which is defined such that the level-sets of G represent the various interfaces within the premixed flame propagating with a local velocity
405:{\displaystyle \omega =B\left({\frac {\rho Y_{F}}{W_{F}}}\right)^{m}\left({\frac {\rho Y_{O_{2}}}{W_{O_{2}}}}\right)^{n}e^{-E_{a}/RT},} 2094:
Here, the pre-mixed gases flow in such a way so as to form a region of stagnation (zero velocity) where the flame may be stabilized.
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propagates through the mixture until the entire charge is depleted. The propagation speed of a premixed flame is known as the
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MITANI, T. (1980). Propagation velocities of two-reactant flames. Combustion Science and Technology, 21(3-4), 175-177.
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Kerstein, Alan R. (1988-01-01). "Field equation for interface propagation in an unsteady homogeneous flow field".
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propagation speed of the flame. In some cases, this is desirable as in stratified combustion of blended fuels.
614: 86:, the extent of reaction and, hence, the temperature attained across the flame may be different from the AFT. 584: 436: 24:
depend on oxygen supply. On the left a rich fuel mixture with no premixed oxygen produces a yellow sooty
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The flow configuration of premixed gases affects the stabilization and burning characteristics of the
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are the reaction orders. Let the unburnt conditions far ahead of the flame be denoted with subscript
195: 2349: 1558: 53: 1827: 1805: 887:{\displaystyle \phi ={\frac {\nu _{O_{2}}W_{O_{2}}}{\nu _{F}W_{F}}}{\frac {Y_{F,u}}{Y_{O_{2},u}}}} 671: 200: 52:. Since the fuel and oxidiser—the key chemical reactants of combustion—are available throughout a 1758: 1611: 491: 1587: 901: 497: 2325: 2308: 2279: 2269: 2172: 1503: 741: 665: 560: 1785: 226: 2317: 1920:
The propagation of such a premixed flame may be analysed using the field equation called as
1901: 190:, the planar, adiabatic flame has explicit expression for the burning velocity derived from 2037: 2023:{\displaystyle {\frac {\partial G}{\partial t}}+\mathbf {v} \cdot \nabla G=U_{L}|\nabla G|} 1527: 746: 535: 466: 442: 16: 2119: 25: 2140: 1927: 723: 703: 590: 566: 418: 183:{\displaystyle \nu _{F}{\rm {{F}+\nu _{O}{\rm {{O}_{2}\rightarrow {\rm {Products}}}}}}} 2354: 2343: 1552: 244: 56: 29: 21: 2083: 1581: 608: 243:(number of moles of fuel consumed per unit volume per unit time) is taken to be 61: 1824:
is the unit normal on the flame surface pointing towards the unburnt gas side,
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Linan, A., & Williams, F. A. (1993). Fundamental aspects of combustion.
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Then the planar laminar burning velocity for fuel-rich mixture (
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is a flame formed under certain conditions during the
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Williams, F. A. (2018). Combustion theory. CRC Press.
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emissions. Due to improved mixing in comparison with
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Similarly one can write the formula for lean 94:For a one-step irreversible chemistry, i.e., 8: 2165:Lewis, Bernard; Elbe, Guenther von (2012). 720:and similarly, the burnt gas conditions by 2168:Combustion, Flames and Explosions of Gases 2045: 2039: 2015: 2004: 1998: 1977: 1954: 1952: 1929: 1884: 1878: 1877: 1861: 1855: 1854: 1851: 1831: 1829: 1809: 1807: 1787: 1766: 1760: 1737: 1729: 1718: 1712: 1702: 1696: 1695: 1682: 1672: 1666: 1665: 1658: 1645: 1632: 1626: 1589: 1562: 1560: 1535: 1529: 1505: 1484: 1476: 1470: 1444: 1411: 1389: 1379: 1374: 1341: 1305: 1284: 1269: 1263: 1255: 1241: 1237: 1221: 1216: 1208: 1198: 1191: 1186: 1178: 1159: 1137: 1130: 1125: 1113: 1108: 1098: 1093: 1077: 1029: 1016: 1011: 1001: 996: 980: 975: 965: 952: 938: 932: 903: 868: 863: 847: 841: 832: 822: 808: 803: 791: 786: 779: 771: 748: 725: 705: 673: 646: 641: 622: 616: 592: 568: 543: 537: 510: 505: 499: 474: 468: 444: 420: 386: 380: 372: 362: 348: 343: 330: 325: 315: 304: 292: 281: 271: 255: 228: 202: 149: 148: 139: 134: 132: 131: 125: 113: 112: 111: 105: 99: 657:{\displaystyle W_{F}\ \&\ W_{O_{2}}} 2157: 668:of fuel and oxidizer, respectively and 7: 2009: 1985: 1965: 1957: 1870: 1726: 1566: 1563: 1480: 1477: 1380: 1212: 1209: 1182: 1179: 681: 631: 171: 168: 165: 162: 159: 156: 153: 150: 135: 126: 114: 14: 1978: 1832: 1810: 1782:is the laminar flame thickness, 1738: 1730: 1719: 1618:effects and may be written as: 2268:. Cambridge University Press. 2016: 2005: 1467: 1455: 1408: 1395: 1364: 1346: 1314: 1298: 1068: 1050: 145: 1: 1573:{\displaystyle \mathrm {Le} } 192:activation energy asymptotics 84:intrinsic flame instabilities 2069:Premixed flame configuration 1839:{\displaystyle \mathbf {v} } 1817:{\displaystyle \mathbf {n} } 693:{\displaystyle m\ \&\ n} 216:{\displaystyle \beta \gg 1.} 2136:Flamelet generated manifold 1775:{\displaystyle \delta _{L}} 1614:and co-workers in the 80s. 763:for the unburnt mixture as 80:adiabatic flame temperature 20:Different flame types of a 2371: 1603:{\displaystyle \phi <1} 917:{\displaystyle \phi >1} 68:Premixed flame propagation 1904:of curvature and strain. 1846:is the flow velocity and 1555:at constant pressure and 521:{\displaystyle Y_{O_{2}}} 2322:10.1103/PhysRevA.37.2728 2264:Peters, Norbert (2000). 1802:is the flame curvature, 1513:{\displaystyle \lambda } 740:, then we can define an 90:Laminar burning velocity 1795:{\displaystyle \kappa } 236:{\displaystyle \omega } 2055: 2024: 1938: 1894: 1840: 1818: 1796: 1776: 1746: 1604: 1574: 1545: 1514: 1494: 1430: 1324: 918: 888: 757: 734: 714: 694: 658: 601: 585:universal gas constant 577: 553: 522: 484: 453: 437:pre-exponential factor 429: 406: 237: 217: 184: 33: 2056: 2054:{\displaystyle U_{L}} 2025: 1939: 1895: 1841: 1819: 1797: 1777: 1747: 1605: 1575: 1546: 1544:{\displaystyle c_{p}} 1515: 1495: 1431: 1325: 919: 889: 758: 756:{\displaystyle \phi } 735: 715: 695: 659: 602: 578: 554: 552:{\displaystyle E_{a}} 523: 485: 483:{\displaystyle Y_{F}} 454: 452:{\displaystyle \rho } 430: 407: 238: 218: 185: 19: 2266:Turbulent combustion 2038: 1951: 1928: 1850: 1828: 1806: 1786: 1759: 1625: 1588: 1559: 1528: 1522:thermal conductivity 1504: 1443: 1340: 931: 902: 770: 747: 724: 704: 672: 615: 591: 567: 536: 498: 467: 443: 419: 254: 227: 201: 98: 1900:are the respective 1384: 1229: 1206: 1154: 1103: 1046: 1006: 991: 2051: 2020: 1934: 1890: 1836: 1814: 1792: 1772: 1742: 1612:Forman A. Williams 1600: 1570: 1541: 1510: 1490: 1426: 1370: 1320: 1207: 1177: 1121: 1089: 1007: 992: 971: 914: 884: 753: 730: 710: 690: 654: 597: 573: 549: 518: 492:fuel mass fraction 480: 449: 425: 402: 233: 223:The reaction rate 213: 180: 34: 2309:Physical Review A 1972: 1937:{\displaystyle G} 1902:Markstein numbers 1875: 1869: 1419: 1231: 882: 839: 742:equivalence ratio 733:{\displaystyle b} 713:{\displaystyle u} 686: 680: 666:molecular weights 636: 630: 600:{\displaystyle T} 576:{\displaystyle R} 561:activation energy 428:{\displaystyle B} 356: 298: 196:Zel'dovich number 2362: 2334: 2333: 2316:(7): 2728–2731. 2303: 2297: 2294: 2288: 2287: 2261: 2255: 2252: 2246: 2243: 2237: 2234: 2228: 2225: 2219: 2216: 2210: 2207: 2201: 2198: 2192: 2189: 2183: 2182: 2162: 2120:diffusion flames 2090:Stagnation flame 2060: 2058: 2057: 2052: 2050: 2049: 2029: 2027: 2026: 2021: 2019: 2008: 2003: 2002: 1981: 1973: 1971: 1963: 1955: 1943: 1941: 1940: 1935: 1899: 1897: 1896: 1891: 1889: 1888: 1883: 1882: 1873: 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1192: 1188: 1172: 1169: 1166: 1163: 1160: 1156: 1150: 1147: 1144: 1141: 1138: 1131: 1127: 1122: 1114: 1110: 1105: 1099: 1094: 1090: 1084: 1081: 1078: 1074: 1065: 1062: 1059: 1056: 1053: 1047: 1042: 1039: 1036: 1033: 1030: 1025: 1022: 1017: 1013: 1008: 1002: 997: 993: 987: 984: 981: 976: 972: 966: 962: 958: 955: 949: 944: 939: 935: 927: 926: 925: 911: 908: 905: 877: 874: 869: 865: 860: 854: 851: 848: 844: 833: 829: 823: 819: 809: 805: 800: 792: 788: 783: 776: 773: 766: 765: 764: 750: 743: 727: 707: 687: 675: 667: 647: 643: 638: 623: 619: 610: 594: 586: 570: 562: 544: 540: 531: 530:mass fraction 511: 507: 502: 493: 475: 471: 462: 446: 438: 422: 399: 394: 391: 387: 381: 377: 373: 369: 363: 358: 349: 345: 340: 331: 327: 322: 318: 312: 305: 300: 293: 289: 282: 278: 274: 268: 263: 260: 257: 250: 249: 248: 246: 230: 210: 207: 204: 197: 193: 140: 122: 118: 106: 102: 89: 87: 85: 81: 72: 67: 65: 63: 58: 55: 51: 47: 43: 39: 31: 30:band emission 27: 23: 22:Bunsen burner 18: 2313: 2307: 2301: 2292: 2265: 2259: 2250: 2241: 2232: 2223: 2214: 2205: 2196: 2187: 2171:. Elsevier. 2167: 2160: 2110: 2107:Applications 2101: 2093: 2084:flame holder 2080: 2077:Bunsen flame 2072: 2063: 2033: 1919: 1915: 1911: 1754: 1616: 1582:Lewis number 1438: 1332: 897: 414: 93: 76: 37: 35: 609:temperature 62:flame speed 54:homogeneous 2350:Combustion 2344:Categories 2152:References 2124:SI engines 1922:G equation 42:combustion 2010:∇ 1986:∇ 1983:⋅ 1966:∂ 1958:∂ 1908:Turbulent 1871:& 1790:κ 1764:δ 1735:⋅ 1727:∇ 1724:⋅ 1710:δ 1689:κ 1680:δ 1652:− 1592:ϕ 1508:λ 1462:− 1459:ϕ 1453:β 1381:∞ 1372:∫ 1307:− 1303:β 1257:− 1223:− 1200:− 1157:β 1148:− 1106:ν 1091:ρ 1040:− 994:ν 973:ρ 963:λ 906:ϕ 820:ν 784:ν 774:ϕ 751:ϕ 682:& 632:& 447:ρ 374:− 319:ρ 275:ρ 258:ω 231:ω 208:≫ 205:β 194:when the 146:→ 123:ν 103:ν 2284:56066895 2146:Oxy-fuel 2130:See also 664:are the 50:oxidiser 2330:9899999 1580:is the 1551:is the 1520:is the 1500:. Here 607:is the 583:is the 559:is the 490:is the 461:density 459:is the 435:is the 73:Laminar 2328:  2282:  2272:  2175:  1874:  1868:  1755:where 1418:  1333:where 685:  679:  635:  629:  415:where 2355:Fire 2326:PMID 2280:OCLC 2270:ISBN 2173:ISBN 1944:as: 1595:< 1439:and 909:> 48:and 46:fuel 2318:doi 2346:: 2324:. 2314:37 2312:. 2278:. 2126:. 2113:NO 1524:, 611:, 587:, 563:, 532:, 494:, 463:, 439:, 247:, 211:1. 36:A 2332:. 2320:: 2286:. 2181:. 2115:x 2047:L 2043:U 2030:, 2017:| 2013:G 2006:| 2000:L 1996:U 1992:= 1989:G 1979:v 1975:+ 1969:t 1961:G 1932:G 1886:a 1880:M 1863:c 1857:M 1833:v 1811:n 1768:L 1739:n 1731:n 1720:n 1714:L 1704:a 1698:M 1692:+ 1684:L 1674:c 1668:M 1660:L 1656:S 1647:L 1643:S 1639:= 1634:L 1630:U 1598:1 1567:e 1564:L 1537:p 1533:c 1486:F 1481:e 1478:L 1472:/ 1468:) 1465:1 1456:( 1450:= 1447:a 1424:y 1421:d 1413:m 1409:) 1405:a 1402:+ 1399:y 1396:( 1391:n 1387:y 1376:0 1368:= 1365:) 1362:a 1359:, 1356:m 1353:, 1350:n 1347:( 1344:G 1318:, 1315:) 1310:1 1299:( 1296:O 1293:+ 1286:b 1282:T 1278:R 1275:2 1271:/ 1265:a 1261:E 1253:e 1247:2 1243:/ 1239:1 1234:} 1226:m 1218:F 1213:e 1210:L 1203:n 1193:2 1189:O 1183:e 1180:L 1173:1 1170:+ 1167:n 1164:+ 1161:m 1151:1 1145:n 1142:+ 1139:m 1132:2 1128:O 1123:W 1115:2 1111:O 1100:2 1095:u 1085:b 1082:, 1079:p 1075:c 1069:) 1066:a 1063:, 1060:m 1057:, 1054:n 1051:( 1048:G 1043:1 1037:n 1034:+ 1031:m 1026:u 1023:, 1018:2 1014:O 1009:Y 1003:m 998:F 988:n 985:+ 982:m 977:b 967:b 959:B 956:2 950:{ 945:= 940:L 936:S 912:1 894:. 878:u 875:, 870:2 866:O 861:Y 855:u 852:, 849:F 845:Y 834:F 830:W 824:F 810:2 806:O 801:W 793:2 789:O 777:= 728:b 708:u 688:n 676:m 648:2 644:O 639:W 624:F 620:W 595:T 571:R 545:a 541:E 512:2 508:O 503:Y 476:F 472:Y 423:B 400:, 395:T 392:R 388:/ 382:a 378:E 370:e 364:n 359:) 350:2 346:O 341:W 332:2 328:O 323:Y 313:( 306:m 301:) 294:F 290:W 283:F 279:Y 269:( 264:B 261:= 172:s 169:t 166:c 163:u 160:d 157:o 154:r 151:P 141:2 136:O 127:O 119:+ 115:F 107:F 32:.

Index


Bunsen burner
diffusion flame
band emission
combustion
fuel
oxidiser
homogeneous
stoichiometric
flame speed
adiabatic flame temperature
intrinsic flame instabilities
activation energy asymptotics
Zel'dovich number
Arrhenius form
pre-exponential factor
density
fuel mass fraction
mass fraction
activation energy
universal gas constant
temperature
molecular weights
equivalence ratio
thermal conductivity
specific heat
Lewis number
Forman A. Williams
Markstein numbers
G equation

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